JP3547440B2 - ルイス酸緩和金属中心酸化による付加重合触媒の製法 - Google Patents

ルイス酸緩和金属中心酸化による付加重合触媒の製法 Download PDF

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Publication number
JP3547440B2
JP3547440B2 JP52102794A JP52102794A JP3547440B2 JP 3547440 B2 JP3547440 B2 JP 3547440B2 JP 52102794 A JP52102794 A JP 52102794A JP 52102794 A JP52102794 A JP 52102794A JP 3547440 B2 JP3547440 B2 JP 3547440B2
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group
cyclopentadienyl
borane
tris
lewis acid
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Expired - Fee Related
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JP52102794A
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English (en)
Japanese (ja)
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JPH07507099A (ja
Inventor
エヌ ニッキアス，ピーター
ジェイ チマース，フランシス
ディ デボア，デビッド
ケイ ローゼン，ロバート
ディ ミュセル，ロバート
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ダウ グローバル テクノロジーズ インコーポレーテッド
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
JP52102794A 1993-03-19 1994-02-10 ルイス酸緩和金属中心酸化による付加重合触媒の製法 Expired - Fee Related JP3547440B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US034,434 1993-03-19
US08/034,434 US5347024A (en) 1993-03-19 1993-03-19 Preparation of addition polymerization catalysts via Lewis acid mitigated metal center oxidation
PCT/US1994/001647 WO1994021693A1 (en) 1993-03-19 1994-02-10 Preparation of addition polymerization catalysts via lewis acid mitigated metal center oxidation

Publications (2)

Publication Number Publication Date
JPH07507099A JPH07507099A (ja) 1995-08-03
JP3547440B2 true JP3547440B2 (ja) 2004-07-28

Family

ID=21876391

Family Applications (1)

Application Number Title Priority Date Filing Date
JP52102794A Expired - Fee Related JP3547440B2 (ja) 1993-03-19 1994-02-10 ルイス酸緩和金属中心酸化による付加重合触媒の製法

Country Status (11)

Country Link
US (1) US5347024A (oth)
EP (1) EP0641360B1 (oth)
JP (1) JP3547440B2 (oth)
KR (1) KR950701651A (oth)
CA (1) CA2134890A1 (oth)
DE (1) DE69405952T2 (oth)
ES (1) ES2107201T3 (oth)
FI (1) FI945435A0 (oth)
NO (1) NO944420D0 (oth)
TW (1) TW273557B (oth)
WO (1) WO1994021693A1 (oth)

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US6111020A (en) * 1994-09-02 2000-08-29 The Dow Chemical Company Crosslinked foams from blends of ethylene vinyl acetate and ethylene-styrene interpolymers
FI104825B (fi) 1996-01-26 2000-04-14 Borealis As Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö
DE19622207A1 (de) * 1996-06-03 1997-12-04 Hoechst Ag Chemische Verbindung
US6066603A (en) * 1996-06-17 2000-05-23 Exxon Chemical Patents Inc. Polar monomer containing copolymers derived from olefins useful as lubricant and useful as lubricant and fuel oil additivies process for preparation of such copolymers and additives and use thereof
ES2158567T3 (es) 1996-06-17 2001-09-01 Exxonmobil Chem Patents Inc Sistemas cataliticos de metales de transicion mixtos para la polimerizacion de olefinas.
US5811379A (en) * 1996-06-17 1998-09-22 Exxon Chemical Patents Inc. Polymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such polymers and additives and use thereof (PT-1267)
US5939503A (en) * 1996-08-09 1999-08-17 California Institute Of Technology Group IV zwitterion ansa metallocene (ZAM) catalysts for α-olefin polymerization
DE59703850D1 (de) * 1996-08-13 2001-07-26 Basell Polyolefine Gmbh Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
ATE325821T1 (de) 1996-08-13 2006-06-15 Basell Polyolefine Gmbh Geträgerte chemische verbindung
ZA977909B (en) 1996-09-04 1999-03-03 Dow Chemical Co Compositions comprising a substantially random interpolymer of at least one alpha-olefin and at least one vinylidene aromatic monomer or hindered aliphatic vinylidene monomer
CA2264821A1 (en) 1996-09-04 1998-03-12 The Dow Chemical Company Floor, wall or ceiling covering
US6319969B1 (en) 1997-06-26 2001-11-20 The Dow Chemical Company Interpolymer compositions for use in sound management
US6262161B1 (en) 1997-06-26 2001-07-17 The Dow Chemical Company Compositions having improved ignition resistance
US6172015B1 (en) 1997-07-21 2001-01-09 Exxon Chemical Patents, Inc Polar monomer containing copolymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such copolymers and additives and use thereof
JP2001520291A (ja) 1997-10-17 2001-10-30 ザ ダウ ケミカル カンパニー アルファ−オレフィンモノマーと１種以上のビニルもしくはビニリデン芳香族モノマーから作られたインターポリマー類の組成物
US6329450B1 (en) 1998-03-11 2001-12-11 The Dow Chemical Company Thermoplastic compositions of interpolymers of alpha-olefin monomers with one or more vinyl or vinylidene aromatic monomers and/or one or more hindered aliphatic or cycloaliphatic vinyl or vinylidene monomers blended with engineering thermoplastics
US6403773B1 (en) 1998-09-30 2002-06-11 Exxon Mobil Chemical Patents Inc. Cationic group 3 catalyst system
US5993707A (en) * 1998-12-04 1999-11-30 The Dow Chemical Company Enlarged cell size foams made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers
US6048909A (en) * 1998-12-04 2000-04-11 The Dow Chemical Company Foams having increased heat distortion temperature made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers
US6231795B1 (en) 1998-12-04 2001-05-15 The Dow Chemical Company Soft and flexible foams made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers
US6187232B1 (en) * 1998-12-04 2001-02-13 The Dow Chemical Company Acoustical insulation foams
KR20010093810A (ko) 1998-12-08 2001-10-29 그래햄 이. 테일러 용융결합가능한 폴리프로필렌/에틸렌 중합체 섬유 및 이를제조하기 위한 조성물
US6331597B1 (en) 1999-08-09 2001-12-18 The Dow Chemical Company Azidosilane-modified, moisture-curable polyolefin polymers, process for making, and articles obtained therefrom
US6362270B1 (en) 1999-08-12 2002-03-26 The Dow Chemical Company Thermoplastic compositions for durable goods applications
US6524702B1 (en) 1999-08-12 2003-02-25 Dow Global Technologies Inc. Electrical devices having polymeric members
KR20020025974A (ko) 1999-08-17 2002-04-04 그래햄 이. 테일러 자유 유동성 중합체 조성물
US6239062B1 (en) 1999-09-02 2001-05-29 Equistar Chemicals, L.P. Olefin polymerization catalysts containing indolyl-amido ligands
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US6160029A (en) * 2000-03-08 2000-12-12 The Dow Chemical Company Olefin polymer and α-olefin/vinyl or α-olefin/vinylidene interpolymer blend foams
US6649671B2 (en) 2000-03-13 2003-11-18 Dow Global Technologies Inc. Concrete and process to make same
KR20030028805A (ko) 2000-07-20 2003-04-10 다우 글로벌 테크놀로지스 인크. 알케닐 방향족 중합체와 알파-올레핀/비닐 또는 비닐리덴방향족 인터폴리머와의 블렌드로부터의 발포체 조성물
AU2002244184A1 (en) * 2001-02-27 2002-09-12 Dow Global Technologies Inc. Fabricated articles prepared from blends of substantially random ethylene/propylene/vinyl aromatic interpolymers with polypropylene
US6953501B2 (en) 2001-08-10 2005-10-11 Inventions & Discoveries, Llc Wood treatment composition and method of use
US20040106739A1 (en) * 2002-02-19 2004-06-03 Cheung Yunwa Wilson Blends of substantially random interpolymers with enhanced thermal performance
DE102007057854A1 (de) * 2007-11-28 2009-06-04 Philipps-Universität Marburg Cyclopentadienylphosphazen-Komplexe (CpPN-Komplexe) von Metallen der 3. und 4. Gruppe und der Lanthanoide
EP3774934A1 (en) 2018-03-30 2021-02-17 Dow Global Technologies LLC Highly soluble bis-borate as binuclear co-catalysts for olefin polymerizations
SG11202008656PA (en) 2018-03-30 2020-10-29 Dow Global Technologies Llc Olefin polymerization activators
ES2932265T3 (es) 2018-03-30 2023-01-17 Dow Global Technologies Llc Activadores de polimerización de olefinas binucleares
CN112074549B (zh) 2018-03-30 2023-06-23 陶氏环球技术有限责任公司 烯烃聚合活化剂
US11787880B2 (en) 2018-03-30 2023-10-17 Dow Global Technologies Llc Highly soluble alkyl substituted carbenium borate as co-catalysts for olefin polymerizations

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US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US5189192A (en) * 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation

Also Published As

Publication number Publication date
US5347024A (en) 1994-09-13
DE69405952T2 (de) 1998-04-16
HK1003598A1 (en) 1998-10-30
DE69405952D1 (de) 1997-11-06
FI945435A7 (fi) 1994-11-18
CA2134890A1 (en) 1994-09-29
EP0641360A1 (en) 1995-03-08
ES2107201T3 (es) 1997-11-16
FI945435L (fi) 1994-11-18
NO944420L (no) 1994-11-18
EP0641360B1 (en) 1997-10-01
KR950701651A (ko) 1995-04-28
TW273557B (oth) 1996-04-01
NO944420D0 (no) 1994-11-18
WO1994021693A1 (en) 1994-09-29
JPH07507099A (ja) 1995-08-03
FI945435A0 (fi) 1994-11-18

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