JP2016540730A5 - - Google Patents
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- Publication number
- JP2016540730A5 JP2016540730A5 JP2016524003A JP2016524003A JP2016540730A5 JP 2016540730 A5 JP2016540730 A5 JP 2016540730A5 JP 2016524003 A JP2016524003 A JP 2016524003A JP 2016524003 A JP2016524003 A JP 2016524003A JP 2016540730 A5 JP2016540730 A5 JP 2016540730A5
- Authority
- JP
- Japan
- Prior art keywords
- methyl
- group
- silane compound
- vinyl silane
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 claims description 29
- 229920000642 polymer Polymers 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 18
- 238000006116 polymerization reaction Methods 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 7
- 239000003921 oil Substances 0.000 claims description 4
- 239000004606 Fillers/Extenders Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- -1 vinylsilane compound Chemical class 0.000 claims 30
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 20
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 11
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 7
- 238000004519 manufacturing process Methods 0.000 claims 7
- 229910052739 hydrogen Inorganic materials 0.000 claims 6
- 239000001257 hydrogen Substances 0.000 claims 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 5
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims 5
- 125000002877 alkyl aryl group Chemical group 0.000 claims 4
- 125000003118 aryl group Chemical group 0.000 claims 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 3
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical group C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims 3
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 3
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 3
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 3
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 3
- 229910052757 nitrogen Inorganic materials 0.000 claims 3
- 125000004433 nitrogen atom Chemical group N* 0.000 claims 3
- 125000000160 oxazolidinyl group Chemical group 0.000 claims 3
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 claims 3
- 125000003386 piperidinyl group Chemical group 0.000 claims 3
- 229920002554 vinyl polymer Polymers 0.000 claims 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 150000004982 aromatic amines Chemical class 0.000 claims 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 2
- 229910052736 halogen Inorganic materials 0.000 claims 2
- 125000005843 halogen group Chemical group 0.000 claims 2
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 2
- 239000000178 monomer Substances 0.000 claims 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 2
- 125000000719 pyrrolidinyl group Chemical group 0.000 claims 2
- 239000002516 radical scavenger Substances 0.000 claims 2
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 claims 2
- 239000000377 silicon dioxide Substances 0.000 claims 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 2
- 125000006710 (C2-C12) alkenyl group Chemical group 0.000 claims 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims 1
- 229920002472 Starch Polymers 0.000 claims 1
- 125000003342 alkenyl group Chemical group 0.000 claims 1
- 125000000304 alkynyl group Chemical group 0.000 claims 1
- 238000010539 anionic addition polymerization reaction Methods 0.000 claims 1
- 125000000129 anionic group Chemical group 0.000 claims 1
- 229910000019 calcium carbonate Inorganic materials 0.000 claims 1
- 239000006229 carbon black Substances 0.000 claims 1
- 239000002041 carbon nanotube Substances 0.000 claims 1
- 229910021393 carbon nanotube Inorganic materials 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical group NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 claims 1
- 125000006312 cyclopentyl amino group Chemical group [H]N(*)C1([H])C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 claims 1
- 238000013016 damping Methods 0.000 claims 1
- 150000001993 dienes Chemical class 0.000 claims 1
- 239000011521 glass Substances 0.000 claims 1
- 229910021389 graphene Inorganic materials 0.000 claims 1
- 229910002804 graphite Inorganic materials 0.000 claims 1
- 239000010439 graphite Substances 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 239000003999 initiator Substances 0.000 claims 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims 1
- 229920005610 lignin Polymers 0.000 claims 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims 1
- 239000001095 magnesium carbonate Substances 0.000 claims 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 150000003139 primary aliphatic amines Chemical class 0.000 claims 1
- 150000003254 radicals Chemical class 0.000 claims 1
- 150000005619 secondary aliphatic amines Chemical class 0.000 claims 1
- 239000008107 starch Substances 0.000 claims 1
- 235000019698 starch Nutrition 0.000 claims 1
- 125000004434 sulfur atom Chemical group 0.000 claims 1
- 229910052723 transition metal Inorganic materials 0.000 claims 1
- 150000003624 transition metals Chemical class 0.000 claims 1
- GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 claims 1
- 238000010626 work up procedure Methods 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 2
- 238000013329 compounding Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/EP2013/071850 WO2015055252A1 (en) | 2013-10-18 | 2013-10-18 | Vinylsilanes for use in functionalized elastomeric polymers |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2016540730A JP2016540730A (ja) | 2016-12-28 |
| JP2016540730A5 true JP2016540730A5 (enExample) | 2018-09-27 |
| JP6461940B2 JP6461940B2 (ja) | 2019-01-30 |
Family
ID=49515326
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016524003A Active JP6461940B2 (ja) | 2013-10-18 | 2013-10-18 | 機能性をもたせたエラストマー重合体における使用のためのビニルシラン |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US10077279B2 (enExample) |
| EP (1) | EP3057974B1 (enExample) |
| JP (1) | JP6461940B2 (enExample) |
| KR (1) | KR102090361B1 (enExample) |
| CN (1) | CN105683203B (enExample) |
| ES (1) | ES2654204T3 (enExample) |
| HU (1) | HUE035157T2 (enExample) |
| MX (1) | MX2016005026A (enExample) |
| PL (1) | PL3057974T3 (enExample) |
| RU (1) | RU2669799C2 (enExample) |
| SA (1) | SA114350791B1 (enExample) |
| SG (1) | SG11201603025RA (enExample) |
| TW (1) | TWI637962B (enExample) |
| WO (1) | WO2015055252A1 (enExample) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITUB20153129A1 (it) * | 2015-08-14 | 2017-02-14 | Directa Plus Spa | Composizione elastomerica comprendente grafene e componenti di pneumatico comprendenti detta composizione. |
| HUE039540T2 (hu) | 2015-10-21 | 2019-01-28 | Trinseo Europe Gmbh | Elasztomer polimerek funkcionalizálása során történõ alkalmazásra szolgáló aminoszilán-funkcionalizált diének |
| JP6759567B2 (ja) * | 2015-12-03 | 2020-09-23 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物の製造方法 |
| EP3241853A1 (de) | 2016-05-04 | 2017-11-08 | Trinseo Europe GmbH | Elastomere polymere mit thioether-modifiziertem rückgrat |
| DE102016207744A1 (de) | 2016-05-04 | 2017-11-09 | Continental Reifen Deutschland Gmbh | Kautschukmischung, Vulkanisat der Kautschukmischung und Fahrzeugreifen |
| PL3257869T3 (pl) * | 2016-06-17 | 2019-07-31 | Trinseo Europe Gmbh | Zwiększenie stabilności magazynowania gumy dzięki zastosowaniu silanu |
| CN106433174A (zh) * | 2016-07-30 | 2017-02-22 | 山东胜伟园林科技有限公司 | 一种含木质素的排盐暗管及其制备方法 |
| US11124590B2 (en) | 2016-11-02 | 2021-09-21 | Public Joint Stock Company “SIBUR Holding” | Method of producing a modified diene-containing rubber, the rubber and a composition based thereon |
| JP6720913B2 (ja) * | 2017-04-18 | 2020-07-08 | 信越化学工業株式会社 | 不飽和結合含有ビスシリル化合物およびその製造方法 |
| EP3434697B1 (en) | 2017-07-27 | 2021-09-01 | Trinseo Europe GmbH | In-situ polymer blend for a tire |
| EP3434699B1 (en) * | 2017-07-27 | 2020-01-01 | Trinseo Europe GmbH | Use of specific aminosilyl monomers in the manufacture of rubber |
| EP3548499B1 (en) * | 2017-08-08 | 2020-09-23 | Synthos Dwory 7 spolka z ograniczona odpowiedzialnoscia spolka jawna | Bissilylaminosilyl-functionalized conjugated dienes and their use in the production of rubbers |
| JP7305368B2 (ja) * | 2018-02-16 | 2023-07-10 | 住友化学株式会社 | 共役ジエン系重合体、共役ジエン系重合体組成物、及び共役ジエン系重合体の製造方法 |
| US12304985B2 (en) * | 2018-07-19 | 2025-05-20 | Shell Usa, Inc. | Process for preparing sulfur containing organosilane polymers |
| CN109575203B (zh) * | 2018-12-04 | 2021-08-20 | 台州泰捷化工科技有限公司 | 高韧性汽车防水密封条及其制备方法 |
| JP7541012B2 (ja) | 2019-01-24 | 2024-08-27 | シントス エス．アー． | ビスシリルアミノ官能化共役ジエン、それらの調製及びゴムの製造におけるそれらの使用 |
| US11180636B2 (en) * | 2019-05-03 | 2021-11-23 | The Goodyear Tire & Rubber Company | Functionalized initiator, method of making initiator and functionalized elastomer |
| US10711084B1 (en) * | 2019-05-03 | 2020-07-14 | The Goodyear Tire & Rubber Company | In-chain functionalized elastomer, rubber composition and pneumatic tire |
| EP3932862A1 (de) | 2020-07-01 | 2022-01-05 | Evonik Operations GmbH | Funktionalisiertes graphen, verfahren zur herstellung eines funktionalisierten graphens und dessen verwendung |
| EP4026800A1 (de) | 2021-01-08 | 2022-07-13 | Evonik Operations GmbH | Hoch gefülltes trans-polyoktenamer-graphen-verbundmaterial, verfahren zu dessen herstellung und dessen verwendung |
| EP4186911A1 (en) | 2021-11-30 | 2023-05-31 | Trinseo Europe GmbH | Amine-containing vinyldisiloxanes in the manufacture of elastomeric polymers |
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| US3078254A (en) | 1959-07-20 | 1963-02-19 | Phillips Petroleum Co | High molecular polymers and method for their preparation |
| US3244664A (en) | 1960-10-24 | 1966-04-05 | Phillips Petroleum Co | Silicon-containing polymers |
| US3281383A (en) | 1962-08-09 | 1966-10-25 | Phillips Petroleum Co | Branched polymers prepared from monolithium-terminated polymers and compounds having at least three reactive sites |
| US3485857A (en) | 1966-12-05 | 1969-12-23 | Dow Corning | Organometallic aminosilicon compounds |
| US3692874A (en) | 1970-09-02 | 1972-09-19 | Ralph C Farrar | Process of coupling alkali metal-terminated polymers with silicic compound in presence of conjugated dienes |
| JPS506240B1 (enExample) * | 1970-12-30 | 1975-03-12 | ||
| US3978103A (en) | 1971-08-17 | 1976-08-31 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler | Sulfur containing organosilicon compounds |
| FR2286832A1 (fr) * | 1974-10-01 | 1976-04-30 | Rhone Poulenc Ind | Composes silicies ethyleniques a groupements fonctionnels |
| US4147711A (en) | 1974-10-01 | 1979-04-03 | Rhone-Poulenc Industries | Ethylenic silicon compounds and thermoplastic elastomers obtained therefrom |
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| DE19844607A1 (de) | 1998-09-29 | 2000-03-30 | Degussa | Sulfanylsilane |
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| DE10354616A1 (de) | 2003-11-21 | 2005-06-23 | Degussa Ag | Kautschukmischungen |
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| PL1963110T3 (pl) | 2005-10-19 | 2010-01-29 | Trinseo Europe Gmbh | Elastomeryczne polimery modyfikowane silano-sulfidowymi końcami łańcucha |
| MX2010013397A (es) | 2008-06-06 | 2011-05-10 | Styron Europe Gmbh | Polimeros elastomericos modificados. |
| SG159474A1 (en) | 2008-08-27 | 2010-03-30 | Sumitomo Chemical Co | Conjugated diene polymer, conjugated diene polymer composition, and method for producing conjugated diene polymer |
| CN101659732A (zh) | 2008-08-27 | 2010-03-03 | 住友化学株式会社 | 共轭二烯系聚合物、共轭二烯系聚合物组合物及其制造方法 |
| TW201026727A (en) | 2008-08-27 | 2010-07-16 | Sumitomo Chemical Co | Conjugated diene polymer, conjugated diene polymer composition, and method for porducing conjugated diene polymer |
| EP2470574B1 (en) | 2009-08-24 | 2014-09-17 | Bridgestone Corporation | Process and catalyst system for polydiene production |
| JP2012131893A (ja) | 2010-12-21 | 2012-07-12 | Sumitomo Rubber Ind Ltd | ゴム組成物及びスタッドレスタイヤ |
| JP2012131890A (ja) | 2010-12-21 | 2012-07-12 | Sumitomo Rubber Ind Ltd | ゴム組成物及びスタッドレスタイヤ |
| JP2012131892A (ja) | 2010-12-21 | 2012-07-12 | Sumitomo Rubber Ind Ltd | ゴム組成物及びスタッドレスタイヤ |
| JP2012131891A (ja) | 2010-12-21 | 2012-07-12 | Sumitomo Rubber Ind Ltd | ゴム組成物及びスタッドレスタイヤ |
| JP5643077B2 (ja) | 2010-12-27 | 2014-12-17 | 住友ゴム工業株式会社 | ゴム組成物及びスタッドレスタイヤ |
| EP2658727B1 (en) * | 2010-12-30 | 2014-12-03 | Bridgestone Corporation | Aminosilane initiators and functionalized polymers prepared therefrom |
| JP5727895B2 (ja) | 2011-02-02 | 2015-06-03 | 住友ゴム工業株式会社 | ゴム組成物及び空気入りタイヤ |
| BR112013027016A2 (pt) | 2011-04-22 | 2017-03-01 | Sumitomo Rubber Ind | composição de borracha e pneumático |
| JP5817377B2 (ja) | 2011-09-20 | 2015-11-18 | 住友ベークライト株式会社 | シリコーンゴム系硬化性組成物、シリコーンゴムの製造方法、シリコーンゴム、成形体および医療用チューブ |
| US8865829B2 (en) | 2011-11-22 | 2014-10-21 | The Goodyear Tire & Rubber Company | Functionalized polymer, rubber composition and pneumatic tire |
| BR112014011261A2 (pt) * | 2011-11-24 | 2017-04-25 | Sumitomo Rubber Ind | composição de borracha, e pneumático |
| US9458253B2 (en) | 2012-09-14 | 2016-10-04 | Trinseo Europe Gmbh | Amino silane-modified polymers |
| CN105008377B (zh) | 2012-09-14 | 2018-07-06 | 盛禧奥欧洲有限责任公司 | 硅烷硫化物改性弹性体聚合物 |
| KR20160033105A (ko) | 2013-07-22 | 2016-03-25 | 트린세오 유럽 게엠베하 | 중합 개시제 |
-
2013
- 2013-10-18 JP JP2016524003A patent/JP6461940B2/ja active Active
- 2013-10-18 KR KR1020167012607A patent/KR102090361B1/ko active Active
- 2013-10-18 US US15/030,240 patent/US10077279B2/en active Active
- 2013-10-18 PL PL13785383T patent/PL3057974T3/pl unknown
- 2013-10-18 WO PCT/EP2013/071850 patent/WO2015055252A1/en not_active Ceased
- 2013-10-18 RU RU2016118991A patent/RU2669799C2/ru active
- 2013-10-18 EP EP13785383.4A patent/EP3057974B1/en active Active
- 2013-10-18 ES ES13785383.4T patent/ES2654204T3/es active Active
- 2013-10-18 SG SG11201603025RA patent/SG11201603025RA/en unknown
- 2013-10-18 HU HUE13785383A patent/HUE035157T2/en unknown
- 2013-10-18 MX MX2016005026A patent/MX2016005026A/es unknown
- 2013-10-18 CN CN201380080315.5A patent/CN105683203B/zh active Active
-
2014
- 2014-08-21 TW TW103128797A patent/TWI637962B/zh active
- 2014-10-15 SA SA114350791A patent/SA114350791B1/ar unknown
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