PL3601389T3 - Dodatek polarny do syntezy kopolimerów monomeru winyloaromatycznego i monomeru sprzężonego dienu o wysokiej zawartości składnika winyloaromatycznego i niskiej zawartości składnika winylowego - Google Patents

Dodatek polarny do syntezy kopolimerów monomeru winyloaromatycznego i monomeru sprzężonego dienu o wysokiej zawartości składnika winyloaromatycznego i niskiej zawartości składnika winylowego

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Publication number
PL3601389T3
PL3601389T3 PL18716170T PL18716170T PL3601389T3 PL 3601389 T3 PL3601389 T3 PL 3601389T3 PL 18716170 T PL18716170 T PL 18716170T PL 18716170 T PL18716170 T PL 18716170T PL 3601389 T3 PL3601389 T3 PL 3601389T3
Authority
PL
Poland
Prior art keywords
vinylaromatic
monomer
copolymers
synthesis
conjugated diene
Prior art date
Application number
PL18716170T
Other languages
English (en)
Polish (pl)
Inventor
Radosław Kozak
Robert BOGACZ
Małgorzata Walenia
Paweł Weda
Original Assignee
Synthos S.A.
Synthos Dwory 7 spółka z ograniczoną odpowiedzialnością spółka jawna
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Synthos S.A., Synthos Dwory 7 spółka z ograniczoną odpowiedzialnością spółka jawna filed Critical Synthos S.A.
Publication of PL3601389T3 publication Critical patent/PL3601389T3/pl

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477Six-membered rings
    • C08K5/3492Triazines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0016Compositions of the tread
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/04Polymerisation in solution
    • C08F2/06Organic solvent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02Monomers containing only one unsaturated aliphatic radical
    • C08F212/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06Hydrocarbons
    • C08F212/08Styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06Butadiene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • C08F4/48Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00Compositions of unspecified rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06Copolymers with styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01Additive used together with the catalyst, excluding compounds containing Al or B
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Tires In General (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
PL18716170T 2017-03-29 2018-03-28 Dodatek polarny do syntezy kopolimerów monomeru winyloaromatycznego i monomeru sprzężonego dienu o wysokiej zawartości składnika winyloaromatycznego i niskiej zawartości składnika winylowego PL3601389T3 (pl)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP17461514 2017-03-29
PCT/EP2018/058014 WO2018178199A1 (en) 2017-03-29 2018-03-28 Polar additive for the synthesis of copolymers of vinylaromatic monomer and conjugated diene monomer having high vinylaromatic and low vinyl contents
EP18716170.8A EP3601389B1 (en) 2017-03-29 2018-03-28 Polar additive for the synthesis of copolymers of vinylaromatic monomer and conjugated diene monomer having high vinylaromatic and low vinyl contents

Publications (1)

Publication Number Publication Date
PL3601389T3 true PL3601389T3 (pl) 2022-02-07

Family

ID=58461256

Family Applications (1)

Application Number Title Priority Date Filing Date
PL18716170T PL3601389T3 (pl) 2017-03-29 2018-03-28 Dodatek polarny do syntezy kopolimerów monomeru winyloaromatycznego i monomeru sprzężonego dienu o wysokiej zawartości składnika winyloaromatycznego i niskiej zawartości składnika winylowego

Country Status (9)

Country Link
US (1) US11525049B2 (enExample)
EP (1) EP3601389B1 (enExample)
JP (2) JP2020515687A (enExample)
KR (1) KR102574992B1 (enExample)
CN (1) CN110678492A (enExample)
BR (1) BR112019020104A2 (enExample)
EA (1) EA201992291A1 (enExample)
PL (1) PL3601389T3 (enExample)
WO (1) WO2018178199A1 (enExample)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20240417549A1 (en) * 2021-10-11 2024-12-19 Japan Elastomer Co., Ltd. Crosslinked Rubber Composition and Method for Producing Crosslinked Rubber Composition

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3558575A (en) 1966-10-03 1971-01-26 Firestone Tire & Rubber Co Process for the production of copolymers free of block polystyrene
US3498960A (en) * 1967-09-28 1970-03-03 Phillips Petroleum Co Production of random copolymers in organolithium polymerization systems
US3787377A (en) 1971-12-16 1974-01-22 Firestone Tire & Rubber Co Continuous process of copolymerizing butadiene and styrene
JPH0627122B2 (ja) * 1984-04-09 1994-04-13 日本エラストマ−株式会社 高スチレン含量のランダムスチレン−ブタジエン共重合体ゴム
JPH0629284B2 (ja) * 1985-01-16 1994-04-20 日本エラストマ−株式会社 タイヤ用ゴム組成物
DE69712962T2 (de) 1996-03-29 2002-11-14 Bridgestone Corp., Tokio/Tokyo Styrol-Butadien-Copolymer und dieses Copolymer enthaltende Gummimischung
DE19914075A1 (de) 1999-03-27 2000-09-28 Basf Ag Glasklares, schlagzähes Polystyrol auf Basis von Styrol-Butadien-Blockcopolymeren
US6372863B1 (en) 1999-08-12 2002-04-16 The Goodyear Tire & Rubber Company Synthesis of styrene-butadiene rubber
US6583244B1 (en) 2001-10-31 2003-06-24 The Goodyear Tire & Rubber Company Synthesis of rubber having a low vinyl content
JP5545800B2 (ja) 2009-06-08 2014-07-09 住友化学株式会社 噴流−流動層型オレフィン重合反応装置、ポリオレフィン製造システム、及び、ポリオレフィン製造方法
TW201211083A (en) * 2010-06-15 2012-03-16 Styron Europe Gmbh Low vinyl styrene-butadiene polymers and methods of making the same
CN101906187B (zh) * 2010-07-26 2012-05-16 中国科学院长春应用化学研究所 限制几何构型稀土配合物在高选择性共轭双烯烃-苯乙烯无规或嵌段共聚合中的应用
EP2537871B1 (en) 2011-06-22 2018-10-17 Trinseo Europe GmbH High styrene high vinyl styrene-butadiene rubber with narrow molecular weight distribution and methods for preparation thereof
HUE031642T2 (en) * 2011-03-04 2017-07-28 Trinseo Europe Gmbh Styrene-butadiene rubber with high styrene and high vinyl content and methods for its production
EP2495266A1 (en) * 2011-03-04 2012-09-05 Styron Deutschland GmbH High styrene high vinyl styrene-butadiene rubber and methods for preparation thereof
ES2545332T3 (es) 2011-06-22 2015-09-10 Trinseo Europe Gmbh Caucho de estireno-butadieno de alto contenido en estireno, alto contenido en vinilo, con distribución de pesos moleculares estrecha y métodos para la preparación de los mismos
CN103374101B (zh) * 2012-04-18 2015-11-25 中国石油化工股份有限公司 一种无规剂和丁苯橡胶的制备方法
US9458362B2 (en) * 2014-04-02 2016-10-04 Kraton Polymers U.S. Llc Adhesive compositions containing a block copolymer with polymyrcene

Also Published As

Publication number Publication date
US11525049B2 (en) 2022-12-13
JP2020515687A (ja) 2020-05-28
JP2023052652A (ja) 2023-04-11
WO2018178199A1 (en) 2018-10-04
KR102574992B1 (ko) 2023-09-05
JP7667190B2 (ja) 2025-04-22
EP3601389B1 (en) 2021-11-17
KR20190130011A (ko) 2019-11-20
EA201992291A1 (ru) 2020-02-28
BR112019020104A2 (pt) 2020-05-05
CN110678492A (zh) 2020-01-10
EP3601389A1 (en) 2020-02-05
US20200255625A1 (en) 2020-08-13

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PL3601389T3 (pl) Dodatek polarny do syntezy kopolimerów monomeru winyloaromatycznego i monomeru sprzężonego dienu o wysokiej zawartości składnika winyloaromatycznego i niskiej zawartości składnika winylowego
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