JP2013540674A5 - - Google Patents
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- Publication number
- JP2013540674A5 JP2013540674A5 JP2013524314A JP2013524314A JP2013540674A5 JP 2013540674 A5 JP2013540674 A5 JP 2013540674A5 JP 2013524314 A JP2013524314 A JP 2013524314A JP 2013524314 A JP2013524314 A JP 2013524314A JP 2013540674 A5 JP2013540674 A5 JP 2013540674A5
- Authority
- JP
- Japan
- Prior art keywords
- lactic acid
- catalyst
- reactor
- acid according
- range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims 48
- 239000003054 catalyst Substances 0.000 claims 43
- 238000007254 oxidation reaction Methods 0.000 claims 33
- 238000000034 method Methods 0.000 claims 25
- 239000004310 lactic acid Substances 0.000 claims 24
- 235000014655 lactic acid Nutrition 0.000 claims 24
- 230000003647 oxidation Effects 0.000 claims 23
- 230000002194 synthesizing effect Effects 0.000 claims 19
- 229910052799 carbon Inorganic materials 0.000 claims 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 7
- 229910000510 noble metal Inorganic materials 0.000 claims 7
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 6
- 239000007789 gas Substances 0.000 claims 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims 6
- 235000013772 propylene glycol Nutrition 0.000 claims 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 4
- 239000012670 alkaline solution Substances 0.000 claims 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 4
- 230000015572 biosynthetic process Effects 0.000 claims 4
- 239000001257 hydrogen Substances 0.000 claims 4
- 229910052739 hydrogen Inorganic materials 0.000 claims 4
- 239000001301 oxygen Substances 0.000 claims 4
- 229910052760 oxygen Inorganic materials 0.000 claims 4
- 238000003786 synthesis reaction Methods 0.000 claims 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 3
- 230000004913 activation Effects 0.000 claims 3
- 238000006243 chemical reaction Methods 0.000 claims 3
- 239000000243 solution Substances 0.000 claims 3
- 238000003756 stirring Methods 0.000 claims 3
- 229910004298 SiO 2 Inorganic materials 0.000 claims 2
- 229910010413 TiO 2 Inorganic materials 0.000 claims 2
- 229910044991 metal oxide Inorganic materials 0.000 claims 2
- 150000004706 metal oxides Chemical class 0.000 claims 2
- 229910052757 nitrogen Inorganic materials 0.000 claims 2
- 229910052763 palladium Inorganic materials 0.000 claims 2
- 229910052697 platinum Inorganic materials 0.000 claims 2
- 238000000926 separation method Methods 0.000 claims 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 1
- GEIAQOFPUVMAGM-UHFFFAOYSA-N ZrO Inorganic materials [Zr]=O GEIAQOFPUVMAGM-UHFFFAOYSA-N 0.000 claims 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 claims 1
- 239000012736 aqueous medium Substances 0.000 claims 1
- 239000008346 aqueous phase Substances 0.000 claims 1
- 239000003125 aqueous solvent Substances 0.000 claims 1
- 230000005587 bubbling Effects 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical group O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 229910052741 iridium Inorganic materials 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 229910052703 rhodium Inorganic materials 0.000 claims 1
- 229910052707 ruthenium Inorganic materials 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BRPI1002970-2 | 2010-08-18 | ||
| BRPI1002970-2A BRPI1002970B1 (pt) | 2010-08-18 | 2010-08-18 | processo para a produção de hidrogênio a partir do etanol |
| PCT/BR2011/000291 WO2012031341A1 (pt) | 2010-08-18 | 2011-08-18 | Processo para a produção de hidrogênio a partir do etanol |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2013540674A JP2013540674A (ja) | 2013-11-07 |
| JP2013540674A5 true JP2013540674A5 (enExample) | 2014-10-16 |
Family
ID=45810031
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013524314A Pending JP2013540674A (ja) | 2010-08-18 | 2011-08-18 | エタノールからの水素の製造方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US8642004B2 (enExample) |
| EP (1) | EP2607302B1 (enExample) |
| JP (1) | JP2013540674A (enExample) |
| BR (1) | BRPI1002970B1 (enExample) |
| WO (1) | WO2012031341A1 (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2807356T3 (es) * | 2012-09-25 | 2021-02-22 | Haldor Topsoe As | Catalizador de reformado con vapor y procedimiento para fabricar el mismo |
| US9181148B2 (en) | 2013-05-22 | 2015-11-10 | Saudi Arabian Oil Company | Ni/CGO and Ni-Ru/CGO based pre-reforming catalysts formulation for methane rich gas production from diesel processing for fuel cell applications |
| US9499403B2 (en) * | 2013-07-10 | 2016-11-22 | Saudi Arabian Oil Company | Catalyst and process for thermo-neutral reforming of liquid hydrocarbons |
| US20160236183A1 (en) * | 2013-10-17 | 2016-08-18 | Petróleo Brasileiro S.A. - Petrobras | Catalyst for the production of synthesis gas and process for obtaining it |
| CN104258913B (zh) * | 2014-08-06 | 2016-03-30 | 中国科学院广州能源研究所 | 一种用于催化生物质合成气合成低碳混合醇的催化剂的还原装置及还原方法 |
| US10953388B1 (en) | 2019-12-27 | 2021-03-23 | Saudi Arabian Oil Company | Ni—Ru—CgO based pre-reforming catalyst for liquid hydrocarbons |
| EP4096823B1 (en) | 2020-01-31 | 2025-01-15 | Topsoe A/S | Reforming catalyst |
| JP2022176895A (ja) * | 2021-05-17 | 2022-11-30 | 大阪瓦斯株式会社 | 高発熱量燃料ガスの製造方法 |
| JPWO2024105814A1 (enExample) * | 2022-11-16 | 2024-05-23 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AR220381A1 (es) * | 1979-04-16 | 1980-10-31 | Sao Paulo Gas | Proceso catalitico para la gasificacion de etanol con vapor |
| US4238371A (en) * | 1979-04-18 | 1980-12-09 | Phillips Petroleum Company | Methanation catalyst |
| GB2068407A (en) * | 1980-01-31 | 1981-08-12 | British Gas Corp | Gas production |
| BR8400305A (pt) * | 1984-01-16 | 1985-06-11 | Catalysts & Chem Europ | Processo para a producao de gases ricos em hidrogenio,metano,oxidos de carbono ou suas misturas |
| JP3313766B2 (ja) * | 1992-07-15 | 2002-08-12 | 財団法人石油産業活性化センター | 水蒸気改質用薄膜状触媒 |
| US7255848B2 (en) | 2002-10-01 | 2007-08-14 | Regents Of The Univeristy Of Minnesota | Production of hydrogen from alcohols |
| US7252692B2 (en) * | 2004-01-21 | 2007-08-07 | Min-Hon Rei | Process and reactor module for quick start hydrogen production |
| JP4594011B2 (ja) * | 2004-09-15 | 2010-12-08 | ハルドール・トプサー・アクチエゼルスカベット | エタノール改質方法 |
| US7585339B2 (en) | 2004-09-15 | 2009-09-08 | Haldor Topsoe A/S | Process for reforming ethanol to hydrogen-rich products |
| EP2137099B1 (en) * | 2007-04-18 | 2013-08-14 | L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Hydrogen production process |
| DK2011907T3 (da) | 2007-07-02 | 2010-05-17 | Centre Nat Rech Scient | Fremgangsmåde til fremstilling af hydrogengas og carbon-nanorør ud fra en katalytisk nedbrydning af ethanol |
| BRPI0703296A2 (pt) | 2007-07-19 | 2009-03-10 | Inst Nac De Tecnologia Int | catalisadores para a produÇço de hidrogÊnio para cÉlulas a combustÍvel de baixa temperatura a partir da reforma a vapor e da reforma autotÉrmica de Álcoois |
| WO2009130197A2 (de) | 2008-04-22 | 2009-10-29 | Basf Se | Verfahren zum prereforming von ethanol |
-
2010
- 2010-08-18 BR BRPI1002970-2A patent/BRPI1002970B1/pt active IP Right Grant
-
2011
- 2011-08-18 WO PCT/BR2011/000291 patent/WO2012031341A1/pt not_active Ceased
- 2011-08-18 US US13/212,772 patent/US8642004B2/en active Active
- 2011-08-18 JP JP2013524314A patent/JP2013540674A/ja active Pending
- 2011-08-18 EP EP11822945.9A patent/EP2607302B1/en active Active
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