CN110678492A - 用于具有高乙烯基芳烃含量和低乙烯基含量的乙烯基芳烃单体与共轭二烯单体的共聚物的合成的极性添加剂 - Google Patents

用于具有高乙烯基芳烃含量和低乙烯基含量的乙烯基芳烃单体与共轭二烯单体的共聚物的合成的极性添加剂 Download PDF

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Publication number
CN110678492A
CN110678492A CN201880035506.2A CN201880035506A CN110678492A CN 110678492 A CN110678492 A CN 110678492A CN 201880035506 A CN201880035506 A CN 201880035506A CN 110678492 A CN110678492 A CN 110678492A
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CN
China
Prior art keywords
rubber
content
weight percent
monomer
copolymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201880035506.2A
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English (en)
Chinese (zh)
Inventor
拉多斯劳·科扎克
罗伯特·博加齐
玛尔戈扎塔·瓦乐妮亚
帕韦尔·韦德
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sisso Dolly Seven
Synthos SA
Original Assignee
Sisso Dolly Seven
Synthos SA
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Publication date
Application filed by Sisso Dolly Seven, Synthos SA filed Critical Sisso Dolly Seven
Publication of CN110678492A publication Critical patent/CN110678492A/zh
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0016—Compositions of the tread
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • C08F4/48—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00—Compositions of unspecified rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00—Compositions of natural rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06—Copolymers with styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Tires In General (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
CN201880035506.2A 2017-03-29 2018-03-28 用于具有高乙烯基芳烃含量和低乙烯基含量的乙烯基芳烃单体与共轭二烯单体的共聚物的合成的极性添加剂 Pending CN110678492A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP17461514 2017-03-29
EPEP17461514 2017-03-29
PCT/EP2018/058014 WO2018178199A1 (en) 2017-03-29 2018-03-28 Polar additive for the synthesis of copolymers of vinylaromatic monomer and conjugated diene monomer having high vinylaromatic and low vinyl contents

Publications (1)

Publication Number Publication Date
CN110678492A true CN110678492A (zh) 2020-01-10

Family

ID=58461256

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201880035506.2A Pending CN110678492A (zh) 2017-03-29 2018-03-28 用于具有高乙烯基芳烃含量和低乙烯基含量的乙烯基芳烃单体与共轭二烯单体的共聚物的合成的极性添加剂

Country Status (9)

Country Link
US (1) US11525049B2 (enExample)
EP (1) EP3601389B1 (enExample)
JP (2) JP2020515687A (enExample)
KR (1) KR102574992B1 (enExample)
CN (1) CN110678492A (enExample)
BR (1) BR112019020104A2 (enExample)
EA (1) EA201992291A1 (enExample)
PL (1) PL3601389T3 (enExample)
WO (1) WO2018178199A1 (enExample)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20240417549A1 (en) * 2021-10-11 2024-12-19 Japan Elastomer Co., Ltd. Crosslinked Rubber Composition and Method for Producing Crosslinked Rubber Composition

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3498960A (en) * 1967-09-28 1970-03-03 Phillips Petroleum Co Production of random copolymers in organolithium polymerization systems
CN101906187A (zh) * 2010-07-26 2010-12-08 中国科学院长春应用化学研究所 限制几何构型稀土配合物在高选择性共轭双烯烃-苯乙烯无规或嵌段共聚合中的应用
CN102947358A (zh) * 2010-06-15 2013-02-27 思迪隆欧洲有限公司 低乙烯基苯乙烯-丁二烯聚合物及其制造方法
CN103443152A (zh) * 2011-03-04 2013-12-11 思迪隆欧洲有限公司 高苯乙烯高乙烯基苯乙烯-丁二烯橡胶及其制备方法
CN103476814A (zh) * 2011-03-04 2013-12-25 思迪隆欧洲有限公司 高苯乙烯高乙烯基苯乙烯-丁二烯橡胶及其制备方法
WO2015153736A1 (en) * 2014-04-02 2015-10-08 Kraton Polymers U.S. Llc Adhesive compositions containing a block copolymer with polymyrcene

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US3558575A (en) 1966-10-03 1971-01-26 Firestone Tire & Rubber Co Process for the production of copolymers free of block polystyrene
US3787377A (en) 1971-12-16 1974-01-22 Firestone Tire & Rubber Co Continuous process of copolymerizing butadiene and styrene
JPH0627122B2 (ja) * 1984-04-09 1994-04-13 日本エラストマ−株式会社 高スチレン含量のランダムスチレン−ブタジエン共重合体ゴム
JPH0629284B2 (ja) * 1985-01-16 1994-04-20 日本エラストマ−株式会社 タイヤ用ゴム組成物
DE69712962T2 (de) 1996-03-29 2002-11-14 Bridgestone Corp., Tokio/Tokyo Styrol-Butadien-Copolymer und dieses Copolymer enthaltende Gummimischung
DE19914075A1 (de) 1999-03-27 2000-09-28 Basf Ag Glasklares, schlagzähes Polystyrol auf Basis von Styrol-Butadien-Blockcopolymeren
US6372863B1 (en) 1999-08-12 2002-04-16 The Goodyear Tire & Rubber Company Synthesis of styrene-butadiene rubber
US6583244B1 (en) 2001-10-31 2003-06-24 The Goodyear Tire & Rubber Company Synthesis of rubber having a low vinyl content
JP5545800B2 (ja) 2009-06-08 2014-07-09 住友化学株式会社 噴流−流動層型オレフィン重合反応装置、ポリオレフィン製造システム、及び、ポリオレフィン製造方法
EP2537871B1 (en) 2011-06-22 2018-10-17 Trinseo Europe GmbH High styrene high vinyl styrene-butadiene rubber with narrow molecular weight distribution and methods for preparation thereof
ES2545332T3 (es) 2011-06-22 2015-09-10 Trinseo Europe Gmbh Caucho de estireno-butadieno de alto contenido en estireno, alto contenido en vinilo, con distribución de pesos moleculares estrecha y métodos para la preparación de los mismos
CN103374101B (zh) * 2012-04-18 2015-11-25 中国石油化工股份有限公司 一种无规剂和丁苯橡胶的制备方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3498960A (en) * 1967-09-28 1970-03-03 Phillips Petroleum Co Production of random copolymers in organolithium polymerization systems
CN102947358A (zh) * 2010-06-15 2013-02-27 思迪隆欧洲有限公司 低乙烯基苯乙烯-丁二烯聚合物及其制造方法
CN101906187A (zh) * 2010-07-26 2010-12-08 中国科学院长春应用化学研究所 限制几何构型稀土配合物在高选择性共轭双烯烃-苯乙烯无规或嵌段共聚合中的应用
CN103443152A (zh) * 2011-03-04 2013-12-11 思迪隆欧洲有限公司 高苯乙烯高乙烯基苯乙烯-丁二烯橡胶及其制备方法
CN103476814A (zh) * 2011-03-04 2013-12-25 思迪隆欧洲有限公司 高苯乙烯高乙烯基苯乙烯-丁二烯橡胶及其制备方法
WO2015153736A1 (en) * 2014-04-02 2015-10-08 Kraton Polymers U.S. Llc Adhesive compositions containing a block copolymer with polymyrcene

Also Published As

Publication number Publication date
US11525049B2 (en) 2022-12-13
JP2020515687A (ja) 2020-05-28
JP2023052652A (ja) 2023-04-11
WO2018178199A1 (en) 2018-10-04
KR102574992B1 (ko) 2023-09-05
JP7667190B2 (ja) 2025-04-22
EP3601389B1 (en) 2021-11-17
KR20190130011A (ko) 2019-11-20
PL3601389T3 (pl) 2022-02-07
EA201992291A1 (ru) 2020-02-28
BR112019020104A2 (pt) 2020-05-05
EP3601389A1 (en) 2020-02-05
US20200255625A1 (en) 2020-08-13

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