JP2015515084A5 - - Google Patents
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- JP2015515084A5 JP2015515084A5 JP2014559277A JP2014559277A JP2015515084A5 JP 2015515084 A5 JP2015515084 A5 JP 2015515084A5 JP 2014559277 A JP2014559277 A JP 2014559277A JP 2014559277 A JP2014559277 A JP 2014559277A JP 2015515084 A5 JP2015515084 A5 JP 2015515084A5
- Authority
- JP
- Japan
- Prior art keywords
- sulfate
- formula
- binder
- anode
- content
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 26
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 19
- 150000001875 compounds Chemical class 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 13
- 239000011230 binding agent Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 239000011149 active material Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 5
- 239000003792 electrolyte Substances 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- 150000001340 alkali metals Chemical class 0.000 claims description 3
- 239000006258 conductive agent Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 238000000151 deposition Methods 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims 2
- 239000010405 anode material Substances 0.000 claims 2
- 239000002608 ionic liquid Substances 0.000 claims 2
- 229910000358 iron sulfate Inorganic materials 0.000 claims 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims 2
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 claims 2
- 229920000642 polymer Polymers 0.000 claims 2
- 239000002243 precursor Substances 0.000 claims 2
- 229910052938 sodium sulfate Inorganic materials 0.000 claims 2
- 235000011152 sodium sulphate Nutrition 0.000 claims 2
- RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 claims 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 1
- 239000006230 acetylene black Substances 0.000 claims 1
- 229910021383 artificial graphite Inorganic materials 0.000 claims 1
- 239000002041 carbon nanotube Substances 0.000 claims 1
- 229910021393 carbon nanotube Inorganic materials 0.000 claims 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims 1
- 239000001768 carboxy methyl cellulose Substances 0.000 claims 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims 1
- 239000004020 conductor Substances 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 claims 1
- 229920002313 fluoropolymer Polymers 0.000 claims 1
- 239000004811 fluoropolymer Substances 0.000 claims 1
- 229910052744 lithium Inorganic materials 0.000 claims 1
- 229910003002 lithium salt Inorganic materials 0.000 claims 1
- 159000000002 lithium salts Chemical class 0.000 claims 1
- 229910021382 natural graphite Inorganic materials 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 159000000000 sodium salts Chemical class 0.000 claims 1
- 239000000725 suspension Substances 0.000 claims 1
- 239000007772 electrode material Substances 0.000 description 13
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 229910001413 alkali metal ion Inorganic materials 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000006183 anode active material Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000011532 electronic conductor Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000010416 ion conductor Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1251854A FR2987498B1 (fr) | 2012-02-29 | 2012-02-29 | Sulfates utiles comme materiaux d'electrode |
| FRFR1251854 | 2012-02-29 | ||
| PCT/FR2013/050397 WO2013128115A1 (fr) | 2012-02-29 | 2013-02-27 | Sulfates utiles comme matériaux d'électrode |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015515084A JP2015515084A (ja) | 2015-05-21 |
| JP2015515084A5 true JP2015515084A5 (OSRAM) | 2017-08-17 |
| JP6228142B2 JP6228142B2 (ja) | 2017-11-08 |
Family
ID=46489362
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014559277A Expired - Fee Related JP6228142B2 (ja) | 2012-02-29 | 2013-02-27 | 電極物質として使用する硫酸塩 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20150017322A1 (OSRAM) |
| EP (1) | EP2820705A1 (OSRAM) |
| JP (1) | JP6228142B2 (OSRAM) |
| FR (1) | FR2987498B1 (OSRAM) |
| WO (1) | WO2013128115A1 (OSRAM) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20160226069A1 (en) * | 2013-09-11 | 2016-08-04 | The University Of Tokyo | Positive electrode material for sodium ion secondary batteries |
| GB201414959D0 (en) | 2014-08-22 | 2014-10-08 | Faradion Ltd | Sodium-ion energy storage devices |
| CN108475813B (zh) * | 2016-01-06 | 2021-07-02 | 株式会社村田制作所 | 非水二次电池、用于非水二次电池的正极活性物质及其制造方法 |
| US11289700B2 (en) | 2016-06-28 | 2022-03-29 | The Research Foundation For The State University Of New York | KVOPO4 cathode for sodium ion batteries |
| CN106058251B (zh) * | 2016-08-12 | 2018-05-25 | 中南大学 | 一种钠离子电池正极Na2Fe2(SO4)3@氧化铝复合材料及其制备方法 |
| CN106848236B (zh) * | 2017-02-20 | 2019-04-09 | 中南大学 | 一种用于钠离子电池的硫酸亚铁钠/石墨烯复合正极材料及其制备方法 |
| WO2019051662A1 (zh) * | 2017-09-13 | 2019-03-21 | 辽宁宏成供电有限公司 | 一种新型高电位多层碳包覆聚阴离子型钠离子电池正极材料及其制备方法 |
| PL236442B1 (pl) * | 2017-11-27 | 2021-01-11 | Akademia Gorniczo Hutnicza Im Stanislawa Staszica W Krakowie | Sposób otrzymywania materiału na katody dla odwracalnych ogniw sodowych |
| CN108023083A (zh) * | 2017-12-04 | 2018-05-11 | 惠州亿纬锂能股份有限公司 | 一种提升电池高温储存性能和过充安全性能的方法 |
| CN110931784B (zh) * | 2019-12-09 | 2020-11-24 | 苏州大学 | 铁基钠离子电池正极材料及其制备方法 |
| WO2021114401A1 (zh) * | 2019-12-09 | 2021-06-17 | 苏州大学 | 铁基钠离子电池正极材料，其制备方法以及钠离子全电池 |
| CN111063871B (zh) * | 2019-12-09 | 2020-11-24 | 苏州大学 | 一种钠离子全电池及其制备方法 |
| US11688853B2 (en) * | 2021-01-13 | 2023-06-27 | Nrgtek, Inc. | Metal-free high-voltage cathodes for secondary lithium-ion and alkali-ion batteries |
| CN114792788A (zh) * | 2022-04-08 | 2022-07-26 | 江苏众钠能源科技有限公司 | 一种钠离子全电池及其制备方法 |
| CN115849454B (zh) * | 2022-11-22 | 2023-07-11 | 湖北万润新能源科技股份有限公司 | 硫酸亚铁钠正极材料的制备方法 |
| CN116093314A (zh) * | 2023-03-21 | 2023-05-09 | 蜂巢能源科技股份有限公司 | 一种铁基钠离子正极材料及其制备方法和应用 |
| CN116154154B (zh) * | 2023-04-13 | 2023-07-04 | 深圳珈钠能源科技有限公司 | 纯相聚阴离子型硫酸盐钠离子电池正极材料及其制备方法 |
| CN116435487B (zh) * | 2023-04-28 | 2024-01-19 | 深圳先进技术研究院 | 一种NaxFe3-0.5x(SO4)3@C正极材料的制备方法和应用 |
| CN116598448B (zh) * | 2023-05-06 | 2025-04-15 | 浙江中哲新能源有限公司 | 一种聚阴离子型硫酸盐正极材料及其制备方法 |
| CN117326595B (zh) * | 2023-09-15 | 2024-04-19 | 广东钠壹新能源科技有限公司 | 一种硫酸铁钠正极材料及其制备方法和应用 |
| CN118380548B (zh) * | 2024-06-25 | 2024-09-20 | 江苏中兴派能电池有限公司 | 硫酸亚铁钠正极极片及制备方法、钠离子电池和用电装置 |
| CN119252891B (zh) * | 2024-09-27 | 2025-11-18 | 孝感楚能新能源创新科技有限公司 | 硫酸铁钠正极材料及其制备方法和正极极片、钠离子电池 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3436292B2 (ja) * | 1995-05-18 | 2003-08-11 | 日本電信電話株式会社 | リチウム電池用正極材料、その製造方法及びそれを用いたリチウム電池 |
| US5695893A (en) * | 1995-05-18 | 1997-12-09 | Nippon Telegraph And Telephone Corporation | Material for use in the positive electrodes of lithium batteries, its manufacture, and lithium batteries incorporating this material |
| JP4001947B2 (ja) * | 1995-12-21 | 2007-10-31 | ソニー株式会社 | リチウム二次電池用正極活物質の製造方法 |
| JPH10116628A (ja) * | 1996-10-11 | 1998-05-06 | Hitachi Ltd | リチウム二次電池 |
| US5908716A (en) * | 1997-04-15 | 1999-06-01 | Valence Technology, Inc. | Lithium--containing sulfates, method of preparation and uses thereof |
| CA2270771A1 (fr) * | 1999-04-30 | 2000-10-30 | Hydro-Quebec | Nouveaux materiaux d'electrode presentant une conductivite de surface elevee |
| US7087348B2 (en) * | 2002-07-26 | 2006-08-08 | A123 Systems, Inc. | Coated electrode particles for composite electrodes and electrochemical cells |
| US20050163699A1 (en) | 2004-01-23 | 2005-07-28 | Jeremy Barker | Fluorosulfate-based electrode active materials and method of making the same |
| WO2006112674A1 (en) * | 2005-04-22 | 2006-10-26 | Lg Chem, Ltd. | New system of lithium ion battery containing material with high irreversible capacity |
| EP2349923B1 (fr) * | 2008-10-23 | 2013-12-04 | Centre National de la Recherche Scientifique | Procede d'elaboration de composes inorganiques |
| GB201201717D0 (en) * | 2012-02-01 | 2012-03-14 | Faradion Ltd | Sulfate electrodes |
-
2012
- 2012-02-29 FR FR1251854A patent/FR2987498B1/fr not_active Expired - Fee Related
-
2013
- 2013-02-27 WO PCT/FR2013/050397 patent/WO2013128115A1/fr not_active Ceased
- 2013-02-27 US US14/378,699 patent/US20150017322A1/en not_active Abandoned
- 2013-02-27 EP EP13714986.0A patent/EP2820705A1/fr not_active Withdrawn
- 2013-02-27 JP JP2014559277A patent/JP6228142B2/ja not_active Expired - Fee Related
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