JP3801187B2 - 薬液再処理方法及び、蛍石の製造方法 - Google Patents
薬液再処理方法及び、蛍石の製造方法 Download PDFInfo
- Publication number
- JP3801187B2 JP3801187B2 JP2004154689A JP2004154689A JP3801187B2 JP 3801187 B2 JP3801187 B2 JP 3801187B2 JP 2004154689 A JP2004154689 A JP 2004154689A JP 2004154689 A JP2004154689 A JP 2004154689A JP 3801187 B2 JP3801187 B2 JP 3801187B2
- Authority
- JP
- Japan
- Prior art keywords
- hydrofluoric acid
- waste liquid
- acid waste
- calcium fluoride
- reaction tower
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 title claims description 115
- 238000000034 method Methods 0.000 title claims description 54
- 239000000126 substance Substances 0.000 title claims description 53
- 238000004519 manufacturing process Methods 0.000 title claims description 47
- 238000012958 reprocessing Methods 0.000 title claims description 45
- 239000010436 fluorite Substances 0.000 title claims description 43
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 295
- 239000002699 waste material Substances 0.000 claims description 132
- 239000007788 liquid Substances 0.000 claims description 128
- 238000006243 chemical reaction Methods 0.000 claims description 107
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 92
- 229910001634 calcium fluoride Inorganic materials 0.000 claims description 63
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 47
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 28
- 229910052731 fluorine Inorganic materials 0.000 claims description 28
- 239000011737 fluorine Substances 0.000 claims description 28
- 230000015271 coagulation Effects 0.000 claims description 11
- 238000005345 coagulation Methods 0.000 claims description 11
- 238000004062 sedimentation Methods 0.000 claims description 11
- 239000003463 adsorbent Substances 0.000 claims description 6
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 6
- 235000011116 calcium hydroxide Nutrition 0.000 claims description 6
- 239000000920 calcium hydroxide Substances 0.000 claims description 6
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 5
- 238000007599 discharging Methods 0.000 claims description 4
- 239000002738 chelating agent Substances 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 2
- 150000002910 rare earth metals Chemical class 0.000 claims description 2
- 238000002347 injection Methods 0.000 claims 2
- 239000007924 injection Substances 0.000 claims 2
- 239000003814 drug Substances 0.000 claims 1
- 229940079593 drug Drugs 0.000 claims 1
- 235000010216 calcium carbonate Nutrition 0.000 description 43
- 239000004065 semiconductor Substances 0.000 description 23
- 239000000243 solution Substances 0.000 description 21
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 20
- 235000011941 Tilia x europaea Nutrition 0.000 description 20
- 239000004571 lime Substances 0.000 description 20
- 238000003756 stirring Methods 0.000 description 13
- 239000012535 impurity Substances 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 238000005530 etching Methods 0.000 description 9
- 238000011084 recovery Methods 0.000 description 7
- 238000001039 wet etching Methods 0.000 description 7
- 239000008155 medical solution Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 5
- 229910052796 boron Inorganic materials 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 239000011229 interlayer Substances 0.000 description 5
- 229910052698 phosphorus Inorganic materials 0.000 description 5
- 239000011574 phosphorus Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 238000004064 recycling Methods 0.000 description 4
- 229910004261 CaF 2 Inorganic materials 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 238000002955 isolation Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000010802 sludge Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- 238000003911 water pollution Methods 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000002894 chemical waste Substances 0.000 description 2
- 208000037998 chronic venous disease Diseases 0.000 description 2
- 230000001112 coagulating effect Effects 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- QPJSUIGXIBEQAC-UHFFFAOYSA-N n-(2,4-dichloro-5-propan-2-yloxyphenyl)acetamide Chemical compound CC(C)OC1=CC(NC(C)=O)=C(Cl)C=C1Cl QPJSUIGXIBEQAC-UHFFFAOYSA-N 0.000 description 2
- 238000004065 wastewater treatment Methods 0.000 description 2
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 1
- FFIDYXJAYFOFFZ-UHFFFAOYSA-N F.[Ca] Chemical compound F.[Ca] FFIDYXJAYFOFFZ-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000005380 borophosphosilicate glass Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000003682 fluorination reaction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 238000005468 ion implantation Methods 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000008239 natural water Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 238000000206 photolithography Methods 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 229920005591 polysilicon Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/20—Halides
- C01F11/22—Fluorides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Removal Of Specific Substances (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004154689A JP3801187B2 (ja) | 2003-08-28 | 2004-05-25 | 薬液再処理方法及び、蛍石の製造方法 |
| CNB2004100570181A CN100393635C (zh) | 2003-08-28 | 2004-08-20 | 药液回收处理方法及药液回收处理装置、萤石的制造方法 |
| US10/922,097 US20050084442A1 (en) | 2003-08-28 | 2004-08-20 | Chemical reprocessing method, chemical reprocessing apparatus, and method of manufacturing fluorite |
| US12/007,022 US20080124267A1 (en) | 2003-08-28 | 2008-01-04 | Chemical reprocessing method, chemical reprocessing apparatus, and method of manufacturing fluorite |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003304589 | 2003-08-28 | ||
| JP2004154689A JP3801187B2 (ja) | 2003-08-28 | 2004-05-25 | 薬液再処理方法及び、蛍石の製造方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005097083A JP2005097083A (ja) | 2005-04-14 |
| JP2005097083A5 JP2005097083A5 (enExample) | 2005-12-22 |
| JP3801187B2 true JP3801187B2 (ja) | 2006-07-26 |
Family
ID=34467295
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004154689A Expired - Fee Related JP3801187B2 (ja) | 2003-08-28 | 2004-05-25 | 薬液再処理方法及び、蛍石の製造方法 |
Country Status (3)
| Country | Link |
|---|---|
| US (2) | US20050084442A1 (enExample) |
| JP (1) | JP3801187B2 (enExample) |
| CN (1) | CN100393635C (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5087829B2 (ja) * | 2005-08-31 | 2012-12-05 | セイコーエプソン株式会社 | 蛍石の製造方法 |
| US20110023908A1 (en) * | 2009-07-30 | 2011-02-03 | Applied Materials, Inc. | Methods and apparatus for process abatement with recovery and reuse of abatement effluent |
| US20110275221A1 (en) * | 2010-05-07 | 2011-11-10 | Lam Research Ag | Method for treatment substrates and treatment composition for said method |
| JP5260796B2 (ja) | 2010-07-22 | 2013-08-14 | 日本結晶光学株式会社 | 蛍石 |
| RU2472705C1 (ru) * | 2011-06-21 | 2013-01-20 | Открытое акционерное общество "Сибирский химический комбинат" | Способ получения синтетического флюорита |
| CN103086555A (zh) * | 2011-10-31 | 2013-05-08 | 库特勒自动化系统(苏州)有限公司 | 硅晶片蚀刻废水处理系统及处理方法 |
| TWI449668B (zh) * | 2012-04-09 | 2014-08-21 | 姚正義 | Preparation method of calcium fluoride |
| TWI490168B (zh) * | 2012-06-25 | 2015-07-01 | Silicor Materials Inc | 純化無機鹽之方法及其用途 |
| JP6079524B2 (ja) * | 2013-09-13 | 2017-02-15 | 旭硝子株式会社 | 再生フッ化カルシウムの製造方法 |
| CN103570053B (zh) * | 2013-10-31 | 2016-06-22 | 阜新金晟环保科技有限公司 | 萤石粉精加工工艺 |
| CN104760984A (zh) * | 2014-01-08 | 2015-07-08 | 贾玉铭 | 采用含硫酸等混酸的氢氟酸制造氟化钙的方法 |
| KR101773577B1 (ko) * | 2016-03-25 | 2017-09-01 | 한국화학연구원 | 폐냉매 분해가스로부터 불화물 회수방법 |
| RU2736038C1 (ru) * | 2020-04-21 | 2020-11-11 | Общество с ограниченной ответственностью "Промтехнологии" | Способ получения минерализатора на основе фторида кальция |
| JP7555541B2 (ja) * | 2020-11-27 | 2024-09-25 | 上田石灰製造株式会社 | フッ素吸着剤の製造方法及びフッ素除去・回収方法 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3956118A (en) * | 1968-05-23 | 1976-05-11 | Rockwell International Corporation | Removal of phosphate from waste water |
| US3743704A (en) * | 1971-05-12 | 1973-07-03 | Du Pont | Removal of hf from an hf-containing gas |
| US4424067A (en) * | 1982-07-29 | 1984-01-03 | Allied Corporation | Purification of anhydrous hydrogen fluoride |
| US4472368A (en) * | 1982-12-27 | 1984-09-18 | Agrico Chemical Company | Neutralization of cooling pond water in phosphoric acid plants |
| CN1010772B (zh) * | 1988-03-26 | 1990-12-12 | 中南工业大学 | 矿山含氟废水处理方法 |
| US4952386A (en) * | 1988-05-20 | 1990-08-28 | Athens Corporation | Method and apparatus for purifying hydrogen fluoride |
| DE69103339T2 (de) * | 1990-06-01 | 1995-03-16 | Asahi Glass Co Ltd | Verfahren zur Herstellung von Fluorwasserstoffsäure. |
| US5362461A (en) * | 1991-10-03 | 1994-11-08 | Kurita Water Industries, Ltd. | Method for recovering calcium fluoride from fluoroetchant |
| JP3266309B2 (ja) * | 1992-04-15 | 2002-03-18 | 栗田工業株式会社 | 酸性フッ素含有水の処理方法 |
| FR2771727B1 (fr) * | 1997-11-28 | 2000-02-11 | Sgs Thomson Microelectronics | Defluoruration d'eaux usees |
| JP3169899B2 (ja) * | 1998-07-15 | 2001-05-28 | 日本電気環境エンジニアリング株式会社 | フッ素含有排水の処理方法とその装置 |
| WO2000003952A1 (en) * | 1998-07-17 | 2000-01-27 | Nec Corporation | Method for treating a fluorine-containing waste water and treating apparatus |
| JP3697361B2 (ja) * | 1999-01-28 | 2005-09-21 | シャープ株式会社 | 排水処理方法および排水処理装置 |
| JP2001137864A (ja) * | 1999-11-10 | 2001-05-22 | Daikin Ind Ltd | フッ酸を含有する廃水の処理方法 |
| US7056477B1 (en) * | 2000-02-03 | 2006-06-06 | Cellular Process Chemistry, Inc. | Modular chemical production system incorporating a microreactor |
| US6613230B2 (en) * | 2000-07-07 | 2003-09-02 | Ionics, Incorporated | Method for simultaneous removal of arsenic and fluoride from aqueous solutions |
| US6645385B2 (en) * | 2000-09-26 | 2003-11-11 | Ionics, Incorporated | System and method for removal of fluoride from wastewater using single fluoride sensing electrode |
| US7097689B2 (en) * | 2002-06-20 | 2006-08-29 | Praxair Technology, Inc. | Process and system for purifying gases |
| US7182873B2 (en) * | 2004-07-08 | 2007-02-27 | Powerchip Semiconductor Corp. | Method of fluoride-containing wastewater treatment |
-
2004
- 2004-05-25 JP JP2004154689A patent/JP3801187B2/ja not_active Expired - Fee Related
- 2004-08-20 CN CNB2004100570181A patent/CN100393635C/zh not_active Expired - Fee Related
- 2004-08-20 US US10/922,097 patent/US20050084442A1/en not_active Abandoned
-
2008
- 2008-01-04 US US12/007,022 patent/US20080124267A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| JP2005097083A (ja) | 2005-04-14 |
| CN100393635C (zh) | 2008-06-11 |
| CN1590310A (zh) | 2005-03-09 |
| US20080124267A1 (en) | 2008-05-29 |
| US20050084442A1 (en) | 2005-04-21 |
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