JP4767373B2 - 製造の過程で変性されるチーグラー／ナッタ触媒組成物 - Google Patents
製造の過程で変性されるチーグラー／ナッタ触媒組成物 Download PDFInfo
- Publication number
- JP4767373B2 JP4767373B2 JP24886697A JP24886697A JP4767373B2 JP 4767373 B2 JP4767373 B2 JP 4767373B2 JP 24886697 A JP24886697 A JP 24886697A JP 24886697 A JP24886697 A JP 24886697A JP 4767373 B2 JP4767373 B2 JP 4767373B2
- Authority
- JP
- Japan
- Prior art keywords
- compound
- titanium
- alkyl
- electron donor
- magnesium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 32
- 239000000203 mixture Substances 0.000 title claims description 37
- 238000004519 manufacturing process Methods 0.000 title claims description 16
- 239000010936 titanium Substances 0.000 claims abstract description 47
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 44
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 40
- 150000001875 compounds Chemical class 0.000 claims abstract description 37
- 239000011777 magnesium Substances 0.000 claims abstract description 17
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 16
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 16
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 15
- 229910052809 inorganic oxide Inorganic materials 0.000 claims abstract description 15
- 239000007787 solid Substances 0.000 claims abstract description 14
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 11
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 9
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 8
- 150000002367 halogens Chemical class 0.000 claims abstract description 8
- 239000003426 co-catalyst Substances 0.000 claims abstract description 3
- 239000008247 solid mixture Substances 0.000 claims description 31
- -1 aluminum compound Chemical class 0.000 claims description 22
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 11
- 150000002681 magnesium compounds Chemical class 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 229910000039 hydrogen halide Inorganic materials 0.000 claims description 6
- 239000012433 hydrogen halide Substances 0.000 claims description 6
- 239000012442 inert solvent Substances 0.000 claims description 6
- 150000003609 titanium compounds Chemical class 0.000 claims description 6
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 239000007795 chemical reaction product Substances 0.000 claims description 4
- 239000004480 active ingredient Substances 0.000 claims description 3
- 150000004703 alkoxides Chemical class 0.000 claims description 3
- 125000003262 carboxylic acid ester group Chemical class [H]C([H])([*:2])OC(=O)C([H])([H])[*:1] 0.000 claims 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 abstract description 16
- 239000002245 particle Substances 0.000 abstract description 14
- 229920000642 polymer Polymers 0.000 abstract description 14
- 239000011148 porous material Substances 0.000 abstract description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 7
- 150000001733 carboxylic acid esters Chemical class 0.000 abstract description 7
- 239000000741 silica gel Substances 0.000 abstract description 7
- 229910002027 silica gel Inorganic materials 0.000 abstract description 7
- 229920001155 polypropylene Polymers 0.000 abstract description 6
- 239000002904 solvent Substances 0.000 abstract description 6
- 150000004996 alkyl benzenes Chemical class 0.000 abstract description 5
- 150000003961 organosilicon compounds Chemical class 0.000 abstract description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 3
- 125000000753 cycloalkyl group Chemical group 0.000 abstract description 3
- 125000003710 aryl alkyl group Chemical group 0.000 abstract description 2
- 238000002360 preparation method Methods 0.000 abstract description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- 238000000465 moulding Methods 0.000 abstract 1
- 239000007921 spray Substances 0.000 abstract 1
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 19
- 229910052801 chlorine Inorganic materials 0.000 description 10
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 9
- 239000000460 chlorine Substances 0.000 description 9
- 238000006116 polymerization reaction Methods 0.000 description 7
- 238000000605 extraction Methods 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 6
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 4
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 4
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000011164 primary particle Substances 0.000 description 4
- 239000008096 xylene Substances 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- 150000002596 lactones Chemical class 0.000 description 3
- 229920001384 propylene homopolymer Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 239000012018 catalyst precursor Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- XFAOZKNGVLIXLC-UHFFFAOYSA-N dimethoxy-(2-methylpropyl)-propan-2-ylsilane Chemical compound CO[Si](C(C)C)(OC)CC(C)C XFAOZKNGVLIXLC-UHFFFAOYSA-N 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000012685 gas phase polymerization Methods 0.000 description 2
- 239000000017 hydrogel Substances 0.000 description 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 150000003021 phthalic acid derivatives Chemical class 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
- 125000000027 (C1-C10) alkoxy group Chemical group 0.000 description 1
- 125000006737 (C6-C20) arylalkyl group Chemical group 0.000 description 1
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
- GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical compound CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 description 1
- RGPSRYWDFHAWOT-UHFFFAOYSA-N CCCCCCCC[Mg]CCCC Chemical compound CCCCCCCC[Mg]CCCC RGPSRYWDFHAWOT-UHFFFAOYSA-N 0.000 description 1
- SGVYKUFIHHTIFL-UHFFFAOYSA-N Isobutylhexyl Natural products CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- NVHCKYSIRWGHRB-UHFFFAOYSA-N butan-2-yl-dimethoxy-(2-methylpropyl)silane Chemical compound CCC(C)[Si](OC)(OC)CC(C)C NVHCKYSIRWGHRB-UHFFFAOYSA-N 0.000 description 1
- PJUXDQIPAXQXHH-UHFFFAOYSA-N butan-2-yl-dimethoxy-propan-2-ylsilane Chemical compound CCC(C)[Si](OC)(OC)C(C)C PJUXDQIPAXQXHH-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- FVAXOELGJXMINU-UHFFFAOYSA-N dicyclopentyl(diethoxy)silane Chemical compound C1CCCC1[Si](OCC)(OCC)C1CCCC1 FVAXOELGJXMINU-UHFFFAOYSA-N 0.000 description 1
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- RIAWHSGONJRETM-UHFFFAOYSA-N diethoxy-(2-methylpropyl)-propan-2-ylsilane Chemical compound CCO[Si](CC(C)C)(OCC)C(C)C RIAWHSGONJRETM-UHFFFAOYSA-N 0.000 description 1
- MYBJXSAXGLILJD-UHFFFAOYSA-N diethyl(methyl)alumane Chemical compound CC[Al](C)CC MYBJXSAXGLILJD-UHFFFAOYSA-N 0.000 description 1
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 1
- NHYFIJRXGOQNFS-UHFFFAOYSA-N dimethoxy-bis(2-methylpropyl)silane Chemical compound CC(C)C[Si](OC)(CC(C)C)OC NHYFIJRXGOQNFS-UHFFFAOYSA-N 0.000 description 1
- VHPUZTHRFWIGAW-UHFFFAOYSA-N dimethoxy-di(propan-2-yl)silane Chemical compound CO[Si](OC)(C(C)C)C(C)C VHPUZTHRFWIGAW-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000002440 hydroxy compounds Chemical class 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- VKPSKYDESGTTFR-UHFFFAOYSA-N isododecane Natural products CC(C)(C)CC(C)CC(C)(C)C VKPSKYDESGTTFR-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 150000002901 organomagnesium compounds Chemical class 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000004260 weight control Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/06—Catalyst characterized by its size
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19637367.0 | 1996-09-13 | ||
| DE19637367A DE19637367A1 (de) | 1996-09-13 | 1996-09-13 | Bei ihrer Herstellung modifizierte Ziegler-Natta-Katalysatorsysteme |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011106826A Division JP2011174087A (ja) | 1996-09-13 | 2011-05-12 | 製造の過程で変性されるチーグラー／ナッタ触媒組成物 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JPH10130318A JPH10130318A (ja) | 1998-05-19 |
| JPH10130318A5 JPH10130318A5 (enExample) | 2005-06-09 |
| JP4767373B2 true JP4767373B2 (ja) | 2011-09-07 |
Family
ID=7805560
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP24886697A Expired - Fee Related JP4767373B2 (ja) | 1996-09-13 | 1997-09-12 | 製造の過程で変性されるチーグラー／ナッタ触媒組成物 |
| JP2011106826A Ceased JP2011174087A (ja) | 1996-09-13 | 2011-05-12 | 製造の過程で変性されるチーグラー／ナッタ触媒組成物 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011106826A Ceased JP2011174087A (ja) | 1996-09-13 | 2011-05-12 | 製造の過程で変性されるチーグラー／ナッタ触媒組成物 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6107231A (enExample) |
| EP (1) | EP0829489B1 (enExample) |
| JP (2) | JP4767373B2 (enExample) |
| AT (1) | ATE229040T1 (enExample) |
| DE (2) | DE19637367A1 (enExample) |
| ES (1) | ES2186831T3 (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6808604B1 (en) | 1999-09-30 | 2004-10-26 | Mitsubishi Denki Kabushiki Kaisha | Discharge surface treatment electrode, manufacturing method thereof and discharge surface treating method |
| US6521301B1 (en) | 1999-11-08 | 2003-02-18 | Mitsubishi Denki Kabushiki Kaisha | Discharge surface processing method |
| DE10002653A1 (de) * | 2000-01-21 | 2001-07-26 | Targor Gmbh | Neuartige Katalysatorsysteme vom Typ der Ziegler-Natta-Katalysatoren |
| JP4149165B2 (ja) | 2000-05-19 | 2008-09-10 | 三菱電機株式会社 | ３次元レーザ加工機用制御装置 |
| US6831032B2 (en) * | 2002-08-19 | 2004-12-14 | Novolen Technology Holdings C.V. | Ziegler-Natta catalyst and methods of making and using same |
| CN1297575C (zh) * | 2004-04-12 | 2007-01-31 | 中国石油化工股份有限公司 | 用于乙烯聚合或共聚合的催化剂组分及其催化剂 |
| WO2012055797A1 (en) | 2010-10-28 | 2012-05-03 | Lummus Novolen Technology Gmbh | Nonwoven and yarn polypropylene with additivation |
| JP5984173B2 (ja) | 2012-09-24 | 2016-09-06 | インディアン オイル コーポレーション リミテッド | オレフィン重合用の触媒を調製するプロセス |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5883006A (ja) * | 1981-11-13 | 1983-05-18 | Mitsui Petrochem Ind Ltd | オレフインの重合方法 |
| JPH0655780B2 (ja) * | 1984-07-09 | 1994-07-27 | 東燃株式会社 | オレフイン重合用触媒成分 |
| JPH06104693B2 (ja) * | 1986-01-06 | 1994-12-21 | 東邦チタニウム株式会社 | オレフイン類重合用触媒 |
| DE3730022A1 (de) * | 1987-09-08 | 1989-03-16 | Basf Ag | Verfahren zum herstellen von homo- und copolymerisaten des propens mittels eines ziegler-natta-katalysatorsystems |
| DE3730717A1 (de) * | 1987-09-12 | 1989-03-23 | Basf Ag | Verfahren zum herstellen von homo- und copolymerisaten des propens mittels eines ziegler-natta-katalysatorsystems |
| DE3888145T2 (de) * | 1987-12-26 | 1994-06-01 | Toho Titanium Co Ltd | Katalysator-Feststoff für Olefinpolymerisation und Olefinpolymerisationskatalysator. |
| JP2673555B2 (ja) * | 1988-07-29 | 1997-11-05 | 東邦チタニウム株式会社 | エチレン−プロピレン共重今体ゴム製造用固体触媒成分 |
| DE3829519A1 (de) * | 1988-08-31 | 1990-03-01 | Basf Ag | Verfahren zum herstellen von homo- und copolymerisaten des propens mittels eines ziegler-natta-katalysatorsystems |
| GB8911074D0 (en) * | 1989-05-15 | 1989-06-28 | Shell Int Research | Solid alpha-olefin polymerization catalyst components |
| DE4128829A1 (de) * | 1991-08-30 | 1993-03-04 | Basf Ag | Verfahren zum herstellen von homo- und copolymerisaten des propens mittels eines ziegler-nata-katalysatorsystems |
| JP3167417B2 (ja) * | 1992-04-24 | 2001-05-21 | 東邦チタニウム株式会社 | オレフィン類重合用触媒及び重合方法 |
| DE4216548A1 (de) * | 1992-05-19 | 1993-11-25 | Basf Ag | Ziegler-Natta-Katalysatorsysteme mit speziellen siliciumorganischen Verbindungen |
| JP3247448B2 (ja) * | 1992-10-02 | 2002-01-15 | 旭化成株式会社 | α−オレフィンの重合方法 |
| DE4340140A1 (de) * | 1993-11-25 | 1995-06-01 | Basf Ag | Katalysatorsysteme vom Typ der Ziegler-Natta-Katalysatoren |
| DE19517716A1 (de) * | 1994-06-03 | 1995-12-07 | Basf Ag | Katalysatorsysteme zur Polymerisation von C¶2¶- bis C¶8¶-Alk-1-enen |
| DE59600133D1 (de) * | 1995-08-09 | 1998-05-07 | Basf Ag | Katalysatorsysteme vom Typ der Ziegler-Natta-Katalysatoren |
| DE19545499A1 (de) * | 1995-12-06 | 1997-06-12 | Basf Ag | Verbesserte statistische Propylencopolymerisate |
| DE19545498A1 (de) * | 1995-12-06 | 1997-06-12 | Basf Ag | Verbesserte Propylenpolymerisate |
| WO1997047662A1 (de) * | 1996-06-11 | 1997-12-18 | Basf Aktiengesellschaft | Metallocenkatalysatorsysteme mit anorganischen oxiden als träger |
-
1996
- 1996-09-13 DE DE19637367A patent/DE19637367A1/de not_active Withdrawn
-
1997
- 1997-09-09 ES ES97115586T patent/ES2186831T3/es not_active Expired - Lifetime
- 1997-09-09 EP EP97115586A patent/EP0829489B1/de not_active Expired - Lifetime
- 1997-09-09 AT AT97115586T patent/ATE229040T1/de not_active IP Right Cessation
- 1997-09-09 DE DE59708870T patent/DE59708870D1/de not_active Expired - Lifetime
- 1997-09-12 JP JP24886697A patent/JP4767373B2/ja not_active Expired - Fee Related
- 1997-09-12 US US08/928,526 patent/US6107231A/en not_active Expired - Lifetime
-
2011
- 2011-05-12 JP JP2011106826A patent/JP2011174087A/ja not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| EP0829489A1 (de) | 1998-03-18 |
| EP0829489B1 (de) | 2002-12-04 |
| JP2011174087A (ja) | 2011-09-08 |
| ATE229040T1 (de) | 2002-12-15 |
| ES2186831T3 (es) | 2003-05-16 |
| DE19637367A1 (de) | 1998-03-19 |
| DE59708870D1 (de) | 2003-01-16 |
| US6107231A (en) | 2000-08-22 |
| JPH10130318A (ja) | 1998-05-19 |
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