JP2013526406A5 - - Google Patents
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- Publication number
- JP2013526406A5 JP2013526406A5 JP2013512084A JP2013512084A JP2013526406A5 JP 2013526406 A5 JP2013526406 A5 JP 2013526406A5 JP 2013512084 A JP2013512084 A JP 2013512084A JP 2013512084 A JP2013512084 A JP 2013512084A JP 2013526406 A5 JP2013526406 A5 JP 2013526406A5
- Authority
- JP
- Japan
- Prior art keywords
- iron
- zeolite beta
- range
- containing zeolite
- amount
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 46
- 229910021536 Zeolite Inorganic materials 0.000 claims description 37
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 37
- 239000010457 zeolite Substances 0.000 claims description 37
- 238000000034 method Methods 0.000 claims description 31
- 229910052742 iron Inorganic materials 0.000 claims description 23
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 14
- 230000015572 biosynthetic process Effects 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- 238000003786 synthesis reaction Methods 0.000 claims description 9
- 229910021529 ammonia Inorganic materials 0.000 claims description 8
- 238000010531 catalytic reduction reaction Methods 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- 150000001768 cations Chemical class 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 239000013078 crystal Substances 0.000 claims description 4
- 239000007789 gas Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000011148 porous material Substances 0.000 claims description 4
- 238000005470 impregnation Methods 0.000 claims description 3
- 238000005342 ion exchange Methods 0.000 claims description 3
- 239000007791 liquid phase Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- 150000002430 hydrocarbons Chemical class 0.000 claims description 2
- 239000004005 microsphere Substances 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 239000008188 pellet Substances 0.000 claims description 2
- 238000005341 cation exchange Methods 0.000 claims 2
- 238000010276 construction Methods 0.000 claims 1
- 230000009466 transformation Effects 0.000 claims 1
- 239000002184 metal Substances 0.000 description 22
- 229910052751 metal Inorganic materials 0.000 description 22
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 8
- 229910052802 copper Inorganic materials 0.000 description 8
- 239000010949 copper Substances 0.000 description 8
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US34721010P | 2010-05-21 | 2010-05-21 | |
| US61/347,210 | 2010-05-21 | ||
| PCT/US2011/036997 WO2011146615A2 (en) | 2010-05-21 | 2011-05-18 | Novel metal-containing zeolite beta for nox reduction and methods of making the same |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015162106A Division JP6231525B2 (ja) | 2010-05-21 | 2015-08-19 | ＮＯｘ還元のための新規の金属含有ゼオライトベータ |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013526406A JP2013526406A (ja) | 2013-06-24 |
| JP2013526406A5 true JP2013526406A5 (enExample) | 2014-06-26 |
| JP5797749B2 JP5797749B2 (ja) | 2015-10-21 |
Family
ID=44972640
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013512084A Active JP5797749B2 (ja) | 2010-05-21 | 2011-05-18 | ＮＯｘ還元のための新規の金属含有ゼオライトベータ |
| JP2015162106A Active JP6231525B2 (ja) | 2010-05-21 | 2015-08-19 | ＮＯｘ還元のための新規の金属含有ゼオライトベータ |
| JP2017013329A Active JP6397064B2 (ja) | 2010-05-21 | 2017-01-27 | ＮＯｘ還元のための新規の金属含有ゼオライトベータ |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015162106A Active JP6231525B2 (ja) | 2010-05-21 | 2015-08-19 | ＮＯｘ還元のための新規の金属含有ゼオライトベータ |
| JP2017013329A Active JP6397064B2 (ja) | 2010-05-21 | 2017-01-27 | ＮＯｘ還元のための新規の金属含有ゼオライトベータ |
Country Status (14)
| Country | Link |
|---|---|
| US (2) | US20110286914A1 (enExample) |
| EP (2) | EP2742991A1 (enExample) |
| JP (3) | JP5797749B2 (enExample) |
| KR (1) | KR101852143B1 (enExample) |
| CN (2) | CN102971065B (enExample) |
| BR (1) | BR112012029648B1 (enExample) |
| CA (1) | CA2800393C (enExample) |
| DK (1) | DK2571604T3 (enExample) |
| ES (1) | ES2465617T3 (enExample) |
| MX (1) | MX343465B (enExample) |
| PL (1) | PL2571604T3 (enExample) |
| RU (1) | RU2641771C1 (enExample) |
| WO (1) | WO2011146615A2 (enExample) |
| ZA (2) | ZA201209485B (enExample) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5351216B2 (ja) | 2010-07-01 | 2013-11-27 | 日本化学工業株式会社 | ゼオライトの製造方法 |
| JP5116880B2 (ja) * | 2011-01-18 | 2013-01-09 | 日本化学工業株式会社 | Ｆｅ（ＩＩ）置換ベータ型ゼオライト、それを含むガス吸着剤及びその製造方法、並びに一酸化窒素及びハイドロカーボンの除去方法 |
| BR112014012818A2 (pt) | 2011-12-02 | 2017-06-13 | Pq Corp | material cristalino microporoso estabilizado, o processo de fabricaçãodo mesmo, e o uso para redução catalítica seletiva de nox |
| US20130202524A1 (en) | 2012-02-06 | 2013-08-08 | Basf Se | Iron- And Copper-Containing Zeolite Beta From Organotemplate-Free Synthesis And Use Thereof In The Selective Catalytic Reduction Of NOx |
| US10792614B2 (en) * | 2012-02-06 | 2020-10-06 | Basf Se | Process and apparatus for treatment of gas streams containing nitrogen oxides |
| CN107362824B (zh) * | 2012-02-06 | 2021-03-23 | 巴斯夫欧洲公司 | 获自无有机模板合成法的含铁和铜的沸石β |
| JP6034224B2 (ja) * | 2012-04-10 | 2016-11-30 | ユニゼオ株式会社 | ベータ型ゼオライト及びその製造方法 |
| JP5988743B2 (ja) * | 2012-07-18 | 2016-09-07 | ユニゼオ株式会社 | Ｆｅ（ＩＩ）置換ベータ型ゼオライト、それを含むガス吸着剤及びその製造方法、並びに一酸化窒素及びハイドロカーボンの除去方法 |
| JP6058433B2 (ja) * | 2013-03-12 | 2017-01-11 | ユニゼオ株式会社 | ハイドロカーボンリフォーマトラップ材及びハイドロカーボンの除去方法 |
| JP6153196B2 (ja) * | 2013-06-14 | 2017-06-28 | ユニゼオ株式会社 | Ｍｎ＋置換ベータ型ゼオライト、それを含むガス吸着剤及びその製造方法、並びに一酸化窒素の除去方法 |
| WO2015001095A1 (en) | 2013-07-05 | 2015-01-08 | Friedrich-Alexander-Universität Erlangen-Nürnberg | Process for the preparation of organo-template free supported zeolite layers |
| CN103691481B (zh) * | 2013-12-23 | 2016-04-13 | 中国科学院上海硅酸盐研究所 | 一种负载型多级孔Beta分子筛催化剂及其制备方法和应用 |
| EP3097054B1 (en) * | 2014-01-03 | 2020-06-03 | Basf Se | Method for the production of a bimetal-exchanged zeolite beta from organotemplate-free synthesis |
| US20150231620A1 (en) * | 2014-02-19 | 2015-08-20 | Ford Global Technologies, Llc | IRON-ZEOLITE CHABAZITE CATALYST FOR USE IN NOx REDUCTION AND METHOD OF MAKING |
| US20150290632A1 (en) * | 2014-04-09 | 2015-10-15 | Ford Global Technologies, Llc | IRON AND COPPER-CONTAINING CHABAZITE ZEOLITE CATALYST FOR USE IN NOx REDUCTION |
| CZ305861B6 (cs) * | 2014-06-27 | 2016-04-13 | Ústav fyzikální chemie J. Heyrovského AV ČR, v. v. i. | Katalyzátor pro selektivní katalytickou redukci oxidů dusíku, způsob jeho výroby a použití |
| TWI657860B (zh) | 2014-07-07 | 2019-05-01 | 荷蘭商蜆殼國際研究公司 | 異構化催化劑 |
| US10207964B2 (en) | 2015-10-06 | 2019-02-19 | Shell Oil Company | Process for making cumene by alkylation of benzene using an organotemplate-free zeolite beta |
| CN107029781B (zh) * | 2016-02-04 | 2019-08-09 | 中触媒新材料股份有限公司 | 铁和铈改性β分子筛选择性还原催化剂及制备方法与应用 |
| GB201608643D0 (en) * | 2016-05-17 | 2016-06-29 | Thermo Fisher Scient Bremen | Elemental analysis system and method |
| RU2020102860A (ru) | 2017-07-11 | 2021-08-11 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Катализатор и способ его применения для конверсии nox и n2o |
| KR102578657B1 (ko) * | 2017-07-11 | 2023-09-15 | 쉘 인터내셔날 리써취 마트샤피지 비.브이. | 촉매 및 이의 사용 방법 |
| WO2019082990A1 (ja) * | 2017-10-25 | 2019-05-02 | 三井金属鉱業株式会社 | 金属置換ベータ型ゼオライト及びその製造方法 |
| US20230173455A1 (en) * | 2017-12-29 | 2023-06-08 | Korea University Research And Business Foundation | Hydrocarbon adsorbent |
| KR102085652B1 (ko) * | 2017-12-29 | 2020-03-06 | 현대자동차 주식회사 | 규칙적인 메조 기공을 가진 제오라이트 입자에 금속이 함침된 탄화수소 흡착제 및 그 제조방법 |
| JP2018108927A (ja) * | 2018-01-29 | 2018-07-12 | 出光興産株式会社 | 金属担持ゼオライト成型体、金属担持ゼオライト成型体の製造方法、硫黄化合物除去用吸着剤、水素の製造方法、及び燃料電池システム |
| US10669908B1 (en) | 2018-12-03 | 2020-06-02 | Wellhead Power Solutions, Llc | Power generating systems and methods for reducing startup NOx emissions in fossile fueled power generation system |
| WO2022158588A1 (ja) * | 2021-01-25 | 2022-07-28 | 国立大学法人東京大学 | ベータ型ゼオライト及びその製造方法 |
| EP4484006A4 (en) | 2022-03-29 | 2025-08-20 | Mitsubishi Heavy Ind Ltd | N2O DECOMPOSITION CATALYST |
| DE102023002844A1 (de) | 2023-07-13 | 2025-01-16 | Hans-Jürgen Eberle | Katalysator zur Reduktion und/oder Zersetzung von Lachgas |
| DE102024004011A1 (de) | 2024-12-03 | 2026-06-03 | Hans-Jürgen Eberle | Hierarchischer Katalysator zur Reduktion und/oder Zersetzung von Lachgas |
| DE102025001848A1 (de) | 2025-01-09 | 2026-07-09 | Hans-Jürgen Eberle | Hochaktiver Katalysator zur Reduktion und/oder Zersetzung von Lachgas |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4952385A (en) | 1987-03-02 | 1990-08-28 | Georgia Tech Research Corp. | Ferrisilicate molecular sieve and use as a catalyst |
| US5744673A (en) | 1988-03-30 | 1998-04-28 | Uop | Activated zeolite beta and its use for hydrocarbon conversion |
| US4961917A (en) * | 1989-04-20 | 1990-10-09 | Engelhard Corporation | Method for reduction of nitrogen oxides with ammonia using promoted zeolite catalysts |
| US5451387A (en) | 1994-07-07 | 1995-09-19 | Mobil Oil Corporation | Selective catalytic reduction of nitrogen oxides using an iron impregnated zeolite catalyst |
| RU2116250C1 (ru) * | 1996-09-05 | 1998-07-27 | Акционерное общество "Ангарская нефтехимическая компания" | Способ получения цеолита бета |
| JP4044984B2 (ja) * | 1997-01-08 | 2008-02-06 | 日本碍子株式会社 | 吸着材 |
| RU2151101C1 (ru) * | 1998-07-21 | 2000-06-20 | Общество с ограниченной ответственностью "Научно-внедренческая фирма "Катализатор" | Способ получения цеолита бета |
| CN1096295C (zh) * | 1998-11-18 | 2002-12-18 | 中国石油化工集团公司 | β沸石 |
| FR2789911B1 (fr) | 1999-02-18 | 2001-05-04 | Grande Paroisse Sa | Procede pour abattre simultanement les oxydes nitriques et le protoxyde d'azote dans les gaz qui en contiennent |
| US6689709B1 (en) * | 2000-11-15 | 2004-02-10 | Engelhard Corporation | Hydrothermally stable metal promoted zeolite beta for NOx reduction |
| US6914026B2 (en) * | 2001-09-07 | 2005-07-05 | Engelhard Corporation | Hydrothermally stable metal promoted zeolite beta for NOx reduction |
| RU2214965C1 (ru) * | 2002-12-18 | 2003-10-27 | Институт катализа им. Г.К. Борескова СО РАН | Способ получения цеолита бета |
| WO2006050820A1 (de) * | 2004-11-12 | 2006-05-18 | Süd-Chemie AG | Verfahren zur synthese von zeolith beta mit diethylentriamin |
| CN100425534C (zh) * | 2005-05-31 | 2008-10-15 | 中国石油化工股份有限公司 | 一种改性β沸石 |
| CN101134172B (zh) * | 2006-08-31 | 2010-10-27 | 中国石油化工股份有限公司 | 一种烃类转化催化剂 |
| CN101205072B (zh) * | 2006-12-18 | 2011-04-20 | 中国石油化工股份有限公司 | 一种低硅铝比β沸石的合成方法 |
| JP6176891B2 (ja) * | 2007-08-13 | 2017-08-09 | ピーキュー コーポレイション | 新規鉄含有アルミノケイ酸塩ゼオライト、ならびにその作製方法および使用方法 |
| CN101249968B (zh) * | 2008-03-10 | 2010-06-02 | 吉林大学 | 无有机模板剂合成Beta分子筛的方法 |
| JP2010096176A (ja) * | 2008-05-20 | 2010-04-30 | Ibiden Co Ltd | ハニカム構造体 |
| NL2001788C2 (nl) * | 2008-07-11 | 2010-01-12 | Stichting Energie | Werkwijze voor de decompositie van N2O, katalysator daarvoor en bereiding van deze katalysator. |
| JP5549839B2 (ja) * | 2008-08-19 | 2014-07-16 | 東ソー株式会社 | 高耐熱性β型ゼオライト及びそれを用いたＳＣＲ触媒 |
| CN104876237A (zh) * | 2009-06-18 | 2015-09-02 | 巴斯夫欧洲公司 | 生产沸石材料的无有机模板合成方法 |
-
2011
- 2011-05-18 CN CN201180032195.2A patent/CN102971065B/zh active Active
- 2011-05-18 KR KR1020127033505A patent/KR101852143B1/ko active Active
- 2011-05-18 MX MX2012013535A patent/MX343465B/es active IP Right Grant
- 2011-05-18 PL PL11721964T patent/PL2571604T3/pl unknown
- 2011-05-18 JP JP2013512084A patent/JP5797749B2/ja active Active
- 2011-05-18 US US13/110,337 patent/US20110286914A1/en not_active Abandoned
- 2011-05-18 ES ES11721964.2T patent/ES2465617T3/es active Active
- 2011-05-18 RU RU2016101257A patent/RU2641771C1/ru active
- 2011-05-18 DK DK11721964.2T patent/DK2571604T3/da active
- 2011-05-18 EP EP14000858.2A patent/EP2742991A1/en not_active Withdrawn
- 2011-05-18 WO PCT/US2011/036997 patent/WO2011146615A2/en not_active Ceased
- 2011-05-18 CN CN201510593813.0A patent/CN105312081B/zh not_active Expired - Fee Related
- 2011-05-18 EP EP11721964.2A patent/EP2571604B1/en active Active
- 2011-05-18 CA CA2800393A patent/CA2800393C/en active Active
- 2011-05-18 BR BR112012029648-5A patent/BR112012029648B1/pt active IP Right Grant
-
2012
- 2012-12-13 ZA ZA2012/09485A patent/ZA201209485B/en unknown
-
2013
- 2013-12-12 ZA ZA2013/09393A patent/ZA201309393B/en unknown
-
2015
- 2015-08-19 JP JP2015162106A patent/JP6231525B2/ja active Active
-
2017
- 2017-01-27 JP JP2017013329A patent/JP6397064B2/ja active Active
-
2018
- 2018-10-23 US US16/168,356 patent/US11786864B2/en active Active
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