CN103561865B - 大晶体、不含有机物的菱沸石以及制造和使用其的方法 - Google Patents

大晶体、不含有机物的菱沸石以及制造和使用其的方法 Download PDF

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Publication number
CN103561865B
CN103561865B CN201280025744.8A CN201280025744A CN103561865B CN 103561865 B CN103561865 B CN 103561865B CN 201280025744 A CN201280025744 A CN 201280025744A CN 103561865 B CN103561865 B CN 103561865B
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chabazite
zeolite
iron
potassium
sar
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Chinese (zh)
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CN103561865A (zh
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黎鸿昕
W·E·科米尔
B·莫登
D·库珀
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Ekovist Catalyst Technology Co ltd
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PQ Corp
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/072—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7015—CHA-type, e.g. Chabazite, LZ-218
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B01J29/763—CHA-type, e.g. Chabazite, LZ-218
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    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
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  • Crystallography & Structural Chemistry (AREA)
  • Geology (AREA)
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  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
CN201280025744.8A 2011-04-18 2012-04-17 大晶体、不含有机物的菱沸石以及制造和使用其的方法 Expired - Fee Related CN103561865B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161476575P 2011-04-18 2011-04-18
US61/476,575 2011-04-18
PCT/US2012/033948 WO2012145323A1 (en) 2011-04-18 2012-04-17 Large crystal, organic-free chabazite, methods of making and using the same

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CN103561865A CN103561865A (zh) 2014-02-05
CN103561865B true CN103561865B (zh) 2016-09-07

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US (1) US20120269719A1 (enExample)
EP (1) EP2699345A4 (enExample)
JP (1) JP6169069B2 (enExample)
KR (2) KR101830326B1 (enExample)
CN (1) CN103561865B (enExample)
WO (1) WO2012145323A1 (enExample)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2464478A (en) † 2008-10-15 2010-04-21 Johnson Matthey Plc Aluminosilicate zeolite catalyst and use thereof in exhaust gas after-treatment
EP2646149B1 (en) * 2010-12-02 2020-03-25 Johnson Matthey Public Limited Company Zeolite catalyst containing metal
JP5895510B2 (ja) * 2010-12-22 2016-03-30 東ソー株式会社 チャバザイト型ゼオライト及びその製造方法、銅が担持されている低シリカゼオライト、及び、そのゼオライトを含む窒素酸化物還元除去触媒、並びに、その触媒を使用する窒素酸化物還元除去方法
WO2012145323A1 (en) * 2011-04-18 2012-10-26 Pq Corporation Large crystal, organic-free chabazite, methods of making and using the same
CN104039704B (zh) * 2011-11-11 2017-10-24 巴斯夫欧洲公司 用于制备cha型结构的沸石材料的无有机模板合成法
US9527751B2 (en) 2011-11-11 2016-12-27 Basf Se Organotemplate-free synthetic process for the production of a zeolitic material of the CHA-type structure
BR112014012818A2 (pt) * 2011-12-02 2017-06-13 Pq Corp material cristalino microporoso estabilizado, o processo de fabricaçãodo mesmo, e o uso para redução catalítica seletiva de nox
DE202013012229U1 (de) 2013-04-05 2015-11-19 Umicore Ag & Co. Kg CuCHA Material für die SCR-Katalyse
US11207666B2 (en) 2013-12-02 2021-12-28 Johnson Matthey Public Limited Company Mixed template synthesis of high silica Cu-CHA
JP5740040B1 (ja) * 2014-07-07 2015-06-24 イビデン株式会社 ゼオライト、ハニカム触媒及び排ガス浄化装置
JP5732170B1 (ja) * 2014-07-07 2015-06-10 イビデン株式会社 ゼオライト、ハニカム触媒及び排ガス浄化装置
US9802831B2 (en) * 2014-07-23 2017-10-31 Chevron U.S.A. Inc. Synthesis of high silica zeolite via interzeolite transformation without OSDAs
US9938157B2 (en) 2014-07-23 2018-04-10 Chevron U.S.A. Inc. Interzeolite transformation and metal encapsulation in the absence of an SDA
JP2016073959A (ja) * 2014-10-09 2016-05-12 イビデン株式会社 ハニカム触媒
JP6546731B2 (ja) * 2014-10-09 2019-07-17 イビデン株式会社 ハニカム触媒
US10173211B2 (en) 2014-10-14 2019-01-08 California Institute Of Technology Organic-free synthesis of small pore zeolite catalysts
WO2016201295A1 (en) * 2015-06-12 2016-12-15 Basf Corporation Exhaust gas treatment system
JP6879680B2 (ja) * 2015-06-29 2021-06-02 日揮触媒化成株式会社 高シリカチャバザイト型ゼオライトの製造方法および高シリカチャバザイト型ゼオライト
WO2017109705A1 (en) * 2015-12-22 2017-06-29 Basf Corporation Process for preparing iron(iii)-exchanged zeolite composition
JP6817022B2 (ja) 2016-06-07 2021-01-20 日揮触媒化成株式会社 高耐水熱性チャバザイト型ゼオライトおよびその製造方法
WO2017213022A1 (ja) * 2016-06-07 2017-12-14 日揮触媒化成株式会社 高耐水熱性チャバザイト型ゼオライトおよびその製造方法
JP6792264B2 (ja) * 2016-11-25 2020-11-25 国立大学法人広島大学 ガリウムを含有する結晶性アルミノシリケートおよびその製造方法
MY199195A (en) 2017-02-22 2023-10-19 Tosoh Corp Chabazite-type zeolite and method of manufacturing chabazite-type zeolite
RU2020102860A (ru) * 2017-07-11 2021-08-11 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Катализатор и способ его применения для конверсии nox и n2o
EP3768638A4 (en) 2018-03-21 2021-12-29 BASF Corporation Cha zeolite material and related method of synthesis
US11247911B2 (en) * 2018-05-03 2022-02-15 Sabic Global Technologies B.V. SDA-free synthesis of chabazite (CHA) zeolite and uses thereof
CN113039157A (zh) * 2018-09-11 2021-06-25 巴斯夫公司 制备具有骨架类型aei的沸石材料的方法
US11027983B2 (en) * 2019-06-13 2021-06-08 Pq Corporation Chabazite zeolite synthesis with organic templates
EP3812034A1 (en) 2019-10-24 2021-04-28 Dinex A/S Durable copper-scr catalyst
CN111268691A (zh) * 2020-03-12 2020-06-12 上海索易分子筛有限公司 一种小晶粒菱沸石及其制备方法和应用
EP4015454A1 (en) * 2020-12-21 2022-06-22 Tosoh Corporation Cha-type zeolite and manufacturing method thereof
DE102022202106A1 (de) 2022-03-01 2023-09-07 Carl von Ossietzky Universität Oldenburg Körperschaft des öffentlichen Rechts Katalysator für die Oxidation mit Hydroxylradikalen
CN119907712A (zh) * 2022-08-26 2025-04-29 巴斯夫移动排放催化剂有限公司 Cu沸石选择性催化还原催化剂和用于废气处理的方法
US12655029B2 (en) * 2023-01-10 2026-06-16 Saudi Arabian Oil Company Method for manufacture of crystalline material having a CHA framework in the presence of ODSO
WO2025164536A1 (ja) * 2024-01-31 2025-08-07 日揮触媒化成株式会社 Fe含有CHAゼオライトおよびその製造方法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2513983B1 (fr) * 1981-09-14 1986-10-24 Raffinage Cie Francaise Procede de preparation de zeolites synthetiques et zeolites obtenues par ce procede
US5011667A (en) * 1988-09-08 1991-04-30 Engelhard Corporation Self-bound sodium chabazite aggregates and methods for preparation thereof
US5935551A (en) * 1995-11-15 1999-08-10 California Institute Of Technology Synthesis of zeolites by hydrothermal reaction of zeolite P1
US6585952B1 (en) * 2000-05-25 2003-07-01 Board Of Trustees Operating Michigan State University Ultrastable hexagonal, cubic and wormhole aluminosilicate mesostructures
FR2887538B1 (fr) * 2005-06-28 2008-01-04 Inst Francais Du Petrole Procede de traitement d'une zeolithe a petits et/ou moyens pores et son utilisation en oligomerisation des olefines legeres
AR065501A1 (es) * 2007-02-27 2009-06-10 Basf Catalysts Llc Catalizadores de zeolita cha de cobre
US10384162B2 (en) * 2007-03-26 2019-08-20 Pq Corporation High silica chabazite for selective catalytic reduction, methods of making and using same
JP6176891B2 (ja) * 2007-08-13 2017-08-09 ピーキュー コーポレイション 新規鉄含有アルミノケイ酸塩ゼオライト、ならびにその作製方法および使用方法
US20090196812A1 (en) * 2008-01-31 2009-08-06 Basf Catalysts Llc Catalysts, Systems and Methods Utilizing Non-Zeolitic Metal-Containing Molecular Sieves Having the CHA Crystal Structure
EP3778484A1 (en) * 2008-05-21 2021-02-17 Basf Se Process for the direct synthesis of cu containing zeolites having cha structure
GB2464478A (en) * 2008-10-15 2010-04-21 Johnson Matthey Plc Aluminosilicate zeolite catalyst and use thereof in exhaust gas after-treatment
US10583424B2 (en) * 2008-11-06 2020-03-10 Basf Corporation Chabazite zeolite catalysts having low silica to alumina ratios
JP2011064882A (ja) * 2009-09-16 2011-03-31 Fuji Xerox Co Ltd 画像形成装置
WO2011045252A1 (en) * 2009-10-14 2011-04-21 Basf Se Copper containing levyne molecular sieve for selective reduction of nox
JP5895510B2 (ja) * 2010-12-22 2016-03-30 東ソー株式会社 チャバザイト型ゼオライト及びその製造方法、銅が担持されている低シリカゼオライト、及び、そのゼオライトを含む窒素酸化物還元除去触媒、並びに、その触媒を使用する窒素酸化物還元除去方法
WO2012145323A1 (en) * 2011-04-18 2012-10-26 Pq Corporation Large crystal, organic-free chabazite, methods of making and using the same

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WO2012145323A1 (en) 2012-10-26
KR101830326B1 (ko) 2018-02-20
JP2014515723A (ja) 2014-07-03
EP2699345A4 (en) 2015-05-06
JP6169069B2 (ja) 2017-07-26
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