WO2013084500A3 - Catalyst for the manufacturing of acrylic acid and a process for producing acrylic acid by using the catalyst - Google Patents

Catalyst for the manufacturing of acrylic acid and a process for producing acrylic acid by using the catalyst Download PDF

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Publication number
WO2013084500A3
WO2013084500A3 PCT/JP2012/007834 JP2012007834W WO2013084500A3 WO 2013084500 A3 WO2013084500 A3 WO 2013084500A3 JP 2012007834 W JP2012007834 W JP 2012007834W WO 2013084500 A3 WO2013084500 A3 WO 2013084500A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
less
acrylic acid
group
producing
Prior art date
Application number
PCT/JP2012/007834
Other languages
French (fr)
Other versions
WO2013084500A2 (en
Inventor
Kimito Okumura
Yasushi Kobayashi
Original Assignee
Nippon Kayaku Kabushiki Kaisha
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Kayaku Kabushiki Kaisha filed Critical Nippon Kayaku Kabushiki Kaisha
Priority to JP2014525215A priority Critical patent/JP6067013B2/en
Publication of WO2013084500A2 publication Critical patent/WO2013084500A2/en
Publication of WO2013084500A3 publication Critical patent/WO2013084500A3/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0036—Grinding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

This invention provides a catalyst for producing unsaturated carboxylic acid from unsaturated aldehyde which is obtained by dehydration reaction of alcohol. In particular, this invention provides a catalyst for producing acrylic acid from acrolein obtained by dehydration reaction of glycerin. This invention provides also a process for producing unsaturated carboxylic acid, especially acrylic acid by using the catalyst. Catalyst used contains an active ingredient having a composition represented by following formula (1): Mo12 Va Wb Cuc Sbd Xe Yf Zg Oh (1), in which Mo, V, W, Cu, Sb and O represent respectively molybdenum, vanadium, tungsten, copper, antimony and oxygen, X is at least one element selected from a group comprising alkali metals and thallium, Y is at least one element selected from a group comprising magnesium, calcium, strontium, barium and zinc, Z is at least one element selected from a group comprising niobium, cerium, tin, chromium, manganese, iron, cobalt, samarium, germanium, titanium and arsenic, "a", "b", "c", "d", "e", "f", "g" and "h" each represents an atom ratio of element and satisfies following respective range when a value for molybdenum atom is considered as 12: "a" is greater than 0 but not greater than 10, "b" is not less than 0 but not greater than 10, "c" is greater than 0 but not greater than 6, "d" is greater than 0 but not greater than 10, "e" is not less than 0 but not greater than 0.5, "f" is not less than 0 but not greater than 1, "g" is not less than 0 but less than 6 and "h" is a number of oxygen atom required for satisfying the valences of above elements.
PCT/JP2012/007834 2011-12-06 2012-12-06 Catalyst for the manufacturing of acrylic acid and a process for producing acrylic acid by using the catalyst WO2013084500A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2014525215A JP6067013B2 (en) 2011-12-06 2012-12-06 Catalyst for producing acrylic acid and process for producing acrylic acid by using this catalyst

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
PCT/JP2011/006831 WO2013084258A1 (en) 2011-12-06 2011-12-06 Catalyst for the manufacturing of acrylic acid and a process for producing acrylic acid by using the catalyst
JPPCT/JP2011/006831 2011-12-06

Publications (2)

Publication Number Publication Date
WO2013084500A2 WO2013084500A2 (en) 2013-06-13
WO2013084500A3 true WO2013084500A3 (en) 2013-07-25

Family

ID=48573670

Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/JP2011/006831 WO2013084258A1 (en) 2011-12-06 2011-12-06 Catalyst for the manufacturing of acrylic acid and a process for producing acrylic acid by using the catalyst
PCT/JP2012/007834 WO2013084500A2 (en) 2011-12-06 2012-12-06 Catalyst for the manufacturing of acrylic acid and a process for producing acrylic acid by using the catalyst

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/JP2011/006831 WO2013084258A1 (en) 2011-12-06 2011-12-06 Catalyst for the manufacturing of acrylic acid and a process for producing acrylic acid by using the catalyst

Country Status (1)

Country Link
WO (2) WO2013084258A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104892382B (en) * 2015-05-28 2017-08-11 珠海凯美科技有限公司 The method that glycerine liquid phase oxidation prepares methacrylaldehyde
KR101960919B1 (en) * 2015-08-11 2019-03-22 주식회사 엘지화학 High performance poly-oxometalate catalyst and method for producing the same
KR102044428B1 (en) 2015-12-23 2019-12-02 주식회사 엘지화학 Process for preparing acrylic acid from glycerin
CN105598619B (en) * 2016-01-22 2017-09-19 哈尔滨工业大学（威海） Al in one kind welding artificial retina2O3The fixture of ceramics and titanacycle
JP6452169B2 (en) * 2016-09-14 2019-01-16 日本化薬株式会社 Catalyst for producing acrylic acid and method for producing acrylic acid
CN109305903A (en) * 2017-07-28 2019-02-05 中国石油化工股份有限公司 For producing acrylic acid
CN108421550B (en) * 2017-08-09 2020-07-31 上海华谊新材料有限公司 Catalyst for preparing acrylic acid by acrolein oxidation and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3786297B2 (en) * 1995-03-03 2006-06-14 日本化薬株式会社 Catalyst production method
JP3883755B2 (en) * 1999-09-17 2007-02-21 日本化薬株式会社 Catalyst production method
WO2010074177A1 (en) * 2008-12-26 2010-07-01 株式会社日本触媒 Method for producing acrylic acid
WO2011033689A1 (en) * 2009-09-18 2011-03-24 Nippon Kayaku Kabushiki Kaisha Catalyst and process for preparing acrolein and/or acrylic acid by dehydration reaction of glycerin
WO2011125623A1 (en) * 2010-03-31 2011-10-13 株式会社日本触媒 Glycerin dehydration catalyst, and acrolein production process, acrylic acid production process and hydrophilic resin production process each using the catalyst

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3786297B2 (en) * 1995-03-03 2006-06-14 日本化薬株式会社 Catalyst production method
JP3883755B2 (en) * 1999-09-17 2007-02-21 日本化薬株式会社 Catalyst production method
WO2010074177A1 (en) * 2008-12-26 2010-07-01 株式会社日本触媒 Method for producing acrylic acid
WO2011033689A1 (en) * 2009-09-18 2011-03-24 Nippon Kayaku Kabushiki Kaisha Catalyst and process for preparing acrolein and/or acrylic acid by dehydration reaction of glycerin
WO2011125623A1 (en) * 2010-03-31 2011-10-13 株式会社日本触媒 Glycerin dehydration catalyst, and acrolein production process, acrylic acid production process and hydrophilic resin production process each using the catalyst

Also Published As

Publication number Publication date
WO2013084258A1 (en) 2013-06-13
WO2013084500A2 (en) 2013-06-13

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