JP2019503894A - 少なくとも1つの酸化ニッケル層を含む熱的特性を有する積層体を備えた基材 - Google Patents
少なくとも1つの酸化ニッケル層を含む熱的特性を有する積層体を備えた基材 Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
- C03C17/366—Low-emissivity or solar control coatings
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3607—Coatings of the type glass/inorganic compound/metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3613—Coatings of type glass/inorganic compound/metal/inorganic compound/metal/other
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3626—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing a nitride, oxynitride, boronitride or carbonitride
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3642—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating containing a metal layer
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3644—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the metal being silver
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3652—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the coating stack containing at least one sacrificial layer to protect the metal from oxidation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/73—Anti-reflective coatings with specific characteristics
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- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Laminated Bodies (AREA)
- Surface Treatment Of Glass (AREA)
- Joining Of Glass To Other Materials (AREA)
- Physical Vapour Deposition (AREA)
- Surface Treatment Of Optical Elements (AREA)
Abstract
Description
− 層の材料は、Niにおいてわずかに化学量論的超であってもよく、例えば0.8≦x<1、特に0.8≦x≦0.95であってもよく、又は
− 層の材料は、Niにおいてわずかに化学量論的未満であってもよく、例えば、1<x≦1.2、特に1.05≦x≦1.2であってもよい。
i− 可視領域の全波長範囲にわたって5より大きいn/k比を示す反射防止性/誘電体材料の層:Si3N4,ZnO、
ii− 赤外線領域及び/又は日射領域での反射特性を有する材料から作られた金属機能層:Ag;銀は可視領域の全波長範囲にわたって0<n/k<5の比を示し、そのバルク電気抵抗率は10−6Ω・cm未満であることが観察された。
iii− 積層体の堆積の間に機能層をその性質の変性から保護することを目的とするアンダーブロッカー層及びオーバーブロッカー層、
iv− 酸化ニッケルNixO層及びNiyO層;図3は、これらの2つの層の堆積条件を示す。
− Rに関しては、スクエアあたりのオームでの4点プローブで通常通りに測定されたシート抵抗である。
− Absに関しては、積層体が堆積された基材の主面の反対側で、発光体D65 2°により測定された%での可視領域における光吸収率である。
− 例1に関しては、それは図4に示されており、かつ、
− 例2に関しては、それは図5に示されている。
i. Niのみを含む金属ターゲットを、酸素を含む、また、さらには、アルゴンなどの中性ガスを含む雰囲気中においてスパッタリングすることにより、
ii. 又は、アルゴンなどの中性ガスを含む、また、さらには酸素を含む雰囲気中において、Ni及び酸素の両方を含有する「セラミック」ターゲットをスパッタリングすることにより、
得ることができるからである。
Claims (11)
- 少なくとも1つ、また、さらには1つのみの金属機能層(140)であって、赤外線領域及び/又は日射領域における反射特性を有し、特に銀又は銀含有金属合金をベースとする金属機能層(140)と、少なくとも1つの誘電体層(122,126;162,168)をそれぞれ含む2つの反射防止性コーティング(120,160)とを含み、前記機能層(140)は、前記2つの反射防止性コーティング(120,160)の間に配置されている、積層体を、主面上に備えた透明基材(30)であって、
少なくとも1つの酸化ニッケルNixO層(135)が、前記基材(30)の方向で機能層(140)の下方でそれと接触して配置されており、前記酸化ニッケルNixO層(135)の物理的厚さは、少なくとも0.3nm、また、さらには0.6〜8.0nmであり、また、さらには1.0〜5.0nmであることを特徴とする、透明基材(30)。 - 前記酸化ニッケルNixO層(135)は、1.2〜0.5、また、さらには0.9〜0.6のxを示すことを特徴とする、請求項1に記載の基材(30)。
- 酸化亜鉛をベースとする層が、前記酸化ニッケルNixO層(135)の下方でそれと接触して配置されていることを特徴とする、請求項1又は2に記載の基材(30)。
- 酸化ニッケルNiyO層(134、136)が、前記酸化ニッケルNixO層(135)の下方でそれと接触して配置されており、かつ/又は、前記酸化ニッケルNixO層(135)の下方でそれと接触して配置されており、前記機能層(140)に最も近い酸化ニッケル層は、より遠い別の酸化ニッケル層よりも低い酸化状態であることを特徴とする、請求項1〜3のいずれか一項に記載の基材(30)。
- 酸化ニッケルNixO層が、機能層(140)の上方でそれと接触して配置されており、前記酸化ニッケルNixO層の物理的厚さは、少なくとも0.3nm、また、さらには0.6〜8.0nmであり、また、さらには1.0〜5.0nmであることを特徴とする、請求項1〜4のいずれか一項に記載の基材(30)。
- 金属層、特にニッケル及びクロムを含む金属層は、前記機能層(140)上でそれと接触して配置されており、前記金属層の物理的厚さは、少なくとも0.3nm、また、さらには0.6〜8.0nm、また、さらには1.0〜5.0nmであることを特徴とする、請求項1〜4のいずれか一項に記載の基材(30)。
- 酸化ニッケル層は、基材(30)の方向で前記機能層(140)上に配置されており、前記酸化ニッケルNixO層と前記機能層(140)との間に、異なる材料から作られた少なくとも1つの層又は1つのみの層が介在しており、この酸化ニッケルNixO層は、好ましくは、0.3〜10.0nm、また、さらには0.6〜8.0nmであり、また、さらには1.0〜5.0nmの厚さを示すことを特徴とする、請求項1〜6のいずれか一項に記載の基材(30)。
- 前記下層の反射防止性コーティング(20)及び上層の反射防止性コーティング(60)は、各々、窒化ケイ素をベースとし、場合により、アルミニウムなどの少なくとも1つの他の元素を用いてドープされている、少なくとも1つの誘電体層(22,66)を含むことを特徴とする、請求項1〜7のいずれか一項に記載の基材(30)。
- 請求項1〜8のいずれか一項に記載の少なくとも1つの基材(30)を、場合により少なくとも1つの他の基材と組み合わせて組み入れた、グレージング(100)。
- モノリシックユニットとして、又は、ダブルグレージング若しくはトリプルグレージング若しくはラミネート化グレージングのタイプの複合グレージングユニットとして取り付けられたグレージング(100)であって、少なくとも、前記積層体を担持した基材が、曲げられ及び/又は強化されていることを特徴とする、請求項9に記載のグレージング(100)。
- 加熱グレージング又はエレクトロクロミックグレージング又は照明デバイス又は表示デバイス又は光起電力パネルの透明電極を製造するための、請求項1〜8のいずれか一項に記載の基材の使用。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1561722A FR3044658B1 (fr) | 2015-12-02 | 2015-12-02 | Substrat muni d'un empilement a proprietes thermiques comportant au moins une couche en oxyde de nickel. |
FR1561722 | 2015-12-02 | ||
PCT/FR2016/053172 WO2017093677A1 (fr) | 2015-12-02 | 2016-12-01 | Substrat muni d'un empilement a proprietes thermiques comportant au moins une couche en oxyde de nickel |
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JP2019503894A true JP2019503894A (ja) | 2019-02-14 |
JP2019503894A5 JP2019503894A5 (ja) | 2019-12-12 |
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JP2018528682A Pending JP2019503894A (ja) | 2015-12-02 | 2016-12-01 | 少なくとも1つの酸化ニッケル層を含む熱的特性を有する積層体を備えた基材 |
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Country | Link |
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US (1) | US20200255329A1 (ja) |
EP (1) | EP3383813A1 (ja) |
JP (1) | JP2019503894A (ja) |
KR (1) | KR20180088432A (ja) |
CN (1) | CN108602717A (ja) |
BR (1) | BR112018011070A2 (ja) |
CA (1) | CA3006339A1 (ja) |
CO (1) | CO2018006932A2 (ja) |
FR (1) | FR3044658B1 (ja) |
MX (1) | MX2018006764A (ja) |
RU (1) | RU2731597C2 (ja) |
WO (1) | WO2017093677A1 (ja) |
Cited By (1)
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JP2019503895A (ja) * | 2015-12-02 | 2019-02-14 | サン−ゴバン グラス フランス | 少なくとも1つの酸化ニッケル層を含む熱的特性を有する積層体を備えた基材 |
Citations (5)
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US20020021495A1 (en) * | 2000-07-10 | 2002-02-21 | Lingle Philip J. | High durable, low-E, heat treatable layer coating system |
US20030150711A1 (en) * | 2001-10-17 | 2003-08-14 | Laird Ronald E. | Coated article with high visible transmission and low emissivity |
JP2015506331A (ja) * | 2012-01-16 | 2015-03-02 | サン−ゴバン グラス フランス | 4つの金属機能層を含む、熱特性を有するマルチレイヤーを備えた基体 |
JP2018528768A (ja) * | 2015-08-24 | 2018-10-04 | フィリップ・モーリス・プロダクツ・ソシエテ・アノニム | 複数構成要素エアロゾル形成物品の製造方法 |
JP2019503895A (ja) * | 2015-12-02 | 2019-02-14 | サン−ゴバン グラス フランス | 少なくとも1つの酸化ニッケル層を含む熱的特性を有する積層体を備えた基材 |
Family Cites Families (12)
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US6576349B2 (en) * | 2000-07-10 | 2003-06-10 | Guardian Industries Corp. | Heat treatable low-E coated articles and methods of making same |
US7087309B2 (en) * | 2003-08-22 | 2006-08-08 | Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) | Coated article with tin oxide, silicon nitride and/or zinc oxide under IR reflecting layer and corresponding method |
US7217461B2 (en) * | 2004-09-01 | 2007-05-15 | Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) | Coated article with low-E coating including IR reflecting layer(s) and corresponding method |
US7597962B2 (en) * | 2005-06-07 | 2009-10-06 | Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) | Coated article with IR reflecting layer and method of making same |
FR2898123B1 (fr) * | 2006-03-06 | 2008-12-05 | Saint Gobain | Substrat muni d'un empilement a proprietes thermiques |
DE102006014796B4 (de) * | 2006-03-29 | 2009-04-09 | Saint-Gobain Glass Deutschland Gmbh | Thermisch hoch belastbares Low-E-Schichtsystem für transparente Substrate |
US8734920B2 (en) * | 2009-04-29 | 2014-05-27 | Guardian Industries Corp. | Coated article with low-E coating having titanium oxide layer and/or NiCr based layer(s) to improve color values and/or transmission, and method of making same |
CN102092960A (zh) * | 2010-12-17 | 2011-06-15 | 华中科技大学 | 一种低辐射玻璃 |
US8559100B2 (en) * | 2011-10-12 | 2013-10-15 | Guardian Industries Corp. | Coated article with low-E coating having absorbing layer over functional layer designed to increase outside reflectance |
CN102745906B (zh) * | 2012-07-26 | 2014-10-22 | 福耀玻璃工业集团股份有限公司 | 一种低辐射镀膜玻璃及其夹层玻璃制品 |
US9242895B2 (en) * | 2012-09-07 | 2016-01-26 | Guardian Industries Corp. | Coated article with low-E coating having absorbing layers for low film side reflectance and low visible transmission |
FR3013043B1 (fr) * | 2013-11-08 | 2015-11-20 | Saint Gobain | Substrat revetu d'un empilement a couches fonctionnelles presentant des proprietes mecaniques ameliorees |
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2015
- 2015-12-02 FR FR1561722A patent/FR3044658B1/fr not_active Expired - Fee Related
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- 2016-12-01 BR BR112018011070-1A patent/BR112018011070A2/pt not_active IP Right Cessation
- 2016-12-01 EP EP16819144.3A patent/EP3383813A1/fr not_active Withdrawn
- 2016-12-01 KR KR1020187018225A patent/KR20180088432A/ko unknown
- 2016-12-01 CN CN201680080901.3A patent/CN108602717A/zh active Pending
- 2016-12-01 WO PCT/FR2016/053172 patent/WO2017093677A1/fr active Application Filing
- 2016-12-01 US US15/780,813 patent/US20200255329A1/en not_active Abandoned
- 2016-12-01 CA CA3006339A patent/CA3006339A1/fr not_active Abandoned
- 2016-12-01 JP JP2018528682A patent/JP2019503894A/ja active Pending
- 2016-12-01 RU RU2018123317A patent/RU2731597C2/ru active
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RU2018123317A3 (ja) | 2020-04-10 |
CA3006339A1 (fr) | 2017-06-08 |
MX2018006764A (es) | 2018-08-01 |
RU2731597C2 (ru) | 2020-09-04 |
BR112018011070A2 (pt) | 2018-11-21 |
WO2017093677A1 (fr) | 2017-06-08 |
RU2018123317A (ru) | 2020-01-09 |
US20200255329A1 (en) | 2020-08-13 |
CO2018006932A2 (es) | 2018-07-19 |
FR3044658B1 (fr) | 2017-12-15 |
KR20180088432A (ko) | 2018-08-03 |
FR3044658A1 (fr) | 2017-06-09 |
CN108602717A (zh) | 2018-09-28 |
EP3383813A1 (fr) | 2018-10-10 |
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