JP2015522084A - 熱可塑性樹脂組成物およびこれを用いた成形品 - Google Patents
熱可塑性樹脂組成物およびこれを用いた成形品 Download PDFInfo
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- JP2015522084A JP2015522084A JP2015519995A JP2015519995A JP2015522084A JP 2015522084 A JP2015522084 A JP 2015522084A JP 2015519995 A JP2015519995 A JP 2015519995A JP 2015519995 A JP2015519995 A JP 2015519995A JP 2015522084 A JP2015522084 A JP 2015522084A
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- acrylate
- copolymer
- thermoplastic resin
- meth
- resin composition
- Prior art date
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- 229920005992 thermoplastic resin Polymers 0.000 title claims abstract description 54
- 239000011342 resin composition Substances 0.000 title claims abstract description 46
- 229920001577 copolymer Polymers 0.000 claims abstract description 70
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 46
- 229920001971 elastomer Polymers 0.000 claims abstract description 41
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 40
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 38
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 36
- 229920000578 graft copolymer Polymers 0.000 claims abstract description 34
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 31
- -1 aromatic vinyl compound Chemical class 0.000 claims description 29
- 239000012792 core layer Substances 0.000 claims description 27
- 229920000642 polymer Polymers 0.000 claims description 13
- 239000012744 reinforcing agent Substances 0.000 claims description 13
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical group CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 11
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 10
- 230000009977 dual effect Effects 0.000 claims description 10
- 229920000058 polyacrylate Polymers 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 229920006164 aromatic vinyl copolymer Polymers 0.000 claims description 5
- ACYXOHNDKRVKLH-UHFFFAOYSA-N 5-phenylpenta-2,4-dienenitrile prop-2-enoic acid Chemical compound OC(=O)C=C.N#CC=CC=CC1=CC=CC=C1 ACYXOHNDKRVKLH-UHFFFAOYSA-N 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 4
- 230000002787 reinforcement Effects 0.000 claims description 4
- 239000003381 stabilizer Substances 0.000 claims description 4
- 239000003242 anti bacterial agent Substances 0.000 claims description 3
- PLOYJEGLPVCRAJ-UHFFFAOYSA-N buta-1,3-diene;prop-2-enoic acid;styrene Chemical compound C=CC=C.OC(=O)C=C.C=CC1=CC=CC=C1 PLOYJEGLPVCRAJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 239000003063 flame retardant Substances 0.000 claims description 3
- 239000000314 lubricant Substances 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 claims description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 2
- 239000000178 monomer Substances 0.000 description 29
- 239000005060 rubber Substances 0.000 description 23
- 229920005989 resin Polymers 0.000 description 19
- 239000011347 resin Substances 0.000 description 19
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical group C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 13
- 238000000034 method Methods 0.000 description 13
- 230000000704 physical effect Effects 0.000 description 10
- 239000002245 particle Substances 0.000 description 9
- 229920002857 polybutadiene Polymers 0.000 description 9
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 8
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 8
- 239000005062 Polybutadiene Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 6
- 229920003244 diene elastomer Polymers 0.000 description 6
- 229920001897 terpolymer Polymers 0.000 description 6
- 229920002943 EPDM rubber Polymers 0.000 description 5
- 239000004566 building material Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229920002379 silicone rubber Polymers 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 4
- 229920009204 Methacrylate-butadiene-styrene Polymers 0.000 description 4
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 4
- 229920000800 acrylic rubber Polymers 0.000 description 4
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 description 4
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 4
- 230000000379 polymerizing effect Effects 0.000 description 4
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 4
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 3
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 3
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 description 3
- 230000009477 glass transition Effects 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 3
- 239000004926 polymethyl methacrylate Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 2
- VDYWHVQKENANGY-UHFFFAOYSA-N 1,3-Butyleneglycol dimethacrylate Chemical compound CC(=C)C(=O)OC(C)CCOC(=O)C(C)=C VDYWHVQKENANGY-UHFFFAOYSA-N 0.000 description 2
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 2
- JJBFVQSGPLGDNX-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)propyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)COC(=O)C(C)=C JJBFVQSGPLGDNX-UHFFFAOYSA-N 0.000 description 2
- XOJWAAUYNWGQAU-UHFFFAOYSA-N 4-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCOC(=O)C(C)=C XOJWAAUYNWGQAU-UHFFFAOYSA-N 0.000 description 2
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 238000012662 bulk polymerization Methods 0.000 description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000004035 construction material Substances 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 238000007333 cyanation reaction Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 2
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 2
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 229920003049 isoprene rubber Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 229920000638 styrene acrylonitrile Polymers 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920006163 vinyl copolymer Polymers 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- OEVVKKAVYQFQNV-UHFFFAOYSA-N 1-ethenyl-2,4-dimethylbenzene Chemical compound CC1=CC=C(C=C)C(C)=C1 OEVVKKAVYQFQNV-UHFFFAOYSA-N 0.000 description 1
- VTPNYMSKBPZSTF-UHFFFAOYSA-N 1-ethenyl-2-ethylbenzene Chemical compound CCC1=CC=CC=C1C=C VTPNYMSKBPZSTF-UHFFFAOYSA-N 0.000 description 1
- XHUZSRRCICJJCN-UHFFFAOYSA-N 1-ethenyl-3-ethylbenzene Chemical compound CCC1=CC=CC(C=C)=C1 XHUZSRRCICJJCN-UHFFFAOYSA-N 0.000 description 1
- WHFHDVDXYKOSKI-UHFFFAOYSA-N 1-ethenyl-4-ethylbenzene Chemical compound CCC1=CC=C(C=C)C=C1 WHFHDVDXYKOSKI-UHFFFAOYSA-N 0.000 description 1
- VSIKJPJINIDELZ-UHFFFAOYSA-N 2,2,4,4,6,6,8,8-octakis-phenyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound O1[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si]1(C=1C=CC=CC=1)C1=CC=CC=C1 VSIKJPJINIDELZ-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- TVONJMOVBKMLOM-UHFFFAOYSA-N 2-methylidenebutanenitrile Chemical compound CCC(=C)C#N TVONJMOVBKMLOM-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- IUMSDRXLFWAGNT-UHFFFAOYSA-N Dodecamethylcyclohexasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 IUMSDRXLFWAGNT-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 125000004104 aryloxy group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- IVRMZWNICZWHMI-UHFFFAOYSA-N azide group Chemical group [N-]=[N+]=[N-] IVRMZWNICZWHMI-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- WWNGFHNQODFIEX-UHFFFAOYSA-N buta-1,3-diene;methyl 2-methylprop-2-enoate;styrene Chemical compound C=CC=C.COC(=O)C(C)=C.C=CC1=CC=CC=C1 WWNGFHNQODFIEX-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000003739 carbamimidoyl group Chemical group C(N)(=N)* 0.000 description 1
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- HAURRGANAANPSQ-UHFFFAOYSA-N cis-2,4,6-Trimethyl-2,4,6-triphenylcyclotrisiloxane Chemical compound O1[Si](C)(C=2C=CC=CC=2)O[Si](C)(C=2C=CC=CC=2)O[Si]1(C)C1=CC=CC=C1 HAURRGANAANPSQ-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 125000000392 cycloalkenyl group Chemical group 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 238000010556 emulsion polymerization method Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- MDNFYIAABKQDML-UHFFFAOYSA-N heptyl 2-methylprop-2-enoate Chemical compound CCCCCCCOC(=O)C(C)=C MDNFYIAABKQDML-UHFFFAOYSA-N 0.000 description 1
- SCFQUKBBGYTJNC-UHFFFAOYSA-N heptyl prop-2-enoate Chemical compound CCCCCCCOC(=O)C=C SCFQUKBBGYTJNC-UHFFFAOYSA-N 0.000 description 1
- HTDJPCNNEPUOOQ-UHFFFAOYSA-N hexamethylcyclotrisiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O1 HTDJPCNNEPUOOQ-UHFFFAOYSA-N 0.000 description 1
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
- 125000000717 hydrazino group Chemical group [H]N([*])N([H])[H] 0.000 description 1
- 125000005638 hydrazono group Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical class O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 125000005439 maleimidyl group Chemical class C1(C=CC(N1*)=O)=O 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- DEAKWVKQKRNPHF-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;prop-2-enenitrile;styrene Chemical compound C=CC#N.COC(=O)C(C)=C.C=CC1=CC=CC=C1 DEAKWVKQKRNPHF-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 description 1
- 229940065472 octyl acrylate Drugs 0.000 description 1
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 description 1
- GYDSPAVLTMAXHT-UHFFFAOYSA-N pentyl 2-methylprop-2-enoate Chemical compound CCCCCOC(=O)C(C)=C GYDSPAVLTMAXHT-UHFFFAOYSA-N 0.000 description 1
- ULDDEWDFUNBUCM-UHFFFAOYSA-N pentyl prop-2-enoate Chemical compound CCCCCOC(=O)C=C ULDDEWDFUNBUCM-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical class [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000007539 photo-oxidation reaction Methods 0.000 description 1
- 229920006124 polyolefin elastomer Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 238000010558 suspension polymerization method Methods 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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Abstract
Description
前記アクリル系グラフト共重合体は、ゴム質重合体に芳香族ビニル化合物−シアン化ビニル化合物共重合体がグラフトされた共重合体であり、具体的には、前記アクリル系グラフト共重合体は、ゴム質重合体とスチレン共重合体を含むコア部に芳香族ビニル化合物−シアン化ビニル化合物共重合体がグラフトされた共重合体である。
前記ポリアルキル(メタ)アクリレートは、加水分解に強く、熱可塑性樹脂組成物の耐スクラッチ性を向上させることができる。
アルキル(メタ)アクリレート−芳香族ビニル−シアン化ビニル共重合体は、(メタ)アクリル酸アルキルエステル単量体または(メタ)アクリル酸エステル単量体、芳香族ビニル化合物単量体およびシアン化ビニル化合物単量体が混合された三元共重合体である。
前記衝撃補強剤としては、グラフト共重合体を用いることができる。前記グラフト共重合体は、ジエン系ゴム、アクリレート系ゴム、およびシリコン系ゴム単量体からなる群より選ばれる1種以上のゴム単量体を重合した後、グラフト共重合が可能なスチレン、α−メチルスチレン;アルキル置換スチレン;アクリロニトリル;メタクリロニトリル;メチルメタクリレート;無水マレイン酸;アルキルまたはフェニル核置換マレイミドなどからなる群より選ばれる1種以上の単量体をゴム質重合体にグラフトさせて製造し、衝撃補強剤中のゴムの含量は20乃至80重量部であり得る。
前記熱可塑性樹脂組成物は、射出成形性および物性バランスなどをさらに付与するために追加的な添加剤をさらに含むことができる。
下記実施例の熱可塑性樹脂組成物の製造に使用される各構成成分は次のとおりである。
ブチルアクリレートとスチレンが共重合された内部コアとブチルアクリレートゴムからなる外部コアから構成された二重コア構造のブチルアクリレートゴム50重量部にそれぞれアクリロニトリル33重量%とスチレン67重量%からなる単量体混合物50重量部をグラフト乳化重合した二重コア−シェル形態のグラフトASA樹脂を用いた。
ブチルアクリレートゴム60重量部にそれぞれアクリロニトリル33重量%とスチレン67重量%からなる単量体混合物40重量部をグラフト乳化重合したゴム粒径が0.5〜0.6μmと0.1〜0.2μmが混在するバイモーダル型(Bi−modal Type)のグラフトASA樹脂を用いた。
メチルメタクリレート単量体を用いて合成されたPMMA樹脂を用いた。前記PMMAの重量平均分子量は約120,000であった。
アクリロニトリル含量が20重量%、スチレン含量が65重量%、メタクリレート含量が15重量%であり、重量平均分子量が約100,000であるMSAN樹脂を用いた。
メチルメタクリレートの含量が25重量%であり、ブタジエンの含量が70重量%であり、スチレンの含量が5重量%であるMBS樹脂を用いた。
下記表1に示した組成で各実施例1乃至3および比較例1乃至4による熱可塑性樹脂組成物を製造した。
前記で製造された物性試片は、下記の方法で物性を測定し、その結果を下記表2に示した。
(1)HAZE(ヘイズ):ASTM D1003の基準により測定した。
(2)IZOD(衝撃強度):ASTM D−256(notched 1/8"試片)により測定した。
(3)MI(溶融指数):ASTM D−1238により測定した。
(4)BSP(Ball type Scratch Profile)幅:Cheil methodに準じて直径0.7mmの先端が円球状であるタングステンカーバイドスタイラス(stylus)を用いてそれぞれ300g、500gおよび1000gの荷重を付与し、75mm/minの速度で試片にスクラッチを付与した後、表面粗度測定器(surface profiler)を用いて粗度観測およびスクラッチ幅(scratch width)を測定した。
アルキル(メタ)アクリレート−芳香族ビニル−シアン化ビニル共重合体は、(メタ)アクリル酸アルキルエステル単量体または(メタ)アクリル酸エステル単量体、芳香族ビニル化合物単量体およびシアン化ビニル化合物単量体が重合された三元共重合体である。
下記表1に示した組成で各実施例1および比較例1乃至4による熱可塑性樹脂組成物を製造した。
Claims (13)
- (A)アクリル系グラフト共重合体;
(B)ポリアルキル(メタ)アクリレート;
(C)アルキル(メタ)アクリレート−芳香族ビニル−シアン化ビニル共重合体;および
(D)衝撃補強剤を含み、
前記アクリル系グラフト共重合体(A)は、ゴム質重合体とスチレン共重合体を含むコア部に芳香族ビニル化合物−シアン化ビニル化合物共重合体がグラフトされるものである、熱可塑性樹脂組成物。 - 前記アクリル系グラフト共重合体(A)は、前記コア部40乃至70重量%と、グラフトされた芳香族ビニル化合物−シアン化ビニル化合物共重合体30乃至60重量%とを含む、請求項1に記載の熱可塑性樹脂組成物。
- 前記芳香族ビニル化合物−シアン化ビニル化合物共重合体は、芳香族ビニル化合物60乃至80重量%と、シアン化ビニル化合物20乃至40重量%とを含む、請求項2に記載の熱可塑性樹脂組成物。
- 前記アクリル系グラフト共重合体は、アルキルアクリレート−芳香族ビニル共重合体を含む内部コア層と、アルキルアクリレート系重合体を含む外部コア層とを含む二重構造コア層のゴム質重合体;および
前記二重構造コア層のゴム質重合体に芳香族ビニル化合物−シアン化ビニル化合物共重合体がグラフトされるものである、請求項1に記載の熱可塑性樹脂組成物。 - 前記アルキルアクリレート−芳香族ビニル共重合体は、アルキルアクリレート化合物20乃至80重量%と、芳香族ビニル化合物80乃至20重量%とを含む、請求項4に記載の熱可塑性樹脂組成物。
- 前記二重構造コア層のゴム質重合体は、内部コア層10乃至50重量%と、外部コア層90乃至50重量%とを含む、請求項4に記載の熱可塑性樹脂組成物。
- 前記アルキルアクリレートは、ブチルアクリレートである、請求項4に記載の熱可塑性樹脂組成物。
- (A)アクリル系グラフト共重合体5乃至50重量部;
(B)ポリアルキル(メタ)アクリレート10乃至80重量部;
(C)アルキル(メタ)アクリレート−芳香族ビニル−シアン化ビニル共重合体20乃至50重量部;および
(D)衝撃補強剤5乃至15重量部
を含む、請求項1に記載の熱可塑性樹脂組成物。 - 前記ポリアルキル(メタ)アクリレート(B)と前記アルキル(メタ)アクリレート−芳香族ビニル−シアン化ビニル共重合体(C)との含量比は、1:1乃至3:1である、請求項1に記載の熱可塑性樹脂組成物。
- 前記アルキル(メタ)アクリレート−芳香族ビニル−シアン化ビニル共重合体(C)は、メチル(メタ)アクリレート−スチレン−アクリロニトリル共重合体である、請求項1に記載の熱可塑性樹脂組成物。
- 前記衝撃補強剤は、アルキル(メタ)アクリレート−ブタジエン−スチレン系(MBS)共重合体である、請求項1に記載の熱可塑性樹脂組成物。
- 前記熱可塑性樹脂組成物は、染料、顔料、難燃剤、充填剤、安定剤、滑剤、抗菌剤、離型剤またはこれらの組み合わせを含む添加剤をさらに含む、請求項1に記載の熱可塑性樹脂組成物。
- 請求項1乃至12のいずれか一項に記載の熱可塑性樹脂組成物を用いて製造された成形品。
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
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KR101644752B1 (ko) | 2014-09-16 | 2016-08-01 | 주식회사 엘지화학 | 열가소성 수지 조성물 및 이로부터 제조된 열가소성 수지 성형품 |
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USD901798S1 (en) | 2018-08-16 | 2020-11-10 | Samsung Electronics Co., Ltd. | Rack for clothing care machine |
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WO2020091371A1 (ko) * | 2018-10-31 | 2020-05-07 | 주식회사 엘지화학 | 열가소성 수지 조성물 |
EP3778763B1 (en) * | 2018-11-13 | 2023-12-27 | Lg Chem, Ltd. | Thermoplastic resin composition |
WO2020101326A1 (ko) * | 2018-11-13 | 2020-05-22 | 주식회사 엘지화학 | 열가소성 수지 조성물 |
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WO2021054679A1 (ko) * | 2019-09-18 | 2021-03-25 | (주) 엘지화학 | 열가소성 수지 조성물, 이의 제조방법 및 이로부터 제조된 성형품 |
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TW202219090A (zh) * | 2020-08-11 | 2022-05-16 | 南韓商Lg化學股份有限公司 | 透明熱塑性樹脂及彼之製備方法 |
WO2022085899A1 (ko) * | 2020-10-22 | 2022-04-28 | (주) 엘지화학 | 열가소성 수지 조성물 및 이로부터 제조된 성형품 |
EP4074779A4 (en) * | 2021-01-22 | 2023-08-02 | Lg Chem, Ltd. | THERMOPLASTIC RESIN COMPOSITION, METHOD FOR PREPARING IT AND MOLDED ARTICLE COMPRISING THEM |
CN113072789A (zh) * | 2021-05-14 | 2021-07-06 | 浙江凯信光电科技有限公司 | 一种pmma/mbs/as聚合物复合材料ams及其制备方法 |
US11970977B2 (en) | 2022-08-26 | 2024-04-30 | Hamilton Sundstrand Corporation | Variable restriction of a secondary circuit of a fuel injector |
KR20240082789A (ko) | 2022-12-02 | 2024-06-11 | 주식회사 엘지화학 | 수지 조성물 및 이의 제조방법 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5736146A (en) * | 1980-08-13 | 1982-02-26 | Mitsubishi Rayon Co Ltd | Resin composition for exterior use without coating |
JP2009535476A (ja) * | 2006-05-04 | 2009-10-01 | チェイル インダストリーズ インコーポレイテッド | 耐スクラッチ性に優れた樹脂組成物 |
JP2009540045A (ja) * | 2006-06-08 | 2009-11-19 | チェイル インダストリーズ インコーポレイテッド | 衝撃強度、着色性、及び耐候性に優れたアクリレート−芳香族ビニル−不飽和ニトリル系グラフト共重合体並びにこれを含有する熱可塑性樹脂組成物 |
JP2011132528A (ja) * | 2009-12-23 | 2011-07-07 | Cheil Industries Inc | 耐スクラッチ性に優れた熱可塑性樹脂組成物およびこれを用いた成形品 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6476126B1 (en) | 1999-04-07 | 2002-11-05 | Bayer Corporation | Weatherable molding composition having improved surface appearance |
CA2299874C (en) | 1999-04-07 | 2009-09-15 | Bayer Corporation | Weatherable molding composition having improved surface appearance |
KR100360987B1 (ko) | 2000-07-06 | 2002-11-18 | 주식회사 엘지화학 | 열가소성 투명수지의 제조방법 |
KR100509868B1 (ko) | 2003-06-09 | 2005-08-22 | 주식회사 엘지화학 | 내후성 및 외관특성이 우수한 열가소성 수지 조성물 |
US8084550B2 (en) * | 2005-05-23 | 2011-12-27 | Sabic Innovative Plastics Ip B.V. | Low gloss thermoplastic composition |
KR101182453B1 (ko) | 2008-10-24 | 2012-09-12 | 주식회사 엘지화학 | 내스크래치성과 내열성이 우수한 내후성 열가소성 수지 조성물 |
KR101314203B1 (ko) | 2009-11-20 | 2013-10-02 | 주식회사 엘지화학 | 내스크래치성 및 블랙감이 우수한 열가소성 수지 조성물, 및 상기 조성물에 의해 형성된 성형품 |
KR101282707B1 (ko) | 2009-12-30 | 2013-07-05 | 제일모직주식회사 | 코어-쉘 구조를 포함하는 그라프트 공중합체로 이루어지는 실리콘계 충격보강제 및 이를 포함하는 열가소성 조성물 |
KR101399390B1 (ko) * | 2010-10-20 | 2014-05-27 | 제일모직주식회사 | 저온 백화가 발생하지 않는 고투명, 고충격 열가소성 수지 조성물 |
KR101486564B1 (ko) | 2012-07-04 | 2015-01-26 | 제일모직 주식회사 | 열가소성 수지 조성물 및 이를 이용한 성형품 |
-
2012
- 2012-07-04 KR KR20120072948A patent/KR101486564B1/ko active IP Right Grant
- 2012-12-18 JP JP2015519995A patent/JP6247288B2/ja active Active
- 2012-12-18 US US14/412,306 patent/US9469759B2/en active Active
- 2012-12-18 WO PCT/KR2012/011041 patent/WO2014007442A1/ko active Application Filing
- 2012-12-18 CN CN201280075600.3A patent/CN104603198B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5736146A (en) * | 1980-08-13 | 1982-02-26 | Mitsubishi Rayon Co Ltd | Resin composition for exterior use without coating |
JP2009535476A (ja) * | 2006-05-04 | 2009-10-01 | チェイル インダストリーズ インコーポレイテッド | 耐スクラッチ性に優れた樹脂組成物 |
JP2009540045A (ja) * | 2006-06-08 | 2009-11-19 | チェイル インダストリーズ インコーポレイテッド | 衝撃強度、着色性、及び耐候性に優れたアクリレート−芳香族ビニル−不飽和ニトリル系グラフト共重合体並びにこれを含有する熱可塑性樹脂組成物 |
JP2011132528A (ja) * | 2009-12-23 | 2011-07-07 | Cheil Industries Inc | 耐スクラッチ性に優れた熱可塑性樹脂組成物およびこれを用いた成形品 |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2018507923A (ja) * | 2015-11-30 | 2018-03-22 | エルジー・ケム・リミテッド | 熱可塑性樹脂組成物及びそれから製造される成形品 |
JP2021521316A (ja) * | 2018-11-13 | 2021-08-26 | エルジー・ケム・リミテッド | 熱可塑性樹脂組成物 |
JP7076882B2 (ja) | 2018-11-13 | 2022-05-30 | エルジー・ケム・リミテッド | 熱可塑性樹脂組成物 |
US11377547B2 (en) | 2018-11-13 | 2022-07-05 | Lg Chem, Ltd. | Thermoplastic resin composition |
JP2022528145A (ja) * | 2019-10-07 | 2022-06-08 | エルジー・ケム・リミテッド | Asa系樹脂組成物、それを含む成形品及びその成形品の製造方法 |
JP2022552188A (ja) * | 2020-08-11 | 2022-12-15 | エルジー・ケム・リミテッド | 透明熱可塑性樹脂及びその製造方法 |
JP7391200B2 (ja) | 2020-08-11 | 2023-12-04 | エルジー・ケム・リミテッド | 透明熱可塑性樹脂及びその製造方法 |
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KR20140005510A (ko) | 2014-01-15 |
WO2014007442A1 (ko) | 2014-01-09 |
KR101486564B1 (ko) | 2015-01-26 |
US9469759B2 (en) | 2016-10-18 |
CN104603198B (zh) | 2019-10-15 |
CN104603198A (zh) | 2015-05-06 |
US20160002455A1 (en) | 2016-01-07 |
JP6247288B2 (ja) | 2017-12-13 |
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