JP6228142B2 - 電極物質として使用する硫酸塩 - Google Patents

電極物質として使用する硫酸塩 Download PDF

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Publication number
JP6228142B2
JP6228142B2 JP2014559277A JP2014559277A JP6228142B2 JP 6228142 B2 JP6228142 B2 JP 6228142B2 JP 2014559277 A JP2014559277 A JP 2014559277A JP 2014559277 A JP2014559277 A JP 2014559277A JP 6228142 B2 JP6228142 B2 JP 6228142B2
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sulfate
formula
compound
anode
lithium
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JP2015515084A (ja
JP2015515084A5 (OSRAM
Inventor
マリーヌ レノー
マリーヌ レノー
モアメド アティ
モアメド アティ
ジャン−ノエル ショタール
ジャン−ノエル ショタール
ジャン−マリ タラソン
ジャン−マリ タラソン
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Universite de Picardie Jules Verne
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Universite de Picardie Jules Verne
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/96—Methods for the preparation of sulfates in general
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D5/00—Sulfates or sulfites of sodium, potassium or alkali metals in general
    • C01D5/02—Preparation of sulfates from alkali metal salts and sulfuric acid or bisulfates; Preparation of bisulfates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/009—Compounds containing iron, with or without oxygen or hydrogen, and containing two or more other elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/14—Sulfates
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0404—Methods of deposition of the material by coating on electrode collectors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0438—Processes of manufacture in general by electrochemical processing
    • H01M4/044—Activating, forming or electrochemical attack of the supporting material
    • H01M4/0445—Forming after manufacture of the electrode, e.g. first charge, cycling
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/049—Manufacturing of an active layer by chemical means
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1397—Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H01M4/622—Binders being polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/88—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by thermal analysis data, e.g. TGA, DTA, DSC
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Electric Double-Layer Capacitors Or The Like (AREA)
JP2014559277A 2012-02-29 2013-02-27 電極物質として使用する硫酸塩 Expired - Fee Related JP6228142B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1251854A FR2987498B1 (fr) 2012-02-29 2012-02-29 Sulfates utiles comme materiaux d'electrode
FRFR1251854 2012-02-29
PCT/FR2013/050397 WO2013128115A1 (fr) 2012-02-29 2013-02-27 Sulfates utiles comme matériaux d'électrode

Publications (3)

Publication Number Publication Date
JP2015515084A JP2015515084A (ja) 2015-05-21
JP2015515084A5 JP2015515084A5 (OSRAM) 2017-08-17
JP6228142B2 true JP6228142B2 (ja) 2017-11-08

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JP2014559277A Expired - Fee Related JP6228142B2 (ja) 2012-02-29 2013-02-27 電極物質として使用する硫酸塩

Country Status (5)

Country Link
US (1) US20150017322A1 (OSRAM)
EP (1) EP2820705A1 (OSRAM)
JP (1) JP6228142B2 (OSRAM)
FR (1) FR2987498B1 (OSRAM)
WO (1) WO2013128115A1 (OSRAM)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3046170B1 (en) * 2013-09-11 2018-11-07 The University of Tokyo Positive electrode material for sodium ion secondary batteries
GB201414959D0 (en) * 2014-08-22 2014-10-08 Faradion Ltd Sodium-ion energy storage devices
JP6583434B2 (ja) * 2016-01-06 2019-10-02 株式会社村田製作所 非水系二次電池、並びに、非水系二次電池用の正極活物質及びその製造方法
US11289700B2 (en) 2016-06-28 2022-03-29 The Research Foundation For The State University Of New York KVOPO4 cathode for sodium ion batteries
CN106058251B (zh) * 2016-08-12 2018-05-25 中南大学 一种钠离子电池正极Na2Fe2(SO4)3@氧化铝复合材料及其制备方法
CN106848236B (zh) * 2017-02-20 2019-04-09 中南大学 一种用于钠离子电池的硫酸亚铁钠/石墨烯复合正极材料及其制备方法
CN110326136B (zh) * 2017-09-13 2022-07-08 辽宁星空钠电电池有限公司 一种新型高电位多层碳包覆聚阴离子型钠离子电池正极材料及其制备方法
PL236442B1 (pl) * 2017-11-27 2021-01-11 Akademia Gorniczo Hutnicza Im Stanislawa Staszica W Krakowie Sposób otrzymywania materiału na katody dla odwracalnych ogniw sodowych
CN108023083A (zh) * 2017-12-04 2018-05-11 惠州亿纬锂能股份有限公司 一种提升电池高温储存性能和过充安全性能的方法
CN111063871B (zh) * 2019-12-09 2020-11-24 苏州大学 一种钠离子全电池及其制备方法
CN110931784B (zh) * 2019-12-09 2020-11-24 苏州大学 铁基钠离子电池正极材料及其制备方法
WO2021114401A1 (zh) * 2019-12-09 2021-06-17 苏州大学 铁基钠离子电池正极材料，其制备方法以及钠离子全电池
US11688853B2 (en) * 2021-01-13 2023-06-27 Nrgtek, Inc. Metal-free high-voltage cathodes for secondary lithium-ion and alkali-ion batteries
CN114792788A (zh) * 2022-04-08 2022-07-26 江苏众钠能源科技有限公司 一种钠离子全电池及其制备方法
CN115849454B (zh) * 2022-11-22 2023-07-11 湖北万润新能源科技股份有限公司 硫酸亚铁钠正极材料的制备方法
CN116093314A (zh) * 2023-03-21 2023-05-09 蜂巢能源科技股份有限公司 一种铁基钠离子正极材料及其制备方法和应用
CN116154154B (zh) * 2023-04-13 2023-07-04 深圳珈钠能源科技有限公司 纯相聚阴离子型硫酸盐钠离子电池正极材料及其制备方法
CN116435487B (zh) * 2023-04-28 2024-01-19 深圳先进技术研究院 一种NaxFe3-0.5x(SO4)3@C正极材料的制备方法和应用
CN116598448B (zh) * 2023-05-06 2025-04-15 浙江中哲新能源有限公司 一种聚阴离子型硫酸盐正极材料及其制备方法
CN117326595B (zh) * 2023-09-15 2024-04-19 广东钠壹新能源科技有限公司 一种硫酸铁钠正极材料及其制备方法和应用
CN118380548B (zh) * 2024-06-25 2024-09-20 江苏中兴派能电池有限公司 硫酸亚铁钠正极极片及制备方法、钠离子电池和用电装置
CN119252891B (zh) * 2024-09-27 2025-11-18 孝感楚能新能源创新科技有限公司 硫酸铁钠正极材料及其制备方法和正极极片、钠离子电池

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JP3436292B2 (ja) * 1995-05-18 2003-08-11 日本電信電話株式会社 リチウム電池用正極材料、その製造方法及びそれを用いたリチウム電池
JP4001947B2 (ja) * 1995-12-21 2007-10-31 ソニー株式会社 リチウム二次電池用正極活物質の製造方法
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CA2270771A1 (fr) * 1999-04-30 2000-10-30 Hydro-Quebec Nouveaux materiaux d'electrode presentant une conductivite de surface elevee
US7087348B2 (en) * 2002-07-26 2006-08-08 A123 Systems, Inc. Coated electrode particles for composite electrodes and electrochemical cells
US20050163699A1 (en) 2004-01-23 2005-07-28 Jeremy Barker Fluorosulfate-based electrode active materials and method of making the same
KR20060111393A (ko) * 2005-04-22 2006-10-27 주식회사 엘지화학 대용량 비가역 물질을 포함하는 새로운 시스템의 리튬 이온전지
JP5706327B2 (ja) * 2008-10-23 2015-04-22 サントル ナスィオナル ド ラ ルシェルシュ スィアンティフィク 無機化合物の製造方法
GB201201717D0 (en) * 2012-02-01 2012-03-14 Faradion Ltd Sulfate electrodes

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JP2015515084A (ja) 2015-05-21
FR2987498A1 (fr) 2013-08-30
US20150017322A1 (en) 2015-01-15
FR2987498B1 (fr) 2017-08-11
WO2013128115A1 (fr) 2013-09-06
EP2820705A1 (fr) 2015-01-07

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