JP3888232B2 - 含フッ素三元共重合体 - Google Patents
含フッ素三元共重合体 Download PDFInfo
- Publication number
- JP3888232B2 JP3888232B2 JP2002163741A JP2002163741A JP3888232B2 JP 3888232 B2 JP3888232 B2 JP 3888232B2 JP 2002163741 A JP2002163741 A JP 2002163741A JP 2002163741 A JP2002163741 A JP 2002163741A JP 3888232 B2 JP3888232 B2 JP 3888232B2
- Authority
- JP
- Japan
- Prior art keywords
- perfluoro
- vinyl ether
- fluorine
- copolymer
- feve
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920001897 terpolymer Polymers 0.000 title claims description 35
- 229910052731 fluorine Inorganic materials 0.000 title claims description 29
- 239000011737 fluorine Substances 0.000 title claims description 29
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 title claims description 27
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 claims description 52
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 47
- -1 perfluoro Chemical group 0.000 claims description 36
- 238000007334 copolymerization reaction Methods 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 20
- KHXKESCWFMPTFT-UHFFFAOYSA-N 1,1,1,2,2,3,3-heptafluoro-3-(1,2,2-trifluoroethenoxy)propane Chemical compound FC(F)=C(F)OC(F)(F)C(F)(F)C(F)(F)F KHXKESCWFMPTFT-UHFFFAOYSA-N 0.000 claims description 15
- 238000002834 transmittance Methods 0.000 claims description 10
- 238000010558 suspension polymerization method Methods 0.000 claims description 7
- 230000009477 glass transition Effects 0.000 claims description 6
- OVGRCEFMXPHEBL-UHFFFAOYSA-N 1-ethenoxypropane Chemical compound CCCOC=C OVGRCEFMXPHEBL-UHFFFAOYSA-N 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 description 47
- 230000000052 comparative effect Effects 0.000 description 18
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 238000006116 polymerization reaction Methods 0.000 description 12
- 239000000243 solution Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000010408 film Substances 0.000 description 10
- 238000000465 moulding Methods 0.000 description 9
- 241000251468 Actinopterygii Species 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 6
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000002347 injection Methods 0.000 description 5
- 239000007924 injection Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- BLTXWCKMNMYXEA-UHFFFAOYSA-N 1,1,2-trifluoro-2-(trifluoromethoxy)ethene Chemical compound FC(F)=C(F)OC(F)(F)F BLTXWCKMNMYXEA-UHFFFAOYSA-N 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 3
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 3
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 3
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000010556 emulsion polymerization method Methods 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 230000009878 intermolecular interaction Effects 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- LGUZHRODIJCVOC-UHFFFAOYSA-N perfluoroheptane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F LGUZHRODIJCVOC-UHFFFAOYSA-N 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- RPBWMJBZQXCSFW-UHFFFAOYSA-N 2-methylpropanoyl 2-methylpropaneperoxoate Chemical compound CC(C)C(=O)OOC(=O)C(C)C RPBWMJBZQXCSFW-UHFFFAOYSA-N 0.000 description 2
- 238000000862 absorption spectrum Methods 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 2
- 150000002221 fluorine Chemical class 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- 239000003505 polymerization initiator Substances 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- 229920006027 ternary co-polymer Polymers 0.000 description 2
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 2
- OHMHBGPWCHTMQE-UHFFFAOYSA-N 2,2-dichloro-1,1,1-trifluoroethane Chemical compound FC(F)(F)C(Cl)Cl OHMHBGPWCHTMQE-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- YOALFLHFSFEMLP-UHFFFAOYSA-N azane;2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctanoic acid Chemical compound [NH4+].[O-]C(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YOALFLHFSFEMLP-UHFFFAOYSA-N 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000012933 diacyl peroxide Substances 0.000 description 1
- 238000012674 dispersion polymerization Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/26—Tetrafluoroethene
- C08F214/262—Tetrafluoroethene with fluorinated vinyl ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Polymerisation Methods In General (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002163741A JP3888232B2 (ja) | 2001-12-18 | 2002-06-05 | 含フッ素三元共重合体 |
| US10/472,851 US7009017B2 (en) | 2001-12-18 | 2002-12-12 | Fluorinated terpolymer |
| AU2002357600A AU2002357600A1 (en) | 2001-12-18 | 2002-12-18 | Fluorinated terpolymer |
| DE60226342T DE60226342T2 (de) | 2001-12-18 | 2002-12-18 | Fluoriertes terpolymer |
| EP02805025A EP1457505B1 (en) | 2001-12-18 | 2002-12-18 | Fluorinated terpolymer |
| PCT/JP2002/013233 WO2003051944A1 (en) | 2001-12-18 | 2002-12-18 | Fluorinated terpolymer |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001383974 | 2001-12-18 | ||
| JP2001-383974 | 2001-12-18 | ||
| JP2002163741A JP3888232B2 (ja) | 2001-12-18 | 2002-06-05 | 含フッ素三元共重合体 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2003246823A JP2003246823A (ja) | 2003-09-05 |
| JP2003246823A5 JP2003246823A5 (OSRAM) | 2004-10-14 |
| JP3888232B2 true JP3888232B2 (ja) | 2007-02-28 |
Family
ID=26625105
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002163741A Expired - Fee Related JP3888232B2 (ja) | 2001-12-18 | 2002-06-05 | 含フッ素三元共重合体 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US7009017B2 (OSRAM) |
| EP (1) | EP1457505B1 (OSRAM) |
| JP (1) | JP3888232B2 (OSRAM) |
| AU (1) | AU2002357600A1 (OSRAM) |
| DE (1) | DE60226342T2 (OSRAM) |
| WO (1) | WO2003051944A1 (OSRAM) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3888232B2 (ja) * | 2001-12-18 | 2007-02-28 | ユニマテック株式会社 | 含フッ素三元共重合体 |
| US20070219331A1 (en) * | 2004-04-15 | 2007-09-20 | Masahiko Ishikawa | Fluorine-Containing Polymer and Treating Agent Composition |
| CN100475867C (zh) * | 2004-04-15 | 2009-04-08 | 大金工业株式会社 | 含氟聚合物和处理剂组合物 |
| JP2005325275A (ja) * | 2004-05-17 | 2005-11-24 | Yunimatekku Kk | 含フッ素重合体成形品およびその積層体 |
| JP4640021B2 (ja) * | 2004-08-25 | 2011-03-02 | 旭硝子株式会社 | 含フッ素共重合体 |
| WO2006069107A2 (en) * | 2004-12-22 | 2006-06-29 | E.I. Dupont De Nemours And Company | Copolymers of perfluoro (alkyl venyl ether) for photochemical reactor, process for increasing fluorine content and production of olefinic compound by photochlorination |
| JP2006316174A (ja) * | 2005-05-13 | 2006-11-24 | Yunimatekku Kk | フッ素化処理含フッ素共重合体の製造法 |
| JP2007112916A (ja) * | 2005-10-21 | 2007-05-10 | Yunimatekku Kk | 非晶質含フッ素共重合体 |
| JP5162818B2 (ja) * | 2005-11-17 | 2013-03-13 | ユニマテック株式会社 | 含フッ素共重合体ブレンド物 |
| JP2007197561A (ja) * | 2006-01-26 | 2007-08-09 | Yunimatekku Kk | 含フッ素三元共重合体の製造法 |
| JP2007302708A (ja) * | 2006-05-08 | 2007-11-22 | Yunimatekku Kk | 可視化計測用もしくは光学的計測用成形体 |
| JPWO2008047906A1 (ja) * | 2006-10-20 | 2010-02-25 | ダイキン工業株式会社 | 含フッ素共重合体、電線及びその製造方法 |
| TWI482784B (zh) * | 2009-02-13 | 2015-05-01 | Solvay Solexis Spa | 全氟彈性體 |
| TWI496796B (zh) * | 2009-02-13 | 2015-08-21 | Solvay Solexis Spa | 全氟彈性體 |
| JP6017550B2 (ja) * | 2011-06-09 | 2016-11-02 | ソルベイ スペシャルティ ポリマーズ イタリー エス．ピー．エー． | 超分岐フルオロエラストマー添加剤 |
| JP6150483B2 (ja) * | 2012-09-27 | 2017-06-21 | 三井・デュポンフロロケミカル株式会社 | パーフルオロ（エチルビニルエーテル）を含有する非晶質フッ素重合体溶剤組成物 |
| CN104926979B (zh) * | 2015-06-18 | 2017-05-10 | 巨化集团技术中心 | 一种乙烯/四氟乙烯共聚物粉体及其制备方法 |
| JP2018184618A (ja) * | 2018-08-03 | 2018-11-22 | 三井・ケマーズ フロロプロダクツ株式会社 | テトラフルオロエチレンとパーフルオロ（エチルビニルエーテル）との共重合体の水性分散体または溶液 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4029868A (en) * | 1976-03-10 | 1977-06-14 | E. I. Du Pont De Nemours And Company | Tetrafluoroethylene terpolymers |
| IT1264661B1 (it) * | 1993-07-05 | 1996-10-04 | Ausimont Spa | Copolimeri termoprocessabilin del tetrafluoroetilene |
| JPH07126329A (ja) * | 1993-10-29 | 1995-05-16 | Nippon Mektron Ltd | テトラフルオロエチレン−パーフルオロビニルエ−テル共重合体 |
| DE69601335T2 (de) * | 1995-08-17 | 1999-08-12 | E.I. Du Pont De Nemours And Co., Wilmington, Del. | Tetrafluorethylen-Terpolymer |
| US5760151A (en) * | 1995-08-17 | 1998-06-02 | E. I. Du Pont De Nemours And Company | Tetrafluoroethylene copolymer |
| US5919878A (en) * | 1996-09-13 | 1999-07-06 | E. I. Du Pont De Nemours And Company | Amorphous fluoropolymer containing perfluoro(ethyl vinyl ether) |
| US6197904B1 (en) * | 1998-02-26 | 2001-03-06 | E. I. Du Pont De Nemours And Company | Low-melting tetrafluoroethylene copolymer |
| JP4392706B2 (ja) * | 2000-02-02 | 2010-01-06 | 三井・デュポンフロロケミカル株式会社 | 熱溶融性フッ素樹脂組成物 |
| JP2002295450A (ja) | 2001-04-02 | 2002-10-09 | Nippon Mektron Ltd | 定着ローラ被覆チューブ用材料 |
| JP3888232B2 (ja) * | 2001-12-18 | 2007-02-28 | ユニマテック株式会社 | 含フッ素三元共重合体 |
-
2002
- 2002-06-05 JP JP2002163741A patent/JP3888232B2/ja not_active Expired - Fee Related
- 2002-12-12 US US10/472,851 patent/US7009017B2/en not_active Expired - Fee Related
- 2002-12-18 EP EP02805025A patent/EP1457505B1/en not_active Expired - Lifetime
- 2002-12-18 WO PCT/JP2002/013233 patent/WO2003051944A1/ja not_active Ceased
- 2002-12-18 AU AU2002357600A patent/AU2002357600A1/en not_active Abandoned
- 2002-12-18 DE DE60226342T patent/DE60226342T2/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP2003246823A (ja) | 2003-09-05 |
| EP1457505A1 (en) | 2004-09-15 |
| EP1457505B1 (en) | 2008-04-30 |
| DE60226342T2 (de) | 2009-06-10 |
| US20040214972A1 (en) | 2004-10-28 |
| EP1457505A4 (en) | 2006-12-06 |
| DE60226342D1 (de) | 2008-06-12 |
| WO2003051944A1 (en) | 2003-06-26 |
| US7009017B2 (en) | 2006-03-07 |
| AU2002357600A1 (en) | 2003-06-30 |
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