JP3275211B2 - 付加重合触媒の製造方法 - Google Patents
付加重合触媒の製造方法Info
- Publication number
- JP3275211B2 JP3275211B2 JP16522892A JP16522892A JP3275211B2 JP 3275211 B2 JP3275211 B2 JP 3275211B2 JP 16522892 A JP16522892 A JP 16522892A JP 16522892 A JP16522892 A JP 16522892A JP 3275211 B2 JP3275211 B2 JP 3275211B2
- Authority
- JP
- Japan
- Prior art keywords
- metal
- group
- cyclopentadienyl
- periodic table
- hydrogen atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/28—Titanium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US70247591A | 1991-05-20 | 1991-05-20 | |
| US702,475 | 1991-05-20 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05230123A JPH05230123A (ja) | 1993-09-07 |
| JP3275211B2 true JP3275211B2 (ja) | 2002-04-15 |
Family
ID=24821367
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16522892A Expired - Lifetime JP3275211B2 (ja) | 1991-05-20 | 1992-05-14 | 付加重合触媒の製造方法 |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0514828B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP3275211B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR100231947B1 (cg-RX-API-DMAC7.html) |
| BR (1) | BR9201964A (cg-RX-API-DMAC7.html) |
| CA (1) | CA2068938C (cg-RX-API-DMAC7.html) |
| DE (1) | DE69222974T2 (cg-RX-API-DMAC7.html) |
| ES (1) | ES2108714T3 (cg-RX-API-DMAC7.html) |
| FI (1) | FI109423B (cg-RX-API-DMAC7.html) |
| TW (1) | TW239865B (cg-RX-API-DMAC7.html) |
Families Citing this family (80)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5264405A (en) | 1989-09-13 | 1993-11-23 | Exxon Chemical Patents Inc. | Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin-copolymer production catalysts |
| USRE37788E1 (en) * | 1987-01-30 | 2002-07-09 | Exxon Chemical Patents, Inc. | Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts |
| US5621126A (en) | 1987-01-30 | 1997-04-15 | Exxon Chemical Patents Inc. | Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts |
| US5763547A (en) * | 1992-10-02 | 1998-06-09 | The Dow Chemical Company | Supported catalyst complexes for olefin in polymerization |
| US5278272A (en) | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
| US6545088B1 (en) | 1991-12-30 | 2003-04-08 | Dow Global Technologies Inc. | Metallocene-catalyzed process for the manufacture of EP and EPDM polymers |
| US5455333A (en) * | 1993-08-16 | 1995-10-03 | Albemarle Corporation | Preparation of metallocenes |
| US5359105A (en) * | 1993-11-01 | 1994-10-25 | Albemarle Corporation | Deprotonation of cyclopentadienyl derivatives |
| US5504223A (en) * | 1994-01-25 | 1996-04-02 | The Dow Chemical Company | Synthesis of cyclopentadienyl metal coordination complexes from metal hydrocarbyloxides |
| US5504224A (en) * | 1994-03-14 | 1996-04-02 | The Dow Chemical Company | Preparation of monocyclopentadienyl metal complexes by nucleophilic substitution of bis(cyclopentadienyl) metal complexes |
| US5486632A (en) * | 1994-06-28 | 1996-01-23 | The Dow Chemical Company | Group 4 metal diene complexes and addition polymerization catalysts therefrom |
| US6111020A (en) * | 1994-09-02 | 2000-08-29 | The Dow Chemical Company | Crosslinked foams from blends of ethylene vinyl acetate and ethylene-styrene interpolymers |
| US5541349A (en) * | 1994-09-12 | 1996-07-30 | The Dow Chemical Company | Metal complexes containing partially delocalized II-bound groups and addition polymerization catalysts therefrom |
| US5495036A (en) * | 1994-09-12 | 1996-02-27 | The Dow Chemical Company | Metal (III) complexes containing conjugated, non-aromatic anionic II-bound groups and addition polymerization catalysts therefrom |
| US7153909B2 (en) | 1994-11-17 | 2006-12-26 | Dow Global Technologies Inc. | High density ethylene homopolymers and blend compositions |
| DE69520449T2 (de) | 1994-12-13 | 2001-11-08 | Asahi Kasei K.K., Osaka | Olefinpolymerisationskatalysator |
| US6194341B1 (en) | 1996-06-17 | 2001-02-27 | Exxon Chemical Patents Inc. | Mixed transition metal catalyst systems for olefin polymerization |
| DE19624581C2 (de) | 1996-06-20 | 1999-02-04 | Targor Gmbh | Übergangsmetallverbindung und ein Verfahren zu ihrer Herstellung, sowie ihre Verwendung |
| DE69717645T2 (de) * | 1996-07-22 | 2003-09-25 | Dow Global Technologies, Inc. | Verbrückte nicht-aromatische anionische dienylgruppen enthaltende metallkomplexe und darauf basierte polymerisatonskatalysatoren |
| KR100466733B1 (ko) * | 1996-07-23 | 2005-01-24 | 다우 글로벌 테크놀로지스 인크. | 13족 화합물을 포함하는 올레핀 중합 촉매 조성물 |
| EP0923589B1 (en) | 1996-08-08 | 2004-09-15 | Dow Global Technologies Inc. | 3-heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process |
| AU712414B2 (en) | 1996-09-04 | 1999-11-04 | Dow Chemical Company, The | Floor, wall or ceiling covering |
| TW412560B (en) | 1996-09-04 | 2000-11-21 | Dow Chemical Co | Compositions and adhesives comprising a substantially random interpolymer of at least one vinylidene and at least one vinylidene aromatic monomer or hindered aliphatic vinylidene monomer, and coextruded or laminated multilayer film and tape |
| US6015868A (en) * | 1996-10-03 | 2000-01-18 | The Dow Chemical Company | Substituted indenyl containing metal complexes and olefin polymerization process |
| US6812289B2 (en) | 1996-12-12 | 2004-11-02 | Dow Global Technologies Inc. | Cast stretch film of interpolymer compositions |
| AR012582A1 (es) | 1997-04-14 | 2000-11-08 | Dow Global Technologies Inc | Composiciones polimericas de elongacion mejorada y formulaciones adhesivas de fusion en caliente que incluyen dicha composicion |
| US6420507B1 (en) | 1997-05-01 | 2002-07-16 | The Dow Chemical Company | Olefin polymers prepared with substituted indenyl containing metal complexes |
| JPH1112289A (ja) * | 1997-06-19 | 1999-01-19 | Sumitomo Chem Co Ltd | 架橋型遷移金属錯体の製造方法 |
| KR20010022700A (ko) | 1997-08-08 | 2001-03-26 | 그래햄 이. 테일러 | 바닥, 벽 또는 천장 피복재로 사용하기에 적합한 시이트재, 및 그를 제조하기 위한 방법 및 중간체 |
| US6921794B2 (en) | 1997-08-12 | 2005-07-26 | Exxonmobil Chemical Patents Inc. | Blends made from propylene ethylene polymers |
| US6635715B1 (en) | 1997-08-12 | 2003-10-21 | Sudhin Datta | Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers |
| US7232871B2 (en) | 1997-08-12 | 2007-06-19 | Exxonmobil Chemical Patents Inc. | Propylene ethylene polymers and production process |
| CA2297135C (en) | 1997-08-15 | 2010-08-24 | The Dow Chemical Company | Films produced from substantially linear homogeneous olefin polymer compositions |
| KR20010023332A (ko) | 1997-08-27 | 2001-03-26 | 그래햄 이. 테일러 | 가공성이 개선된 탄성중합체 |
| US6380294B1 (en) | 1997-10-17 | 2002-04-30 | The Dow Chemical Company | COMPOSITIONS OF INTERPOLYMERS OF α-OLEFIN MONOMERS WITH ONE OR MORE VINYL OR VINYLIDENE AROMATIC MONOMERS AND/OR ONE OR MORE HINDERED ALIPHATIC OR CYCLOALIPHATIC VINYL OR VINYLIDENE MONOMERS BLENDED WITH A CONDUCTIVE ADDITIVE |
| US6699573B1 (en) | 1998-03-16 | 2004-03-02 | Dow Global Technologies Inc. | Liner compositions |
| JP2002519497A (ja) | 1998-07-01 | 2002-07-02 | エクソンモービル・ケミカル・パテンツ・インク | 結晶性プロピレンポリマーと結晶化可能プロピレンポリマーとを含んでなる弾性ブレンド |
| UA57864C2 (uk) * | 1998-10-08 | 2003-07-15 | Бп Кемікалз Лімітед | Спосіб полімеризації олефінів з використанням місточкових металевих комплексів |
| MXPA01004337A (es) | 1998-11-02 | 2002-04-24 | Pont Dow Elastomers L L C Du | Interpolimeros de alfa-olefina/etileno que disminuyen el esfuerzo cortante. |
| US6187232B1 (en) | 1998-12-04 | 2001-02-13 | The Dow Chemical Company | Acoustical insulation foams |
| US5993707A (en) * | 1998-12-04 | 1999-11-30 | The Dow Chemical Company | Enlarged cell size foams made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers |
| US6231795B1 (en) | 1998-12-04 | 2001-05-15 | The Dow Chemical Company | Soft and flexible foams made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers |
| US6048909A (en) * | 1998-12-04 | 2000-04-11 | The Dow Chemical Company | Foams having increased heat distortion temperature made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers |
| JP2002531721A (ja) | 1998-12-08 | 2002-09-24 | ザ ダウ ケミカル カンパニー | 熔融接合可能なポリプロピレン/エチレン重合体の繊維および該繊維製造用組成物 |
| US6617407B1 (en) | 1999-04-29 | 2003-09-09 | The Dow Chemical Company | Bis(n,n-dihydrocarbylamino)-substituted cyclopentadienes and metal complexes thereof |
| US6555634B1 (en) | 1999-05-13 | 2003-04-29 | The Dow Chemical Company | Di- and tri-heteroatom substituted indenyl metal complexes |
| JP2002544281A (ja) | 1999-05-13 | 2002-12-24 | ザ ダウ ケミカル カンパニー | オレフィン重合法用の橋かけ性ヘテロ原子含有金属錯体 |
| US6420299B1 (en) | 1999-06-04 | 2002-07-16 | Dow Global Technologies Inc. | Boron-substituted cyclopentadienes and metal complexes thereof |
| US6331597B1 (en) | 1999-08-09 | 2001-12-18 | The Dow Chemical Company | Azidosilane-modified, moisture-curable polyolefin polymers, process for making, and articles obtained therefrom |
| WO2001012716A2 (en) | 1999-08-17 | 2001-02-22 | The Dow Chemical Company | Free-flowing polymer composition |
| US6369176B1 (en) | 1999-08-19 | 2002-04-09 | Dupont Dow Elastomers Llc | Process for preparing in a single reactor polymer blends having a broad molecular weight distribution |
| WO2001051547A1 (en) | 2000-01-07 | 2001-07-19 | Dow Global Technologies Inc. | Thermoformable ethylene/styrene interpolymer-based polymer blend film for three-dimensional transfer finish foil |
| US6160029A (en) * | 2000-03-08 | 2000-12-12 | The Dow Chemical Company | Olefin polymer and α-olefin/vinyl or α-olefin/vinylidene interpolymer blend foams |
| US6649671B2 (en) | 2000-03-13 | 2003-11-18 | Dow Global Technologies Inc. | Concrete and process to make same |
| EP1305364A1 (en) | 2000-07-20 | 2003-05-02 | Dow Global Technologies Inc. | Foam compositions from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic interpolymers |
| US6559230B2 (en) | 2000-09-29 | 2003-05-06 | Dupont Dow Elastomers L.L.C. | Thermosetting ethylene/alpha-olefin composition and safety glass interlayer film made from the composition |
| ATE485319T1 (de) | 2001-04-12 | 2010-11-15 | Exxonmobil Chem Patents Inc | Verfahren zur polymerisation von propylen und ethylen in lösung |
| KR20040023813A (ko) | 2001-07-25 | 2004-03-19 | 피렐리 뉴아티씨 소시에떼 퍼 아찌오니 | 엘라스토머 혼합물의 연속제조 공정 및 장치 |
| US6953501B2 (en) | 2001-08-10 | 2005-10-11 | Inventions & Discoveries, Llc | Wood treatment composition and method of use |
| MY139205A (en) | 2001-08-31 | 2009-08-28 | Pennzoil Quaker State Co | Synthesis of poly-alpha olefin and use thereof |
| JP2005508415A (ja) | 2001-11-06 | 2005-03-31 | ダウ グローバル テクノロジーズ インコーポレイティド | アイソタクチックプロピレンコポリマー類、その製法および用途 |
| US6927256B2 (en) | 2001-11-06 | 2005-08-09 | Dow Global Technologies Inc. | Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent |
| US6906160B2 (en) | 2001-11-06 | 2005-06-14 | Dow Global Technologies Inc. | Isotactic propylene copolymer fibers, their preparation and use |
| US7964128B2 (en) | 2001-12-19 | 2011-06-21 | Pirelli Pneumatici S.P.A. | Process and apparatus for continuously producing an elastomeric composition |
| US8236215B2 (en) | 2002-07-11 | 2012-08-07 | Pirelli Pneumatici S.P.A. | Process and apparatus for continuously producing an elastomeric composition |
| US7795365B2 (en) | 2002-10-02 | 2010-09-14 | Dow Global Technologies Inc. | Liquid and gel-like low molecular weight ethylene polymers |
| ATE402222T1 (de) | 2002-10-17 | 2008-08-15 | Dow Global Technologies Inc | Hochgefüllte polymerzusammensetzungen |
| WO2004037739A1 (en) | 2002-10-23 | 2004-05-06 | Pirelli & C. S.P.A. | Optical fiber with thermoplastic material based coating |
| US7579407B2 (en) | 2002-11-05 | 2009-08-25 | Dow Global Technologies Inc. | Thermoplastic elastomer compositions |
| US7459500B2 (en) | 2002-11-05 | 2008-12-02 | Dow Global Technologies Inc. | Thermoplastic elastomer compositions |
| CN100509872C (zh) | 2002-12-13 | 2009-07-08 | 陶氏环球技术公司 | 含有13族氨化物衍生物的烯烃聚合催化剂组合物 |
| US7084219B2 (en) * | 2003-03-25 | 2006-08-01 | Sumitomo Chemical Company, Limited | Contact product, and catalyst component and catalyst for addition polymerization, and process for producing addition polymer |
| ES2337936T3 (es) | 2003-08-19 | 2010-04-30 | Dow Global Technologies Inc. | Interpolimeros adecuados para usar en colas termoplasticas y procesos para prepararlos. |
| EP1805229A1 (en) | 2004-10-28 | 2007-07-11 | Dow Gloval Technologies Inc. | Method of controlling a polymerization reactor |
| MY148274A (en) | 2005-07-08 | 2013-03-29 | Dow Global Technologies Inc | Layered film compositions, packages prepared therefrom, and methods of use |
| KR101369090B1 (ko) | 2005-07-11 | 2014-03-06 | 다우 글로벌 테크놀로지스 엘엘씨 | 실란 그래프팅된 올레핀 중합체, 그로부터 제조된 조성물및 물품, 및 그의 제조 방법 |
| EP2363420B1 (en) | 2006-06-15 | 2012-12-12 | Dow Global Technologies LLC | Functionalized olefin interpolymers, compositions and articles prepared therefrom, and methods for making the same |
| EP2250146B1 (en) * | 2008-02-29 | 2014-05-07 | Albemarle Corporation | Processes for producing transition metal amido and imido compounds |
| JP5667701B2 (ja) | 2010-11-24 | 2015-02-12 | エクソンモービル アジア パシフィック リサーチ アンド デベロップメント カンパニー リミテッド | フィラー高充填ポリマー組成物 |
| US8841379B2 (en) | 2011-11-07 | 2014-09-23 | E I Du Pont De Nemours And Company | Method to form an aqueous dispersion of an ionomer-polyolefin blend |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5055438A (en) * | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
| NZ235032A (en) * | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
| US5064802A (en) * | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
-
1992
- 1992-05-14 JP JP16522892A patent/JP3275211B2/ja not_active Expired - Lifetime
- 1992-05-19 DE DE69222974T patent/DE69222974T2/de not_active Expired - Lifetime
- 1992-05-19 EP EP92108417A patent/EP0514828B1/en not_active Expired - Lifetime
- 1992-05-19 TW TW081103906A patent/TW239865B/zh not_active IP Right Cessation
- 1992-05-19 CA CA002068938A patent/CA2068938C/en not_active Expired - Lifetime
- 1992-05-19 BR BR929201964A patent/BR9201964A/pt not_active IP Right Cessation
- 1992-05-19 ES ES92108417T patent/ES2108714T3/es not_active Expired - Lifetime
- 1992-05-19 FI FI922273A patent/FI109423B/fi not_active IP Right Cessation
- 1992-05-19 KR KR1019920008445A patent/KR100231947B1/ko not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CA2068938C (en) | 2003-01-07 |
| CA2068938A1 (en) | 1992-11-21 |
| EP0514828A1 (en) | 1992-11-25 |
| TW239865B (cg-RX-API-DMAC7.html) | 1995-02-01 |
| KR100231947B1 (ko) | 1999-12-01 |
| FI922273A0 (fi) | 1992-05-19 |
| EP0514828B1 (en) | 1997-11-05 |
| ES2108714T3 (es) | 1998-01-01 |
| FI922273A7 (fi) | 1992-11-21 |
| BR9201964A (pt) | 1993-01-05 |
| KR920021588A (ko) | 1992-12-18 |
| JPH05230123A (ja) | 1993-09-07 |
| DE69222974T2 (de) | 1998-03-05 |
| DE69222974D1 (de) | 1997-12-11 |
| FI109423B (fi) | 2002-07-31 |
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