JP2014503038A - 塗料塗布前のブリキ板の多段階前処理方法 - Google Patents
塗料塗布前のブリキ板の多段階前処理方法 Download PDFInfo
- Publication number
- JP2014503038A JP2014503038A JP2013549743A JP2013549743A JP2014503038A JP 2014503038 A JP2014503038 A JP 2014503038A JP 2013549743 A JP2013549743 A JP 2013549743A JP 2013549743 A JP2013549743 A JP 2013549743A JP 2014503038 A JP2014503038 A JP 2014503038A
- Authority
- JP
- Japan
- Prior art keywords
- water
- acidic aqueous
- aqueous composition
- tinplate
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000005028 tinplate Substances 0.000 title claims abstract description 71
- 238000000576 coating method Methods 0.000 title claims abstract description 18
- 239000011248 coating agent Substances 0.000 title claims abstract description 17
- 238000002203 pretreatment Methods 0.000 title description 3
- 238000000034 method Methods 0.000 claims abstract description 88
- 239000000203 mixture Substances 0.000 claims abstract description 33
- 230000002378 acidificating effect Effects 0.000 claims abstract description 32
- 239000003792 electrolyte Substances 0.000 claims abstract description 22
- 150000003839 salts Chemical class 0.000 claims abstract description 22
- 235000013305 food Nutrition 0.000 claims abstract description 17
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 15
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 13
- 229910052735 hafnium Inorganic materials 0.000 claims abstract description 11
- 150000002484 inorganic compounds Chemical class 0.000 claims abstract description 11
- 229910010272 inorganic material Inorganic materials 0.000 claims abstract description 11
- 239000005022 packaging material Substances 0.000 claims abstract description 5
- 239000008151 electrolyte solution Substances 0.000 claims description 19
- 230000010287 polarization Effects 0.000 claims description 19
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 12
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 9
- 125000001153 fluoro group Chemical group F* 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 8
- 150000001282 organosilanes Chemical class 0.000 claims description 8
- 238000002161 passivation Methods 0.000 claims description 8
- 125000001424 substituent group Chemical group 0.000 claims description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 5
- 229920000620 organic polymer Polymers 0.000 claims description 5
- 229910001413 alkali metal ion Inorganic materials 0.000 claims description 4
- -1 alkali metal salt Chemical class 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- 125000000524 functional group Chemical group 0.000 claims description 3
- 235000006408 oxalic acid Nutrition 0.000 claims description 3
- 229920000647 polyepoxide Polymers 0.000 claims description 3
- 229920001228 polyisocyanate Polymers 0.000 claims description 3
- 239000005056 polyisocyanate Substances 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920001665 Poly-4-vinylphenol Polymers 0.000 claims description 2
- 125000003277 amino group Chemical group 0.000 claims description 2
- 238000009835 boiling Methods 0.000 claims description 2
- 230000007062 hydrolysis Effects 0.000 claims description 2
- 238000006460 hydrolysis reaction Methods 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract description 28
- 229910052751 metal Inorganic materials 0.000 abstract description 9
- 239000002184 metal Substances 0.000 abstract description 9
- 102000004169 proteins and genes Human genes 0.000 abstract description 7
- 108090000623 proteins and genes Proteins 0.000 abstract description 7
- 150000003464 sulfur compounds Chemical class 0.000 abstract description 7
- 230000007797 corrosion Effects 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 4
- 235000013361 beverage Nutrition 0.000 abstract description 3
- 238000003860 storage Methods 0.000 abstract description 3
- 239000007788 liquid Substances 0.000 abstract description 2
- 239000010936 titanium Substances 0.000 description 10
- 229910004298 SiO 2 Inorganic materials 0.000 description 9
- 239000010410 layer Substances 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 6
- 239000002932 luster Substances 0.000 description 6
- 239000002987 primer (paints) Substances 0.000 description 6
- 238000002845 discoloration Methods 0.000 description 5
- 239000003973 paint Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 235000019353 potassium silicate Nutrition 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 239000005003 food packaging material Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- DPLVEEXVKBWGHE-UHFFFAOYSA-N potassium sulfide Chemical compound [S-2].[K+].[K+] DPLVEEXVKBWGHE-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 229910001887 tin oxide Inorganic materials 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910001128 Sn alloy Inorganic materials 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 229910001963 alkali metal nitrate Inorganic materials 0.000 description 1
- 229910000318 alkali metal phosphate Inorganic materials 0.000 description 1
- 229910052936 alkali metal sulfate Inorganic materials 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000013332 fish product Nutrition 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 159000000014 iron salts Chemical class 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000013622 meat product Nutrition 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 235000021485 packed food Nutrition 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 235000013324 preserved food Nutrition 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000027756 respiratory electron transport chain Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- CVNKFOIOZXAFBO-UHFFFAOYSA-J tin(4+);tetrahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[Sn+4] CVNKFOIOZXAFBO-UHFFFAOYSA-J 0.000 description 1
- 238000006276 transfer reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
- B65D85/70—Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for
- B65D85/72—Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for for edible or potable liquids, semiliquids, or plastic or pasty materials
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/04—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/34—Anodisation of metals or alloys not provided for in groups C25D11/04 - C25D11/32
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
- C25D11/16—Pretreatment, e.g. desmutting
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Electrochemistry (AREA)
- Inorganic Chemistry (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Chemical Treatment Of Metals (AREA)
- Electroplating Methods And Accessories (AREA)
Abstract
Description
で示される化合物から選択される。
本発明の方法を説明するために、まず、清浄なブリキ板(スズ塗布重量2.8g/m2)を電解前処理に付し、次いで、蒸留水で濯ぎ、その後、Chemcoater(登録商標)を用いて不動態化剤の未乾燥塗膜を塗布し、50℃で1分間乾燥した。相応の一連の試験を表1に示す。
0:変色せず;金属光沢
1:個々の黒変;表面の10%未満
2:小斑点状に黒変;表面の30%未満
3:小斑点状に黒変;表面の50%未満
4:50%超が小斑点状に黒変し、金属光沢がほぼ完全に喪失
5:50%超が小斑点状に黒変し、金属光沢が完全に喪失
Claims (15)
- 有機トップコートの塗布前にブリキ板を前処理する方法であって、第一工程で、少なくとも1種の不活性水溶性塩を含有する水性電解液中でアノード分極を行い、次いで第二工程で、元素Zr、Ti、Hfおよび/またはSiの水溶性無機化合物を含有する酸性水性組成物とブリキ板を接触させることによって不動態化を行う方法。
- 方法の第二工程の酸性水性組成物が、元素Zr、Ti、Hfおよび/またはSiの水溶性無機化合物として、そのフルオロ酸および/またはそのフルオロ酸塩、好ましくは元素Zrおよび/またはTiのフルオロ酸および/またはフルオロ酸塩を含有する、請求項1に記載の方法。
- 方法の第二工程の酸性水性組成物における元素Zr、Ti、Hfおよび/またはSiの水溶性無機化合物の含量が、各元素Zr、Ti、Hfおよび/またはSiに基づいて合計で少なくとも0.001重量%、特に好ましくは少なくとも0.01重量%、しかしながら合計で好ましくは0.5重量%以下である、請求項1または2に記載の方法。
- 方法の第二工程の酸性水性組成物がリン酸イオンを付加的に含有する、請求項1〜3のいずれかに記載の方法。
- 方法の第二工程の酸性水性組成物が、ポリアクリレート、ポリイソシアネート、ポリエポキシド、ポリビニルアミン、ポリアルキレンイミンまたはアミノ置換ポリビニルフェノール誘導体から選択される水溶性および/または水分散性有機ポリマーを付加的に含有する、請求項1〜4のいずれかに記載の方法。
- 方法の第二工程の酸性水性組成物における有機ポリマーの含量が、合計で0.05〜10重量%の範囲、好ましくは2〜5重量%の範囲である、請求項5に記載の方法。
- 方法の第二工程の酸性水性組成物のpH値が2.5〜5.5の範囲である、請求項1〜6のいずれかに記載の方法。
- 方法の第二工程において、元素Zr、Ti、Hfおよび/またはSiに基づいて少なくとも0.3mg/m2、好ましくは少なくとも2mg/m2、しかしながら30mg/m2以下、好ましくは20mg/m2以下の塗布重量をブリキ板に塗布する、請求項1〜7のいずれかに記載の方法。
- 第二工程の酸性水性組成物を未乾燥塗膜としてブリキ板に塗布し、塗布直後に未乾燥塗膜を乾燥する、請求項1〜8のいずれかに記載の方法。
- 方法の第一工程のアノード分極を、少なくとも0.2秒、好ましくは少なくとも1秒、しかしながら合計で300秒を超えずに行う、請求項1〜9のいずれかに記載の方法。
- 方法の第一工程のアノード分極を、少なくとも0.005A/dm2、しかしながら6A/dm2以下、好ましくは4A/dm2以下の電流密度で行う、請求項1〜10のいずれかに記載の方法。
- 方法の第一工程の電解液が、6個以下の炭素原子を有する有機ジカルボン酸および/またはその塩、好ましくはシュウ酸および/またはそのアルカリ金属塩を付加的に含有する、請求項1〜11のいずれかに記載の方法。
- 方法の第一工程の電解液が、組成式:M2O・nSiO2[式中、Mはアルカリ金属イオンまたは第四級アンモニウムイオンであり、nは0.8〜7の自然数である]で示される少なくとも1種の水溶性ケイ酸塩を付加的に含有する、請求項1〜12のいずれかに記載の方法。
- 方法の第一工程の電解液が、100℃未満の沸点を有するアルコールとして加水分解時に分離される少なくとも1つの加水分解性置換基と、少なくとも幾つかの第一級アミノ官能基を好ましくは有する少なくとも1つの非加水分解性置換基とを有する少なくとも1種のオルガノシランを付加的に含有する、請求項13に記載の方法。
- 食料を貯蔵するための包装材料、好ましくは缶を製造するための、請求項1〜14のいずれかに記載の方法に従って処理したブリキ板の使用。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102011002837A DE102011002837A1 (de) | 2011-01-18 | 2011-01-18 | Mehrstufige Vorbehandlung von Weißblech vor einer Lackierung |
DE102011002837.4 | 2011-01-18 | ||
PCT/EP2011/072769 WO2012097927A1 (de) | 2011-01-18 | 2011-12-14 | Mehrstufige vorbehandlung von weissblech vor einer lackierung |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2014503038A true JP2014503038A (ja) | 2014-02-06 |
JP6061864B2 JP6061864B2 (ja) | 2017-01-18 |
Family
ID=45406721
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2013549743A Active JP6061864B2 (ja) | 2011-01-18 | 2011-12-14 | 塗料塗布前のブリキ板の多段階前処理方法 |
Country Status (8)
Country | Link |
---|---|
US (1) | US10011915B2 (ja) |
EP (1) | EP2665846B1 (ja) |
JP (1) | JP6061864B2 (ja) |
CN (1) | CN103429795B (ja) |
DE (1) | DE102011002837A1 (ja) |
ES (1) | ES2547091T3 (ja) |
RS (1) | RS54307B1 (ja) |
WO (1) | WO2012097927A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016102263A (ja) * | 2014-01-24 | 2016-06-02 | Jfeスチール株式会社 | 容器用鋼板の製造方法 |
WO2019039044A1 (ja) * | 2017-08-25 | 2019-02-28 | Jfeスチール株式会社 | 容器用鋼板及びその製造方法 |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102012000414B4 (de) * | 2012-01-12 | 2014-03-20 | Thyssenkrupp Rasselstein Gmbh | Verfahren zur Passivierung von Weißblech, sowie verzinntes Stahlband oder -blech |
DK2728041T3 (en) * | 2012-10-30 | 2017-03-20 | Hydro Aluminium Rolled Prod | Coated aluminum strip and method of manufacture |
DE102017117080A1 (de) * | 2017-07-28 | 2019-01-31 | Thyssenkrupp Ag | Stahlblech mit einer Konversionsschicht, Verfahren zur Herstellung eines konversionsbeschichteten Stahlblechs und Behandlungsmittel zur Applizierung einer Konversionsschicht auf einem Stahlblech |
CA3162200C (en) | 2019-12-20 | 2024-04-16 | Jan Paul Penning | Method for manufacturing laminated tinplate, a laminated tinplate produced thereby and use thereof |
US20230220579A1 (en) * | 2020-03-13 | 2023-07-13 | Tata Steel Ijmuiden B.V. | Method for passivating a tinplate strip and apparatus for producing said passivated tinplate strip |
CN115247263A (zh) * | 2022-06-20 | 2022-10-28 | 上海兴赛尔表面材料有限公司 | 一种镀锡板用环保型钝化组合物及其制备方法和应用 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5468734A (en) * | 1977-11-11 | 1979-06-02 | Nippon Packaging Kk | Surface treatment of tin plated steel plate and can |
JPS56150199A (en) * | 1980-04-21 | 1981-11-20 | Toyo Kohan Co Ltd | Preparation of tin plated steel plate with excellent corrosion resistance of processed part |
JP2000248398A (ja) * | 1999-02-26 | 2000-09-12 | Toyo Kohan Co Ltd | 表面処理鋼板の製造方法および表面処理鋼板 |
JP2008202094A (ja) * | 2007-02-20 | 2008-09-04 | Nippon Steel Corp | 缶用めっき鋼板及びその製造方法 |
WO2008123632A1 (ja) * | 2007-04-04 | 2008-10-16 | Nippon Steel Corporation | 缶用めっき鋼板及びその製造方法 |
Family Cites Families (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE421943A (ja) | 1936-06-06 | |||
US2312076A (en) * | 1939-04-29 | 1943-02-23 | Carnegie Illinois Steel Corp | Method of treating tin |
US2687994A (en) * | 1950-03-17 | 1954-08-31 | Ekco Products Company | Method of forming an oxide coating on tin |
US3491001A (en) | 1966-10-31 | 1970-01-20 | Canada Steel Co | Electro-chemical passivation of tinplate |
US3658662A (en) | 1969-01-21 | 1972-04-25 | Durolith Corp | Corrosion resistant metallic plates particularly useful as support members for photo-lithographic plates and the like |
US3616307A (en) * | 1969-05-16 | 1971-10-26 | Bethlehem Steel Corp | Process and composition for anodizing a tincoated article |
US3834999A (en) | 1971-04-15 | 1974-09-10 | Atlas Technology Corp | Electrolytic production of glassy layers on metals |
JPS5130546A (en) | 1974-09-10 | 1976-03-15 | Nippon Kokan Kk | Suzumetsukikohan no denkaikaseishoriho |
JPS5827358B2 (ja) | 1980-10-20 | 1983-06-08 | 東洋鋼鈑株式会社 | 錫めつき鋼板の表面処理法 |
CA1162504A (en) * | 1980-11-25 | 1984-02-21 | Mobuyuki Oda | Treating tin plated steel sheet with composition containing titanium or zirconium compounds |
IL63243A (en) | 1981-07-07 | 1984-11-30 | Reznick David | Method for anodically treating metal surfaces and treated metal surface |
EP0202870A1 (en) | 1985-05-17 | 1986-11-26 | David Reznik | Apparatus and method for anodic treatment |
JP2606451B2 (ja) * | 1990-12-28 | 1997-05-07 | 東洋製罐株式会社 | 深絞り缶及びその製造方法 |
US6599643B2 (en) | 1997-01-31 | 2003-07-29 | Elisha Holding Llc | Energy enhanced process for treating a conductive surface and products formed thereby |
US6361833B1 (en) * | 1998-10-28 | 2002-03-26 | Henkel Corporation | Composition and process for treating metal surfaces |
US6174426B1 (en) * | 1999-08-12 | 2001-01-16 | Usx Corporation | Tin-plated steel with adhesion promoter |
DE10001831A1 (de) | 2000-01-18 | 2001-08-16 | Keimfarben Gmbh & Co Kg | Silikatische Beschichtungsmasse mit verbesserter Stabilität |
DE10063519A1 (de) | 2000-12-20 | 2002-07-04 | Nano X Gmbh | Lösungsmittelarme Sol-Gel-Systeme |
US6911139B2 (en) * | 2001-08-03 | 2005-06-28 | Elisha Holding Llc | Process for treating a conductive surface and products formed thereby |
US20050194262A1 (en) | 2001-08-03 | 2005-09-08 | Elisha Holding Llc | Process for treating a conductive surface and products formed thereby |
TW200417420A (en) * | 2002-12-24 | 2004-09-16 | Nippon Paint Co Ltd | Chemical conversion coating agent and surface-treated metal |
WO2004097069A2 (en) | 2003-04-25 | 2004-11-11 | Elisha Holding Llc | Method for preparing and using silicate systems to treat electrically conductive surfaces and products obtained therefrom |
CN100590225C (zh) | 2003-04-25 | 2010-02-17 | 以利沙控股有限公司 | 制备和使用硅酸盐体系处理导电表面的方法和由此得到的产品 |
EP1712659A1 (en) | 2005-04-11 | 2006-10-18 | Elisha Holding LLC | Corrosion resistant article and method of production thereof |
TWI340770B (en) * | 2005-12-06 | 2011-04-21 | Nippon Steel Corp | Composite coated metal sheet, treatment agent and method of manufacturing composite coated metal sheet |
CN101384753B (zh) | 2006-02-09 | 2011-06-01 | 新日本制铁株式会社 | 具有耐腐蚀性的镀锡钢板 |
JP4276689B2 (ja) * | 2006-12-20 | 2009-06-10 | 日本ペイント株式会社 | カチオン電着塗装方法、及びカチオン電着塗装された金属基材 |
ES2391870T3 (es) * | 2007-02-12 | 2012-11-30 | Henkel Ag & Co. Kgaa | Procedimiento para tratar superficies metálicas |
CN101784700B (zh) * | 2007-08-23 | 2012-10-24 | 新日本制铁株式会社 | 对环境的负荷少的容器材料用钢板及其制造方法和使用该钢板的对环境的负荷少的容器材料用复合钢板以及容器材料用预涂钢板 |
CN101358340A (zh) * | 2008-08-12 | 2009-02-04 | 武汉钢铁(集团)公司 | 一种镀锡板无铬钝化液以及钝化方法 |
EP2186928A1 (en) | 2008-11-14 | 2010-05-19 | Enthone, Inc. | Method for the post-treatment of metal layers |
US20100181201A1 (en) | 2009-01-20 | 2010-07-22 | Bibber John W | Electrolytic passivated tin plated steel |
US20130276873A1 (en) | 2012-04-20 | 2013-10-24 | California Institute Of Technology | High level injection systems |
-
2011
- 2011-01-18 DE DE102011002837A patent/DE102011002837A1/de not_active Withdrawn
- 2011-12-14 ES ES11801688.0T patent/ES2547091T3/es active Active
- 2011-12-14 RS RS20150593A patent/RS54307B1/en unknown
- 2011-12-14 EP EP11801688.0A patent/EP2665846B1/de active Active
- 2011-12-14 CN CN201180069111.2A patent/CN103429795B/zh active Active
- 2011-12-14 WO PCT/EP2011/072769 patent/WO2012097927A1/de active Application Filing
- 2011-12-14 JP JP2013549743A patent/JP6061864B2/ja active Active
-
2013
- 2013-07-16 US US13/943,111 patent/US10011915B2/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5468734A (en) * | 1977-11-11 | 1979-06-02 | Nippon Packaging Kk | Surface treatment of tin plated steel plate and can |
JPS56150199A (en) * | 1980-04-21 | 1981-11-20 | Toyo Kohan Co Ltd | Preparation of tin plated steel plate with excellent corrosion resistance of processed part |
JP2000248398A (ja) * | 1999-02-26 | 2000-09-12 | Toyo Kohan Co Ltd | 表面処理鋼板の製造方法および表面処理鋼板 |
JP2008202094A (ja) * | 2007-02-20 | 2008-09-04 | Nippon Steel Corp | 缶用めっき鋼板及びその製造方法 |
WO2008123632A1 (ja) * | 2007-04-04 | 2008-10-16 | Nippon Steel Corporation | 缶用めっき鋼板及びその製造方法 |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016102263A (ja) * | 2014-01-24 | 2016-06-02 | Jfeスチール株式会社 | 容器用鋼板の製造方法 |
JP2016130368A (ja) * | 2014-01-24 | 2016-07-21 | Jfeスチール株式会社 | 容器用鋼板およびその製造方法 |
WO2019039044A1 (ja) * | 2017-08-25 | 2019-02-28 | Jfeスチール株式会社 | 容器用鋼板及びその製造方法 |
KR20200026978A (ko) * | 2017-08-25 | 2020-03-11 | 제이에프이 스틸 가부시키가이샤 | 용기용 강판 및 그 제조 방법 |
KR102337924B1 (ko) * | 2017-08-25 | 2021-12-09 | 제이에프이 스틸 가부시키가이샤 | 용기용 강판 및 그 제조 방법 |
Also Published As
Publication number | Publication date |
---|---|
JP6061864B2 (ja) | 2017-01-18 |
WO2012097927A1 (de) | 2012-07-26 |
US20130299379A1 (en) | 2013-11-14 |
US10011915B2 (en) | 2018-07-03 |
DE102011002837A1 (de) | 2012-07-19 |
ES2547091T3 (es) | 2015-10-01 |
EP2665846A1 (de) | 2013-11-27 |
RS54307B1 (en) | 2016-02-29 |
CN103429795A (zh) | 2013-12-04 |
EP2665846B1 (de) | 2015-06-17 |
CN103429795B (zh) | 2016-04-20 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6061864B2 (ja) | 塗料塗布前のブリキ板の多段階前処理方法 | |
EP3385405B1 (en) | Chromium-free surface-treated tinplate, production method and surface treating agent therefor | |
JP4920800B2 (ja) | 容器用鋼板の製造方法 | |
JP5845563B2 (ja) | 容器用鋼板の製造方法 | |
WO2012002360A1 (ja) | 容器用鋼板およびその製造方法 | |
WO2012036200A1 (ja) | 容器用鋼板の製造方法 | |
GB2068418A (en) | Phosphating compositions | |
JP5973464B2 (ja) | 塗料塗布前のブリキ板の前処理方法 | |
JP2005325401A (ja) | 亜鉛又は亜鉛系合金メッキ鋼材の表面処理方法 | |
CN111748748B (zh) | 高耐蚀无铬钝化镀锡板及其制造方法和钝化处理用钝化液 | |
CN109913782B (zh) | 一种用于镀锡钢板的软熔助剂及镀锡钢板表面处理方法 | |
JPH1135880A (ja) | アルミニウム系材料用水性表面処理液およびそれを用いる表面処理方法 | |
JPS62278297A (ja) | 金属表面処理鋼板のクロメ−ト処理方法 | |
EP3415660A1 (en) | Chemical conversion bath replenishment method | |
JP5678817B2 (ja) | 錫めっき鋼板の製造方法 | |
JP2009197297A (ja) | 溶融亜鉛めっき処理品の生産方法 | |
JPS59219496A (ja) | 錫メツキ鋼板の表面処理法 | |
JPH0459994A (ja) | 耐錆性と外観に優れた容器用表面処理鋼板 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20141126 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20151109 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20151117 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20160216 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20160510 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20160705 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20161104 |
|
A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20161109 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20161129 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20161213 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6061864 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |