JP4495214B2 - ポリエチレンテレフタレートコポリエステルを製造する方法、それによって得られたコポリエステルとその使用、および本発明の方法に適した触媒組成物 - Google Patents
ポリエチレンテレフタレートコポリエステルを製造する方法、それによって得られたコポリエステルとその使用、および本発明の方法に適した触媒組成物 Download PDFInfo
- Publication number
- JP4495214B2 JP4495214B2 JP2007512591A JP2007512591A JP4495214B2 JP 4495214 B2 JP4495214 B2 JP 4495214B2 JP 2007512591 A JP2007512591 A JP 2007512591A JP 2007512591 A JP2007512591 A JP 2007512591A JP 4495214 B2 JP4495214 B2 JP 4495214B2
- Authority
- JP
- Japan
- Prior art keywords
- zinc
- antimony
- copolyester
- polycondensation
- ppm
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 82
- 238000000034 method Methods 0.000 title claims abstract description 58
- 229920000139 polyethylene terephthalate Polymers 0.000 title claims abstract description 57
- 239000005020 polyethylene terephthalate Substances 0.000 title claims abstract description 57
- 230000008569 process Effects 0.000 title claims abstract description 46
- 229920001634 Copolyester Polymers 0.000 title claims abstract description 34
- -1 polyethylene terephthalate Polymers 0.000 title claims abstract description 30
- 239000000203 mixture Substances 0.000 title claims abstract description 22
- 239000011701 zinc Substances 0.000 claims abstract description 96
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims abstract description 90
- 238000006068 polycondensation reaction Methods 0.000 claims abstract description 81
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 81
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 79
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 72
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims abstract description 48
- 238000005886 esterification reaction Methods 0.000 claims abstract description 15
- 230000032050 esterification Effects 0.000 claims abstract description 14
- 150000003752 zinc compounds Chemical class 0.000 claims abstract description 11
- 239000000835 fiber Substances 0.000 claims description 30
- 239000000155 melt Substances 0.000 claims description 21
- 229910052751 metal Inorganic materials 0.000 claims description 21
- 239000002184 metal Substances 0.000 claims description 21
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 16
- 238000006116 polymerization reaction Methods 0.000 claims description 11
- 229910052698 phosphorus Inorganic materials 0.000 claims description 9
- 239000011574 phosphorus Substances 0.000 claims description 9
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 8
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 7
- 239000003381 stabilizer Substances 0.000 claims description 5
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims description 4
- 238000012937 correction Methods 0.000 claims description 4
- 239000004246 zinc acetate Substances 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 4
- 238000001125 extrusion Methods 0.000 claims description 3
- 150000002903 organophosphorus compounds Chemical class 0.000 claims description 3
- 229920000137 polyphosphoric acid Polymers 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 claims description 2
- 239000005083 Zinc sulfide Substances 0.000 claims description 2
- 238000010923 batch production Methods 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 238000010924 continuous production Methods 0.000 claims description 2
- DLINORNFHVEIFE-UHFFFAOYSA-N hydrogen peroxide;zinc Chemical compound [Zn].OO DLINORNFHVEIFE-UHFFFAOYSA-N 0.000 claims description 2
- 239000011261 inert gas Substances 0.000 claims description 2
- 239000011667 zinc carbonate Substances 0.000 claims description 2
- 229910000010 zinc carbonate Inorganic materials 0.000 claims description 2
- 235000004416 zinc carbonate Nutrition 0.000 claims description 2
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 claims description 2
- 229940007718 zinc hydroxide Drugs 0.000 claims description 2
- 229910021511 zinc hydroxide Inorganic materials 0.000 claims description 2
- 229940105296 zinc peroxide Drugs 0.000 claims description 2
- 229910052984 zinc sulfide Inorganic materials 0.000 claims description 2
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 229910052787 antimony Inorganic materials 0.000 description 89
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 88
- 229920000642 polymer Polymers 0.000 description 69
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 35
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 28
- 230000000052 comparative effect Effects 0.000 description 23
- 239000010936 titanium Substances 0.000 description 14
- 230000000694 effects Effects 0.000 description 11
- 230000002829 reductive effect Effects 0.000 description 10
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 9
- 230000035484 reaction time Effects 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 229910052719 titanium Inorganic materials 0.000 description 7
- 238000005809 transesterification reaction Methods 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000004753 textile Substances 0.000 description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
- 239000011572 manganese Substances 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 5
- 229910052718 tin Inorganic materials 0.000 description 5
- 150000001463 antimony compounds Chemical class 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 4
- 238000002425 crystallisation Methods 0.000 description 4
- 230000008025 crystallization Effects 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- JVLRYPRBKSMEBF-UHFFFAOYSA-K diacetyloxystibanyl acetate Chemical compound [Sb+3].CC([O-])=O.CC([O-])=O.CC([O-])=O JVLRYPRBKSMEBF-UHFFFAOYSA-K 0.000 description 4
- 238000010036 direct spinning Methods 0.000 description 4
- 238000004043 dyeing Methods 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 230000007062 hydrolysis Effects 0.000 description 4
- 238000006460 hydrolysis reaction Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 238000006722 reduction reaction Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 229940011182 cobalt acetate Drugs 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 150000003018 phosphorus compounds Chemical class 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 229940058905 antimony compound for treatment of leishmaniasis and trypanosomiasis Drugs 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 238000011021 bench scale process Methods 0.000 description 2
- QPKOBORKPHRBPS-UHFFFAOYSA-N bis(2-hydroxyethyl) terephthalate Chemical compound OCCOC(=O)C1=CC=C(C(=O)OCCO)C=C1 QPKOBORKPHRBPS-UHFFFAOYSA-N 0.000 description 2
- 235000014171 carbonated beverage Nutrition 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000009776 industrial production Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 230000037361 pathway Effects 0.000 description 2
- 150000004023 quaternary phosphonium compounds Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 238000005979 thermal decomposition reaction Methods 0.000 description 2
- 238000004383 yellowing Methods 0.000 description 2
- SLGGJMDAZSEJNG-UHFFFAOYSA-N 2-(2-hydroxyethoxy)ethanol;terephthalic acid Chemical compound OCCOCCO.OC(=O)C1=CC=C(C(O)=O)C=C1 SLGGJMDAZSEJNG-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000012691 depolymerization reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- WUOBERCRSABHOT-UHFFFAOYSA-N diantimony Chemical compound [Sb]#[Sb] WUOBERCRSABHOT-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- GBHRVZIGDIUCJB-UHFFFAOYSA-N hydrogenphosphite Chemical class OP([O-])[O-] GBHRVZIGDIUCJB-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000008301 phosphite esters Chemical class 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 238000007440 spherical crystallization Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- DJWUNCQRNNEAKC-UHFFFAOYSA-L zinc acetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O DJWUNCQRNNEAKC-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/83—Alkali metals, alkaline earth metals, beryllium, magnesium, copper, silver, gold, zinc, cadmium, mercury, manganese, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/183—Terephthalic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/80—Solid-state polycondensation
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/78—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products
- D01F6/84—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from copolyesters
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Polyesters Or Polycarbonates (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP04010616A EP1593702B1 (en) | 2004-05-05 | 2004-05-05 | Process for the production of polyethylene terephthalate copolyester |
| PCT/IB2005/001577 WO2005105888A1 (en) | 2004-05-05 | 2005-04-08 | Process for the production of polyethylene terephthalate copolyester; copolyester obtained thereby and its use and catalyst useful in the process |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2008507593A JP2008507593A (ja) | 2008-03-13 |
| JP2008507593A5 JP2008507593A5 (https=) | 2010-04-02 |
| JP4495214B2 true JP4495214B2 (ja) | 2010-06-30 |
Family
ID=34924851
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007512591A Expired - Fee Related JP4495214B2 (ja) | 2004-05-05 | 2005-04-08 | ポリエチレンテレフタレートコポリエステルを製造する方法、それによって得られたコポリエステルとその使用、および本発明の方法に適した触媒組成物 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20080064797A1 (https=) |
| EP (1) | EP1593702B1 (https=) |
| JP (1) | JP4495214B2 (https=) |
| KR (1) | KR101189354B1 (https=) |
| CN (1) | CN100509911C (https=) |
| AT (1) | ATE382066T1 (https=) |
| DE (1) | DE602004010887T2 (https=) |
| EG (1) | EG26048A (https=) |
| ES (1) | ES2298645T3 (https=) |
| TW (1) | TWI365201B (https=) |
| WO (1) | WO2005105888A1 (https=) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7714094B2 (en) * | 2007-11-15 | 2010-05-11 | Eastman Chemical Company | Simplified isophthalic acid process for modifying PET |
| CN102146157B (zh) * | 2011-03-21 | 2013-01-09 | 浙江万凯新材料有限公司 | Ipa酯化瓶级聚酯生产设备及其生产方法 |
| EP2746435A4 (en) * | 2011-08-17 | 2015-04-15 | Kolon Inc | METHOD FOR MANUFACTURING POLYESTER YARN |
| KR101995457B1 (ko) | 2012-05-25 | 2019-07-02 | 에스케이케미칼 주식회사 | 폴리에스테르 수지의 제조 방법 |
| KR101969004B1 (ko) * | 2012-06-05 | 2019-04-15 | 에스케이케미칼 주식회사 | 폴리에스테르 수지 및 이의 제조 방법 |
| KR101952941B1 (ko) * | 2012-06-05 | 2019-02-27 | 에스케이케미칼 주식회사 | 폴리에스테르 수지 및 이의 제조 방법 |
| CN103572400B (zh) * | 2012-08-06 | 2016-01-06 | 中国石油化工股份有限公司 | 一种涡流纺专用涤纶短纤维的加工方法 |
| CN105504241B (zh) * | 2015-12-29 | 2018-06-12 | 江苏恒力化纤股份有限公司 | 一种高模低缩聚酯工业丝及其制备方法 |
| MX2019009974A (es) * | 2017-02-24 | 2020-01-27 | Dupont Ind Biosciences Usa Llc | Proceso para preparar poli (furanodicarboxilato de trimetileno) usando un catalizador de zinc. |
| EP3790925B1 (en) * | 2018-05-11 | 2024-01-03 | SABIC Global Technologies B.V. | Reinforced polyester structural components |
| ES3053126T3 (en) * | 2020-11-25 | 2026-01-19 | Continental Reifen Deutschland Gmbh | Rubberized reinforcement for elastomeric products, especially vehicle tyres, whereby the reinforcement comprises at least one first yarn, method for producing the rubberized reinforcement and vehicle tyres comprising at least one rubberized reinforcement |
| CN114907554B (zh) * | 2021-02-10 | 2023-08-08 | 中国科学院大连化学物理研究所 | 一种纺丝用呋喃基聚酯及其制备方法 |
| CN114292388B (zh) * | 2021-11-12 | 2023-08-29 | 浙江恒逸石化研究院有限公司 | 一种可降解pet基共聚酯的制备方法 |
| CN114479027A (zh) * | 2022-02-23 | 2022-05-13 | 浙江大学 | 具有抗菌与成骨活性的聚酯催化剂及制备方法 |
| CN115353614A (zh) * | 2022-08-30 | 2022-11-18 | 科泽新材料股份有限公司 | 一种复合催化剂及其制备方法与在无锑聚酯合成中的应用 |
| CN115197408A (zh) * | 2022-08-30 | 2022-10-18 | 科泽新材料股份有限公司 | 一种锌系催化剂及其制备方法与在无锑聚酯合成中的应用 |
| CN119640432B (zh) * | 2025-02-17 | 2025-07-01 | 江苏芮邦科技有限公司 | 一种聚酯纤维的制备方法及催化剂的制备方法 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3070575A (en) * | 1958-01-27 | 1962-12-25 | Du Pont | Process for the preparation of polyesters from dicarboxylic acids and bis (hydroxy-alkyl) esters |
| GB1047429A (https=) * | 1962-09-03 | 1900-01-01 | ||
| GB1047072A (en) * | 1964-03-03 | 1966-11-02 | Toyo Rayon Co Ltd | Production of linear polyesters of high molecular weight |
| FR1436968A (fr) * | 1964-06-01 | 1966-04-29 | Monsanto Co | Préparation de polyesters |
| US4122107A (en) * | 1976-03-26 | 1978-10-24 | M&T Chemicals Inc. | Reaction products of specific antimony compounds with a carboxylate of zinc calcium or manganese and an alcohol or glycol |
| JPS58108223A (ja) | 1981-12-21 | 1983-06-28 | Mitsubishi Rayon Co Ltd | ポリエステル中空成形体用成形材料 |
| US5162488A (en) * | 1989-05-22 | 1992-11-10 | Hoechst Celanese Corporation | Catalyst system and process for preparing polyethylene terephthalate |
| US5153164A (en) * | 1989-05-22 | 1992-10-06 | Hoechst Celanese Corporation | Catalyst system for preparing polyethylene terephthalate |
| US5166311A (en) * | 1989-05-22 | 1992-11-24 | Hoechst Celanese Corporation | Catalyst system and process for preparing high clarity, colorless polyethylene terephthalate |
| US5008230A (en) * | 1989-05-22 | 1991-04-16 | Hoechst Celanese Corporation | Catalyst for preparing high clarity, colorless polyethylene terephthalate |
| US5262513A (en) * | 1991-07-15 | 1993-11-16 | Mitsubishi Kasei Corporation | Copolyester, and hollow container and stretched film made thereof |
| JP3300433B2 (ja) * | 1992-11-04 | 2002-07-08 | 三菱レイヨン株式会社 | 樹脂組成物 |
| US5385773A (en) * | 1993-04-27 | 1995-01-31 | Eastman Chemical Company | Copolyester of cyclohexanenedimethanol and process for producing such polyester |
| US5608031A (en) * | 1995-11-30 | 1997-03-04 | Eastman Chemical Company | Polyesters modified with 1,4-cyclohexaned imethanol having high clarity prepared utilizing an antimony containing catalyst/stabilizer system |
| EP0864596A1 (en) * | 1997-03-14 | 1998-09-16 | Hoechst Diafoil GmbH | Process for the production of polyethylene terephthalate |
| US6255441B1 (en) * | 1998-04-17 | 2001-07-03 | E. I. Du Pont De Nemours And Company | Titanium-containing catalyst composition and processes therefor and therewith |
| US6346070B1 (en) * | 1998-12-25 | 2002-02-12 | Mitsui Chemicals Inc | Catalyst for polyester production, process for producing polyester using the catalyst, polyester obtained by the process, and uses of the polyester |
| US6506853B2 (en) * | 2001-02-28 | 2003-01-14 | E. I. Du Pont De Nemours And Company | Copolymer comprising isophthalic acid |
| CN1156511C (zh) * | 2001-06-14 | 2004-07-07 | 中国石化上海石油化工股份有限公司 | 一种制备聚对苯二甲酸乙二酯的方法 |
-
2004
- 2004-05-05 ES ES04010616T patent/ES2298645T3/es not_active Expired - Lifetime
- 2004-05-05 EP EP04010616A patent/EP1593702B1/en not_active Expired - Lifetime
- 2004-05-05 AT AT04010616T patent/ATE382066T1/de not_active IP Right Cessation
- 2004-05-05 DE DE602004010887T patent/DE602004010887T2/de not_active Expired - Lifetime
-
2005
- 2005-04-08 JP JP2007512591A patent/JP4495214B2/ja not_active Expired - Fee Related
- 2005-04-08 US US11/579,286 patent/US20080064797A1/en not_active Abandoned
- 2005-04-08 WO PCT/IB2005/001577 patent/WO2005105888A1/en not_active Ceased
- 2005-04-08 KR KR1020067023698A patent/KR101189354B1/ko not_active Expired - Fee Related
- 2005-04-08 CN CNB2005800176864A patent/CN100509911C/zh not_active Expired - Fee Related
- 2005-04-14 TW TW094111875A patent/TWI365201B/zh not_active IP Right Cessation
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Also Published As
| Publication number | Publication date |
|---|---|
| ATE382066T1 (de) | 2008-01-15 |
| TW200609269A (en) | 2006-03-16 |
| TWI365201B (en) | 2012-06-01 |
| EP1593702A1 (en) | 2005-11-09 |
| EP1593702B1 (en) | 2007-12-26 |
| CN100509911C (zh) | 2009-07-08 |
| EG26048A (en) | 2013-01-09 |
| DE602004010887T2 (de) | 2008-12-18 |
| US20080064797A1 (en) | 2008-03-13 |
| WO2005105888A1 (en) | 2005-11-10 |
| DE602004010887D1 (de) | 2008-02-07 |
| CN1961022A (zh) | 2007-05-09 |
| KR20070012471A (ko) | 2007-01-25 |
| ES2298645T3 (es) | 2008-05-16 |
| KR101189354B1 (ko) | 2012-10-09 |
| JP2008507593A (ja) | 2008-03-13 |
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