CN103561865B - 大晶体、不含有机物的菱沸石以及制造和使用其的方法 - Google Patents
大晶体、不含有机物的菱沸石以及制造和使用其的方法 Download PDFInfo
- Publication number
- CN103561865B CN103561865B CN201280025744.8A CN201280025744A CN103561865B CN 103561865 B CN103561865 B CN 103561865B CN 201280025744 A CN201280025744 A CN 201280025744A CN 103561865 B CN103561865 B CN 103561865B
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- China
- Prior art keywords
- chabazite
- zeolite
- iron
- potassium
- sar
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9413—Processes characterised by a specific catalyst
- B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
- B01J29/072—Iron group metals or copper
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7015—CHA-type, e.g. Chabazite, LZ-218
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/76—Iron group metals or copper
- B01J29/763—CHA-type, e.g. Chabazite, LZ-218
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
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- B01J35/615—100-500 m2/g
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/10—Heat treatment in the presence of water, e.g. steam
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/30—Ion-exchange
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
- C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
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- B01D2251/2062—Ammonia
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- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
- B01D2253/1085—Zeolites characterized by a silicon-aluminium ratio
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- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161476575P | 2011-04-18 | 2011-04-18 | |
| US61/476,575 | 2011-04-18 | ||
| PCT/US2012/033948 WO2012145323A1 (en) | 2011-04-18 | 2012-04-17 | Large crystal, organic-free chabazite, methods of making and using the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103561865A CN103561865A (zh) | 2014-02-05 |
| CN103561865B true CN103561865B (zh) | 2016-09-07 |
Family
ID=47021502
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280025744.8A Expired - Fee Related CN103561865B (zh) | 2011-04-18 | 2012-04-17 | 大晶体、不含有机物的菱沸石以及制造和使用其的方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20120269719A1 (enExample) |
| EP (1) | EP2699345A4 (enExample) |
| JP (1) | JP6169069B2 (enExample) |
| KR (2) | KR101830326B1 (enExample) |
| CN (1) | CN103561865B (enExample) |
| WO (1) | WO2012145323A1 (enExample) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2464478A (en) † | 2008-10-15 | 2010-04-21 | Johnson Matthey Plc | Aluminosilicate zeolite catalyst and use thereof in exhaust gas after-treatment |
| RU2614411C2 (ru) * | 2010-12-02 | 2017-03-28 | Джонсон Мэтти Паблик Лимитед Компани | Цеолитный катализатор, содержащий металл |
| JP5895510B2 (ja) * | 2010-12-22 | 2016-03-30 | 東ソー株式会社 | チャバザイト型ゼオライト及びその製造方法、銅が担持されている低シリカゼオライト、及び、そのゼオライトを含む窒素酸化物還元除去触媒、並びに、その触媒を使用する窒素酸化物還元除去方法 |
| KR101830326B1 (ko) * | 2011-04-18 | 2018-02-20 | 피큐 코포레이션 | 대결정 유기물-비함유 차바자이트, 이의 제조 및 사용 방법 |
| US9527751B2 (en) | 2011-11-11 | 2016-12-27 | Basf Se | Organotemplate-free synthetic process for the production of a zeolitic material of the CHA-type structure |
| CA2855572C (en) * | 2011-11-11 | 2020-04-28 | Basf Se | Organotemplate-free synthetic process for the production of a zeolitic material of the cha-type structure |
| WO2013082550A1 (en) * | 2011-12-02 | 2013-06-06 | Pq Corporation | Stabilized microporous crystalline material, the method of making the same, and the use for selective catalytic reduction of nox |
| DE202013012229U1 (de) | 2013-04-05 | 2015-10-08 | Umicore Ag & Co. Kg | CuCHA Material für die SCR-Katalyse |
| KR102299703B1 (ko) * | 2013-12-02 | 2021-09-09 | 존슨 맛쎄이 퍼블릭 리미티드 컴파니 | 고실리카 Cu-CHA의 혼합 주형 합성 |
| JP5740040B1 (ja) | 2014-07-07 | 2015-06-24 | イビデン株式会社 | ゼオライト、ハニカム触媒及び排ガス浄化装置 |
| JP5732170B1 (ja) * | 2014-07-07 | 2015-06-10 | イビデン株式会社 | ゼオライト、ハニカム触媒及び排ガス浄化装置 |
| US9938157B2 (en) | 2014-07-23 | 2018-04-10 | Chevron U.S.A. Inc. | Interzeolite transformation and metal encapsulation in the absence of an SDA |
| US9802831B2 (en) * | 2014-07-23 | 2017-10-31 | Chevron U.S.A. Inc. | Synthesis of high silica zeolite via interzeolite transformation without OSDAs |
| JP2016073959A (ja) * | 2014-10-09 | 2016-05-12 | イビデン株式会社 | ハニカム触媒 |
| JP6546731B2 (ja) * | 2014-10-09 | 2019-07-17 | イビデン株式会社 | ハニカム触媒 |
| US10173211B2 (en) | 2014-10-14 | 2019-01-08 | California Institute Of Technology | Organic-free synthesis of small pore zeolite catalysts |
| EP3307997B1 (en) * | 2015-06-12 | 2020-03-18 | BASF Corporation | Exhaust gas treatment system |
| JP6879680B2 (ja) * | 2015-06-29 | 2021-06-02 | 日揮触媒化成株式会社 | 高シリカチャバザイト型ゼオライトの製造方法および高シリカチャバザイト型ゼオライト |
| WO2017109705A1 (en) * | 2015-12-22 | 2017-06-29 | Basf Corporation | Process for preparing iron(iii)-exchanged zeolite composition |
| JP6817022B2 (ja) * | 2016-06-07 | 2021-01-20 | 日揮触媒化成株式会社 | 高耐水熱性チャバザイト型ゼオライトおよびその製造方法 |
| CN109311684B (zh) * | 2016-06-07 | 2022-05-06 | 日挥触媒化成株式会社 | 高耐水热性菱沸石型沸石和其制造方法 |
| JP6792264B2 (ja) * | 2016-11-25 | 2020-11-25 | 国立大学法人広島大学 | ガリウムを含有する結晶性アルミノシリケートおよびその製造方法 |
| MY199195A (en) | 2017-02-22 | 2023-10-19 | Tosoh Corp | Chabazite-type zeolite and method of manufacturing chabazite-type zeolite |
| AU2018301347B2 (en) * | 2017-07-11 | 2021-07-15 | Shell Internationale Research Maatschappij B.V. | Catalyst and method of use thereof in the conversion of NOX and N2O |
| US11267717B2 (en) | 2018-03-21 | 2022-03-08 | Basf Corporation | CHA zeolite material and related method of synthesis |
| CN112020478A (zh) * | 2018-05-03 | 2020-12-01 | 沙特基础工业全球技术公司 | 菱沸石(cha)的无sda合成及其用途 |
| KR102833006B1 (ko) * | 2018-09-11 | 2025-07-14 | 바스프 모바일 에미션스 카탈리스츠 엘엘씨 | 골격 유형 aei를 갖는 제올라이트성 물질의 제조 방법 |
| WO2020252447A1 (en) * | 2019-06-13 | 2020-12-17 | Pq Corporation | Chabazite zeolite synthesis with organic templates |
| EP3812034A1 (en) | 2019-10-24 | 2021-04-28 | Dinex A/S | Durable copper-scr catalyst |
| CN111268691A (zh) * | 2020-03-12 | 2020-06-12 | 上海索易分子筛有限公司 | 一种小晶粒菱沸石及其制备方法和应用 |
| EP4015454A1 (en) * | 2020-12-21 | 2022-06-22 | Tosoh Corporation | Cha-type zeolite and manufacturing method thereof |
| DE102022202106A1 (de) | 2022-03-01 | 2023-09-07 | Carl von Ossietzky Universität Oldenburg Körperschaft des öffentlichen Rechts | Katalysator für die Oxidation mit Hydroxylradikalen |
| WO2025164536A1 (ja) * | 2024-01-31 | 2025-08-07 | 日揮触媒化成株式会社 | Fe含有CHAゼオライトおよびその製造方法 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2513983B1 (fr) * | 1981-09-14 | 1986-10-24 | Raffinage Cie Francaise | Procede de preparation de zeolites synthetiques et zeolites obtenues par ce procede |
| US5011667A (en) * | 1988-09-08 | 1991-04-30 | Engelhard Corporation | Self-bound sodium chabazite aggregates and methods for preparation thereof |
| AU1050597A (en) * | 1995-11-15 | 1997-06-05 | California Institute Of Technology | Synthesis of zeolites by hydrothermal reaction of zeolite p1 |
| US6585952B1 (en) * | 2000-05-25 | 2003-07-01 | Board Of Trustees Operating Michigan State University | Ultrastable hexagonal, cubic and wormhole aluminosilicate mesostructures |
| FR2887538B1 (fr) * | 2005-06-28 | 2008-01-04 | Inst Francais Du Petrole | Procede de traitement d'une zeolithe a petits et/ou moyens pores et son utilisation en oligomerisation des olefines legeres |
| BRPI0808091A2 (pt) * | 2007-02-27 | 2014-07-15 | Basf Catalysts Llc | Catalisador, sistema de tratamento de gás de exaustão, processo para a redução de óxidos de nitrogênio, e, artigo de catalisador. |
| US10384162B2 (en) * | 2007-03-26 | 2019-08-20 | Pq Corporation | High silica chabazite for selective catalytic reduction, methods of making and using same |
| EP2689846A1 (en) * | 2007-08-13 | 2014-01-29 | PQ Corporation | Selective catalytic reduction of nitrogen oxides in the presence of iron-containing aluminosilicate zeolites |
| US20090196812A1 (en) * | 2008-01-31 | 2009-08-06 | Basf Catalysts Llc | Catalysts, Systems and Methods Utilizing Non-Zeolitic Metal-Containing Molecular Sieves Having the CHA Crystal Structure |
| US8715618B2 (en) * | 2008-05-21 | 2014-05-06 | Basf Se | Process for the direct synthesis of Cu containing zeolites having CHA structure |
| GB2464478A (en) * | 2008-10-15 | 2010-04-21 | Johnson Matthey Plc | Aluminosilicate zeolite catalyst and use thereof in exhaust gas after-treatment |
| US10583424B2 (en) * | 2008-11-06 | 2020-03-10 | Basf Corporation | Chabazite zeolite catalysts having low silica to alumina ratios |
| JP2011064882A (ja) * | 2009-09-16 | 2011-03-31 | Fuji Xerox Co Ltd | 画像形成装置 |
| CN102574116A (zh) * | 2009-10-14 | 2012-07-11 | 巴斯夫欧洲公司 | 用于选择性还原NOx 的含铜插晶菱沸石分子筛 |
| JP5895510B2 (ja) * | 2010-12-22 | 2016-03-30 | 東ソー株式会社 | チャバザイト型ゼオライト及びその製造方法、銅が担持されている低シリカゼオライト、及び、そのゼオライトを含む窒素酸化物還元除去触媒、並びに、その触媒を使用する窒素酸化物還元除去方法 |
| KR101830326B1 (ko) * | 2011-04-18 | 2018-02-20 | 피큐 코포레이션 | 대결정 유기물-비함유 차바자이트, 이의 제조 및 사용 방법 |
-
2012
- 2012-04-17 KR KR1020137030394A patent/KR101830326B1/ko active Active
- 2012-04-17 KR KR1020187004270A patent/KR101948254B1/ko not_active Expired - Fee Related
- 2012-04-17 CN CN201280025744.8A patent/CN103561865B/zh not_active Expired - Fee Related
- 2012-04-17 EP EP12773612.2A patent/EP2699345A4/en not_active Withdrawn
- 2012-04-17 JP JP2014506486A patent/JP6169069B2/ja active Active
- 2012-04-17 WO PCT/US2012/033948 patent/WO2012145323A1/en not_active Ceased
- 2012-04-17 US US13/449,230 patent/US20120269719A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| KR101830326B1 (ko) | 2018-02-20 |
| WO2012145323A1 (en) | 2012-10-26 |
| KR101948254B1 (ko) | 2019-02-14 |
| EP2699345A1 (en) | 2014-02-26 |
| KR20180021204A (ko) | 2018-02-28 |
| US20120269719A1 (en) | 2012-10-25 |
| EP2699345A4 (en) | 2015-05-06 |
| JP6169069B2 (ja) | 2017-07-26 |
| JP2014515723A (ja) | 2014-07-03 |
| KR20140027280A (ko) | 2014-03-06 |
| CN103561865A (zh) | 2014-02-05 |
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