JP2020515687A - 高ビニル芳香性および低ビニル含有量を有するビニル芳香族モノマーと共役ジエンモノマーとのコポリマーの合成のための極性添加剤 - Google Patents

高ビニル芳香性および低ビニル含有量を有するビニル芳香族モノマーと共役ジエンモノマーとのコポリマーの合成のための極性添加剤 Download PDF

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Publication number
JP2020515687A
JP2020515687A JP2019553501A JP2019553501A JP2020515687A JP 2020515687 A JP2020515687 A JP 2020515687A JP 2019553501 A JP2019553501 A JP 2019553501A JP 2019553501 A JP2019553501 A JP 2019553501A JP 2020515687 A JP2020515687 A JP 2020515687A
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Japan
Prior art keywords
rubber
weight percent
copolymer
vinyl aromatic
content
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Pending
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JP2019553501A
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English (en)
Japanese (ja)
Inventor
コザック、ラドスワフ
ボガチュ、ロベルト
ワレニア、マルゴルザータ
ヴェダ、パヴェウ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Synthos SA
Synthos Styrenics Synthos Dwory 2 Sp zoo
Original Assignee
Synthos SA
Synthos Styrenics Synthos Dwory 2 Sp zoo
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Application filed by Synthos SA, Synthos Styrenics Synthos Dwory 2 Sp zoo filed Critical Synthos SA
Publication of JP2020515687A publication Critical patent/JP2020515687A/ja
Priority to JP2023010231A priority Critical patent/JP7667190B2/ja
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0016—Compositions of the tread
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • C08F4/48—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00—Compositions of unspecified rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00—Compositions of natural rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06—Copolymers with styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages

Landscapes

  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Tires In General (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
JP2019553501A 2017-03-29 2018-03-28 高ビニル芳香性および低ビニル含有量を有するビニル芳香族モノマーと共役ジエンモノマーとのコポリマーの合成のための極性添加剤 Pending JP2020515687A (ja)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2023010231A JP7667190B2 (ja) 2017-03-29 2023-01-26 高ビニル芳香性および低ビニル含有量を有するビニル芳香族モノマーと共役ジエンモノマーとのコポリマーの合成のための極性添加剤

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP17461514.6 2017-03-29
EP17461514 2017-03-29
PCT/EP2018/058014 WO2018178199A1 (en) 2017-03-29 2018-03-28 Polar additive for the synthesis of copolymers of vinylaromatic monomer and conjugated diene monomer having high vinylaromatic and low vinyl contents

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2023010231A Division JP7667190B2 (ja) 2017-03-29 2023-01-26 高ビニル芳香性および低ビニル含有量を有するビニル芳香族モノマーと共役ジエンモノマーとのコポリマーの合成のための極性添加剤

Publications (1)

Publication Number Publication Date
JP2020515687A true JP2020515687A (ja) 2020-05-28

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JP2019553501A Pending JP2020515687A (ja) 2017-03-29 2018-03-28 高ビニル芳香性および低ビニル含有量を有するビニル芳香族モノマーと共役ジエンモノマーとのコポリマーの合成のための極性添加剤
JP2023010231A Active JP7667190B2 (ja) 2017-03-29 2023-01-26 高ビニル芳香性および低ビニル含有量を有するビニル芳香族モノマーと共役ジエンモノマーとのコポリマーの合成のための極性添加剤

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Country Status (9)

Country Link
US (1) US11525049B2 (enExample)
EP (1) EP3601389B1 (enExample)
JP (2) JP2020515687A (enExample)
KR (1) KR102574992B1 (enExample)
CN (1) CN110678492A (enExample)
BR (1) BR112019020104A2 (enExample)
EA (1) EA201992291A1 (enExample)
PL (1) PL3601389T3 (enExample)
WO (1) WO2018178199A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2023063188A1 (enExample) * 2021-10-11 2023-04-20

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3498960A (en) * 1967-09-28 1970-03-03 Phillips Petroleum Co Production of random copolymers in organolithium polymerization systems
JPS61268710A (ja) * 1985-01-16 1986-11-28 Nippon Erasutomaa Kk タイヤ用ゴム組成物

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US3558575A (en) 1966-10-03 1971-01-26 Firestone Tire & Rubber Co Process for the production of copolymers free of block polystyrene
US3787377A (en) 1971-12-16 1974-01-22 Firestone Tire & Rubber Co Continuous process of copolymerizing butadiene and styrene
JPH0627122B2 (ja) * 1984-04-09 1994-04-13 日本エラストマ−株式会社 高スチレン含量のランダムスチレン−ブタジエン共重合体ゴム
DE69712962T2 (de) 1996-03-29 2002-11-14 Bridgestone Corp., Tokio/Tokyo Styrol-Butadien-Copolymer und dieses Copolymer enthaltende Gummimischung
DE19914075A1 (de) 1999-03-27 2000-09-28 Basf Ag Glasklares, schlagzähes Polystyrol auf Basis von Styrol-Butadien-Blockcopolymeren
US6372863B1 (en) 1999-08-12 2002-04-16 The Goodyear Tire & Rubber Company Synthesis of styrene-butadiene rubber
US6583244B1 (en) 2001-10-31 2003-06-24 The Goodyear Tire & Rubber Company Synthesis of rubber having a low vinyl content
JP5545800B2 (ja) 2009-06-08 2014-07-09 住友化学株式会社 噴流−流動層型オレフィン重合反応装置、ポリオレフィン製造システム、及び、ポリオレフィン製造方法
TW201211083A (en) * 2010-06-15 2012-03-16 Styron Europe Gmbh Low vinyl styrene-butadiene polymers and methods of making the same
CN101906187B (zh) * 2010-07-26 2012-05-16 中国科学院长春应用化学研究所 限制几何构型稀土配合物在高选择性共轭双烯烃-苯乙烯无规或嵌段共聚合中的应用
EP2537871B1 (en) 2011-06-22 2018-10-17 Trinseo Europe GmbH High styrene high vinyl styrene-butadiene rubber with narrow molecular weight distribution and methods for preparation thereof
HUE031642T2 (en) * 2011-03-04 2017-07-28 Trinseo Europe Gmbh Styrene-butadiene rubber with high styrene and high vinyl content and methods for its production
EP2495266A1 (en) * 2011-03-04 2012-09-05 Styron Deutschland GmbH High styrene high vinyl styrene-butadiene rubber and methods for preparation thereof
ES2545332T3 (es) 2011-06-22 2015-09-10 Trinseo Europe Gmbh Caucho de estireno-butadieno de alto contenido en estireno, alto contenido en vinilo, con distribución de pesos moleculares estrecha y métodos para la preparación de los mismos
CN103374101B (zh) * 2012-04-18 2015-11-25 中国石油化工股份有限公司 一种无规剂和丁苯橡胶的制备方法
US9458362B2 (en) * 2014-04-02 2016-10-04 Kraton Polymers U.S. Llc Adhesive compositions containing a block copolymer with polymyrcene

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3498960A (en) * 1967-09-28 1970-03-03 Phillips Petroleum Co Production of random copolymers in organolithium polymerization systems
JPS61268710A (ja) * 1985-01-16 1986-11-28 Nippon Erasutomaa Kk タイヤ用ゴム組成物

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2023063188A1 (enExample) * 2021-10-11 2023-04-20

Also Published As

Publication number Publication date
US11525049B2 (en) 2022-12-13
JP2023052652A (ja) 2023-04-11
WO2018178199A1 (en) 2018-10-04
KR102574992B1 (ko) 2023-09-05
JP7667190B2 (ja) 2025-04-22
EP3601389B1 (en) 2021-11-17
KR20190130011A (ko) 2019-11-20
PL3601389T3 (pl) 2022-02-07
EA201992291A1 (ru) 2020-02-28
BR112019020104A2 (pt) 2020-05-05
CN110678492A (zh) 2020-01-10
EP3601389A1 (en) 2020-02-05
US20200255625A1 (en) 2020-08-13

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