JP2018528107A5 - - Google Patents
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- JP2018528107A5 JP2018528107A5 JP2018512552A JP2018512552A JP2018528107A5 JP 2018528107 A5 JP2018528107 A5 JP 2018528107A5 JP 2018512552 A JP2018512552 A JP 2018512552A JP 2018512552 A JP2018512552 A JP 2018512552A JP 2018528107 A5 JP2018528107 A5 JP 2018528107A5
- Authority
- JP
- Japan
- Prior art keywords
- epoxy resin
- weight percent
- temperature
- optionally
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000000034 method Methods 0.000 claims description 39
- 229920005989 resin Polymers 0.000 claims description 24
- 239000011347 resin Substances 0.000 claims description 24
- 239000003822 epoxy resin Substances 0.000 claims description 21
- 229920000647 polyepoxide Polymers 0.000 claims description 21
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 239000000178 monomer Substances 0.000 claims description 12
- 230000005855 radiation Effects 0.000 claims description 12
- 239000003085 diluting agent Substances 0.000 claims description 9
- 239000000945 filler Substances 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 9
- 239000000049 pigment Substances 0.000 claims description 9
- 229920000642 polymer Polymers 0.000 claims description 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 7
- 150000003573 thiols Chemical class 0.000 claims description 7
- 229920001567 vinyl ester resin Polymers 0.000 claims description 7
- 239000004593 Epoxy Substances 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 229940124543 ultraviolet light absorber Drugs 0.000 claims description 6
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 6
- 229920002554 vinyl polymer Polymers 0.000 claims description 5
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 4
- -1 alicyclic amine Chemical class 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 150000008064 anhydrides Chemical class 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical class CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 239000004711 α-olefin Substances 0.000 claims description 4
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- ZCILGMFPJBRCNO-UHFFFAOYSA-N 4-phenyl-2H-benzotriazol-5-ol Chemical compound OC1=CC=C2NN=NC2=C1C1=CC=CC=C1 ZCILGMFPJBRCNO-UHFFFAOYSA-N 0.000 claims description 3
- VMRIVYANZGSGRV-UHFFFAOYSA-N 4-phenyl-2h-triazin-5-one Chemical compound OC1=CN=NN=C1C1=CC=CC=C1 VMRIVYANZGSGRV-UHFFFAOYSA-N 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 150000003926 acrylamides Chemical class 0.000 claims description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 3
- 239000004844 aliphatic epoxy resin Substances 0.000 claims description 3
- 150000004982 aromatic amines Chemical class 0.000 claims description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 3
- 239000012965 benzophenone Substances 0.000 claims description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 3
- 239000012964 benzotriazole Substances 0.000 claims description 3
- 239000004841 bisphenol A epoxy resin Substances 0.000 claims description 3
- 239000004842 bisphenol F epoxy resin Substances 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- 239000011258 core-shell material Substances 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- 229920001971 elastomer Polymers 0.000 claims description 3
- 239000004845 glycidylamine epoxy resin Substances 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- 239000013067 intermediate product Substances 0.000 claims description 3
- 230000001678 irradiating effect Effects 0.000 claims description 3
- 150000002734 metacrylic acid derivatives Chemical class 0.000 claims description 3
- FTWUXYZHDFCGSV-UHFFFAOYSA-N n,n'-diphenyloxamide Chemical compound C=1C=CC=CC=1NC(=O)C(=O)NC1=CC=CC=C1 FTWUXYZHDFCGSV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004843 novolac epoxy resin Substances 0.000 claims description 3
- 150000002924 oxiranes Chemical class 0.000 claims description 3
- 239000000047 product Substances 0.000 claims description 3
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims description 3
- 150000003440 styrenes Chemical class 0.000 claims description 3
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- 239000008158 vegetable oil Substances 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 229920002959 polymer blend Polymers 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 239000004848 polyfunctional curative Substances 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- LLVWLCAZSOLOTF-UHFFFAOYSA-N 1-methyl-4-[1,4,4-tris(4-methylphenyl)buta-1,3-dienyl]benzene Chemical compound C1=CC(C)=CC=C1C(C=1C=CC(C)=CC=1)=CC=C(C=1C=CC(C)=CC=1)C1=CC=C(C)C=C1 LLVWLCAZSOLOTF-UHFFFAOYSA-N 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201562215944P | 2015-09-09 | 2015-09-09 | |
| US62/215,944 | 2015-09-09 | ||
| US201562270637P | 2015-12-22 | 2015-12-22 | |
| US62/270,637 | 2015-12-22 | ||
| US201662369409P | 2016-08-01 | 2016-08-01 | |
| US62/369,409 | 2016-08-01 | ||
| PCT/US2016/050043 WO2017044381A1 (en) | 2015-09-09 | 2016-09-02 | Epoxy dual cure resins for additive manufacturing |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2018528107A JP2018528107A (ja) | 2018-09-27 |
| JP2018528107A5 true JP2018528107A5 (enExample) | 2019-10-10 |
| JP6845226B2 JP6845226B2 (ja) | 2021-03-17 |
Family
ID=56940402
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018512552A Active JP6845226B2 (ja) | 2015-09-09 | 2016-09-02 | 積層造形用エポキシ二重硬化樹脂 |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US10975193B2 (enExample) |
| EP (1) | EP3347399B1 (enExample) |
| JP (1) | JP6845226B2 (enExample) |
| CN (1) | CN108291011B (enExample) |
| WO (1) | WO2017044381A1 (enExample) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016117606A1 (ja) | 2015-01-22 | 2016-07-28 | 積水化学工業株式会社 | インクジェット用接着剤、半導体装置の製造方法及び電子部品 |
| JP7189015B2 (ja) * | 2015-12-22 | 2022-12-13 | カーボン，インコーポレイテッド | 二重硬化樹脂を用いた積層造形のための二重前駆体樹脂システム |
| US11883842B2 (en) | 2017-04-14 | 2024-01-30 | Polynt Composites USA, Inc. | Adhesive compositions and methods for coating objects |
| EP3609970A4 (en) * | 2017-04-14 | 2020-11-25 | Polynt Composites USA, Inc. | ADHESIVE COMPOSITION AND PROCESS FOR COATING OBJECTS |
| JP6894015B2 (ja) | 2017-06-21 | 2021-06-23 | カーボン，インコーポレイテッド | 積層造形の方法 |
| WO2019035387A1 (ja) | 2017-08-15 | 2019-02-21 | 住友ゴム工業株式会社 | 三次元積層造形用ゴム組成物 |
| EP3732021A1 (en) | 2017-12-29 | 2020-11-04 | DSM IP Assets B.V. | Compositions and articles for additive fabrication and methods of using the same |
| FR3079517B1 (fr) * | 2018-03-28 | 2021-01-01 | Ecole Centrale Marseille | Procede pour la realisation d’un objet tridimensionnel par un processus de photo-polymerisation multi-photonique et dispositif associe |
| WO2019225318A1 (ja) * | 2018-05-23 | 2019-11-28 | コニカミノルタ株式会社 | 立体造形用重合性組成物、およびこれを用いた立体造形物の製造方法、ならびに立体造形物 |
| CN108976788A (zh) * | 2018-06-05 | 2018-12-11 | 宁波市石生科技有限公司 | 一种耐高温三维制造材料及使用该材料制造三维物的方法 |
| US11149108B1 (en) | 2018-06-26 | 2021-10-19 | National Technology & Engineering Solutions Of Sandia, Llc | Self-assembly assisted additive manufacturing of thermosets |
| IL279630B2 (en) | 2018-06-26 | 2025-02-01 | Arkema France | Curable compositions based on multistage polymers |
| CN108976777A (zh) * | 2018-07-04 | 2018-12-11 | 宁波市石生科技有限公司 | 一种用于光固化3d打印的柔性材料及其应用 |
| EP3768494B1 (en) * | 2018-08-01 | 2023-04-19 | Carbon, Inc. | Production of low density products by additive manufacturing |
| WO2020041320A1 (en) * | 2018-08-21 | 2020-02-27 | Laird Technologies, Inc. | Patterned materials and films and systems and methods for making the same |
| US12022642B2 (en) | 2018-08-21 | 2024-06-25 | Laird Technologies, Inc. | Patterned electromagnetic interference (EMI) mitigation materials including carbon nanotubes |
| DE102018121067A1 (de) * | 2018-08-29 | 2020-03-05 | Delo Industrie Klebstoffe Gmbh & Co. Kgaa | Härtbare Zweikomponentenmasse |
| CN115943062A (zh) | 2018-09-10 | 2023-04-07 | 卡本有限公司 | 用于生产阻燃物体的双固化增材制造树脂 |
| US11426898B2 (en) | 2018-12-28 | 2022-08-30 | Konica Minolta Business Solutions U.S.A., Inc. | Process for fabrication of fiber composites using dual-cure free-form 3D-printed tailored fiber placement preform |
| JP2020152832A (ja) * | 2019-03-20 | 2020-09-24 | 株式会社リコー | インクジェット用活性エネルギー線硬化型組成物、及び立体物の造形方法 |
| WO2020191690A1 (en) * | 2019-03-28 | 2020-10-01 | Henkel Ag & Co. Kgaa | Photo-curable compositions for additive manufacturing |
| WO2020191689A1 (en) * | 2019-03-28 | 2020-10-01 | Henkel Ag & Co. Kgaa | Photo-curable compositions for additive manufacturing |
| DE102019110245A1 (de) * | 2019-04-18 | 2020-10-22 | Comprise Tec Gmbh | Werkstoff, Werkstoffkomposition, Werkstoffherstellungsverfahren und Fertigungsverfahren |
| EP3738771B1 (en) * | 2019-05-13 | 2023-08-16 | Henkel AG & Co. KGaA | Dual cure epoxy formulations for 3d printing applications |
| CN110372997A (zh) * | 2019-07-09 | 2019-10-25 | 捷安特（昆山）有限公司 | 用于制备碳纤维预浸布的环氧树脂组合物及其制备方法 |
| CA3151655A1 (en) * | 2019-09-03 | 2021-03-11 | National Research Council Of Canada | 3d printed graded refractive index device |
| JP7776427B2 (ja) * | 2020-02-18 | 2025-11-26 | ローワン・ユニバーシティ | 逐次硬化相互侵入ポリマーによる付加製造高ガラス転移温度材料の網目構造強靭化 |
| CN115151586B (zh) * | 2020-02-28 | 2024-09-20 | 卡本有限公司 | 用于增材制造的单份可湿固化树脂 |
| EP3909747A1 (en) * | 2020-05-12 | 2021-11-17 | TIGER Coatings GmbH & Co. KG | Thermosetting material for use in a 3d printing process |
| CN112057750B (zh) * | 2020-08-06 | 2023-04-07 | 恒新增材制造研究中心(佛山)有限公司 | 一种用于放疗的组织补偿物及其制备方法 |
| WO2022066565A1 (en) * | 2020-09-25 | 2022-03-31 | Carbon, Inc. | Epoxy dual cure resin for the production of moisture-resistant articles by additive manufacturing |
| EP4466142A1 (en) | 2022-01-18 | 2024-11-27 | Noga 3D Innovations Ltd | Dual-cure epoxy resins for 3d printing of high-performance materials |
| JP7571990B2 (ja) * | 2022-04-04 | 2024-10-23 | 幸士 生田 | 光硬化性組成物、硬化体及び硬化体の製造方法 |
| WO2023220523A1 (en) | 2022-05-09 | 2023-11-16 | Carbon, Inc. | Method for direct coloration of resins for additive manufacturing |
| DE102023120631A1 (de) | 2023-08-03 | 2025-02-06 | Delo Industrie Klebstoffe Gmbh & Co. Kgaa | Verfahren zum Fügen, Vergießen oder Beschichten von Substraten und härtbare Masse dafür |
| WO2025080931A1 (en) | 2023-10-12 | 2025-04-17 | Carbon, Inc. | Dual cure resins for mixed modulus materials |
| CN118165195B (zh) * | 2024-05-14 | 2024-08-02 | 北京极溯光学科技有限公司 | 双重固化树脂、3d打印方法和3d打印制品 |
Family Cites Families (123)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3051671A (en) | 1959-12-07 | 1962-08-28 | Pacific Vegets Le Oil Corp | Epoxy resin-isano oil compositions |
| US3386955A (en) | 1966-01-14 | 1968-06-04 | American Cyanamid Co | Substituted ureas as low temperature epoxy curing agents |
| US3639928A (en) | 1970-11-27 | 1972-02-08 | Jefferson Chem Co Inc | Accelerator combination for epoxy curing |
| US3945972A (en) | 1973-10-09 | 1976-03-23 | Nitto Kasei Co. Ltd. | Curable epoxy resin composition comprising an epoxy resin and a reactive diluent |
| US3947395A (en) | 1974-05-07 | 1976-03-30 | Hitachi, Ltd. | Epoxy surface coating compositions |
| CH637411A5 (de) | 1979-04-20 | 1983-07-29 | Ciba Geigy Ag | Epoxidharz, haerter und haertungsbeschleuniger enthaltende, lagerfaehige homogene mischung und deren verwendung zur herstellung gehaerteter erzeugnisse. |
| US4421822A (en) | 1979-08-20 | 1983-12-20 | Minnesota Mining And Manufacturing Co. | Ultraviolet polymerization of acrylate monomers using oxidizable tin compounds |
| US4389514A (en) | 1980-09-26 | 1983-06-21 | Congoleum Corporation | Accelerated polymerization of acrylic monomers initiated by dialkyl and diaralkyl peroxide free radical generators in the presence of tin accelerators |
| CH646956A5 (de) | 1981-12-15 | 1984-12-28 | Ciba Geigy Ag | Imidazolide. |
| US4529821A (en) | 1982-02-23 | 1985-07-16 | Ciba-Geigy Corporation | Cyanoacylamide compounds |
| US4550203A (en) | 1982-02-23 | 1985-10-29 | Ciba Geigy Corporation | Process for the preparation of N-substituted N-cyancarboxylic acid amides |
| US4618712A (en) | 1982-02-23 | 1986-10-21 | Ciba-Geigy Corporation | N-cyanocarboxylic acid amides, processes for their preparation and their use |
| EP0124482B1 (de) | 1983-04-29 | 1989-11-08 | Ciba-Geigy Ag | Neue Imidazolide und deren Verwendung als Härter für Polyepoxidverbindungen |
| US5236637A (en) | 1984-08-08 | 1993-08-17 | 3D Systems, Inc. | Method of and apparatus for production of three dimensional objects by stereolithography |
| EP0200674B1 (de) | 1985-02-01 | 1988-05-25 | Ciba-Geigy Ag | (Acylthiopropyl)-Polyphenole |
| US4626642A (en) | 1985-10-08 | 1986-12-02 | General Motors Corporation | Microwave method of curing a thermoset polymer |
| ATE113746T1 (de) * | 1986-06-03 | 1994-11-15 | Cubital Ltd | Gerät zur entwicklung dreidimensionaler modelle. |
| US4785075A (en) * | 1987-07-27 | 1988-11-15 | Interez, Inc. | Metal acetylacetonate/alkylphenol curing catalyst for polycyanate esters of polyhydric phenols |
| US4800222A (en) | 1987-08-24 | 1989-01-24 | Texaco Inc. | Accelerator for curing epoxy resins comprising piperazine, triethanolamine and tris(dimethylaminomethyl)phenol |
| DE3750166T2 (de) | 1987-08-26 | 1995-02-23 | Asahi Chemical Ind | Härtemittel für ein härtbares Eintopfepoxidharzsystem. |
| EP0310545A3 (de) | 1987-09-02 | 1989-07-26 | Ciba-Geigy Ag | Cyanoguanidine als Härter für Epoxidharze |
| JPH0224121A (ja) * | 1988-07-13 | 1990-01-26 | Mitsui Eng & Shipbuild Co Ltd | 光学的造形法 |
| JPH0224127A (ja) * | 1988-07-13 | 1990-01-26 | Mitsui Eng & Shipbuild Co Ltd | 光学的造形法 |
| JPH0757532B2 (ja) | 1988-10-19 | 1995-06-21 | 松下電工株式会社 | 三次元形状の形成方法 |
| US5011635A (en) | 1989-05-18 | 1991-04-30 | Desoto, Inc. | Stereolithographic method and apparatus in which a membrane separates phases |
| US5248456A (en) | 1989-06-12 | 1993-09-28 | 3D Systems, Inc. | Method and apparatus for cleaning stereolithographically produced objects |
| US5189078A (en) | 1989-10-18 | 1993-02-23 | Minnesota Mining And Manufacturing Company | Microwave radiation absorbing adhesive |
| US5093385A (en) | 1989-12-21 | 1992-03-03 | Minnesota Mining And Manufacturing Company | Method of accelerating photoiniferter polymerization, polymer produced thereby, and product produced therewith |
| DE4004620C1 (en) | 1990-02-15 | 1991-09-05 | Du Pont De Nemours (Deutschland) Gmbh, 6380 Bad Homburg, De | Photo-structured layer of three=dimensional object prodn. - by using fusible plastisol or organosol contg. unsatd. monomer, photoinitiator and thermally reactive cpd. |
| US5158858A (en) | 1990-07-05 | 1992-10-27 | E. I. Du Pont De Nemours And Company | Solid imaging system using differential tension elastomeric film |
| DE69109773T2 (de) | 1990-07-25 | 1995-09-21 | John A Shomer | Homogenes Beschleunigersystem für Epoxydharze. |
| US5122441A (en) | 1990-10-29 | 1992-06-16 | E. I. Du Pont De Nemours And Company | Method for fabricating an integral three-dimensional object from layers of a photoformable composition |
| US5510226A (en) | 1991-05-01 | 1996-04-23 | Alliedsignal Inc. | Stereolithography using vinyl ether-epoxide polymers |
| EP0525578A1 (en) | 1991-08-02 | 1993-02-03 | E.I. Du Pont De Nemours And Company | Photopolymer composition for the production of three-dimensional objects |
| DE4206392A1 (de) | 1992-02-29 | 1993-09-02 | Hoechst Ag | Haertungsmittel fuer epoxidharze |
| CA2092131A1 (en) | 1992-03-27 | 1993-09-28 | Victor Kadziela (Nmi) | Low viscosity self-toughening acrylate composition |
| DE69315003T2 (de) | 1992-07-17 | 1998-03-12 | Ethicon Inc | Strahlenhärtbare Urethan-Acrylatprepolymere und vernetzte Polymere |
| US5264061A (en) | 1992-10-22 | 1993-11-23 | Motorola, Inc. | Method of forming a three-dimensional printed circuit assembly |
| US5679719A (en) * | 1993-03-24 | 1997-10-21 | Loctite Corporation | Method of preparing fiber/resin composites |
| DE69433193D1 (de) * | 1993-03-24 | 2003-11-06 | Loctite Corp | Faser/harzverbundwerkstoffe und methode zur deren herstellung |
| AU685796B2 (en) | 1993-03-30 | 1998-01-29 | Shell Internationale Research Maatschappij B.V. | Epoxidized vegetable oil modification of epoxy esters |
| DE59407524D1 (de) | 1993-08-26 | 1999-02-04 | Ciba Geigy Ag | Flüssige strahlungshärtbare Zusammensetzung, insbesondere für die Stereolithographie |
| US5418112A (en) | 1993-11-10 | 1995-05-23 | W. R. Grace & Co.-Conn. | Photosensitive compositions useful in three-dimensional part-building and having improved photospeed |
| US5494618A (en) | 1994-06-27 | 1996-02-27 | Alliedsignal Inc. | Increasing the useful range of cationic photoinitiators in stereolithography |
| US5705116A (en) | 1994-06-27 | 1998-01-06 | Sitzmann; Eugene Valentine | Increasing the useful range of cationic photoinitiators in stereolithography |
| IL112140A (en) | 1994-12-25 | 1997-07-13 | Cubital Ltd | Method of forming three dimensional objects |
| US5639413A (en) | 1995-03-30 | 1997-06-17 | Crivello; James Vincent | Methods and compositions related to stereolithography |
| US5707780A (en) * | 1995-06-07 | 1998-01-13 | E. I. Du Pont De Nemours And Company | Photohardenable epoxy composition |
| JP3668310B2 (ja) | 1996-01-22 | 2005-07-06 | 三菱レイヨン株式会社 | 光学的立体造形用樹脂組成物 |
| JP2001527590A (ja) * | 1997-02-18 | 2001-12-25 | アライド シグナル インコーポレイテッド | ステレオリソグラフィのための耐熱性ポリマー |
| EP0872505B1 (de) | 1997-04-16 | 2001-07-11 | Vantico GmbH & Co. KG | Härtbare Mischungen aus Glycidylverbindungen, aminischen Härtern und heterocyclischen Beschleunigern |
| JP2000007641A (ja) | 1998-06-17 | 2000-01-11 | Takemoto Oil & Fat Co Ltd | 光学的立体造形用樹脂及び光学的立体造形用樹脂組成物 |
| DE19926629A1 (de) | 1999-06-11 | 2000-12-14 | Cognis Deutschland Gmbh | Epoxidharzhärter-Zusammensetzungen |
| US6658314B1 (en) | 1999-10-06 | 2003-12-02 | Objet Geometries Ltd. | System and method for three dimensional model printing |
| DE19961926A1 (de) | 1999-12-22 | 2001-07-05 | Basf Coatings Ag | Thermisch mit aktinischer Strahlung härtbare Stoffgemische und ihre Verwendung |
| US7300619B2 (en) | 2000-03-13 | 2007-11-27 | Objet Geometries Ltd. | Compositions and methods for use in three dimensional model printing |
| US6309797B1 (en) | 2000-04-26 | 2001-10-30 | Spectra Group Limited, Inc. | Selectively colorable polymerizable compositions |
| FR2809741B1 (fr) | 2000-05-31 | 2002-08-16 | Atofina | Materiaux thermodurs a tenue au choc amelioree |
| JP3723927B2 (ja) | 2000-07-11 | 2005-12-07 | 日本ライナー株式会社 | エポキシ樹脂を短時間で硬化する方法及び、該硬化方法によって得られたエポキシ樹脂硬化物による電磁波吸収方法 |
| DE10037883A1 (de) | 2000-08-03 | 2002-02-14 | Henkel Kgaa | Ferromagnetische Resonanzanregung und ihre Verwendung zur Erwärmung teilchengefüllter Substrate |
| JP4382978B2 (ja) * | 2000-12-04 | 2009-12-16 | 学校法人神奈川大学 | 光硬化性・熱硬化性樹脂組成物 |
| DE10115505B4 (de) | 2001-03-29 | 2007-03-08 | Basf Coatings Ag | Thermisch und mit aktinischer Strahlung härtbare wäßrige Dispersionen, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE10119817A1 (de) | 2001-04-23 | 2002-10-24 | Envision Technologies Gmbh | Vorrichtung und Verfahren für die zerstörungsfreie Trennung ausgehärteter Materialschichten von einer planen Bauebene |
| GB0129675D0 (en) | 2001-12-12 | 2002-01-30 | Hexcel Composites Ltd | Accelerator system for epoxy resins |
| US6861475B2 (en) | 2002-10-16 | 2005-03-01 | Rohm And Haas Company | Smooth, flexible powder coatings |
| DE10324486A1 (de) | 2003-05-30 | 2004-12-16 | Degussa Ag | Verwendung von Harnstoff-Derivaten als Beschleuniger für Epoxidharze |
| KR100780582B1 (ko) | 2003-06-09 | 2007-11-29 | 카네카 코포레이션 | 변성 에폭시 수지의 제조방법 |
| JP4652235B2 (ja) * | 2003-11-26 | 2011-03-16 | 三井化学株式会社 | １液型の光及び熱併用硬化性樹脂組成物及びその用途 |
| PL1727663T3 (pl) | 2004-03-22 | 2012-04-30 | Huntsman Adv Mat Switzerland | Kompozycje fotoutwardzalne |
| US7642316B2 (en) | 2004-10-14 | 2010-01-05 | Dow Global Technologies, Inc. | Rubber modified monovinylidene aromatic polymers and fabricated articles prepared therefrom |
| EP2402127B1 (en) | 2004-10-19 | 2018-07-18 | Rolls-Royce Corporation | Method associated with anisotropic shrink in sintered ceramic items |
| BRPI0516699A (pt) | 2004-11-10 | 2008-09-16 | Dow Global Technologies Inc | composição de resina epóxi adesiva curável, processo para preparar uma composição de resina epóxi adesiva curável e dois ou mais substratos |
| US20100152314A1 (en) | 2005-09-29 | 2010-06-17 | Cmet Inc. | Resin composition for stereolithography |
| US20070178133A1 (en) | 2005-11-09 | 2007-08-02 | Liquidia Technologies, Inc. | Medical device, materials, and methods |
| US8481622B2 (en) | 2006-09-01 | 2013-07-09 | The Curators Of The University Of Missouri | Soybean based epoxy resin and methods of making and use |
| US20080103226A1 (en) | 2006-10-31 | 2008-05-01 | Dsm Ip Assets B.V. | Photo-curable resin composition |
| US7892474B2 (en) | 2006-11-15 | 2011-02-22 | Envisiontec Gmbh | Continuous generative process for producing a three-dimensional object |
| US8128393B2 (en) | 2006-12-04 | 2012-03-06 | Liquidia Technologies, Inc. | Methods and materials for fabricating laminate nanomolds and nanoparticles therefrom |
| WO2008105189A1 (ja) | 2007-02-28 | 2008-09-04 | Kaneka Corporation | ゴム状重合体粒子分散熱硬化性樹脂組成物、及びその製造方法 |
| KR101433413B1 (ko) | 2007-03-20 | 2014-08-26 | 디에스엠 아이피 어셋츠 비.브이. | 입체리소그래피 수지 조성물 및 이로부터 제조된 3차원 물체 |
| JP5606308B2 (ja) | 2007-04-03 | 2014-10-15 | ビーエーエスエフ ソシエタス・ヨーロピア | 光活性窒素塩基 |
| US8088245B2 (en) | 2007-04-11 | 2012-01-03 | Dow Global Technologies Llc | Structural epoxy resins containing core-shell rubbers |
| CN101679579B (zh) | 2007-06-20 | 2012-05-30 | 陶氏环球技术公司 | 对温度变化的敏感性非常低的耐碰撞环氧粘合剂 |
| DK2052693T4 (da) | 2007-10-26 | 2021-03-15 | Envisiontec Gmbh | Proces og fri-formfabrikationssystem til at fremstille en tredimensionel genstand |
| JP5603256B2 (ja) | 2008-01-23 | 2014-10-08 | ダウ グローバル テクノロジーズ エルエルシー | エポキシ樹脂硬化剤組成物及び前記硬化剤組成物を含むエポキシ樹脂組成物 |
| US8777602B2 (en) | 2008-12-22 | 2014-07-15 | Nederlandse Organisatie Voor Tobgepast-Natuurwetenschappelijk Onderzoek TNO | Method and apparatus for layerwise production of a 3D object |
| DE102009027826A1 (de) | 2009-04-29 | 2010-11-04 | Evonik Degussa Gmbh | Katalyse von Epoxidharzformulierungen |
| US20100280151A1 (en) | 2009-05-04 | 2010-11-04 | Toray Industries, Inc. | Toughened fiber reinforced polymer composite with core-shell particles |
| US20100297745A1 (en) | 2009-05-19 | 2010-11-25 | Nanyang Technological University | Flow-through method of functionalizing inner surfaces of a microfluidic device |
| US9169386B2 (en) | 2009-10-27 | 2015-10-27 | Eco Green Resins, Llc | Organic vegetable oil based resin and preparation method thereof |
| US20120251841A1 (en) | 2009-12-17 | 2012-10-04 | Dsm Ip Assets, B.V. | Liquid radiation curable resins for additive fabrication comprising a triaryl sulfonium borate cationic photoinitiator |
| US8574558B2 (en) | 2010-01-25 | 2013-11-05 | Mycone Dental Supply Co., Inc. | UV-curable nail coating formulations based on renewable polyols |
| ES2934103T3 (es) | 2011-01-31 | 2023-02-16 | Global Filtration Systems Dba Gulf Filtration Systems Inc | Aparato para fabricar objetos tridimensionales a partir de múltiples materiales solidificables |
| KR101722208B1 (ko) * | 2011-07-28 | 2017-05-02 | 주식회사 프로타빅 코리아 | 하이브리드 열경화 접착제 조성물 |
| WO2013021039A1 (en) | 2011-08-11 | 2013-02-14 | Basf Se | Microwave absorbing composition |
| JP2013166893A (ja) * | 2012-02-16 | 2013-08-29 | Jsr Corp | 光学的立体造形用放射線硬化性組成物 |
| US9120270B2 (en) | 2012-04-27 | 2015-09-01 | University Of Southern California | Digital mask-image-projection-based additive manufacturing that applies shearing force to detach each added layer |
| US9636873B2 (en) | 2012-05-03 | 2017-05-02 | B9Creations, LLC | Solid image apparatus with improved part separation from the image plate |
| BR112014032019A2 (pt) | 2012-08-27 | 2017-06-27 | Dow Global Technologies Llc | adesivo, método para fazer um adesivo de epóxi e kit |
| WO2014043048A2 (en) | 2012-09-17 | 2014-03-20 | 3M Innovative Properties Company | Powder coating epoxy compositions, methods, and articles |
| EP3225644A1 (en) * | 2012-10-15 | 2017-10-04 | Daicel Corporation | Curable resin composition, and cured product thereof |
| EP2757118A1 (en) | 2013-01-17 | 2014-07-23 | Allnex Belgium, S.A. | Radiation curable aqueous compositions with reversible drying. |
| EP3187938A1 (en) | 2013-02-12 | 2017-07-05 | CARBON3D, Inc. | Method and apparatus for three-dimensional fabrication with feed through carrier |
| ES2667676T3 (es) * | 2013-02-12 | 2018-05-14 | Carbon, Inc. | Método y aparato para fabricación tridimensional |
| US9080007B2 (en) | 2013-02-28 | 2015-07-14 | Air Products And Chemicals, Inc. | Anhydride accelerators for epoxy resin systems |
| CN112147844B (zh) | 2013-07-04 | 2025-01-28 | 味之素株式会社 | 感光性树脂组合物 |
| JP6414411B2 (ja) | 2013-08-09 | 2018-10-31 | ディーエスエム アイピー アセッツ ビー．ブイ．Ｄｓｍ Ｉｐ Ａｓｓｅｔｓ Ｂ．Ｖ． | 積層造形用の低粘度液状放射線硬化型歯科アライナー成形型用樹脂組成物 |
| KR101956281B1 (ko) * | 2013-08-13 | 2019-03-08 | 삼성전기주식회사 | 수지 조성물, 이를 이용한 인쇄회로기판 및 그 제조방법 |
| US9360757B2 (en) | 2013-08-14 | 2016-06-07 | Carbon3D, Inc. | Continuous liquid interphase printing |
| US20160280864A1 (en) * | 2013-10-08 | 2016-09-29 | Timothy A. Morley | Low odor epoxy resin systems based on nadic anhydride-type hardeners |
| CN103571211A (zh) | 2013-10-13 | 2014-02-12 | 甘春丽 | 双重固化组合物 |
| JP6433651B2 (ja) * | 2013-11-21 | 2018-12-05 | スリーエム イノベイティブ プロパティズ カンパニー | 接着剤、接着剤付部材及び部材間の接続方法 |
| US20160280846A1 (en) * | 2013-12-18 | 2016-09-29 | Dow Global Technologies Llc | Curable compositions |
| US9654377B2 (en) | 2014-01-30 | 2017-05-16 | Thomson Licensing | Per port ethernet packet processing mode by device type |
| US10259171B2 (en) | 2014-04-25 | 2019-04-16 | Carbon, Inc. | Continuous three dimensional fabrication from immiscible liquids |
| BR112016029766A2 (pt) | 2014-06-23 | 2017-08-22 | Carbon Inc | métodos de produção de objetos tridimensionais de poliuretano a partir de materiais tendo múltiplos mecanismos de endurecimento |
| TW201609934A (zh) * | 2014-07-01 | 2016-03-16 | 精工愛普生股份有限公司 | 三維造形用組合物、三維造形物之製造方法及三維造形物 |
| JP6509507B2 (ja) | 2014-07-17 | 2019-05-08 | 任天堂株式会社 | ゲームシステム、端末装置、コンピュータプログラム及び情報表示方法 |
| US9574039B1 (en) | 2014-07-22 | 2017-02-21 | Full Spectrum Laser | Additive use in photopolymer resin for 3D printing to enhance the appearance of printed parts |
| KR101514746B1 (ko) * | 2014-08-28 | 2015-04-23 | 애경화학 주식회사 | 정밀주조 열분해 마스터모델 성형용 광경화 조성물 |
| WO2016145050A1 (en) * | 2015-03-10 | 2016-09-15 | Carbon3D, Inc. | Microfluidic devices having flexible features and methods of making the same |
| CN104842565A (zh) * | 2015-05-14 | 2015-08-19 | 何岷洪 | 一种快速液体界面3d打印系统 |
| US9708440B2 (en) | 2015-06-18 | 2017-07-18 | Novoset, Llc | High temperature three dimensional printing compositions |
-
2016
- 2016-09-02 EP EP16766749.2A patent/EP3347399B1/en active Active
- 2016-09-02 CN CN201680050993.0A patent/CN108291011B/zh active Active
- 2016-09-02 WO PCT/US2016/050043 patent/WO2017044381A1/en not_active Ceased
- 2016-09-02 JP JP2018512552A patent/JP6845226B2/ja active Active
- 2016-09-02 US US15/754,681 patent/US10975193B2/en active Active
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2021
- 2021-03-04 US US17/192,768 patent/US11814472B2/en active Active
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