JP2014517827A5 - - Google Patents
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- Publication number
- JP2014517827A5 JP2014517827A5 JP2014508537A JP2014508537A JP2014517827A5 JP 2014517827 A5 JP2014517827 A5 JP 2014517827A5 JP 2014508537 A JP2014508537 A JP 2014508537A JP 2014508537 A JP2014508537 A JP 2014508537A JP 2014517827 A5 JP2014517827 A5 JP 2014517827A5
- Authority
- JP
- Japan
- Prior art keywords
- concentration
- catalyst
- ethylene
- promoter
- silver
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000003054 catalyst Substances 0.000 claims description 16
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 5
- 239000005977 Ethylene Substances 0.000 claims description 5
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 5
- 239000001569 carbon dioxide Substances 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical group CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 claims description 2
- 229960003750 ethyl chloride Drugs 0.000 claims description 2
- 239000007789 gas Substances 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 16
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 10
- 229910052709 silver Inorganic materials 0.000 claims 10
- 239000004332 silver Substances 0.000 claims 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 9
- 150000000180 1,2-diols Chemical class 0.000 claims 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 4
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 3
- 238000006243 chemical reaction Methods 0.000 claims 3
- 229910052702 rhenium Inorganic materials 0.000 claims 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical group [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 2
- 229910052721 tungsten Inorganic materials 0.000 claims 2
- 239000010937 tungsten Substances 0.000 claims 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 claims 1
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 229910052776 Thorium Inorganic materials 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 1
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- 229910052796 boron Inorganic materials 0.000 claims 1
- 229910052792 caesium Inorganic materials 0.000 claims 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- 239000011651 chromium Substances 0.000 claims 1
- 230000003247 decreasing effect Effects 0.000 claims 1
- 238000006735 epoxidation reaction Methods 0.000 claims 1
- 229910052731 fluorine Inorganic materials 0.000 claims 1
- 239000011737 fluorine Substances 0.000 claims 1
- 229910052733 gallium Inorganic materials 0.000 claims 1
- 229910052732 germanium Inorganic materials 0.000 claims 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims 1
- 229910052735 hafnium Inorganic materials 0.000 claims 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims 1
- 230000003301 hydrolyzing effect Effects 0.000 claims 1
- 229910052744 lithium Inorganic materials 0.000 claims 1
- 229910052750 molybdenum Inorganic materials 0.000 claims 1
- 239000011733 molybdenum Substances 0.000 claims 1
- 229910052758 niobium Inorganic materials 0.000 claims 1
- 239000010955 niobium Substances 0.000 claims 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 claims 1
- 239000011593 sulfur Substances 0.000 claims 1
- 229910052715 tantalum Inorganic materials 0.000 claims 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims 1
- 229910052716 thallium Inorganic materials 0.000 claims 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 229910052720 vanadium Inorganic materials 0.000 claims 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
- 239000012530 fluid Substances 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161480581P | 2011-04-29 | 2011-04-29 | |
| US61/480,581 | 2011-04-29 | ||
| PCT/US2012/035106 WO2012149098A1 (en) | 2011-04-29 | 2012-04-26 | Process for improving the selectivity of an eo catalyst |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014517827A JP2014517827A (ja) | 2014-07-24 |
| JP2014517827A5 true JP2014517827A5 (cg-RX-API-DMAC7.html) | 2016-09-29 |
| JP6104888B2 JP6104888B2 (ja) | 2017-03-29 |
Family
ID=47068406
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014508537A Active JP6104888B2 (ja) | 2011-04-29 | 2012-04-26 | Ｅｏ触媒の選択率を改善する方法 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US9174928B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP2714670B2 (cg-RX-API-DMAC7.html) |
| JP (1) | JP6104888B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR102027597B1 (cg-RX-API-DMAC7.html) |
| CN (1) | CN103502229B (cg-RX-API-DMAC7.html) |
| BR (1) | BR112013027585B1 (cg-RX-API-DMAC7.html) |
| CA (1) | CA2834299C (cg-RX-API-DMAC7.html) |
| RU (1) | RU2606504C2 (cg-RX-API-DMAC7.html) |
| TW (1) | TWI566831B (cg-RX-API-DMAC7.html) |
| WO (1) | WO2012149098A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SG11201403042SA (en) | 2011-12-09 | 2014-10-30 | Dow Technology Investments Llc | Method of maintaining the value of an alkylene oxide production parameter in a process of making an alkylene oxide using a high efficiency catalyst |
| CN104437663B (zh) * | 2013-09-16 | 2016-09-21 | 中国石油化工股份有限公司 | 一种制备α-氧化铝载体的方法 |
| CN106311228B (zh) * | 2015-07-02 | 2019-06-28 | 中国石油化工股份有限公司 | 银催化剂、其制备方法及应用 |
| CN105233824B (zh) * | 2015-11-05 | 2018-02-06 | 中国海洋石油总公司 | 一种高选择性乙烯氧化制环氧乙烷银催化剂及其使用方法 |
| WO2019055773A1 (en) | 2017-09-15 | 2019-03-21 | MultiPhase Solutions, Inc. | GAS PHASE CHROMATOGRAPHY OF SELECTIVE HALOGEN DETECTION FOR ONLINE ANALYSIS AND CONTROL OF SELECTIVE OXIDATION CHEMICAL PRODUCTION PROCESSES |
| CN111406049B (zh) | 2017-12-08 | 2023-10-03 | 国际壳牌研究有限公司 | 用于制备碳酸亚乙酯和乙二醇的方法 |
| CN110357837B (zh) * | 2018-03-26 | 2021-07-02 | 中国石油化工股份有限公司 | 一种乙烯环氧化方法 |
| TW202239751A (zh) * | 2021-04-08 | 2022-10-16 | 荷蘭商蜆殼國際研究所 | 用於乙烯之環氧化的緩和劑及催化劑效能最佳化 |
Family Cites Families (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4400559A (en) | 1982-06-14 | 1983-08-23 | The Halcon Sd Group, Inc. | Process for preparing ethylene glycol |
| US4845296A (en) | 1983-12-13 | 1989-07-04 | Union Carbide Corporation | Process for preparing alkanolamines |
| US4761394A (en) | 1986-10-31 | 1988-08-02 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
| US4766105A (en) | 1986-10-31 | 1988-08-23 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
| US4874879A (en) | 1988-07-25 | 1989-10-17 | Shell Oil Company | Process for starting-up an ethylene oxide reactor |
| KR0147853B1 (ko) * | 1990-10-12 | 1998-08-17 | 티모시 엔. 비숍 | 활성 및/또는 안정성이 개선된 알킬렌 옥사이드 촉매 |
| US5155242A (en) | 1991-12-05 | 1992-10-13 | Shell Oil Company | Process for starting-up an ethylene oxide reactor |
| US5380697A (en) | 1993-09-08 | 1995-01-10 | Shell Oil Company | Ethylene oxide catalyst and process |
| US5739075A (en) | 1995-10-06 | 1998-04-14 | Shell Oil Company | Process for preparing ethylene oxide catalysts |
| US5801259A (en) | 1996-04-30 | 1998-09-01 | Shell Oil Company | Ethylene oxide catalyst and process |
| US6040467A (en) | 1997-07-24 | 2000-03-21 | Praxair Technology, Inc. | High purity oxygen for ethylene oxide production |
| JP3781549B2 (ja) * | 1998-03-19 | 2006-05-31 | 三菱化学株式会社 | モノエチレングリコールの製造方法 |
| JP3817947B2 (ja) * | 1999-01-26 | 2006-09-06 | 三菱化学株式会社 | エチレングリコールの製造方法 |
| US6080897A (en) | 1998-03-19 | 2000-06-27 | Mitsubishi Chemical Corporation | Method for producing monoethylene glycol |
| WO2000015333A1 (en) | 1998-09-14 | 2000-03-23 | Shell Internationale Research Maatschappij B.V. | Process for removing ionizable species from catalyst surface to improve catalytic properties |
| US6372925B1 (en) | 2000-06-09 | 2002-04-16 | Shell Oil Company | Process for operating the epoxidation of ethylene |
| US7193094B2 (en) * | 2001-11-20 | 2007-03-20 | Shell Oil Company | Process and systems for the epoxidation of an olefin |
| AU2002356973B2 (en) | 2001-11-20 | 2008-11-06 | Shell Internationale Research Maatschappij B.V. | A process and systems for the epoxidation of an olefin |
| CA2494767C (en) * | 2002-06-28 | 2012-07-17 | John Robert Lockemeyer | A method for the start-up of an epoxidation process and a process for the epoxidation of an olefin |
| AU2003243757A1 (en) | 2002-06-28 | 2004-01-19 | Shell Oil Company | A method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
| CN100376561C (zh) | 2002-06-28 | 2008-03-26 | 国际壳牌研究有限公司 | 环氧化方法的开车方法、烯烃环氧化的催化剂和方法 |
| MY153179A (en) | 2003-02-28 | 2015-01-29 | Shell Int Research | A method of manufacturing ethylene oxide |
| MY146505A (en) * | 2003-02-28 | 2012-08-15 | Shell Int Research | A method of manufacturing ethylene oxide |
| MY136774A (en) | 2003-02-28 | 2008-11-28 | Shell Int Research | Method of improving the operation of a manufacturing process |
| US7348444B2 (en) * | 2003-04-07 | 2008-03-25 | Shell Oil Company | Process for the production of an olefin oxide |
| US8148555B2 (en) | 2003-06-26 | 2012-04-03 | Shell Oil Company | Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
| US7615655B2 (en) | 2003-09-29 | 2009-11-10 | Dow Global Technologies, Inc. | Process for the production of alkylene oxide using a gas-phase promoter system |
| MXPA06014561A (es) | 2004-06-18 | 2007-03-23 | Shell Int Research | Proceso para la produccion de un oxido de olefina, un 1,2-diol, un 1,2-diol eter o una alcanolamina. |
| EA011641B1 (ru) | 2005-03-22 | 2009-04-28 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Реакторная система и способ для производства окиси этилена |
| BRPI0707608A2 (pt) | 2006-02-10 | 2011-05-10 | Shell Int Research | processo para preparar um catalisador, o catalisador, e um processo para a produÇço de àxido de olefina, 1,2-diol,1,2-diol Éter, ou alcanolamina |
| RU2008145498A (ru) | 2006-04-18 | 2010-05-27 | Дау Глобал Текнолоджиз Инк. (Us) | Катализатор оксида алкилена и его применение |
| TWI464154B (zh) * | 2007-05-09 | 2014-12-11 | Shell Int Research | 製備烯烴氧化物、１，２－二醇、１，２－二醇醚、１，２－碳酸酯或烷醇胺之方法 |
| TWI446964B (zh) | 2007-05-09 | 2014-08-01 | Shell Int Research | 環氧化催化劑，製備該催化劑之方法及製備烯烴氧化物、１，２-二醇、１，２-二醇醚、１，２-碳酸酯或烷醇胺之方法 |
| US7803957B2 (en) | 2007-09-11 | 2010-09-28 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Ethylene oxide production using fixed moderator concentration |
| US7553980B2 (en) * | 2007-09-26 | 2009-06-30 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Process for initiating a highly selective ethylene oxide catalyst |
| KR101629037B1 (ko) * | 2008-05-07 | 2016-06-09 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 에폭시화 방법의 스타트업 방법, 산화에틸렌, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산방법 |
| KR101629038B1 (ko) * | 2008-05-07 | 2016-06-09 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 산화올레핀, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산방법 |
| CA2759496C (en) | 2009-04-21 | 2018-05-01 | Dow Technology Investments Llc | Epoxidation reactions and operating conditions thereof |
| SG175771A1 (en) | 2009-04-21 | 2011-12-29 | Dow Technology Investments Llc | Improved method of achieving and maintaining a specified alkylene oxide production parameter with a high efficiency catalyst |
| EP2421840B1 (en) | 2009-04-21 | 2015-12-16 | Dow Technology Investments LLC | Simplified method for producing alkylene oxides with a high efficiency catalyst |
| JP5584284B2 (ja) * | 2009-04-21 | 2014-09-03 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | レニウム促進されたエポキシ化触媒の効率を高める方法及びこれらの方法を利用したエポキシ化方法 |
| US8802900B2 (en) * | 2010-11-29 | 2014-08-12 | Shell Oil Company | Process for the preparation of ethylene glycol |
| US8742147B2 (en) * | 2010-12-08 | 2014-06-03 | Shell Oil Company | Process for improving the selectivity of an EO catalyst |
-
2012
- 2012-04-26 CA CA2834299A patent/CA2834299C/en active Active
- 2012-04-26 BR BR112013027585-5A patent/BR112013027585B1/pt active IP Right Grant
- 2012-04-26 JP JP2014508537A patent/JP6104888B2/ja active Active
- 2012-04-26 US US13/456,774 patent/US9174928B2/en active Active
- 2012-04-26 EP EP12776466.0A patent/EP2714670B2/en active Active
- 2012-04-26 RU RU2013153098A patent/RU2606504C2/ru active
- 2012-04-26 KR KR1020137028065A patent/KR102027597B1/ko active Active
- 2012-04-26 WO PCT/US2012/035106 patent/WO2012149098A1/en not_active Ceased
- 2012-04-26 CN CN201280020804.7A patent/CN103502229B/zh active Active
- 2012-04-27 TW TW101115254A patent/TWI566831B/zh active
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