JP2016166329A - 感圧接着剤組成物およびインクジェット記録用圧着シート - Google Patents
感圧接着剤組成物およびインクジェット記録用圧着シート Download PDFInfo
- Publication number
- JP2016166329A JP2016166329A JP2016018413A JP2016018413A JP2016166329A JP 2016166329 A JP2016166329 A JP 2016166329A JP 2016018413 A JP2016018413 A JP 2016018413A JP 2016018413 A JP2016018413 A JP 2016018413A JP 2016166329 A JP2016166329 A JP 2016166329A
- Authority
- JP
- Japan
- Prior art keywords
- pressure
- sensitive adhesive
- sheet
- adhesive composition
- pressure sensitive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004820 Pressure-sensitive adhesive Substances 0.000 title claims abstract description 89
- 239000000203 mixture Substances 0.000 title claims abstract description 25
- 239000000853 adhesive Substances 0.000 claims abstract description 45
- 230000001070 adhesive effect Effects 0.000 claims abstract description 44
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229920001577 copolymer Polymers 0.000 claims abstract description 25
- 229920006317 cationic polymer Polymers 0.000 claims abstract description 20
- 239000000945 filler Substances 0.000 claims abstract description 17
- 239000010419 fine particle Substances 0.000 claims abstract description 17
- 229910002029 synthetic silica gel Inorganic materials 0.000 claims abstract description 10
- 239000010410 layer Substances 0.000 claims description 34
- 239000003292 glue Substances 0.000 claims description 9
- 238000013329 compounding Methods 0.000 claims description 2
- 238000002788 crimping Methods 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 12
- 238000000034 method Methods 0.000 abstract description 12
- 238000013518 transcription Methods 0.000 abstract 2
- 230000035897 transcription Effects 0.000 abstract 2
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
- 238000012546 transfer Methods 0.000 description 22
- 239000000123 paper Substances 0.000 description 16
- 239000001023 inorganic pigment Substances 0.000 description 15
- 238000007639 printing Methods 0.000 description 14
- -1 amine compound Chemical class 0.000 description 11
- 239000000377 silicon dioxide Substances 0.000 description 9
- 229920006173 natural rubber latex Polymers 0.000 description 8
- 229920001131 Pulp (paper) Polymers 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 229920000126 latex Polymers 0.000 description 4
- 239000004816 latex Substances 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- 235000019698 starch Nutrition 0.000 description 4
- 244000043261 Hevea brasiliensis Species 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 230000000903 blocking effect Effects 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920003052 natural elastomer Polymers 0.000 description 3
- 229920001194 natural rubber Polymers 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 125000000320 amidine group Chemical group 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 238000010009 beating Methods 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 238000003490 calendering Methods 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000003623 enhancer Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 239000011121 hardwood Substances 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000002655 kraft paper Substances 0.000 description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 2
- 239000001095 magnesium carbonate Substances 0.000 description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000011164 primary particle Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000011122 softwood Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 244000215068 Acacia senegal Species 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 239000004368 Modified starch Substances 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 1
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 1
- 125000006294 amino alkylene group Chemical group 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- BXKDSDJJOVIHMX-UHFFFAOYSA-N edrophonium chloride Chemical compound [Cl-].CC[N+](C)(C)C1=CC=CC(O)=C1 BXKDSDJJOVIHMX-UHFFFAOYSA-N 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 229910052621 halloysite Inorganic materials 0.000 description 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 229940098779 methanesulfonic acid Drugs 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 229940005657 pyrophosphoric acid Drugs 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Credit Cards Or The Like (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Adhesive Tapes (AREA)
Abstract
Description
R1及びR2は、水素原子または炭素数1〜10のアルキル基を表し、炭素数1〜10のアルキル基は、より好ましくは炭素数1〜4のアルキル基であり、特に好ましくは炭素数1〜2のアルキル基である。A−は陰イオンを表し、AHで表される酸の対イオンである。AHで表される酸としては、無機酸、有機酸のいずれでもよく、例えば、塩酸、硫酸、硝酸、リン酸、ピロリン酸、メタンスルホン酸、p−トルエンスルホン酸等が挙げられ、特に塩酸、硫酸であることが好ましい。
インクジェットプリンター(商品名「MP−990」、Canon製)に水性マゼンタインク(商品名「BCI−321M」、Canon製)を注入し、テスト印字パターンを圧着シートに印字した。印字後の圧着シートを幅25mm、長さ100mmに裁断して試料を作成し、この試料2枚を25mmの長さで重ね合わせ7MPaの荷重を加えて圧着した。これを接着剤の剥離接着強さ試験方法JIS−K6854に準じて、万能試験機(商品名「テンシロン」、オリエンテック社製)を用いてT型剥離試験を行い、剥離面の印字物の転写の有無を目視観察して以下のように評価した。△以上を合格とした。
◎:転写が無い
○:転写が見られるが、文字やバーコードを読み取ることはできない
△:転写した文字やバーコードが辛うじて読み取れる
×:転写した文字やバーコードがはっきり読み取れる
接着剤基剤として、天然ゴムにメタクリル酸メチルをグラフト重合させた天然ゴム系ラテックス100質量部に対して、カチオン性ポリマーとしてビニルアミジン共重合物(商品名「KP7000」、ダイヤニトリックス社製)を10質量部、BET比表面積370m2/gの多孔性合成非晶質シリカ(商品名「NIPGEL AY−4A2」、東ソー・シリカ社製)を50質量部、平均粒子径20μmのスターチ80質量部を調製した。これを上質紙100g/m2からなる支持体の片面に感圧接着剤層として乾燥質量で7g/m2塗工して、圧着シートを得た。
カチオン性ポリマーとして、ビニルアミジン共重合物(商品名「ハイマックスSC−700」、ハイモ社製)を、天然ゴム系ラテックス100質量部に対して10質量部配合した以外は、実施例1と同様にして圧着シートを得た。
BET比表面積220m2/gの多孔性合成非晶質シリカ(商品名「NIPGEL AY−451」、東ソー・シリカ社製)を使用した以外は、実施例1と同様にして圧着シートを得た。
多孔性合成非晶質シリカを天然ゴム系ラテックス100質量部に対して150質量部配合した以外は、実施例1と同様にして圧着シートを得た。
カチオン性ポリマーとして、ビニルアミジン共重合物を、天然ゴム系ラテックス100質量部に対して0.1質量部配合した以外は、実施例1と同様にして圧着シートを得た。
感圧接着剤層を支持体の片面に乾燥質量で4g/m2塗工した以外は、実施例1と同様にして圧着シートを得た。
カチオン性ポリマーとして、ビニルアミン共重合物(商品名「カチオファストVFH」、星光PMC社製)を、天然ゴム系ラテックス100質量部に対して10質量部配合した以外は、実施例1と同様にして圧着シートを得た。
カチオン性ポリマーとして、メチルジアリルアミン共重合物(商品名「PAS−M−1」、ニットーボーメディカル社製)を、天然ゴム系ラテックス100質量部に対して10質量部配合した以外は、実施例1と同様にして圧着シートを得た。
Claims (9)
- 接着剤基剤、微粒子充填剤及びカチオン性ポリマーを含み、該カチオン性ポリマーの全てまたは一部がビニルアミジン共重合物である感圧接着剤組成物。
- 前記ビニルアミジン共重合物の配合量が、質量比で前記接着剤基剤100部に対して1〜50部である感圧接着剤組成物。
- 前記微粒子充填剤のBET比表面積が350m2/g以上である、請求項1または2のいずれかに記載の感圧接着剤組成物。
- 前記微粒子充填剤が多孔性合成非晶質シリカである、請求項3に記載の感圧接着剤組成物。
- 前記微粒子充填剤が、前記接着剤基剤100部に対して質量比で30〜120部含まれる、請求項3または4のいずれかに記載の感圧接着剤組成物。
- 先糊用である、請求項1〜5のいずれかに記載の感圧接着剤組成物。
- 少なくとも片面に感圧接着剤層を有する圧着シートであって、該感圧接着剤層が請求項1〜6のいずれかに記載の感圧接着剤組成物からなる、インクジェット記録用圧着シート。
- 前記感圧接着剤層が乾燥質量で5〜15g/m2である、請求項7に記載のインクジェット記録用圧着シート。
- 前記圧着シートが先糊用圧着シートである、請求項7または8のいずれかに記載のインクジェット記録用圧着シート。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2015044101 | 2015-03-05 | ||
| JP2015044101 | 2015-03-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2016166329A true JP2016166329A (ja) | 2016-09-15 |
Family
ID=56898150
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016018413A Pending JP2016166329A (ja) | 2015-03-05 | 2016-02-02 | 感圧接着剤組成物およびインクジェット記録用圧着シート |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2016166329A (ja) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0839927A (ja) * | 1994-08-01 | 1996-02-13 | Hymo Corp | 紙の表面塗布剤 |
| JP2005125639A (ja) * | 2003-10-24 | 2005-05-19 | Mitsubishi Paper Mills Ltd | 高速輪転インクジェット記録用圧着葉書用紙 |
| JP2005131987A (ja) * | 2003-10-31 | 2005-05-26 | Lintec Corp | インクジェット記録用シート |
-
2016
- 2016-02-02 JP JP2016018413A patent/JP2016166329A/ja active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0839927A (ja) * | 1994-08-01 | 1996-02-13 | Hymo Corp | 紙の表面塗布剤 |
| JP2005125639A (ja) * | 2003-10-24 | 2005-05-19 | Mitsubishi Paper Mills Ltd | 高速輪転インクジェット記録用圧着葉書用紙 |
| JP2005131987A (ja) * | 2003-10-31 | 2005-05-26 | Lintec Corp | インクジェット記録用シート |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2009138317A (ja) | 印刷用塗工紙 | |
| JP3392649B2 (ja) | インクジェット記録用圧着葉書用紙 | |
| JP4017532B2 (ja) | インクジェット記録用圧着葉書用紙 | |
| JP6344822B2 (ja) | インクジェット記録用圧着紙 | |
| JP2005125639A (ja) | 高速輪転インクジェット記録用圧着葉書用紙 | |
| JP2004082466A (ja) | 感圧接着シート | |
| JP2001219680A (ja) | 隠蔽葉書 | |
| JP3105943B2 (ja) | インクジェット記録用ラベル | |
| JP2009270220A (ja) | 封入封緘シート用塗工紙 | |
| JP4037430B2 (ja) | 圧着用紙 | |
| JP6590615B2 (ja) | 圧着葉書用紙 | |
| JP4767490B2 (ja) | 高速輪転インクジェット記録用圧着葉書用紙 | |
| JP4849658B2 (ja) | 記録用紙、それを用いた擬似接着記録用紙 | |
| JP4332303B2 (ja) | 圧着記録用紙 | |
| JP6722970B2 (ja) | 感圧接着剤組成物および圧着シート | |
| JP4640890B2 (ja) | 再剥離性圧着記録用紙 | |
| JP2004216669A (ja) | 高速輪転インクジェット記録用圧着葉書用紙 | |
| JP6177209B2 (ja) | 圧着用原紙および圧着用紙 | |
| JP3909748B2 (ja) | 再剥離性圧着記録用紙 | |
| JP2019031765A (ja) | 圧着用印刷用紙および圧着用紙 | |
| JP2019035164A (ja) | 圧着用原紙および圧着用紙 | |
| JP2001354928A (ja) | 圧着シート | |
| JP2005126859A (ja) | 圧着記録用紙 | |
| JP3696868B2 (ja) | 擬似接着用紙 | |
| JP2000335102A (ja) | インクジェット記録シート |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20170927 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20180625 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20180702 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20180820 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20181031 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20181115 |
