KR101852143B1 - ＮＯｘ 환원을 위한 신규한 금속―함유 제올라이트 베타 - Google Patents

ＮＯｘ 환원을 위한 신규한 금속―함유 제올라이트 베타 Download PDF

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KR101852143B1
KR101852143B1 KR1020127033505A KR20127033505A KR101852143B1 KR 101852143 B1 KR101852143 B1 KR 101852143B1 KR 1020127033505 A KR1020127033505 A KR 1020127033505A KR 20127033505 A KR20127033505 A KR 20127033505A KR 101852143 B1 KR101852143 B1 KR 101852143B1
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zeolite beta
metal
beta
free
iron
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KR20130109980A (ko
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홍-신 리
윌리엄 이. 코미어
비외른 모던
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피큐 코포레이션
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B01J29/7615—Zeolite Beta
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2062—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20738—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20761—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/50—Zeolites
    • B01D2255/502—Beta zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Geology (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Exhaust Gas After Treatment (AREA)
KR1020127033505A 2010-05-21 2011-05-18 ＮＯｘ 환원을 위한 신규한 금속―함유 제올라이트 베타 Active KR101852143B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US34721010P 2010-05-21 2010-05-21
US61/347,210 2010-05-21
PCT/US2011/036997 WO2011146615A2 (en) 2010-05-21 2011-05-18 Novel metal-containing zeolite beta for nox reduction and methods of making the same

Publications (2)

Publication Number Publication Date
KR20130109980A KR20130109980A (ko) 2013-10-08
KR101852143B1 true KR101852143B1 (ko) 2018-04-25

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KR1020127033505A Active KR101852143B1 (ko) 2010-05-21 2011-05-18 ＮＯｘ 환원을 위한 신규한 금속―함유 제올라이트 베타

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US (2) US20110286914A1 (enExample)
EP (2) EP2742991A1 (enExample)
JP (3) JP5797749B2 (enExample)
KR (1) KR101852143B1 (enExample)
CN (2) CN102971065B (enExample)
BR (1) BR112012029648B1 (enExample)
CA (1) CA2800393C (enExample)
DK (1) DK2571604T3 (enExample)
ES (1) ES2465617T3 (enExample)
MX (1) MX343465B (enExample)
PL (1) PL2571604T3 (enExample)
RU (1) RU2641771C1 (enExample)
WO (1) WO2011146615A2 (enExample)
ZA (2) ZA201209485B (enExample)

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JP5351216B2 (ja) 2010-07-01 2013-11-27 日本化学工業株式会社 ゼオライトの製造方法
JP5116880B2 (ja) * 2011-01-18 2013-01-09 日本化学工業株式会社 Ｆｅ（ＩＩ）置換ベータ型ゼオライト、それを含むガス吸着剤及びその製造方法、並びに一酸化窒素及びハイドロカーボンの除去方法
CN108249454A (zh) * 2011-12-02 2018-07-06 Pq公司 稳定化的微孔结晶材料、其制备方法以及选择性催化还原NOx的用途
CN104203823A (zh) * 2012-02-06 2014-12-10 巴斯夫欧洲公司 获自无有机模板合成法的含铁和铜的沸石β及其在选择性催化还原NOx中的用途
EP3744427A1 (en) * 2012-02-06 2020-12-02 Basf Se Process and apparatus for the treatment of gas streams containing nitrogen oxides
JP2015510484A (ja) * 2012-02-06 2015-04-09 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 有機鋳型を用いない合成からの鉄及び銅含有ゼオライトベータ、及びそのＮＯｘの選択的触媒還元における使用方法
JP6034224B2 (ja) * 2012-04-10 2016-11-30 ユニゼオ株式会社 ベータ型ゼオライト及びその製造方法
JP5988743B2 (ja) * 2012-07-18 2016-09-07 ユニゼオ株式会社 Ｆｅ（ＩＩ）置換ベータ型ゼオライト、それを含むガス吸着剤及びその製造方法、並びに一酸化窒素及びハイドロカーボンの除去方法
JP6058433B2 (ja) * 2013-03-12 2017-01-11 ユニゼオ株式会社 ハイドロカーボンリフォーマトラップ材及びハイドロカーボンの除去方法
JP6153196B2 (ja) * 2013-06-14 2017-06-28 ユニゼオ株式会社 Ｍｎ＋置換ベータ型ゼオライト、それを含むガス吸着剤及びその製造方法、並びに一酸化窒素の除去方法
WO2015001095A1 (en) 2013-07-05 2015-01-08 Friedrich-Alexander-Universität Erlangen-Nürnberg Process for the preparation of organo-template free supported zeolite layers
CN103691481B (zh) * 2013-12-23 2016-04-13 中国科学院上海硅酸盐研究所 一种负载型多级孔Beta分子筛催化剂及其制备方法和应用
JP6509877B2 (ja) * 2014-01-03 2019-05-08 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 有機テンプレートを使用しない合成による二金属交換ゼオライトベータ、およびＮＯｘの選択触媒還元においてそれを使用する方法
US20150231620A1 (en) * 2014-02-19 2015-08-20 Ford Global Technologies, Llc IRON-ZEOLITE CHABAZITE CATALYST FOR USE IN NOx REDUCTION AND METHOD OF MAKING
US20150290632A1 (en) * 2014-04-09 2015-10-15 Ford Global Technologies, Llc IRON AND COPPER-CONTAINING CHABAZITE ZEOLITE CATALYST FOR USE IN NOx REDUCTION
CZ2014448A3 (cs) * 2014-06-27 2016-04-13 Ústav fyzikální chemie J. Heyrovského AV ČR, v. v. i. Katalyzátor pro selektivní katalytickou redukci oxidů dusíku, způsob jeho výroby a použití
CN106660025B (zh) 2014-07-07 2020-05-19 国际壳牌研究有限公司 异构化催化剂
WO2017062323A1 (en) 2015-10-06 2017-04-13 Shell Oil Company A process for making cumene by alkylation of benzene using an organotemplate-free zeolite beta
CN107029781B (zh) * 2016-02-04 2019-08-09 中触媒新材料股份有限公司 铁和铈改性β分子筛选择性还原催化剂及制备方法与应用
GB201608643D0 (en) * 2016-05-17 2016-06-29 Thermo Fisher Scient Bremen Elemental analysis system and method
JP7164591B2 (ja) * 2017-07-11 2022-11-01 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー Ｎｏｘおよびｎ２０の変換における触媒およびその使用方法
KR102578657B1 (ko) 2017-07-11 2023-09-15 쉘 인터내셔날 리써취 마트샤피지 비.브이. 촉매 및 이의 사용 방법
KR102397255B1 (ko) * 2017-10-25 2022-05-12 미쓰이금속광업주식회사 금속 치환 베타형 제올라이트 및 그의 제조 방법
US20230173455A1 (en) * 2017-12-29 2023-06-08 Korea University Research And Business Foundation Hydrocarbon adsorbent
KR102085652B1 (ko) * 2017-12-29 2020-03-06 현대자동차 주식회사 규칙적인 메조 기공을 가진 제오라이트 입자에 금속이 함침된 탄화수소 흡착제 및 그 제조방법
JP2018108927A (ja) * 2018-01-29 2018-07-12 出光興産株式会社 金属担持ゼオライト成型体、金属担持ゼオライト成型体の製造方法、硫黄化合物除去用吸着剤、水素の製造方法、及び燃料電池システム
US10669908B1 (en) 2018-12-03 2020-06-02 Wellhead Power Solutions, Llc Power generating systems and methods for reducing startup NOx emissions in fossile fueled power generation system
WO2023190385A1 (ja) 2022-03-29 2023-10-05 三菱重工業株式会社 Ｎ２ｏ分解触媒
DE102023002844A1 (de) 2023-07-13 2025-01-16 Hans-Jürgen Eberle Katalysator zur Reduktion und/oder Zersetzung von Lachgas

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CN105312081A (zh) 2016-02-10
BR112012029648B1 (pt) 2020-12-22
RU2641771C1 (ru) 2018-01-22
ZA201209485B (en) 2014-02-26
US20190054420A1 (en) 2019-02-21
CA2800393C (en) 2016-08-02
CN102971065B (zh) 2015-11-25
JP5797749B2 (ja) 2015-10-21
JP6397064B2 (ja) 2018-09-26
JP2017109924A (ja) 2017-06-22
DK2571604T3 (da) 2014-05-12
ZA201309393B (en) 2014-08-27
ES2465617T3 (es) 2014-06-06
US20110286914A1 (en) 2011-11-24
EP2571604A2 (en) 2013-03-27
WO2011146615A2 (en) 2011-11-24
JP2015205277A (ja) 2015-11-19
CN102971065A (zh) 2013-03-13
WO2011146615A3 (en) 2012-04-26
PL2571604T3 (pl) 2014-09-30
BR112012029648A2 (pt) 2016-08-02
EP2742991A1 (en) 2014-06-18
RU2012155698A (ru) 2014-06-27
MX2012013535A (es) 2013-04-03
CN105312081B (zh) 2020-09-15
EP2571604B1 (en) 2014-04-16
CA2800393A1 (en) 2011-11-24
JP2013526406A (ja) 2013-06-24
US11786864B2 (en) 2023-10-17
KR20130109980A (ko) 2013-10-08
MX343465B (es) 2016-11-07
JP6231525B2 (ja) 2017-11-15

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