JP4300445B2 - 重合調節剤としての長アルキル鎖を有する2,2,6,6−テトラアルキルピペリジン−n−オキシルラジカルの使用 - Google Patents

重合調節剤としての長アルキル鎖を有する2,2,6,6−テトラアルキルピペリジン−n−オキシルラジカルの使用 Download PDF

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Publication number
JP4300445B2
JP4300445B2 JP2000555948A JP2000555948A JP4300445B2 JP 4300445 B2 JP4300445 B2 JP 4300445B2 JP 2000555948 A JP2000555948 A JP 2000555948A JP 2000555948 A JP2000555948 A JP 2000555948A JP 4300445 B2 JP4300445 B2 JP 4300445B2
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carbon atoms
group
polymerization
polymer
oligomer
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Japanese (ja)
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JP2002518559A5 (https=
JP2002518559A (ja
Inventor
ヴィーブケ ウンデルリッヒ
マルゴー クルー
ミハエル ロス
フランチェスコ フソ
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BASF Schweiz AG
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Ciba Holding AG
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F112/00Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F112/02Monomers containing only one unsaturated aliphatic radical
    • C08F112/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F112/06Hydrocarbons
    • C08F112/08Styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts

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  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Hydrogenated Pyridines (AREA)
  • Graft Or Block Polymers (AREA)
JP2000555948A 1998-06-25 1999-06-15 重合調節剤としての長アルキル鎖を有する2,2,6,6−テトラアルキルピペリジン−n−オキシルラジカルの使用 Expired - Fee Related JP4300445B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP98810585 1998-06-25
EP98810585.4 1998-06-25
PCT/EP1999/004119 WO1999067298A1 (en) 1998-06-25 1999-06-15 Use of 2,2,6,6 tetraalkylpiperidine-n-oxyl radicals having long alkyl chains as polymerization regulators

Publications (3)

Publication Number Publication Date
JP2002518559A JP2002518559A (ja) 2002-06-25
JP2002518559A5 JP2002518559A5 (https=) 2006-08-03
JP4300445B2 true JP4300445B2 (ja) 2009-07-22

Family

ID=8236156

Family Applications (1)

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JP2000555948A Expired - Fee Related JP4300445B2 (ja) 1998-06-25 1999-06-15 重合調節剤としての長アルキル鎖を有する2,2,6,6−テトラアルキルピペリジン−n−オキシルラジカルの使用

Country Status (11)

Country Link
US (1) US6569940B1 (https=)
EP (1) EP1095066B1 (https=)
JP (1) JP4300445B2 (https=)
KR (1) KR100578457B1 (https=)
AU (1) AU4772399A (https=)
CA (1) CA2334563C (https=)
DE (1) DE69930517T2 (https=)
ES (1) ES2259835T3 (https=)
MY (1) MY133149A (https=)
TW (1) TWI246519B (https=)
WO (1) WO1999067298A1 (https=)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030073762A1 (en) * 1999-12-09 2003-04-17 Tunja Jung Additive compostion for increasing the storage stability of ethylenically unsaturated resins
TW541303B (en) * 2000-03-22 2003-07-11 Ciba Sc Holding Ag 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides
EP1655303B1 (en) 2000-05-19 2011-02-23 Basf Se Process for the Controlled Increase in Molecular Weight of Polyethylene or Polyethylene Blends
TW574236B (en) * 2000-09-25 2004-02-01 Ciba Sc Holding Ag Process for controlled radical polymerization in aqueous dispersion
DE60330340D1 (de) * 2002-06-24 2010-01-14 Basf Se Kationische alkoxyaminen zur verwendung in der herstellung von nanopartikeln von natürlichen oder synthetischen clays
JP4046678B2 (ja) * 2003-10-15 2008-02-13 横浜ゴム株式会社 タイヤトレッド用ゴム組成物及びそれを用いた空気入りタイヤ
CN100577692C (zh) 2005-01-11 2010-01-06 西巴特殊化学品控股有限公司 用受控自由基聚合方法制备的均聚物和共聚物的后改性方法
JP4046734B2 (ja) 2005-01-18 2008-02-13 横浜ゴム株式会社 ポリマーの変性方法
WO2012000992A1 (en) 2010-06-29 2012-01-05 Basf Se Process for improving the flow properties of polymer melts
WO2013060708A1 (en) 2011-10-25 2013-05-02 Basf Se Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes
US9790452B2 (en) 2013-03-27 2017-10-17 Basf Se Block copolymers as soil release agents in laundry processes
CN108498458B (zh) * 2018-05-03 2019-10-11 大连理工大学 一种基于普鲁兰多糖的用于超声控制释放的纳米药物载体、药物载体系统及制备方法
EP4251665B1 (en) 2020-11-30 2025-01-08 Basf Se Process of producing polymer dispersions
EP4314155B1 (en) 2021-03-26 2025-04-09 Basf Se Polymer composition comprising polyacrylic block copolymer and aromatic based polyalkyleneoxide as dispersant

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4314933A (en) * 1979-02-15 1982-02-09 Ciba-Geigy Corporation Method for light stabilization of two-layer uni-lacquer coatings
DE3486145T2 (de) 1983-07-11 1993-09-23 Commw Scient Ind Res Org Verfahren zur polymerisation und nach diesem verfahren hergestellte polymere.
US5204473A (en) 1987-09-21 1993-04-20 Ciba-Geigy Corporation O-substituted N-hydroxy hindered amine stabilizers
US5412047A (en) 1994-05-13 1995-05-02 Xerox Corporation Homoacrylate polymerization processes with oxonitroxides
DE19510184A1 (de) 1995-03-21 1996-09-26 Basf Ag 4-Acylaminopiperidin-N-oxyle
US5654434A (en) * 1995-11-09 1997-08-05 Ciba-Geigy Corporation Hydrogen peroxide oxidation of 4-hydroxy-2, 2, 6, 6-tetramethylpiperidine
JP3673525B2 (ja) 1996-03-29 2005-07-20 ダウ グローバル テクノロジーズ インコーポレーテッド ビニル芳香族モノマーの重合中のその場でのブロックコポリマーの製造
DE19622441A1 (de) * 1996-06-05 1997-12-11 Basf Ag Verfahren zum Verdichten ethylenisch ungesättigter Monomerer
US5910549A (en) 1996-08-22 1999-06-08 Carnegie-Mellon University Method for preparation of alkoxyamines from nitroxyl radicals
DE19648811A1 (de) 1996-11-27 1998-05-28 Basf Ag Verfahren zur Polymerisation vinylischer Monomerer
US6281311B1 (en) 1997-03-31 2001-08-28 Pmd Holdings Corp. Controlled free radical polymerization process
US6140396A (en) * 1997-12-19 2000-10-31 Nippon Shokubai Co., Ltd. Thermosetting resin composition and producing process thereof

Also Published As

Publication number Publication date
CA2334563C (en) 2007-07-31
CA2334563A1 (en) 1999-12-29
EP1095066A1 (en) 2001-05-02
JP2002518559A (ja) 2002-06-25
EP1095066B1 (en) 2006-03-22
MY133149A (en) 2007-10-31
KR20010053043A (ko) 2001-06-25
DE69930517D1 (de) 2006-05-11
AU4772399A (en) 2000-01-10
KR100578457B1 (ko) 2006-05-10
US6569940B1 (en) 2003-05-27
TWI246519B (en) 2006-01-01
WO1999067298A1 (en) 1999-12-29
DE69930517T2 (de) 2006-08-17
ES2259835T3 (es) 2006-10-16

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