JP4624943B2 - 染料含有ネガ型感光性組成物、カラーフィルタおよびその製造方法 - Google Patents
染料含有ネガ型感光性組成物、カラーフィルタおよびその製造方法 Download PDFInfo
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- JP4624943B2 JP4624943B2 JP2006061734A JP2006061734A JP4624943B2 JP 4624943 B2 JP4624943 B2 JP 4624943B2 JP 2006061734 A JP2006061734 A JP 2006061734A JP 2006061734 A JP2006061734 A JP 2006061734A JP 4624943 B2 JP4624943 B2 JP 4624943B2
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- aliphatic
- dye
- acid
- triazine
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- 125000000623 heterocyclic group Chemical group 0.000 description 33
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- 125000001424 substituent group Chemical group 0.000 description 24
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- BFQFFNWLTHFJOZ-UHFFFAOYSA-N 2-(1,3-benzodioxol-5-yl)-4,6-bis(trichloromethyl)-1,3,5-triazine Chemical compound ClC(Cl)(Cl)C1=NC(C(Cl)(Cl)Cl)=NC(C=2C=C3OCOC3=CC=2)=N1 BFQFFNWLTHFJOZ-UHFFFAOYSA-N 0.000 description 3
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- 229940079877 pyrogallol Drugs 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- COEZWFYORILMOM-UHFFFAOYSA-M sodium 4-[(2,4-dihydroxyphenyl)diazenyl]benzenesulfonate Chemical compound [Na+].OC1=CC(O)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 COEZWFYORILMOM-UHFFFAOYSA-M 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 description 1
- 229940039790 sodium oxalate Drugs 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- STZCRXQWRGQSJD-UHFFFAOYSA-N sodium;4-[[4-(dimethylamino)phenyl]diazenyl]benzenesulfonic acid Chemical compound [Na+].C1=CC(N(C)C)=CC=C1N=NC1=CC=C(S(O)(=O)=O)C=C1 STZCRXQWRGQSJD-UHFFFAOYSA-N 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical group O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 1
- 125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229940073455 tetraethylammonium hydroxide Drugs 0.000 description 1
- LRGJRHZIDJQFCL-UHFFFAOYSA-M tetraethylazanium;hydroxide Chemical compound [OH-].CC[N+](CC)(CC)CC LRGJRHZIDJQFCL-UHFFFAOYSA-M 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- WNQPPENQFWLADQ-UHFFFAOYSA-J tetrasodium;4-hydroxy-5-[[4-[[4-[(8-hydroxy-3,6-disulfonatonaphthalen-1-yl)diazenyl]-2-methoxy-5-methylphenyl]carbamoylamino]-5-methoxy-2-methylphenyl]diazenyl]naphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]S(=O)(=O)C1=CC(O)=C2C(N=NC3=C(C)C=C(C(=C3)OC)NC(=O)NC3=CC(C)=C(N=NC=4C5=C(O)C=C(C=C5C=C(C=4)S([O-])(=O)=O)S([O-])(=O)=O)C=C3OC)=CC(S([O-])(=O)=O)=CC2=C1 WNQPPENQFWLADQ-UHFFFAOYSA-J 0.000 description 1
- 238000012719 thermal polymerization Methods 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 125000003866 trichloromethyl group Chemical group ClC(Cl)(Cl)* 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- VRVDFJOCCWSFLI-UHFFFAOYSA-K trisodium 3-[[4-[(6-anilino-1-hydroxy-3-sulfonatonaphthalen-2-yl)diazenyl]-5-methoxy-2-methylphenyl]diazenyl]naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].[Na+].COc1cc(N=Nc2cc(c3cccc(c3c2)S([O-])(=O)=O)S([O-])(=O)=O)c(C)cc1N=Nc1c(O)c2ccc(Nc3ccccc3)cc2cc1S([O-])(=O)=O VRVDFJOCCWSFLI-UHFFFAOYSA-K 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
- C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B47/00—Porphines; Azaporphines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/41—Organic pigments; Organic dyes
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/0005—Production of optical devices or components in so far as characterised by the lithographic processes or materials used therefor
- G03F7/0007—Filters, e.g. additive colour filters; Components for display devices
Description
上記の顔料分散法としては、アルカリ可溶性樹脂に光重合性モノマーと光重合開始剤とを併用したネガ型感光性組成物を用いたものが開示されている(例えば、特許文献1参照)。
また、アルカリ可溶性の樹脂成分の含有量が多い処方では、上記の異物発生や密着性の改善の点では有効なものの、感度の向上をも両立することは困難であった。
<1> 染料と、光重合開始剤と、重合性モノマーと、無色の数平均分子量1000以上5000以下の化合物とを少なくとも含有し、アルカリ可溶性樹脂の含有量が全固形分中10質量%以下である染料含有ネガ型硬化性組成物である。
<6> 前記光重合開始剤が、オキシム系光重合開始剤であることを特徴とする前記<1>〜<5>のいずれか1つに記載の染料含有ネガ型硬化性組成物である。
<7> 前記染料の少なくとも一種が、下記一般式(I)で表されるフタロシアニン化合物であることを特徴とする前記<1>〜<6>のいずれか1つに記載の染料含有ネガ型硬化性組成物である。
<11> 前記<1>〜<9>のいずれか1つに記載の染料含有ネガ型硬化性組成物を支持体上に塗布後、マスクを通して露光し、現像してパターンを形成する工程を有するカラーフィルタの製造方法である。
本発明の染料含有ネガ型硬化性組成物(以下、「本発明の組成物」という場合がある。)は、染料と、光重合開始剤と、重合性モノマーと、無色の分子量1000以上5000以下の化合物とを少なくとも含み、アルカリ可溶性樹脂の含有量を全固形分中10質量%以下とする。また、一般には有機溶剤を用いて構成され、また、架橋剤などの他の成分を用いて構成することができる。
本発明の染料含有硬化性組成物は、染料の少なくとも一種を含有する。
染料としては、公知の染料の中から目的等に応じて適宜選択することができ、一種のみならず二種以上を組み合わせて含有することができる。
ここで、有機溶剤可溶性とは、染料が有機溶剤(25℃)に20%溶液として完溶する性質をいう。
特に好ましくは、ピラゾールアゾ系、アニリノアゾ系、ピラゾロトリアゾールアゾ系、ピリドンアゾ系、アンスラピリドン系の染料である。
有用である。
酸性染料は、スルホン酸やカルボン酸やフェノール性水酸基等の酸性基を有する色素であれば、特に制限されものではないが、組成物の調製や現像処理に用いる有機溶剤や現像液に対する溶解性、塩基性化合物との塩形成性、吸光度、硬化性組成物中の他の成分との相互作用、耐光性、耐熱性等の必要とされる性能の全てを考慮して選択される。
acid alizarin violet N;
acid black 1,2,24,48;
acid blue 1,7,9,15,18,23,25,27,29,40,42,45,51,62,70,74,80,83,86,87,90,92,96,103,112,113,120,129,138,147,150,158,171,182,192,210,242,243,256,259,267,278,280,285,290,296,315,324:1,335,340;
acid chrome violet K;
acid Fuchsin;
acid green 1,3,5,9,16,25,27,50,58,63,65,80,104,105,106,109;
acid orange 6,7,8,10,12,26,50,51,52,56,62,63,64,74,75,94,95107,108,169,173;
acid violet 6B,7,9,17,19;
acid yellow 1,3,7,9,11,17,23,25,29,34,36,38,40,42,54,65,72,73,76,79,98,99,111,112,113,114,116,119,123,128,134,135,138,139,140,144,150,155,157,160,161,163,168,169,172,177,178,179,184,190,193,196,197,199,202,203,204,205,207,212,214,220,221,228,230,232,235,238,240,242,243,251;
Direct Orange 34,39,41,46,50,52,56,57,61,64,65,68,70,96,97,106,107;
Direct Red 79,82,83,84,91,92,96,97,98,99,105,106,107,172,173,176,177,179,181,182,184,204,207,211,213,218,220,221,222,232,233,234,241,243,246,250;
Direct Violet 47,52,54,59,60,65,66,79,80,81,82,84,89,90,93,95,96,103,104;
Direct Green 25,27,31,32,34,37,63,65,66,67,68,69,72,77,79,82;
Mordant Yellow 5,8,10,16,20,26,30,31,33,42,43,45,56,50,61,62,65;
Mordant Orange 3,4,5,8,12,13,14,20,21,23,24,28,29,32,34,35,36,37,42,43,47,48;
Mordant Violet 2,4,5,7,14,22,24,30,31,32,37,40,41,44,45,47,48,53,58;
Mordant Blue 2,3,7,8,9,12,13,15,16,19,20,21,22,23,24,26,30,31,32,39,40,41,43,44,48,49,53,61,74,77,83,84;
Mordant Green 1,3,4,5,10,15,19,26,29,33,34,35,41,43,53;
Food Yellow 3;
及びこれらの染料の誘導体が挙げられる。
acid blue 23,25,29,62,80,86,87,92,138,158,182,243,324:1;
acid orange 8,51,56,74,63;
acid red 1,4,8,34,37,42,52,57,80,97,114,143,145,151,183,217,249;
acid violet 7;
acid yellow 17,25,29,34,42,72,76,99,111,112,114,116,134,155,169,172,184,220,228,230,232,243;
Acid Green 25;
等の染料及びこれらの染料の誘導体が好ましい。
また、酸性染料と塩を形成する含窒素化合物、及び酸性染料とアミド結合を形成する含窒素化合物については、塩またはアミド化合物の有機溶剤や現像液に対する溶解性、塩形成性、染料の吸光度・色価、硬化性組成物中の他の成分との相互作用、着色剤としての耐熱性及び耐光性等の全てを勘案して選択される。吸光度・色価の観点のみで選択する場合には、前記含窒素化合物としてはできるだけ分子量の低いものが好ましく、中でも分子量300以下のものが好ましく、分子量280以下のものがより好ましく、分子量250以下のものが特に好ましい。
本発明の染料含有ネガ型硬化性組成物は、着色剤として、有機溶剤に可溶なフタロシアニン染料の少なくとも一種を含有することが好ましい。有機溶剤に可溶なフタロシアニン染料であれば、特に制限なく使用することができる。
一般式(I)で表される色素化合物について説明する。
下記一般式(I)で表される色素化合物は、モル吸光係数εおよび色価の良好な有機溶剤可溶性フタロシアニン染料であり、高い耐光性と高い耐熱性とを同時に満足する化合物である。
次に、下記一般式(II)で表される色素化合物について説明する。
また、cr1、cr2、cr3及びcr4は、0または1を表し、cr1+cr2+cr3+cr4≧1を満たす。中でも、cr1+cr2+cr3+cr4が3または4である態様が好ましい。
なお、一般式(II−1)におけるRc1、M、cm、cn並びにcr1、cr2、cr3及びcr4は、前記一般式(II)おける場合と同義であり、好ましい態様も同様である。
本発明の染料含有ネガ型硬化性組成物は、光重合開始剤の少なくとも一種を含有する。光重合開始剤は、重合性を有するモノマーを重合させ得るものであれば特に制限はなく、特性、開始効率、吸収波長、入手性、コスト等の観点から選ばれることが好ましい。
具体的には、米国特許第2,367,660号明細書に記載のビシナールポリケトルアルドニル化合物、米国特許第2,367,661号および第2,367,670号明細書に記載のα−カルボニル化合物、米国特許第2,448,828号明細書に記載のアシロインエーテル、米国特許第2,722,512号明細書に記載のα−炭化水素で置換された芳香族アシロイン化合物、米国特許第3,046,127号および第2,951,758号明細書に記載の多核キノン化合物、米国特許第3,549,367号明細書に記載のトリアリルイミダゾールダイマー/p−アミノフェニルケトンの組合せ、特公昭51−48516号公報に記載のベンゾチアゾール系化合物/トリハロメチール−s−トリアジン系化合物、等を挙げることができる。
具体的な例として、ベンゾイン、ベンゾインメチルエーテル、9−フルオレノン、2−クロロ−9−フルオレノン、2−メチル−9−フルオレノン、9−アントロン、2−ブロモ−9−アントロン、2−エチル−9−アントロン、9,10−アントラキノン、2−エチル−9,10−アントラキノン、2−t−ブチル−9,10−アントラキノン、2,6−ジクロロ−9,10−アントラキノン、キサントン、2−メチルキサントン、2−メトキシキサントン、2−エトキシキサントン、チオキサントン、2,4−ジエチルチオキサントン、アクリドン、10−ブチル−2−クロロアクリドン、ベンジル、ジベンザルアセトン、p−(ジメチルアミノ)フェニルスチリルケトン、p−(ジメチルアミノ)フェニル−p−メチルスチリルケトン、ベンゾフェノン、p−(ジメチルアミノ)ベンゾフェノン(またはミヒラーケトン)、p−(ジエチルアミノ)ベンゾフェノン、ベンゾアントロン等や特公昭51−48516号公報記載のベンゾチアゾール系化合物等や、チヌビン1130、同400等が挙げられる。
本発明の染料含有ネガ型硬化性組成物は、重合性モノマーの少なくとも一種を含有する。重合性モノマーとしては、常圧下で100℃以上の沸点を有し、少なくとも1つの付加重合可能なエチレン性不飽和基を持つ化合物が好ましい。
前記一般式(III−1)または(III−2)で表されるラジカル重合性モノマーのうち、具体的な例として、下記例示化合物(M−1)〜(M−12)が好適であり、中でも、(M−2)、(M−3)、および(M−5)で表される化合物が好ましい。
本発明の染料含有ネガ型硬化性組成物は、無色の数平均分子量1000以上5000以下の化合物の少なくとも一種(以下、「本発明に係る無色化合物」ということがある。)を含有する。この化合物を染料と共に用いることによって、異物発生を抑えた経時安定性および被塗物や下地との密着性を確保できると共に、感度を向上させることができる。また、現像残渣のない良好なパターンの形成にも効果的である。
また、本発明に係る無色化合物は、経時による異物発生の抑制の観点からは、2個以上のヒドロキシル基を含む化合物が好ましい。
また、本発明に係る無色化合物は、高感度化の観点からは、アルカリ不溶性であることがより好ましい。「アルカリ不溶性」とは、アルカリ溶液に溶解した場合に、10%溶液として完溶しない性質であることをいう。アルカリ溶液には、水にアルカリ剤を溶解したアルカリ水溶液等が含まれる。
前記脂肪族基としては、炭素数1〜5のアルキレン基が好適であり、例えばメチレン基、エチレン基、プロピレン基、イソプロピレン基等が挙げられる。また、芳香族基としては、フェニレン基及びその誘導体が好適であり、例えば、フェニレン基、メチルフェニレン基、ジメチルフェニレン基等が挙げられる。
また、aは2または3を表し、bはb=2aで表される整数である。
例えば、ポリ(プロピレングリコール)、ポリ(エチレングリコール−プロピレングリコール)、ポリ(エチレングリコール)、ポリ(エチレングリコール又はプロピレングリコール)モノブチルエーテル、グリセロールエトキシレート、グリセロールプロポキシレート、グリセロールプロポキシレート−B−エトキシレートトリオール、グリセロールエトキシレート−コ−プロポキシレートトリオール、ポリ(エチレングリコール)メチルエーテル、ポリ(エチレングリコール)ブチルエーテル、トリメチロールプロパンエトキシレート、トリメチロールプロパンプロポキシレート、ネオペンチルグリコールエトキシレート、ネオペンチルグリコールプロポキシレート、ペンタエリスリトールエトキシレート、ペンタエリスリトールプロポキシレート、ポリ(エチレングリコール)テトラヒドロフリルエーテル、トリエタノールアミンエトキシレート、ビスフェノールAエトキシレート、ビスフェノールAプロポキシレート、ビスフェノールAプロポキシレート/エトキシレート、ポリオキシエチレンビス(アミン)、ポリ(プロピレングリコール)ビス(2−アミノプロピルエーテル)、等が挙げられる。
本発明の染料含有ネガ型硬化性組成物は、アルカリ可溶性樹脂を含有してもよい。この樹脂(以下、バインダーということがある。)は、アルカリ可溶性であれば特に限定されないが、耐熱性、現像性、入手性等の観点から選ばれることが好ましい。
このような線状有機高分子重合体としては、側鎖にカルボン酸を有するポリマー、例えば特開昭59−44615号、特公昭54−34327号、特公昭58−12577号、特公昭54−25957号、特開昭59−53836号、特開昭59−71048号等の公報に記載のメタクリル酸共重合体、アクリル酸共重合体、イタコン酸共重合体、クロトン酸共重合体、マレイン酸共重合体、部分エステル化マレイン酸共重合体等が挙げられ、また同様に側鎖にカルボン酸を有する酸性セルロース誘導体が有用である。これらのほか、水酸基を有するポリマーに酸無水物を付加させたもの等や、ポリヒドロキシスチレン系樹脂、ポリシロキサン系樹脂、ポリ(2−ヒドロキシエチル(メタ)アクリレート)、ポリビニールピロリドンやポリエチレンオキサイド、ポリビニルアルコール、等も有用である。
OH基を有する例えば2−ヒドロキシエチルアクリレートと、COOH基を有する例えばメタクリル酸と、これらと共重合可能なアクリル系もしくはビニル系化合物等のモノマーとの共重合体に、OH基と反応性を有するエポキシ環と炭素−炭素不飽和結合を有する化合物、例えばグリシジルアクリレート等の化合物を反応させて得られる化合物等が使用できる。OHとの反応ではエポキシ環の他に酸無水物、イソシアネート基を有し、アクリロイル基を有する化合物も使用できる。また、特開平6−102669号、特開平6−1938号に記載の、エポキシ環を有する化合物にアクリル酸のような不飽和カルボン酸を反応させて得られる化合物に、飽和もしくは不飽和多塩基酸無水物を反応させて得られる反応物も使用できる。COOHのようなアルカリ可溶化基と炭素−炭素不飽和基を併せ持つ化合物として例えばダイヤナールNRシリーズ(三菱レイヨン(株)製)、Photomer6173(COOH含有Polyurethane acrylic oligomer、Diamond Shamrock Co.Ltd.,製)、ビスコートR−264、KSレジスト106(いずれも大阪有機化学工業(株)製)、サイクロマーPシリーズ、プラクセル CF200シリーズ(いずれもダイセル化学工業(株)製)、Ebecryl3800(ダイセルユーシービー(株)製)などが挙げられる。
本発明の染料含有ネガ型硬化性組成物は、一般に溶剤を用いて構成することができる。
溶剤は、組成物の溶解性、塗布性を満足すれば基本的に特に制限はなく、特に染料、本発明にかかる無色化合物の溶解性、塗布性、安全性を考慮して選ばれることが好ましい。
具体的には、例えば、ギ酸、酢酸、プロピオン酸、酪酸、吉草酸、ピバル酸、カプロン酸、ジエチル酢酸、エナント酸、カプリル酸等の脂肪族モノカルボン酸;シュウ酸、マロン酸、コハク酸、グルタル酸、アジピン酸、ピメリン酸、スベリン酸、アゼライン酸、セバシン酸、ブラシル酸、メチルマロン酸、エチルマロン酸、ジメチルマロン酸、メチルコハク酸、テトラメチルコハク酸、シトラコン酸等の脂肪族ジカルボン酸;トリカルバリル酸、アコニット酸、カンホロン酸等の脂肪族トリカルボン酸;安息香酸、トルイル酸、クミン酸、ヘメリト酸、メシチレン酸等の芳香族モノカルボン酸;フタル酸、イソフタル酸、テレフタル酸、トリメリト酸、トリメシン酸、メロファン酸、ピロメリト酸等の芳香族ポリカルボン酸;フェニル酢酸、ヒドロアトロパ酸、ヒドロケイ皮酸、マンデル酸、フェニルコハク酸、アトロパ酸、ケイ皮酸、ケイ皮酸メチル、ケイ皮酸ベンジル、シンナミリデン酢酸、クマル酸、ウンベル酸等のその他のカルボン酸が挙げられる。
次に、本発明のカラーフィルタについて、その製造方法を通じて詳述する。
本発明のカラーフィルタは本発明の組成物を用いて製造されるものである。本発明のカラーフィルタは、例えば本発明の組成物を用いた本発明のカラーフィルタの製造方法により最も好適に作製することができ、具体的には、支持体上に本発明の組成物を回転塗布、流延塗布、ロール塗布等の塗布方法により塗布して感光性の組成物層を形成し、形成された組成物層を所定のマスクパターンを介して露光し、露光後現像液で現像し、着色されたパターンを形成することで作製することができる。本発明のカラーフィルタの製造方法においては、必要に応じて露光・現像後のパターンを更に加熱及び/又は露光することによって硬化させる硬化工程を更に設けることができる。
上記の露光に使用される放射線としては、特にg線、h線、i線等の紫外線が好ましい。
また、これらの支持体上には必要により、形成される層との更なる密着改良、物質の拡散防止あるいは基板表面の平坦化の目的で下塗り層を設けてもよい。
前記アルカリ性の水溶液としては、例えば、水酸化ナトリウム、水酸化カリウム、炭酸ナトリウム,硅酸ナトリウム、メタ硅酸ナトリウム、アンモニア水、エチルアミン、ジエチルアミン、ジメチルエタノールアミン、テトラメチルアンモニウムヒドロキシド、テトラエチルアンモニウムヒドロキシド、コリン、ピロール、ピペリジン、1,8−ジアザビシクロ−〔5.4.0〕−7−ウンデセン等のアルカリ性化合物を、濃度が0.001〜10質量%、好ましくは0.01〜1質量%となるように溶解したアルカリ性水溶液が挙げられる。なお、アルカリ性の水溶液を現像液として用いた場合は、一般に現像後に水で洗浄を行なう。
1)レジスト液の調製
下記組成の成分を混合して溶解し、レジスト液を調製した。
〈組成〉
・プロピレングリコールモノメチルエーテルアセテート …19.20部
(PGMEA)
・乳酸エチル …36.67部
・樹脂 …30.51部
〔メタクリル酸ベンジル/メタクリル酸/メタクリル酸−2−ヒドロキシエチル共重合体(モル比=60/22/18)の40%PGMEA溶液〕
・ジペンタエリスリトールヘキサアクリレート …12.20部
(光重合性化合物)
・重合禁止剤(p−メトキシフェノール) … 0.0061部
・フッ素系界面活性剤 … 0.83部
(F−475、大日本インキ化学工業(株)製)
・光重合開始剤 … 0.586部
(TAZ−107(トリハロメチルトリアジン系の光重合開始剤)、みどり化学社製)
6inchシリコンウエハーをオーブン中で200℃のもと30分加熱処理した。次いで、このシリコンウエハー上に前記レジスト液を乾燥膜厚が2μmになるように塗布し、更に220℃のオーブン中で1時間加熱乾燥させて下塗り層を形成し、下塗り層付シリコンウエハー基板を得た。
下記組成A−1の化合物を混合して溶解し、着色感光性樹脂組成物A−1を調製した。
〈組成A−1〉
・シクロヘキサノン …80部
・着色剤A … 6.0部
〔既述の一般式(I)で表される色素化合物の具体例28〕
・着色剤B〔下記の化合物b〕 … 4.0部
・ラジカル重合性モノマー … 7.0部
〔既述の例示化合物(M−2)とジペンタエリスリトールヘキサアクリレートとの3:7の混合物〕
・光重合開始剤 … 2.5部
(CGI−124、チバ・スペシャルティ・ケミカルズ社製;オキシム系光重合開始剤)
・グリセロールプロポキシレート … 0.5部
(数平均分子量Mn:1500、モル吸光係数ε=0、本発明に係る無色化合物)
上記で調製した着色感光性樹脂組成物A−1について、調製直後及び室温で1週間放置した後の各々について、経時での液中パーティクル(異物)を、液中パーティクルカウンター(リオン社製)を用いて測定した。経時により数の増加が見られないか、あるいは小さいものが好ましい。測定結果は下記表2に示す。
−パターンの形成と感度の評価−
前記3)で調製した着色感光性樹脂組成物A−1を、前記2)で得られた下塗り層付シリコンウエハー基板の下塗り層上に塗布し、光硬化性の塗布膜を形成した。そして、この塗布膜の乾燥膜厚が0.9μmになるように、100℃のホットプレートを用いて120秒間加熱処理(プリベーク)を行なった。次いで、i線ステッパー露光装置FPA−3000i5+(Canon(株)製)を使用して365nmの波長でパターンが2μm四方のIslandパターンマスクを通して1000mJ/cm2の露光量で照射した。その後、照射された塗布膜が形成されているシリコンウエハー基板をスピン・シャワー現像機(DW−30型、(株)ケミトロニクス製)の水平回転テーブル上に載置し、CD−2000(富士フイルムエレクトロニクスマテリアルズ(株)製)を用いて23℃で60秒間パドル現像を行ない、シリコンウエハー基板に着色パターンを形成した。
次に、スプレー乾燥後の下塗り層付シリコンウエハー基板の4mm×3mmの範囲を光学顕微鏡にて観察して、剥がれにより消失しているパターンの数をカウントし、消失したパターン数を密着性を評価する指標とした。測定評価の結果は下記表2に示す。
実施例1において、着色感光性樹脂組成物A−1の調製に用いた組成A−1中の着色剤、及び本発明に係る無色化合物を下記表1に示すようにそれぞれ変更したこと以外、実施例1と同様にして、着色感光性樹脂組成物A−2〜A−14を調製すると共に、着色パターンの形成、及び評価を行なった。測定評価の結果は下記表2に示す。
Claims (3)
- 染料と、光重合開始剤と、重合性モノマーと、無色の数平均分子量1000以上5000以下の化合物とを少なくとも含有し、アルカリ可溶性樹脂の含有量が全固形分中10質量%以下である染料含有ネガ型硬化性組成物。
- 請求項1に記載の染料含有ネガ型硬化性組成物を用いてなるカラーフィルタ。
- 請求項1に記載の染料含有ネガ型硬化性組成物を支持体上に塗布後、マスクを通して露光し、現像してパターンを形成する工程を有するカラーフィルタの製造方法。
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0418558A (ja) * | 1989-10-11 | 1992-01-22 | Fuji Photo Film Co Ltd | 感光材料 |
JPH07261387A (ja) * | 1994-03-22 | 1995-10-13 | Shinnakamura Kagaku Kogyo Kk | 感光性樹脂組成物 |
JP2004233504A (ja) * | 2003-01-29 | 2004-08-19 | Fuji Photo Film Co Ltd | 染料含有硬化性組成物、カラーフィルタ及びその製造方法 |
JP2005265995A (ja) * | 2004-03-16 | 2005-09-29 | Fuji Photo Film Co Ltd | 染料含有硬化性組成物、カラーフィルタ及びその製造方法 |
JP2005274968A (ja) * | 2004-03-24 | 2005-10-06 | Fuji Photo Film Co Ltd | 染料含有ネガ型硬化性組成物、カラーフィルターおよびその製造方法 |
Family Cites Families (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01102469A (ja) | 1987-10-15 | 1989-04-20 | Fuji Electric Co Ltd | 電子写真用感光体 |
CA1337194C (en) | 1988-04-07 | 1995-10-03 | Koichi Kamijima | Tetraazaporphin, process for producing the same, as well as optical recording media using the same and production processes thereof |
DE3821584A1 (de) | 1988-06-25 | 1989-12-28 | Hoechst Ag | Strahlungshaertbares gemisch und daraus hergestelltes strahlungsempfindliches aufzeichungsmaterial fuer hochenergetische strahlung |
JPH07111485B2 (ja) | 1988-10-24 | 1995-11-29 | ポラロイド コーポレーシヨン | カラーフィルターの製造方法 |
JP2762511B2 (ja) | 1989-01-30 | 1998-06-04 | 凸版印刷株式会社 | カラーフィルターおよびその製造方法 |
JP2890576B2 (ja) | 1989-12-25 | 1999-05-17 | 大日本インキ化学工業株式会社 | インクジェット記録用油性インク |
JPH0675375A (ja) | 1992-08-26 | 1994-03-18 | Sony Corp | カラーレジスト材料 |
JP3575045B2 (ja) | 1993-06-21 | 2004-10-06 | 住友化学工業株式会社 | カラーフィルター |
JPH0713014A (ja) | 1993-06-29 | 1995-01-17 | Fuji Photo Film Co Ltd | カラーフイルターアレイ素子 |
JP3455915B2 (ja) | 1993-09-24 | 2003-10-14 | Jsr株式会社 | カラーフィルタ用感放射線性組成物およびカラーフィルタ |
DE69632168T2 (de) | 1995-05-12 | 2004-08-12 | Ciba Specialty Chemicals Holding Inc. | Verfahren zum Färben von hochmolekularen organischen Kunststoffen in der Masse mit löslichen phthalocyaninen Precursoren |
US5804102A (en) | 1995-12-22 | 1998-09-08 | Mitsui Chemicals, Inc. | Plasma display filter |
JPH11302285A (ja) | 1998-04-21 | 1999-11-02 | Canon Inc | ポルフィラジン誘導体、インク、カラーフィルタ、液晶パネル、コンピュータ及びカラーフィルタの製造方法 |
JP3428492B2 (ja) | 1999-04-26 | 2003-07-22 | 富士電機株式会社 | 青色カラーフィルターおよび有機エレクトロルミネッセンス板 |
JP2002014221A (ja) | 2000-06-30 | 2002-01-18 | Sumitomo Chem Co Ltd | 緑色フィルタ層を有する色フィルタアレイおよびその製造方法 |
JP2002014222A (ja) | 2000-06-30 | 2002-01-18 | Sumitomo Chem Co Ltd | 青色フィルタ層を有する色フィルタアレイおよびその製造方法 |
JP4513208B2 (ja) | 2000-12-22 | 2010-07-28 | 住友化学株式会社 | 保存安定性に優れた着色感光性樹脂組成物 |
JP2002278056A (ja) | 2001-03-16 | 2002-09-27 | Sumitomo Chem Co Ltd | 着色感光性樹脂組成物 |
JP2002338825A (ja) | 2001-05-22 | 2002-11-27 | Fuji Photo Film Co Ltd | 着色樹脂組成物、着色感光性組成物及びカラーフィルタ |
JP4328158B2 (ja) | 2002-09-24 | 2009-09-09 | 富士フイルム株式会社 | 染料含有ネガ型硬化性組成物、カラーフィルタ及びその製造方法 |
JP4401196B2 (ja) | 2003-03-10 | 2010-01-20 | 富士フイルム株式会社 | 染料含有硬化性組成物、カラーフィルタ及びその製造方法 |
US20040185372A1 (en) | 2003-03-10 | 2004-09-23 | Fuji Photo Film Co., Ltd. | Dye-containing curable composition, color filter, and process of preparing color filter |
JP4303560B2 (ja) * | 2003-10-31 | 2009-07-29 | 富士フイルム株式会社 | 染料含有硬化性組成物、並びに、カラーフィルターおよびその製造方法 |
JP2005227722A (ja) | 2004-02-16 | 2005-08-25 | Fuji Photo Film Co Ltd | 染料含有ネガ型硬化性組成物、カラーフィルタ及びその製造方法 |
JPWO2005083521A1 (ja) | 2004-03-02 | 2008-01-17 | 日本化薬株式会社 | ネガ型着色感光性組成物 |
JP2005266149A (ja) | 2004-03-17 | 2005-09-29 | Fuji Photo Film Co Ltd | 染料含有硬化性組成物、カラーフィルタ及びその製造方法 |
EP1780598A4 (en) | 2004-08-02 | 2012-11-28 | Fujifilm Corp | COLORED CURABLE COMPOSITIONS, COLOR FILTERS AND MANUFACTURING PROCESS THEREFOR |
JP4357392B2 (ja) | 2004-09-03 | 2009-11-04 | 富士フイルム株式会社 | 染料含有ネガ型硬化性組成物、カラーフィルタおよびその製造方法 |
KR101259491B1 (ko) | 2005-04-28 | 2013-05-06 | 후지필름 가부시키가이샤 | 착색제함유 경화성 조성물, 컬러필터 및 그 제조방법 |
KR101258169B1 (ko) | 2005-04-28 | 2013-04-25 | 후지필름 가부시키가이샤 | 착색 경화성 조성물, 컬러필터 및 그 제조방법 |
JP4652197B2 (ja) | 2005-09-29 | 2011-03-16 | 富士フイルム株式会社 | 染料含有ネガ型硬化性組成物、カラーフィルタ及びその製造方法 |
US7279255B2 (en) * | 2006-02-07 | 2007-10-09 | Eastman Kodak Company | Negative-working radiation-sensitive compositions and imageable materials |
JP4926552B2 (ja) | 2006-02-16 | 2012-05-09 | 富士フイルム株式会社 | 染料含有感光性組成物並びにそれを用いたカラーフィルター及びその製造方法 |
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0418558A (ja) * | 1989-10-11 | 1992-01-22 | Fuji Photo Film Co Ltd | 感光材料 |
JPH07261387A (ja) * | 1994-03-22 | 1995-10-13 | Shinnakamura Kagaku Kogyo Kk | 感光性樹脂組成物 |
JP2004233504A (ja) * | 2003-01-29 | 2004-08-19 | Fuji Photo Film Co Ltd | 染料含有硬化性組成物、カラーフィルタ及びその製造方法 |
JP2005265995A (ja) * | 2004-03-16 | 2005-09-29 | Fuji Photo Film Co Ltd | 染料含有硬化性組成物、カラーフィルタ及びその製造方法 |
JP2005274968A (ja) * | 2004-03-24 | 2005-10-06 | Fuji Photo Film Co Ltd | 染料含有ネガ型硬化性組成物、カラーフィルターおよびその製造方法 |
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