JP3786297B2 - 触媒の製造方法 - Google Patents

触媒の製造方法 Download PDF

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Publication number
JP3786297B2
JP3786297B2 JP06394796A JP6394796A JP3786297B2 JP 3786297 B2 JP3786297 B2 JP 3786297B2 JP 06394796 A JP06394796 A JP 06394796A JP 6394796 A JP6394796 A JP 6394796A JP 3786297 B2 JP3786297 B2 JP 3786297B2
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Japan
Prior art keywords
catalyst
catalytically active
parts
active component
diameter
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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JP06394796A
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English (en)
Japanese (ja)
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JPH08299797A (ja
Inventor
秀樹 椙
文雄 坂井
鴻一 和田
一男 白石
利丈 小島
昌 梅島
純將 瀬尾
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Nippon Kayaku Co Ltd
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Nippon Kayaku Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to JP06394796A priority Critical patent/JP3786297B2/ja
Application filed by Nippon Kayaku Co Ltd filed Critical Nippon Kayaku Co Ltd
Priority to EP03020308A priority patent/EP1375466A1/en
Priority to EP96904311A priority patent/EP0758562B1/en
Priority to DE69636206T priority patent/DE69636206T2/de
Priority to PCT/JP1996/000506 priority patent/WO1996027437A1/ja
Priority to BR9605919A priority patent/BR9605919A/pt
Priority to MXPA/A/1996/005309A priority patent/MXPA96005309A/xx
Priority to US08/737,028 priority patent/US5959143A/en
Priority to CN96190146A priority patent/CN1087658C/zh
Priority to MYPI96000770A priority patent/MY113436A/en
Priority to TW85102922A priority patent/TW372888B/zh
Publication of JPH08299797A publication Critical patent/JPH08299797A/ja
Application granted granted Critical
Publication of JP3786297B2 publication Critical patent/JP3786297B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027Powdering
    • B01J37/0045Drying a slurry, e.g. spray drying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002Mixed oxides other than spinels, e.g. perovskite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/88Molybdenum
    • B01J23/887Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877Vanadium, tantalum, niobium or polonium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34Mechanical properties
    • B01J35/38Abrasion or attrition resistance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/612Surface area less than 10 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66Pore distribution
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15X-ray diffraction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34Mechanical properties
    • B01J35/36Mechanical strength
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0236Drying, e.g. preparing a suspension, adding a soluble salt and drying

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP06394796A 1995-03-03 1996-02-27 触媒の製造方法 Expired - Fee Related JP3786297B2 (ja)

Priority Applications (11)

Application Number Priority Date Filing Date Title
JP06394796A JP3786297B2 (ja) 1995-03-03 1996-02-27 触媒の製造方法
CN96190146A CN1087658C (zh) 1995-03-03 1996-03-01 催化剂和其制备方法
DE69636206T DE69636206T2 (de) 1995-03-03 1996-03-01 Verfahren zur Herstellung eines Katalysators
PCT/JP1996/000506 WO1996027437A1 (en) 1995-03-03 1996-03-01 Catalyst and process for producing the same
BR9605919A BR9605919A (pt) 1995-03-03 1996-03-01 Catalisadores e processos para sua preparação
MXPA/A/1996/005309A MXPA96005309A (es) 1995-03-03 1996-03-01 Catalizadores y proceso para la preparacion de los mismos
EP03020308A EP1375466A1 (en) 1995-03-03 1996-03-01 Multi metal oxide catalyst, process for preparing and use for the preparation of acrylic acid
EP96904311A EP0758562B1 (en) 1995-03-03 1996-03-01 Process for the preparation of a catalyst
US08/737,028 US5959143A (en) 1995-03-03 1996-03-01 Catalysts and process for the preparation thereof
MYPI96000770A MY113436A (en) 1995-03-03 1996-03-02 Catalysts and process for the preparation thereof
TW85102922A TW372888B (https=) 1995-03-03 1996-03-11

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP6895195 1995-03-03
JP7-68951 1995-03-03
JP06394796A JP3786297B2 (ja) 1995-03-03 1996-02-27 触媒の製造方法

Publications (2)

Publication Number Publication Date
JPH08299797A JPH08299797A (ja) 1996-11-19
JP3786297B2 true JP3786297B2 (ja) 2006-06-14

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Family Applications (1)

Application Number Title Priority Date Filing Date
JP06394796A Expired - Fee Related JP3786297B2 (ja) 1995-03-03 1996-02-27 触媒の製造方法

Country Status (9)

Country Link
US (1) US5959143A (https=)
EP (2) EP1375466A1 (https=)
JP (1) JP3786297B2 (https=)
CN (1) CN1087658C (https=)
BR (1) BR9605919A (https=)
DE (1) DE69636206T2 (https=)
MY (1) MY113436A (https=)
TW (1) TW372888B (https=)
WO (1) WO1996027437A1 (https=)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013084258A1 (en) * 2011-12-06 2013-06-13 Nippon Kayaku Kabushiki Kaisha Catalyst for the manufacturing of acrylic acid and a process for producing acrylic acid by using the catalyst
WO2018051933A1 (ja) 2016-09-14 2018-03-22 日本化薬株式会社 アクリル酸製造用触媒ならびにアクリル酸の製造方法

Families Citing this family (68)

* Cited by examiner, † Cited by third party
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DE19542755A1 (de) 1995-11-16 1997-05-22 Basf Ag Multimetalloxide
JP3537253B2 (ja) * 1996-03-06 2004-06-14 株式会社日本触媒 アクリル酸の製造方法
FR2760009A1 (fr) * 1997-02-27 1998-08-28 Atochem Elf Sa Procede de fabrication d'acide acrylique a partir de l'acroleine par reaction redox et l'utilisation d'une composition solide d'oxydes mixtes comme systeme redox dans ladite reaction
DE19815278A1 (de) * 1998-04-06 1999-10-07 Basf Ag Multimetalloxidmassen
DE19815281A1 (de) 1998-04-06 1999-10-07 Basf Ag Multimetalloxidmassen
DE19815280A1 (de) * 1998-04-06 1999-10-07 Basf Ag Multimetalloxidmassen
CN1166452C (zh) * 1998-08-28 2004-09-15 旭化成株式会社 从丙烷或异丁烷生产丙烯腈或甲基丙烯腈中所使用的氧化催化剂的制备方法
JP4247565B2 (ja) 1999-03-10 2009-04-02 東亞合成株式会社 アクリル酸製造用の触媒およびそれを用いたアクリル酸の製造方法
JP3883755B2 (ja) * 1999-09-17 2007-02-21 日本化薬株式会社 触媒の製造方法
US6762148B2 (en) 1999-09-17 2004-07-13 Nippon Kayaku Kabushiki Kaisha Catalyst process of making
US6444845B1 (en) 2000-04-28 2002-09-03 Saudia Basic Industries Corporation Process for the oxidation of unsaturated aldehydes to produce carboxylic acids using Mo-V based catalysts
US6531631B1 (en) 2000-04-28 2003-03-11 Saudi Basic Industries Corporation Oxidation of ethane to acetic acid and ethylene using molybdenum and vanadium based catalysts
CN1270824C (zh) * 2000-09-21 2006-08-23 日本化药株式会社 生产甲基丙烯酸的催化剂、涂层催化剂及其制造方法
DE10046928A1 (de) * 2000-09-21 2002-04-11 Basf Ag Verfahren zur Herstellung von Multimetalloxidmassen
TW583023B (en) * 2000-12-22 2004-04-11 Nippon Kayaku Kk Alkane oxidizing catalyst, method for producing the same and method for producing unsaturated oxygen-containing compound
ZA200200049B (en) 2001-01-25 2002-07-16 Nippon Catalytic Chem Ind Fixed-bed shell-and-tube reactor and its usage.
JP3892244B2 (ja) * 2001-03-21 2007-03-14 株式会社日本触媒 不飽和アルデヒドおよび不飽和カルボン酸製造用触媒の製造方法
JP5134745B2 (ja) * 2001-09-19 2013-01-30 株式会社日本触媒 アクリル酸の製造方法
US20040038820A1 (en) * 2002-08-20 2004-02-26 Nippon Shokubai Co., Ltd. Production process for catalyst
US7022643B2 (en) 2002-08-20 2006-04-04 Nippon Shokubai Co., Ltd. Production process for catalyst
US20060205978A1 (en) * 2002-08-20 2006-09-14 Nippon Shokubai Co., Ltd. Production process for catalyst
JP4253176B2 (ja) 2002-11-12 2009-04-08 株式会社日本触媒 アクリル酸製造用触媒およびアクリル酸の製造方法
JP4295521B2 (ja) * 2003-02-13 2009-07-15 株式会社日本触媒 アクリル酸製造用触媒およびアクリル酸の製造方法
US7524792B2 (en) * 2003-06-04 2009-04-28 Basf Aktiengesellschaft Preparation of catalytically active multielement oxide materials which contain at least one of the elements Nb and W and the elements Mo, V and Cu
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JP5006507B2 (ja) * 2004-01-30 2012-08-22 株式会社日本触媒 アクリル酸の製造方法
US7378367B2 (en) 2004-03-25 2008-05-27 Nippon Shokubai Co., Ltd. Catalyst for production of acrylic acid and process for production of acrylic acid using the catalyst
JP4442317B2 (ja) * 2004-05-21 2010-03-31 三菱化学株式会社 複合酸化物触媒の製造方法
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US8507626B2 (en) * 2007-06-13 2013-08-13 Nippon Shokubai Co., Ltd. Catalyst for producing of acrylic acid, method for producing acrylic acid using the catalyst and method for producing water-absorbent resin using the acrylic acid
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JP7347282B2 (ja) * 2020-03-18 2023-09-20 三菱ケミカル株式会社 不飽和カルボン酸合成用触媒の製造方法
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KR20230002897A (ko) * 2020-04-21 2023-01-05 바스프 에스이 원소 Mo, W, V 및 Cu를 함유하는 촉매 활성 다원소 산화물의 제조 방법
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JP7237268B1 (ja) * 2021-10-14 2023-03-10 日本化薬株式会社 不飽和カルボン酸製造用触媒およびその製造方法、並びに不飽和カルボン酸の製造方法
JP2025541831A (ja) 2022-12-07 2025-12-23 ベーアーエスエフ・エスエー 元素Mo、W、V、Cu、およびSbを含有する触媒活性多元素酸化物を製造するための方法
EP4640312A1 (en) 2022-12-20 2025-10-29 Nippon Kayaku Kabushiki Kaisha Catalyst and method for producing compound using same
JP7709611B2 (ja) 2023-03-23 2025-07-16 日本化薬株式会社 不飽和カルボン酸製造用触媒
WO2025057681A1 (ja) 2023-09-15 2025-03-20 日本化薬株式会社 不飽和カルボン酸製造用触媒および不飽和カルボン酸の製造方法
WO2025125092A1 (de) 2023-12-14 2025-06-19 Basf Se Verfahren zur herstellung eines die elemente mo, w, v, cu und sb enthaltenden katalytisch aktiven multielementoxids

Family Cites Families (25)

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WO2013084258A1 (en) * 2011-12-06 2013-06-13 Nippon Kayaku Kabushiki Kaisha Catalyst for the manufacturing of acrylic acid and a process for producing acrylic acid by using the catalyst
WO2013084500A3 (en) * 2011-12-06 2013-07-25 Nippon Kayaku Kabushiki Kaisha Catalyst for the manufacturing of acrylic acid and a process for producing acrylic acid by using the catalyst
WO2018051933A1 (ja) 2016-09-14 2018-03-22 日本化薬株式会社 アクリル酸製造用触媒ならびにアクリル酸の製造方法
KR20190046853A (ko) 2016-09-14 2019-05-07 닛뽄 가야쿠 가부시키가이샤 아크릴산 제조용 촉매 및 아크릴산의 제조 방법
US10940464B2 (en) 2016-09-14 2021-03-09 Nippon Kayaku Kabushiki Kaisha Catalyst for producing acrylic acid and method for producing acrylic acid

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MX198952B (https=) 2000-10-06
CN1148352A (zh) 1997-04-23
EP0758562A1 (en) 1997-02-19
US5959143A (en) 1999-09-28
DE69636206T2 (de) 2006-10-05
DE69636206D1 (de) 2006-07-20
EP1375466A1 (en) 2004-01-02
BR9605919A (pt) 1997-11-18
CN1087658C (zh) 2002-07-17
EP0758562B1 (en) 2006-06-07
MX9605309A (es) 1998-07-31
WO1996027437A1 (en) 1996-09-12
MY113436A (en) 2002-02-28
TW372888B (https=) 1999-11-01
JPH08299797A (ja) 1996-11-19

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