JP4162726B2 - 接着可能な固定部材 - Google Patents
接着可能な固定部材 Download PDFInfo
- Publication number
- JP4162726B2 JP4162726B2 JP01244995A JP1244995A JP4162726B2 JP 4162726 B2 JP4162726 B2 JP 4162726B2 JP 01244995 A JP01244995 A JP 01244995A JP 1244995 A JP1244995 A JP 1244995A JP 4162726 B2 JP4162726 B2 JP 4162726B2
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- JP
- Japan
- Prior art keywords
- adhesive
- fixing member
- dried
- fixing
- support member
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000000853 adhesive Substances 0.000 title claims abstract description 63
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- 238000004026 adhesive bonding Methods 0.000 claims description 5
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- 229920006337 unsaturated polyester resin Polymers 0.000 claims description 3
- 238000001746 injection moulding Methods 0.000 claims description 2
- 238000006068 polycondensation reaction Methods 0.000 claims description 2
- 230000002459 sustained effect Effects 0.000 claims description 2
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- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
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Images
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- Y10T428/2905—Plural and with bonded intersections only
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- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
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- Adhesives Or Adhesive Processes (AREA)
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Description
【産業上の利用分野】
本発明は、請求項1に記載された、実質的に平面の支持部材上に構造部材または機能部材を保持するための接着可能な固定部材であって、支持部材(8)の表面との接着結合を得るための接着性機能部と、構成部材との形状に適した結合または間接的な結合を得るための少なくとも1つの他の保持部(2、3、4および6)とからなり、該接着性機能部が支持部材の表面に平らに係合可能な、接着剤層を備えた接着面(1)を有し、この接着面(1)が標準温度で乾燥しうるような性質を有する硬化可能な反応性溶融接着剤(7)を備えており、即ち耐摩耗性で非粘着性であり、熱または他のエネルギーの供給により再活性化可能であり、持続的に接着結合を形成する接着可能な固定部材に関し、殊に自動車の組立の場合にライニングストリップもしくは装飾品、導線、ナットまたは他の取付部材を固定するために備えられている固定部材に関する。この場合には、自動車の車体の薄板上に固定部材を接着することにより、これまで穿孔された固定用孔中に固定する場合に局部的な応力によって生じていたような欠点または固定用ボルトもしくはナットを自動車の車体の薄板上に溶接することにより局部的な応力によって生じていたような欠点は回避されるはずである。
【0002】
【従来の技術】
フランス国特許第2542829号明細書の記載から、両面に作用する接着テープによって接着結合が達成されるような固定部材は、公知であり、この接着テープの外向きの接着面は、差当たり薄いフィルムによって被覆されており、かつこのフィルムを取り除いた後に初めて有効になる。保護フィルムを予め取り除くことが煩わしいことと感じることを除いて、付着結合では、経験によれば、ライニングストリップと自動車車体の表面との間の持続的な結合に必要とされる保持力も達成されない。また、運搬の間に保護フィルムが損なわれ、さらに部材が互いに接着し合うという危険が存在する。この種の接着固定は、自動車の組立の場合には、明らかに有効ではなく、したがって未だ殆ど使用されていない。
【0003】
【発明が解決しようとする課題】
本発明の課題は、これまで使用されてきた接着テープよりも本質的に良好な付着作用(密着性)を有し、かつその上、固定部材が包装品の形で互いに接着せず、しかし、接着作用もしくは接着機能はいつでも使用場所で活性化可能であるように構成されている接着剤層を有する前記の固定部材を提供することである。
【0004】
【課題を解決するための手段】
この課題は、前記の固定部材の場合に本発明によれば、この反応性溶融接着剤(7)が80℃までの温度で乾燥するような性質を有し、三価エポキシ樹脂、四価エポキシ樹脂および/または多価エポキシ樹脂または不飽和ポリエステル樹脂からなる特殊なバックボーン結合剤(Rueckgratbindemittel)に基づいて構成されており、このバックボーン結合剤が重合機構、重付加機構および/または重縮合反応機構により凝固しかつ硬化することによって解決される。
【0005】
このようなプラスチック層を備えた固定部材は、接着剤層が固定部材の使用の直前まで絶対に接着しないかまたは接着剤耐性であるという大きな利点を提供する。溶融接着剤の使用場所での反応化によって初めて、接着剤層の付着力が放出され、この接着剤層は、相応する硬化後に実際に取り外すことのできない結合を生じる。
【0006】
更に、接着剤層を硬化させるために、薄板の次のラッカー塗布に必要とされる乾燥炉は、付加的に利用することができる。
【0007】
溶融接着剤の反応に必要とされる熱は、例えば超音波、エネルギー照射、発熱素子の使用によって発生させることができるかまたは支持面と接着面との間の摩擦によって発生させることができる。
【0008】
溶融接着剤の反応は、特に接着面の加熱によって生じ、この接着面は、軟化または溶融の後に支持部材に接して保持され、かつ次いで押し付けられる。
【0009】
溶融接着剤の塗布は、接着面を浸漬浴中に1回浸漬することによって行なわれ、この場合金属性の固定部材は、本発明によるもう1つの特徴によって完全に浸漬されることができ、それによって防錆性の保護被覆を備えることができ、したがって同時に有効で安価な腐蝕抑制が達成される。
【0010】
これとは異なり、プラスチックからなる固定部材の場合には、溶融接着剤は、射出成形の進行中に、溶融接着剤を金型の開放後にほとばしり出た部分の噴出前に露出する接着面上に塗布し、かつ次いでなお完全には冷却されていない部材の残留熱によって急速に乾燥することにより、簡単な方法で塗布することができる。それによって、溶融接着剤を塗布するための他の作業過程は節約することができる。
【0011】
接着面は、接着剤層中での応力のピークを阻止するために、材料の厚さを縁部領域に向かって減少させるかまたは縁部領域に薄いリップを備えさせるようにして形成させることができる。
【0012】
図面には、本発明による固定部材の種々の実施例ならびに特定の使用までの個々の加工過程が示されており、かつ次にこのことについて詳細に記載することにする。
【0013】
【実施例】
図1a)〜d)には、4つの典型的な接着可能の固定部材が図示されており、これらの固定部材は、自動車の組立において構成部材または機能部材を保持するために使用されている。これらの固定部材には、それぞれ支持部材、例えば自動車の車体の薄板の表面との接着結合を得るための板1が備えられている。
【0014】
板1上には、それぞれ構成部材または機能部材との形状に適した結合を得るための保持部2、3、4または6が一体成形されている。この場合、図1a)による保持部は、所謂平頭ボルト2であり、図1b)の場合には、所謂ねじ付ボルト3であり、図1c)の場合には、側方に開いた鍵穴5を有する保持板4であり、この場合この鍵穴には、別の構成部材または固定部材から離れた平頭ボルトが噛み合い可能であり、かつ図1d)の場合には、ナット6である。
【0015】
板1には、接着結合を得るために設けられた下側に接して硬化可能または架橋可能な一成分の高反応性の溶融接着剤が備えられているかもしくは被覆されており、この溶融接着剤は、特殊な脊柱部結合剤に基づいて構成されておりかつ80℃までの温度で接着しないし、耐摩耗性であるという性質を有する。しかし、この溶融接着剤は、熱の供給によって再び反応することができ、この場合この熱は、例えば超音波、発熱素子、マイクロ波または摩擦のような別のエネルギーの形で発生させることができる。
【0016】
固定部材上への接着剤層の短い凝結時間および硬化時間を保証するために、バックボーン結合剤およびその硬化系は、極めて高い反応性を有しなければならない。特に有利なバックボーン結合剤は、重付加または重合によって得られる三価エポキシ樹脂、四価エポキシ樹脂および/または多価エポキシ樹脂である。このために適当な硬化剤系は、重付加については分子中に少なくとも2個の活性水素原子を有する化合物(例えば、脂肪族、脂環式または芳香族アミン、ジシアンジアミド等)が使用され、かつ陽イオンまたは陰イオン重合については触媒作用するルイス酸および/または塩基が場合によっては金属錯化合物の存在下に使用されることによって区別される。
【0017】
更に、好ましいバックボーン結合剤、例えば不飽和ポリエステル樹脂は、不飽和ポリマーの種類に属する。このバックボーン結合剤は、フリーラジカルにより温度依存性の硬化系および促進剤系により凝固させかつ硬化させることができるか、または光開始剤の存在下でのUV線ならびに電子線により凝固させかつ硬化させることができる。
【0018】
溶融接着剤の塗布は、例えば図2に示されているように固定部材を接着板1と一緒に溶融接着剤浴9の表面上に沈下させ、かつ再び持ち上げることによって行なうことができる。更に、下側に付着する接着剤層7は、なお乾燥させなければならない(図3)。その後に、固定部材は包装することができ、かつ特定の場所に運搬することができ、この場合、この固定部材は、くっつき合うという危険は存在しない。
【0019】
例えば、自動車の車体の薄板であることができる支持部材8の表面との接着結合を得るために、固定部材は、150〜180℃に加熱された接着剤層7と一緒に支持板8上に該支持板と平行に緊密に保持され、かつ次いで溶融接着剤が硬化されるまで支持板8上に押し付けられる。更に、接着剤層を硬化させるために、薄板の次のラッカー塗布に必要とされる乾燥炉を付加的に使用することができる。
【0020】
固定部材の位置決めおよび押圧は、有利に図8に略示されている工業用ロボットにより行なわれる。
【0021】
図1a)〜d)による固定部材は、金属から製造されていてもよいし、プラスチックから製造されていてもよい。金属からの構成の場合には、図5に略示したように固定部材に浸漬浴中で接着剤層7を被覆する方法も存在している。固定部材の全面を被覆すること(図6)によって、この固定部材は同時に錆から保護される。
【0022】
図7による固定部材の位置決めおよび接着は、図4に図示した場合と同様に行なわれる。この場合、接着剤層7は、溶融のために接着板1の下側に局部的にのみもたらされ;残りの被覆は、この場合には、当てはまらない。
【0023】
プラスチックからなる固定部材の場合には、溶融接着剤の塗布は、射出成形用金型中で射出成形の進行中に、溶融接着剤を射出成形用金型の開放後にほとばしり出た部分の噴出前に露出する接着面上に塗布し、かつ次いで急速に乾燥することにより、実施することができる。
【0024】
図9による固定部材の場合には、接着面の外側縁部に薄く先端が延びているリップ9が備えられている。それによって、接着層の縁部領域中に応力ピークが構成されることが阻止され、したがって接着された固定部材の付着効果は、ボルト頭部上への側方の力作用およびそれと結び付いた剥離効果に対する十分な耐性を提供する。
【0025】
本発明は、例えばストリップ、異形成形棒、薄板またはプラスチック板および決着結合を得るための類似物のような構成部材または機能部材を装備させるかまたは被覆するために接着可能な構成部材のみに限定されるのではなく、一般に前記の溶融接着剤の使用にも及んでいる。
【図面の簡単な説明】
【図1】a)、b)、c)およびd)は、それぞれ本発明による接着可能な固定部材の4つの異なる実施形式を示す略図。
【図2】溶融接着剤浴中に接着面を浸漬させた場合の固体部材を示す略図。
【図3】溶融接着剤を乾燥させた際の図2と同様の固定部材を示す略図。
【図4】接着面を溶融した際の支持板上の押し付け位置での固定部材を示す略図。
【図5】浸漬浴中に完全に浸漬した際の固定部材を示す略図。
【図6】接着剤で全面が被覆された乾燥の際の固定部材を示す略図。
【図7】図4の溶融の際と同じ押し付け位置の固定部材を示す略図。
【図8】ロボットを用いての固定部材の接着工程を示す略図。
【図9】材料の厚さが縁部領域で減少する接着板を有する固定部材を示す略図。
【符号の説明】
1 接着板、 2、3、4、6 保持領域、 5 鍵穴、 7 接着剤層、 8 支持板、 9 リップ
Claims (3)
- 実質的に平面の支持部材上に構造部材または機能部材を保持するための接着可能な固定部材であって、支持部材(8)の表面との接着結合を得るための接着性機能部と、構成部材との形状に適した結合または間接的な結合を得るための少なくとも1つの他の保持部(2、3、4および6)とからなり、該接着性機能部が支持部材の表面に平らに係合可能な、接着剤層を備えた接着面(1)を有し、この接着面(1)が標準温度で乾燥しうるような性質を有する硬化可能な反応性溶融接着剤(7)を備えており、即ち耐摩耗性で非粘着性であり、熱または他のエネルギーの供給により再活性化可能であり、持続的に接着結合を形成する接着可能な固定部材において、
この反応性溶融接着剤(7)が80℃までの温度で乾燥するような性質を有し、三価エポキシ樹脂、四価エポキシ樹脂および/または多価エポキシ樹脂または不飽和ポリエステル樹脂からなる特殊なバックボーン結合剤に基づいて構成されており、このバックボーン結合剤が重合機構、重付加機構および / または重縮合反応機構により凝固しかつ硬化することを特徴とする、接着可能な固定部材。 - 溶融接着剤(7)が射出成形の進行中に金型の開放直後に露出する接着面(1)上に塗布され、次になお冷却されていない部材の残留熱によって急速に乾燥されている、請求項1記載の硬質弾性または粘弾性のプラスチックからなる固定部材。
- 接着面(1)の縁部領域に薄く先端が延びているリップ(10)を備えている、請求項1記載の固定部材。
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DE4402550A DE4402550A1 (de) | 1994-01-28 | 1994-01-28 | Verklebbares Befestigungselement zum Halten von Bau- oder Funktionsteilen auf Trägerteilen |
DE4402550.5 | 1994-01-28 |
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JPH0842528A JPH0842528A (ja) | 1996-02-13 |
JP4162726B2 true JP4162726B2 (ja) | 2008-10-08 |
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JP7519852A Pending JPH09502010A (ja) | 1994-01-28 | 1995-01-05 | 被着部上に構成部材または機能部材を保持するための接着可能な固定部材 |
JP01244995A Expired - Fee Related JP4162726B2 (ja) | 1994-01-28 | 1995-01-30 | 接着可能な固定部材 |
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JP7519852A Pending JPH09502010A (ja) | 1994-01-28 | 1995-01-05 | 被着部上に構成部材または機能部材を保持するための接着可能な固定部材 |
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EP (1) | EP0741842B1 (ja) |
JP (2) | JPH09502010A (ja) |
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AT (1) | ATE179494T1 (ja) |
BR (1) | BR9506588A (ja) |
CA (1) | CA2181468C (ja) |
CZ (1) | CZ291381B6 (ja) |
DE (2) | DE4402550A1 (ja) |
ES (1) | ES2133726T3 (ja) |
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-
1994
- 1994-01-28 DE DE4402550A patent/DE4402550A1/de not_active Ceased
-
1995
- 1995-01-05 EP EP95906302A patent/EP0741842B1/de not_active Expired - Lifetime
- 1995-01-05 AT AT95906302T patent/ATE179494T1/de active
- 1995-01-05 JP JP7519852A patent/JPH09502010A/ja active Pending
- 1995-01-05 WO PCT/EP1995/000034 patent/WO1995020726A1/de active IP Right Grant
- 1995-01-05 DE DE59505776T patent/DE59505776D1/de not_active Expired - Lifetime
- 1995-01-05 KR KR1019960704069A patent/KR100310281B1/ko not_active IP Right Cessation
- 1995-01-05 ES ES95906302T patent/ES2133726T3/es not_active Expired - Lifetime
- 1995-01-05 CZ CZ19961832A patent/CZ291381B6/cs not_active IP Right Cessation
- 1995-01-05 MX MX9603024A patent/MX9603024A/es not_active IP Right Cessation
- 1995-01-05 CA CA002181468A patent/CA2181468C/en not_active Expired - Fee Related
- 1995-01-05 BR BR9506588A patent/BR9506588A/pt not_active IP Right Cessation
- 1995-01-30 JP JP01244995A patent/JP4162726B2/ja not_active Expired - Fee Related
- 1995-01-30 US US08/380,518 patent/US5756185A/en not_active Expired - Lifetime
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US5756185A (en) | 1998-05-26 |
JPH09502010A (ja) | 1997-02-25 |
CZ183296A3 (en) | 1997-03-12 |
CZ291381B6 (cs) | 2003-02-12 |
CA2181468C (en) | 2005-03-29 |
MX9603024A (es) | 1997-06-28 |
EP0741842B1 (de) | 1999-04-28 |
DE59505776D1 (de) | 1999-06-02 |
KR970700825A (ko) | 1997-02-12 |
KR100310281B1 (ko) | 2001-12-15 |
CA2181468A1 (en) | 1995-08-03 |
ES2133726T3 (es) | 1999-09-16 |
ATE179494T1 (de) | 1999-05-15 |
BR9506588A (pt) | 1997-09-23 |
DE4402550A1 (de) | 1995-08-03 |
JPH0842528A (ja) | 1996-02-13 |
WO1995020726A1 (de) | 1995-08-03 |
EP0741842A1 (de) | 1996-11-13 |
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