JP2014502305A - ポリウレタン複合材料 - Google Patents
ポリウレタン複合材料 Download PDFInfo
- Publication number
- JP2014502305A JP2014502305A JP2013542504A JP2013542504A JP2014502305A JP 2014502305 A JP2014502305 A JP 2014502305A JP 2013542504 A JP2013542504 A JP 2013542504A JP 2013542504 A JP2013542504 A JP 2013542504A JP 2014502305 A JP2014502305 A JP 2014502305A
- Authority
- JP
- Japan
- Prior art keywords
- composite material
- prepolymer
- isocyanate
- material according
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
- C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/36—Hydroxylated esters of higher fatty acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4825—Polyethers containing two hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
- C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/35—Composite foams, i.e. continuous macromolecular foams containing discontinuous cellular particles or fragments
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/0066—≥ 150kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Dispersion Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP10194004 | 2010-12-07 | ||
| EP10194004.7 | 2010-12-07 | ||
| PCT/EP2011/071877 WO2012076506A1 (de) | 2010-12-07 | 2011-12-06 | Polyurethan-verbundmaterial |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2014502305A true JP2014502305A (ja) | 2014-01-30 |
| JP2014502305A5 JP2014502305A5 (enExample) | 2015-01-29 |
Family
ID=45099096
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013542504A Ceased JP2014502305A (ja) | 2010-12-07 | 2011-12-06 | ポリウレタン複合材料 |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP2649115B2 (enExample) |
| JP (1) | JP2014502305A (enExample) |
| KR (1) | KR20130124960A (enExample) |
| BR (1) | BR112013014105A2 (enExample) |
| ES (1) | ES2538800T3 (enExample) |
| WO (1) | WO2012076506A1 (enExample) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101607496B1 (ko) | 2014-04-21 | 2016-03-30 | 주식회사 빅스 | 이소시아네이트화 된 에어로겔을 이용한 투습방수포용 폴리우레탄 수지의 제조방법 |
| WO2017038775A1 (ja) * | 2015-09-01 | 2017-03-09 | 日立化成株式会社 | エアロゲル |
| JP2018145331A (ja) * | 2017-03-07 | 2018-09-20 | 日立化成株式会社 | エアロゲルパウダー分散液 |
| JP2020044677A (ja) * | 2018-09-14 | 2020-03-26 | 住友理工株式会社 | 断熱部材およびそれを用いた内装部品 |
| JP2025530576A (ja) * | 2022-08-17 | 2025-09-12 | エアロゲル アールアンドディー ピーティーイー.リミテッド | インソール用複合材料 |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2581216A1 (en) * | 2011-10-12 | 2013-04-17 | Dow Global Technologies LLC | Panel with fire barrier |
| US9944793B2 (en) | 2012-06-04 | 2018-04-17 | Basf Se | Aerogel-containing polyurethane composite material |
| CN103074762A (zh) * | 2013-01-23 | 2013-05-01 | 浙江理工大学 | 一种隔音纺织品的制备方法 |
| JP6191012B2 (ja) * | 2013-12-12 | 2017-09-06 | パナソニックIpマネジメント株式会社 | 断熱材 |
| EP2924058B1 (en) * | 2014-03-28 | 2016-05-25 | Huntsman International Llc | Reinforced organic natural fiber composites |
| WO2016163670A1 (ko) * | 2015-04-07 | 2016-10-13 | 주식회사 엘지화학 | 에어로겔 함유 조성물 및 이를 이용하여 제조된 단열 블랑켓 |
| KR102023531B1 (ko) | 2015-04-07 | 2019-09-24 | 주식회사 엘지화학 | 에어로겔 함유 조성물 및 이를 이용하여 제조된 단열 블랑켓 |
| KR102388720B1 (ko) | 2017-06-02 | 2022-04-21 | 삼성디스플레이 주식회사 | 나노 복합체, 이의 제조 방법 및 이를 이용한 나노 복합 필름 |
| DE102017212104A1 (de) | 2017-07-14 | 2019-01-17 | Eurochem Agro Gmbh | Beschichtete harnstoffhaltige Düngemittelteilchen und Verfahren zu ihrer Herstellung |
| KR102259655B1 (ko) * | 2019-03-14 | 2021-06-02 | 한국과학기술연구원 | 코팅형 유무기 단열 복합재료, 이를 포함하는 구조체, 및 제조방법 |
| CN110041505B (zh) * | 2019-04-30 | 2021-10-22 | 青岛科技大学 | 一种发泡型杂化高分子堵漏材料及其制备方法 |
| CN117903678B (zh) * | 2023-12-20 | 2024-12-10 | 广东桑泰科技有限公司 | 一种气凝胶隔热涂料及其制备方法 |
| US20250326881A1 (en) * | 2024-04-18 | 2025-10-23 | Stockmeier Urethanes Usa, Inc. | Foamed base for multi-use surfaces made in one step from a novel polyurethane system |
Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61185561A (ja) * | 1985-02-13 | 1986-08-19 | Mitsui Toatsu Chem Inc | チクソ性を改良したウレタン組成物 |
| JPH07267756A (ja) * | 1994-03-18 | 1995-10-17 | Basf Ag | シリカ−エーロゲル−粒子を含有する成形体 |
| JPH10147664A (ja) * | 1996-11-20 | 1998-06-02 | C I Kasei Co Ltd | エアロゲル断熱パネルおよびその製造方法 |
| JP2000072839A (ja) * | 1998-06-19 | 2000-03-07 | Takeda Chem Ind Ltd | 一液型揺変性ポリウレタン樹脂組成物 |
| JP2001092467A (ja) * | 1999-09-17 | 2001-04-06 | Sekisui Chem Co Ltd | 難燃性撥水吸音体及びその製造方法 |
| WO2001032791A1 (en) * | 1999-11-04 | 2001-05-10 | Huntsman International Llc | Urethane-group containing insulating coating |
| JP2001515537A (ja) * | 1997-03-17 | 2001-09-18 | ザ ダウ ケミカル カンパニー | ポリウレタンラテックスの連続製造方法 |
| JP2001279221A (ja) * | 2000-03-29 | 2001-10-10 | Sekisui Chem Co Ltd | 湿気硬化型ウレタン系接着剤又はシーリング剤及びその製造方法 |
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| JP2007522325A (ja) * | 2004-02-10 | 2007-08-09 | ダウ グローバル テクノロジーズ インコーポレイティド | バイオポリマー系低密度吸音発泡体 |
| JP2009242599A (ja) * | 2008-03-31 | 2009-10-22 | Aica Kogyo Co Ltd | ウレアウレタン樹脂組成物 |
| US20100144962A1 (en) * | 2006-10-27 | 2010-06-10 | The University Of Akron | Shape memory polymer aerogel composites |
| JP2013534958A (ja) * | 2010-06-30 | 2013-09-09 | ダウ グローバル テクノロジーズ エルエルシー | 水分散性ポリウレタンバインダーを有する無機ナノ多孔質粒子 |
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| ES2189881T3 (es) | 1995-09-11 | 2003-07-16 | Cabot Corp | MATERIAL COMPUESTO QUE CONTIENE AEROGEL Y ADHESIVO, PROCEDIMIENTO PARAsu FABRICACION ASI COMO SU UTILIZACION. |
| DE19533564A1 (de) | 1995-09-11 | 1997-03-13 | Hoechst Ag | Faserhaltiges Aerogel-Verbundmaterial |
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| KR100369729B1 (ko) † | 1998-10-13 | 2003-02-05 | 미쯔이카가쿠 가부시기가이샤 | 바인더조성물을 함유해서 이루어진 보드 |
| DE10008150A1 (de) † | 2000-02-22 | 2001-08-23 | Bayer Ag | Wasserdispergierbare Isocyanate zur Herstellung ultraphober Beschichtungen |
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| US10196814B2 (en) † | 2009-04-27 | 2019-02-05 | Cabot Corporation | Aerogel compositions and methods of making and using them |
| WO2012062796A1 (en) † | 2010-11-09 | 2012-05-18 | Rockwool International A/S | Method for manufacturing an aerogel-containing composite and composite produced by said method |
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- 2011-12-06 JP JP2013542504A patent/JP2014502305A/ja not_active Ceased
- 2011-12-06 KR KR1020137017658A patent/KR20130124960A/ko not_active Withdrawn
- 2011-12-06 BR BR112013014105A patent/BR112013014105A2/pt not_active IP Right Cessation
- 2011-12-06 ES ES11791558.7T patent/ES2538800T3/es active Active
- 2011-12-06 WO PCT/EP2011/071877 patent/WO2012076506A1/de not_active Ceased
- 2011-12-06 EP EP11791558.7A patent/EP2649115B2/de not_active Not-in-force
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101607496B1 (ko) | 2014-04-21 | 2016-03-30 | 주식회사 빅스 | 이소시아네이트화 된 에어로겔을 이용한 투습방수포용 폴리우레탄 수지의 제조방법 |
| WO2017038775A1 (ja) * | 2015-09-01 | 2017-03-09 | 日立化成株式会社 | エアロゲル |
| JPWO2017038775A1 (ja) * | 2015-09-01 | 2018-03-22 | 日立化成株式会社 | エアロゲル |
| JP2018076231A (ja) * | 2015-09-01 | 2018-05-17 | 日立化成株式会社 | エアロゲル |
| US10227455B2 (en) | 2015-09-01 | 2019-03-12 | Hitachi Chemical Company, Ltd. | Aerogel |
| JP2018145331A (ja) * | 2017-03-07 | 2018-09-20 | 日立化成株式会社 | エアロゲルパウダー分散液 |
| JP7024191B2 (ja) | 2017-03-07 | 2022-02-24 | 昭和電工マテリアルズ株式会社 | エアロゲルパウダー分散液 |
| JP2020044677A (ja) * | 2018-09-14 | 2020-03-26 | 住友理工株式会社 | 断熱部材およびそれを用いた内装部品 |
| JP7146541B2 (ja) | 2018-09-14 | 2022-10-04 | 住友理工株式会社 | 断熱部材およびそれを用いた内装部品 |
| JP2025530576A (ja) * | 2022-08-17 | 2025-09-12 | エアロゲル アールアンドディー ピーティーイー.リミテッド | インソール用複合材料 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2012076506A1 (de) | 2012-06-14 |
| KR20130124960A (ko) | 2013-11-15 |
| EP2649115B1 (de) | 2015-03-11 |
| EP2649115A1 (de) | 2013-10-16 |
| EP2649115B2 (de) | 2018-07-04 |
| ES2538800T3 (es) | 2015-06-24 |
| BR112013014105A2 (pt) | 2019-09-24 |
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