JP2014515723A5 - - Google Patents
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- Publication number
- JP2014515723A5 JP2014515723A5 JP2014506486A JP2014506486A JP2014515723A5 JP 2014515723 A5 JP2014515723 A5 JP 2014515723A5 JP 2014506486 A JP2014506486 A JP 2014506486A JP 2014506486 A JP2014506486 A JP 2014506486A JP 2014515723 A5 JP2014515723 A5 JP 2014515723A5
- Authority
- JP
- Japan
- Prior art keywords
- zeolite
- iron
- potassium
- chabazite
- range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 claims 22
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 18
- 229910021536 Zeolite Inorganic materials 0.000 claims 14
- 239000010457 zeolite Substances 0.000 claims 14
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 12
- 229910052742 iron Inorganic materials 0.000 claims 9
- 239000010949 copper Substances 0.000 claims 8
- 239000002178 crystalline material Substances 0.000 claims 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 6
- UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 claims 6
- 229910052802 copper Inorganic materials 0.000 claims 6
- 239000000463 material Substances 0.000 claims 6
- 239000000377 silicon dioxide Substances 0.000 claims 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 5
- 229910052700 potassium Inorganic materials 0.000 claims 5
- 239000011591 potassium Substances 0.000 claims 5
- 229910052676 chabazite Inorganic materials 0.000 claims 4
- 239000013078 crystal Substances 0.000 claims 4
- 150000004761 hexafluorosilicates Chemical class 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims 3
- 229910021529 ammonia Inorganic materials 0.000 claims 3
- 239000004111 Potassium silicate Substances 0.000 claims 2
- 229910004298 SiO 2 Inorganic materials 0.000 claims 2
- 229910000323 aluminium silicate Inorganic materials 0.000 claims 2
- 230000015572 biosynthetic process Effects 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 238000010438 heat treatment Methods 0.000 claims 2
- 238000005342 ion exchange Methods 0.000 claims 2
- 239000007791 liquid phase Substances 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims 2
- 229910052913 potassium silicate Inorganic materials 0.000 claims 2
- 235000019353 potassium silicate Nutrition 0.000 claims 2
- 239000007787 solid Substances 0.000 claims 2
- 238000003786 synthesis reaction Methods 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- 239000004202 carbamide Substances 0.000 claims 1
- 238000010531 catalytic reduction reaction Methods 0.000 claims 1
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 239000012297 crystallization seed Substances 0.000 claims 1
- 238000000151 deposition Methods 0.000 claims 1
- -1 hexafluorosilicic acid Chemical compound 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- 239000004005 microsphere Substances 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- LXPCOISGJFXEJE-UHFFFAOYSA-N oxifentorex Chemical group C=1C=CC=CC=1C[N+](C)([O-])C(C)CC1=CC=CC=C1 LXPCOISGJFXEJE-UHFFFAOYSA-N 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 239000008188 pellet Substances 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
- 229910001868 water Inorganic materials 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161476575P | 2011-04-18 | 2011-04-18 | |
| US61/476,575 | 2011-04-18 | ||
| PCT/US2012/033948 WO2012145323A1 (en) | 2011-04-18 | 2012-04-17 | Large crystal, organic-free chabazite, methods of making and using the same |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014515723A JP2014515723A (ja) | 2014-07-03 |
| JP2014515723A5 true JP2014515723A5 (enExample) | 2015-05-28 |
| JP6169069B2 JP6169069B2 (ja) | 2017-07-26 |
Family
ID=47021502
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014506486A Active JP6169069B2 (ja) | 2011-04-18 | 2012-04-17 | 大型結晶で有機を含まないチャバザイトと、同材料の作成方法および使用方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20120269719A1 (enExample) |
| EP (1) | EP2699345A4 (enExample) |
| JP (1) | JP6169069B2 (enExample) |
| KR (2) | KR101830326B1 (enExample) |
| CN (1) | CN103561865B (enExample) |
| WO (1) | WO2012145323A1 (enExample) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2464478A (en) † | 2008-10-15 | 2010-04-21 | Johnson Matthey Plc | Aluminosilicate zeolite catalyst and use thereof in exhaust gas after-treatment |
| RU2614411C2 (ru) * | 2010-12-02 | 2017-03-28 | Джонсон Мэтти Паблик Лимитед Компани | Цеолитный катализатор, содержащий металл |
| JP5895510B2 (ja) * | 2010-12-22 | 2016-03-30 | 東ソー株式会社 | チャバザイト型ゼオライト及びその製造方法、銅が担持されている低シリカゼオライト、及び、そのゼオライトを含む窒素酸化物還元除去触媒、並びに、その触媒を使用する窒素酸化物還元除去方法 |
| KR101830326B1 (ko) * | 2011-04-18 | 2018-02-20 | 피큐 코포레이션 | 대결정 유기물-비함유 차바자이트, 이의 제조 및 사용 방법 |
| US9527751B2 (en) | 2011-11-11 | 2016-12-27 | Basf Se | Organotemplate-free synthetic process for the production of a zeolitic material of the CHA-type structure |
| CA2855572C (en) * | 2011-11-11 | 2020-04-28 | Basf Se | Organotemplate-free synthetic process for the production of a zeolitic material of the cha-type structure |
| WO2013082550A1 (en) * | 2011-12-02 | 2013-06-06 | Pq Corporation | Stabilized microporous crystalline material, the method of making the same, and the use for selective catalytic reduction of nox |
| DE202013012229U1 (de) | 2013-04-05 | 2015-10-08 | Umicore Ag & Co. Kg | CuCHA Material für die SCR-Katalyse |
| KR102299703B1 (ko) * | 2013-12-02 | 2021-09-09 | 존슨 맛쎄이 퍼블릭 리미티드 컴파니 | 고실리카 Cu-CHA의 혼합 주형 합성 |
| JP5740040B1 (ja) | 2014-07-07 | 2015-06-24 | イビデン株式会社 | ゼオライト、ハニカム触媒及び排ガス浄化装置 |
| JP5732170B1 (ja) * | 2014-07-07 | 2015-06-10 | イビデン株式会社 | ゼオライト、ハニカム触媒及び排ガス浄化装置 |
| US9938157B2 (en) | 2014-07-23 | 2018-04-10 | Chevron U.S.A. Inc. | Interzeolite transformation and metal encapsulation in the absence of an SDA |
| US9802831B2 (en) * | 2014-07-23 | 2017-10-31 | Chevron U.S.A. Inc. | Synthesis of high silica zeolite via interzeolite transformation without OSDAs |
| JP2016073959A (ja) * | 2014-10-09 | 2016-05-12 | イビデン株式会社 | ハニカム触媒 |
| JP6546731B2 (ja) * | 2014-10-09 | 2019-07-17 | イビデン株式会社 | ハニカム触媒 |
| US10173211B2 (en) | 2014-10-14 | 2019-01-08 | California Institute Of Technology | Organic-free synthesis of small pore zeolite catalysts |
| EP3307997B1 (en) * | 2015-06-12 | 2020-03-18 | BASF Corporation | Exhaust gas treatment system |
| JP6879680B2 (ja) * | 2015-06-29 | 2021-06-02 | 日揮触媒化成株式会社 | 高シリカチャバザイト型ゼオライトの製造方法および高シリカチャバザイト型ゼオライト |
| WO2017109705A1 (en) * | 2015-12-22 | 2017-06-29 | Basf Corporation | Process for preparing iron(iii)-exchanged zeolite composition |
| JP6817022B2 (ja) * | 2016-06-07 | 2021-01-20 | 日揮触媒化成株式会社 | 高耐水熱性チャバザイト型ゼオライトおよびその製造方法 |
| CN109311684B (zh) * | 2016-06-07 | 2022-05-06 | 日挥触媒化成株式会社 | 高耐水热性菱沸石型沸石和其制造方法 |
| JP6792264B2 (ja) * | 2016-11-25 | 2020-11-25 | 国立大学法人広島大学 | ガリウムを含有する結晶性アルミノシリケートおよびその製造方法 |
| MY199195A (en) | 2017-02-22 | 2023-10-19 | Tosoh Corp | Chabazite-type zeolite and method of manufacturing chabazite-type zeolite |
| AU2018301347B2 (en) * | 2017-07-11 | 2021-07-15 | Shell Internationale Research Maatschappij B.V. | Catalyst and method of use thereof in the conversion of NOX and N2O |
| US11267717B2 (en) | 2018-03-21 | 2022-03-08 | Basf Corporation | CHA zeolite material and related method of synthesis |
| CN112020478A (zh) * | 2018-05-03 | 2020-12-01 | 沙特基础工业全球技术公司 | 菱沸石(cha)的无sda合成及其用途 |
| KR102833006B1 (ko) * | 2018-09-11 | 2025-07-14 | 바스프 모바일 에미션스 카탈리스츠 엘엘씨 | 골격 유형 aei를 갖는 제올라이트성 물질의 제조 방법 |
| WO2020252447A1 (en) * | 2019-06-13 | 2020-12-17 | Pq Corporation | Chabazite zeolite synthesis with organic templates |
| EP3812034A1 (en) | 2019-10-24 | 2021-04-28 | Dinex A/S | Durable copper-scr catalyst |
| CN111268691A (zh) * | 2020-03-12 | 2020-06-12 | 上海索易分子筛有限公司 | 一种小晶粒菱沸石及其制备方法和应用 |
| EP4015454A1 (en) * | 2020-12-21 | 2022-06-22 | Tosoh Corporation | Cha-type zeolite and manufacturing method thereof |
| DE102022202106A1 (de) | 2022-03-01 | 2023-09-07 | Carl von Ossietzky Universität Oldenburg Körperschaft des öffentlichen Rechts | Katalysator für die Oxidation mit Hydroxylradikalen |
| WO2025164536A1 (ja) * | 2024-01-31 | 2025-08-07 | 日揮触媒化成株式会社 | Fe含有CHAゼオライトおよびその製造方法 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2513983B1 (fr) * | 1981-09-14 | 1986-10-24 | Raffinage Cie Francaise | Procede de preparation de zeolites synthetiques et zeolites obtenues par ce procede |
| US5011667A (en) * | 1988-09-08 | 1991-04-30 | Engelhard Corporation | Self-bound sodium chabazite aggregates and methods for preparation thereof |
| AU1050597A (en) * | 1995-11-15 | 1997-06-05 | California Institute Of Technology | Synthesis of zeolites by hydrothermal reaction of zeolite p1 |
| US6585952B1 (en) * | 2000-05-25 | 2003-07-01 | Board Of Trustees Operating Michigan State University | Ultrastable hexagonal, cubic and wormhole aluminosilicate mesostructures |
| FR2887538B1 (fr) * | 2005-06-28 | 2008-01-04 | Inst Francais Du Petrole | Procede de traitement d'une zeolithe a petits et/ou moyens pores et son utilisation en oligomerisation des olefines legeres |
| BRPI0808091A2 (pt) * | 2007-02-27 | 2014-07-15 | Basf Catalysts Llc | Catalisador, sistema de tratamento de gás de exaustão, processo para a redução de óxidos de nitrogênio, e, artigo de catalisador. |
| US10384162B2 (en) * | 2007-03-26 | 2019-08-20 | Pq Corporation | High silica chabazite for selective catalytic reduction, methods of making and using same |
| EP2689846A1 (en) * | 2007-08-13 | 2014-01-29 | PQ Corporation | Selective catalytic reduction of nitrogen oxides in the presence of iron-containing aluminosilicate zeolites |
| US20090196812A1 (en) * | 2008-01-31 | 2009-08-06 | Basf Catalysts Llc | Catalysts, Systems and Methods Utilizing Non-Zeolitic Metal-Containing Molecular Sieves Having the CHA Crystal Structure |
| US8715618B2 (en) * | 2008-05-21 | 2014-05-06 | Basf Se | Process for the direct synthesis of Cu containing zeolites having CHA structure |
| GB2464478A (en) * | 2008-10-15 | 2010-04-21 | Johnson Matthey Plc | Aluminosilicate zeolite catalyst and use thereof in exhaust gas after-treatment |
| US10583424B2 (en) * | 2008-11-06 | 2020-03-10 | Basf Corporation | Chabazite zeolite catalysts having low silica to alumina ratios |
| JP2011064882A (ja) * | 2009-09-16 | 2011-03-31 | Fuji Xerox Co Ltd | 画像形成装置 |
| CN102574116A (zh) * | 2009-10-14 | 2012-07-11 | 巴斯夫欧洲公司 | 用于选择性还原NOx 的含铜插晶菱沸石分子筛 |
| JP5895510B2 (ja) * | 2010-12-22 | 2016-03-30 | 東ソー株式会社 | チャバザイト型ゼオライト及びその製造方法、銅が担持されている低シリカゼオライト、及び、そのゼオライトを含む窒素酸化物還元除去触媒、並びに、その触媒を使用する窒素酸化物還元除去方法 |
| KR101830326B1 (ko) * | 2011-04-18 | 2018-02-20 | 피큐 코포레이션 | 대결정 유기물-비함유 차바자이트, 이의 제조 및 사용 방법 |
-
2012
- 2012-04-17 KR KR1020137030394A patent/KR101830326B1/ko active Active
- 2012-04-17 KR KR1020187004270A patent/KR101948254B1/ko not_active Expired - Fee Related
- 2012-04-17 CN CN201280025744.8A patent/CN103561865B/zh not_active Expired - Fee Related
- 2012-04-17 EP EP12773612.2A patent/EP2699345A4/en not_active Withdrawn
- 2012-04-17 JP JP2014506486A patent/JP6169069B2/ja active Active
- 2012-04-17 WO PCT/US2012/033948 patent/WO2012145323A1/en not_active Ceased
- 2012-04-17 US US13/449,230 patent/US20120269719A1/en not_active Abandoned
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