JP2013525088A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2013525088A5 JP2013525088A5 JP2013501536A JP2013501536A JP2013525088A5 JP 2013525088 A5 JP2013525088 A5 JP 2013525088A5 JP 2013501536 A JP2013501536 A JP 2013501536A JP 2013501536 A JP2013501536 A JP 2013501536A JP 2013525088 A5 JP2013525088 A5 JP 2013525088A5
- Authority
- JP
- Japan
- Prior art keywords
- reaction
- electrode
- catalytically active
- rhe
- substance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000006243 chemical reaction Methods 0.000 claims description 35
- 239000003054 catalyst Substances 0.000 claims description 24
- 239000007795 chemical reaction product Substances 0.000 claims description 20
- 239000003792 electrolyte Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 239000000376 reactant Substances 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 229910052718 tin Inorganic materials 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 229910052737 gold Inorganic materials 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052763 palladium Inorganic materials 0.000 claims description 6
- 229910052697 platinum Inorganic materials 0.000 claims description 6
- 229910052707 ruthenium Inorganic materials 0.000 claims description 6
- 229910052709 silver Inorganic materials 0.000 claims description 6
- 229910052797 bismuth Inorganic materials 0.000 claims description 5
- 229910052793 cadmium Inorganic materials 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 229910052738 indium Inorganic materials 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 229910052745 lead Inorganic materials 0.000 claims description 5
- 239000003446 ligand Substances 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 150000002892 organic cations Chemical class 0.000 claims description 5
- 125000005496 phosphonium group Chemical group 0.000 claims description 5
- 229910052703 rhodium Inorganic materials 0.000 claims description 5
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium group Chemical group [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 claims description 5
- 229910052721 tungsten Inorganic materials 0.000 claims description 5
- 229910052726 zirconium Inorganic materials 0.000 claims description 5
- 229910052684 Cerium Inorganic materials 0.000 claims description 4
- 229910052779 Neodymium Inorganic materials 0.000 claims description 4
- 229910052772 Samarium Inorganic materials 0.000 claims description 4
- 229910052771 Terbium Inorganic materials 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 229910052787 antimony Inorganic materials 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 229910052735 hafnium Inorganic materials 0.000 claims description 4
- 229910052741 iridium Inorganic materials 0.000 claims description 4
- 229910052746 lanthanum Inorganic materials 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 229910052753 mercury Inorganic materials 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 229910052758 niobium Inorganic materials 0.000 claims description 4
- 229910052702 rhenium Inorganic materials 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 229910052715 tantalum Inorganic materials 0.000 claims description 4
- 229910052716 thallium Inorganic materials 0.000 claims description 4
- 229910052720 vanadium Inorganic materials 0.000 claims description 4
- -1 1-ethyl-3-methylimidazolium cations Chemical class 0.000 claims description 3
- OEYIOHPDSNJKLS-UHFFFAOYSA-N choline Chemical compound C[N+](C)(C)CCO OEYIOHPDSNJKLS-UHFFFAOYSA-N 0.000 claims description 3
- 229960001231 choline Drugs 0.000 claims description 3
- 150000002891 organic anions Chemical class 0.000 claims description 3
- 150000003003 phosphines Chemical class 0.000 claims description 3
- 239000001763 2-hydroxyethyl(trimethyl)azanium Substances 0.000 claims description 2
- JJCWKVUUIFLXNZ-UHFFFAOYSA-M 2-hydroxyethyl(trimethyl)azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCO JJCWKVUUIFLXNZ-UHFFFAOYSA-M 0.000 claims description 2
- FNPBHXSBDADRBT-UHFFFAOYSA-M 2-hydroxyethyl(trimethyl)azanium;iodide Chemical compound [I-].C[N+](C)(C)CCO FNPBHXSBDADRBT-UHFFFAOYSA-M 0.000 claims description 2
- 235000019743 Choline chloride Nutrition 0.000 claims description 2
- 229960003178 choline chloride Drugs 0.000 claims description 2
- SGMZJAMFUVOLNK-UHFFFAOYSA-M choline chloride Chemical compound [Cl-].C[N+](C)(C)CCO SGMZJAMFUVOLNK-UHFFFAOYSA-M 0.000 claims description 2
- 239000000446 fuel Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 235000008979 vitamin B4 Nutrition 0.000 claims description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 19
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 19
- WHBHBVVOGNECLV-OBQKJFGGSA-N 11-deoxycortisol Chemical compound O=C1CC[C@]2(C)[C@H]3CC[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 WHBHBVVOGNECLV-OBQKJFGGSA-N 0.000 claims 10
- 239000000203 mixture Substances 0.000 claims 10
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 claims 5
- 239000003426 co-catalyst Substances 0.000 claims 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 4
- 238000002484 cyclic voltammetry Methods 0.000 claims 4
- 125000003118 aryl group Chemical group 0.000 claims 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 3
- 125000004433 nitrogen atom Chemical group N* 0.000 claims 3
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 claims 3
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 2
- 239000001569 carbon dioxide Substances 0.000 claims 2
- 229910052757 nitrogen Inorganic materials 0.000 claims 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N phosphine group Chemical group P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims 2
- 230000002441 reversible effect Effects 0.000 claims 2
- 239000000126 substance Substances 0.000 claims 2
- 229910052789 astatine Inorganic materials 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- 150000001767 cationic compounds Chemical class 0.000 claims 1
- 238000002848 electrochemical method Methods 0.000 claims 1
- 229910001411 inorganic cation Inorganic materials 0.000 claims 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 5
- 239000010931 gold Substances 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical group COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000002608 ionic liquid Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US31795510P | 2010-03-26 | 2010-03-26 | |
| US61/317,955 | 2010-03-26 | ||
| US12/830,338 | 2010-07-04 | ||
| US12/830,338 US20110237830A1 (en) | 2010-03-26 | 2010-07-04 | Novel catalyst mixtures |
| PCT/US2011/030098 WO2011120021A1 (en) | 2010-03-26 | 2011-03-25 | Novel catalyst mixtures |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015232576A Division JP6254565B2 (ja) | 2010-03-26 | 2015-11-30 | 二酸化炭素を電気化学的に転換するための新規触媒混合物及び電気化学的装置 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2013525088A JP2013525088A (ja) | 2013-06-20 |
| JP2013525088A5 true JP2013525088A5 (https=) | 2014-08-21 |
Family
ID=44657192
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013501536A Withdrawn JP2013525088A (ja) | 2010-03-26 | 2011-03-25 | 新規触媒混合物 |
| JP2015232576A Active JP6254565B2 (ja) | 2010-03-26 | 2015-11-30 | 二酸化炭素を電気化学的に転換するための新規触媒混合物及び電気化学的装置 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015232576A Active JP6254565B2 (ja) | 2010-03-26 | 2015-11-30 | 二酸化炭素を電気化学的に転換するための新規触媒混合物及び電気化学的装置 |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US20110237830A1 (https=) |
| EP (1) | EP2553147B1 (https=) |
| JP (2) | JP2013525088A (https=) |
| KR (1) | KR101721287B1 (https=) |
| CN (1) | CN102892929B (https=) |
| AU (1) | AU2011230545C1 (https=) |
| CA (1) | CA2794105C (https=) |
| WO (1) | WO2011120021A1 (https=) |
Families Citing this family (69)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8313634B2 (en) | 2009-01-29 | 2012-11-20 | Princeton University | Conversion of carbon dioxide to organic products |
| US8721866B2 (en) | 2010-03-19 | 2014-05-13 | Liquid Light, Inc. | Electrochemical production of synthesis gas from carbon dioxide |
| US8500987B2 (en) | 2010-03-19 | 2013-08-06 | Liquid Light, Inc. | Purification of carbon dioxide from a mixture of gases |
| US8845877B2 (en) | 2010-03-19 | 2014-09-30 | Liquid Light, Inc. | Heterocycle catalyzed electrochemical process |
| US20110237830A1 (en) | 2010-03-26 | 2011-09-29 | Dioxide Materials Inc | Novel catalyst mixtures |
| US9193593B2 (en) | 2010-03-26 | 2015-11-24 | Dioxide Materials, Inc. | Hydrogenation of formic acid to formaldehyde |
| US8956990B2 (en) | 2010-03-26 | 2015-02-17 | Dioxide Materials, Inc. | Catalyst mixtures |
| US10173169B2 (en) | 2010-03-26 | 2019-01-08 | Dioxide Materials, Inc | Devices for electrocatalytic conversion of carbon dioxide |
| US9012345B2 (en) | 2010-03-26 | 2015-04-21 | Dioxide Materials, Inc. | Electrocatalysts for carbon dioxide conversion |
| US9815021B2 (en) | 2010-03-26 | 2017-11-14 | Dioxide Materials, Inc. | Electrocatalytic process for carbon dioxide conversion |
| US9566574B2 (en) * | 2010-07-04 | 2017-02-14 | Dioxide Materials, Inc. | Catalyst mixtures |
| US9945040B2 (en) * | 2010-07-04 | 2018-04-17 | Dioxide Materials, Inc. | Catalyst layers and electrolyzers |
| US9790161B2 (en) | 2010-03-26 | 2017-10-17 | Dioxide Materials, Inc | Process for the sustainable production of acrylic acid |
| US9957624B2 (en) * | 2010-03-26 | 2018-05-01 | Dioxide Materials, Inc. | Electrochemical devices comprising novel catalyst mixtures |
| US9849450B2 (en) | 2010-07-04 | 2017-12-26 | Dioxide Materials, Inc. | Ion-conducting membranes |
| US10047446B2 (en) | 2010-07-04 | 2018-08-14 | Dioxide Materials, Inc. | Method and system for electrochemical production of formic acid from carbon dioxide |
| US8524066B2 (en) | 2010-07-29 | 2013-09-03 | Liquid Light, Inc. | Electrochemical production of urea from NOx and carbon dioxide |
| US8845878B2 (en) | 2010-07-29 | 2014-09-30 | Liquid Light, Inc. | Reducing carbon dioxide to products |
| US8568581B2 (en) | 2010-11-30 | 2013-10-29 | Liquid Light, Inc. | Heterocycle catalyzed carbonylation and hydroformylation with carbon dioxide |
| US8961774B2 (en) | 2010-11-30 | 2015-02-24 | Liquid Light, Inc. | Electrochemical production of butanol from carbon dioxide and water |
| US9090976B2 (en) | 2010-12-30 | 2015-07-28 | The Trustees Of Princeton University | Advanced aromatic amine heterocyclic catalysts for carbon dioxide reduction |
| US8562811B2 (en) | 2011-03-09 | 2013-10-22 | Liquid Light, Inc. | Process for making formic acid |
| WO2013006710A2 (en) | 2011-07-06 | 2013-01-10 | Liquid Light, Inc. | Carbon dioxide capture and conversion to organic products |
| EP2729601B1 (en) | 2011-07-06 | 2018-05-09 | Avantium Knowledge Centre B.V. | Reduction of carbon dioxide to oxalic acid, and hydrogenation thereof |
| CN103987442A (zh) * | 2011-12-15 | 2014-08-13 | 松下电器产业株式会社 | 二氧化碳透过装置和输送二氧化碳的方法 |
| WO2013134418A1 (en) * | 2012-03-06 | 2013-09-12 | Liquid Light, Inc. | Reducing carbon dioxide to products |
| US9943841B2 (en) | 2012-04-12 | 2018-04-17 | Dioxide Materials, Inc. | Method of making an anion exchange membrane |
| US9982353B2 (en) * | 2012-04-12 | 2018-05-29 | Dioxide Materials, Inc. | Water electrolyzers |
| US10329676B2 (en) | 2012-07-26 | 2019-06-25 | Avantium Knowledge Centre B.V. | Method and system for electrochemical reduction of carbon dioxide employing a gas diffusion electrode |
| US8641885B2 (en) | 2012-07-26 | 2014-02-04 | Liquid Light, Inc. | Multiphase electrochemical reduction of CO2 |
| US8821709B2 (en) | 2012-07-26 | 2014-09-02 | Liquid Light, Inc. | System and method for oxidizing organic compounds while reducing carbon dioxide |
| US9267212B2 (en) | 2012-07-26 | 2016-02-23 | Liquid Light, Inc. | Method and system for production of oxalic acid and oxalic acid reduction products |
| US9175407B2 (en) | 2012-07-26 | 2015-11-03 | Liquid Light, Inc. | Integrated process for producing carboxylic acids from carbon dioxide |
| US8858777B2 (en) | 2012-07-26 | 2014-10-14 | Liquid Light, Inc. | Process and high surface area electrodes for the electrochemical reduction of carbon dioxide |
| US9873951B2 (en) | 2012-09-14 | 2018-01-23 | Avantium Knowledge Centre B.V. | High pressure electrochemical cell and process for the electrochemical reduction of carbon dioxide |
| CN104822861B (zh) | 2012-09-24 | 2017-03-08 | 二氧化碳材料公司 | 用于将二氧化碳转化为有用燃料和化学品的装置和方法 |
| US10647652B2 (en) | 2013-02-24 | 2020-05-12 | Dioxide Materials, Inc. | Process for the sustainable production of acrylic acid |
| WO2014192891A1 (ja) * | 2013-05-29 | 2014-12-04 | 株式会社 東芝 | 還元触媒および化学反応装置 |
| EP3680365A1 (en) * | 2014-06-19 | 2020-07-15 | Avantium Knowledge Centre B.V. | Integrated method for producing oxalic acid and co-products |
| US10774431B2 (en) | 2014-10-21 | 2020-09-15 | Dioxide Materials, Inc. | Ion-conducting membranes |
| US10724142B2 (en) | 2014-10-21 | 2020-07-28 | Dioxide Materials, Inc. | Water electrolyzers employing anion exchange membranes |
| US10975480B2 (en) | 2015-02-03 | 2021-04-13 | Dioxide Materials, Inc. | Electrocatalytic process for carbon dioxide conversion |
| US10280378B2 (en) * | 2015-05-05 | 2019-05-07 | Dioxide Materials, Inc | System and process for the production of renewable fuels and chemicals |
| CN106876722B (zh) * | 2015-12-13 | 2019-07-26 | 中国科学院大连化学物理研究所 | 一种二氧化碳电化学还原用气体扩散电极及其制备和应用 |
| KR102277793B1 (ko) * | 2016-04-04 | 2021-07-15 | 디옥시드 머티리얼즈, 인크. | 수 전해장치 |
| EP3440239B1 (en) * | 2016-04-04 | 2020-11-18 | Dioxide Materials, Inc. | Ion-conducting membranes |
| WO2017176600A1 (en) | 2016-04-04 | 2017-10-12 | Dioxide Materials, Inc. | Electrocatalytic process for carbon dioxide conversion |
| EP3440238B1 (en) * | 2016-04-04 | 2021-10-27 | Dioxide Materials, Inc. | Electrolyzers having catalyst layers |
| JP6784776B2 (ja) | 2016-05-03 | 2020-11-11 | オーパス １２ インコーポレイテッドＯｐｕｓ １２ Ｉｎｃｏｒｐｏｒａｔｅｄ | Ｃｏ２、ｃｏおよび他の化学化合物の電気化学反応のための先進的構造を有するリアクタ |
| US12359325B2 (en) | 2016-05-03 | 2025-07-15 | Twelve Benefit Corporation | Membrane electrode assembly for COx reduction |
| KR20190043156A (ko) * | 2016-08-29 | 2019-04-25 | 디옥시드 머티리얼즈, 인크. | 재생가능한 연료 및 화학물질의 생산을 위한 시스템 및 방법 |
| DE102016217730A1 (de) | 2016-09-16 | 2018-03-22 | Siemens Aktiengesellschaft | CO2-Elektrolyseverfahren |
| WO2018067632A1 (en) * | 2016-10-04 | 2018-04-12 | Johna Leddy | Carbon dioxide reduction and carbon compound electrochemistry in the presence of lanthanides |
| JP6649293B2 (ja) | 2017-01-25 | 2020-02-19 | 株式会社東芝 | 還元触媒、ならびにそれを用いた化学反応装置、還元方法、および還元物生産システム |
| US10147974B2 (en) | 2017-05-01 | 2018-12-04 | Dioxide Materials, Inc | Battery separator membrane and battery employing same |
| US10396329B2 (en) | 2017-05-01 | 2019-08-27 | Dioxide Materials, Inc. | Battery separator membrane and battery employing same |
| DE102017211930A1 (de) * | 2017-07-12 | 2019-01-17 | Siemens Aktiengesellschaft | Membran gekoppelte Kathode zur Reduktion von Kohlendioxid in säurebasierten Elektrolyten ohne mobile Kationen |
| CN108855231A (zh) * | 2018-06-29 | 2018-11-23 | 枣庄学院 | 一种用于电化学应用的催化剂 |
| BR112021010368A2 (pt) | 2018-11-28 | 2021-08-24 | Opus 12 Incorporated | Eletrolisador e método de uso |
| WO2020146402A1 (en) | 2019-01-07 | 2020-07-16 | Opus 12 Inc. | System and method for methane production |
| CN110038636B (zh) * | 2019-04-11 | 2021-11-30 | 浙江工商大学 | 一种AgI/Ag-Ce-2MI复合光催化剂及其制备和应用 |
| EP4065753A1 (en) | 2019-11-25 | 2022-10-05 | Twelve Benefit Corporation | Membrane electrode assembly for co x reduction |
| JP7700110B2 (ja) | 2020-05-14 | 2025-06-30 | 日東電工株式会社 | 二酸化炭素捕捉処理システム及びｃｏ２ネガティブエミッション工場 |
| CN116235326A (zh) * | 2020-05-19 | 2023-06-06 | 新泽西州立拉特格斯大学 | 用于直接电化学co2还原成烃的路易斯/布朗斯台德酸/碱和磷化镍二元催化剂体系(助催化剂) |
| CN116096477A (zh) * | 2020-07-14 | 2023-05-09 | 伊利诺伊大学评议会 | 用于碳捕获和转化的系统和工艺 |
| EP4192999A4 (en) * | 2020-08-06 | 2025-07-02 | Evoloh Inc | WATER ELECTROLYSER |
| US12305304B2 (en) | 2022-10-13 | 2025-05-20 | Twelve Benefit Corporation | Interface for carbon oxide electrolyzer bipolar membrane |
| US12378685B2 (en) | 2022-12-22 | 2025-08-05 | Twelve Benefit Corporation | Surface modification of metal catalysts with hydrophobic ligands or ionomers |
| FR3156142A1 (fr) * | 2023-12-04 | 2025-06-06 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Procédé de conversion électrochimique du CO2 capté par un solvant eutectique profond en présence d'un catalyseur de palladium |
Family Cites Families (115)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE183856C (https=) | ||||
| US1919850A (en) | 1933-07-25 | Emil luscher | ||
| US2511198A (en) | 1948-01-02 | 1950-06-13 | Allied Chem & Dye Corp | Preparation of concentrated formic acid |
| US2996359A (en) * | 1957-11-26 | 1961-08-15 | Matheson Company Inc | Method for continuous manufacture of carbon monoxide |
| US4299891A (en) | 1972-10-27 | 1981-11-10 | The Richardson Company | Method for forming battery terminals and terminals produced thereby |
| US3959094A (en) | 1975-03-13 | 1976-05-25 | The United States Of America As Represented By The United States Energy Research And Development Administration | Electrolytic synthesis of methanol from CO2 |
| US4207151A (en) | 1976-06-04 | 1980-06-10 | Monsanto Company | Electrohydrodimerization process improvement and improved electrolyte recovery process |
| DE2849065A1 (de) | 1978-11-11 | 1980-05-22 | Basf Ag | Verwendung von quartaeren ammoniumsalzen als leitsalze |
| US4240882A (en) | 1979-11-08 | 1980-12-23 | Institute Of Gas Technology | Gas fixation solar cell using gas diffusion semiconductor electrode |
| US4315753A (en) * | 1980-08-14 | 1982-02-16 | The United States Of America As Represented By The Secretary Of The Interior | Electrochemical apparatus for simultaneously monitoring two gases |
| NO824150L (no) | 1981-12-11 | 1983-06-13 | British Petroleum Co | Elektrokemisk organisk syntese. |
| GB8401005D0 (en) | 1984-01-14 | 1984-02-15 | Bp Chem Int Ltd | Formate salts |
| US4523981A (en) | 1984-03-27 | 1985-06-18 | Texaco Inc. | Means and method for reducing carbon dioxide to provide a product |
| US4609451A (en) | 1984-03-27 | 1986-09-02 | Texaco Inc. | Means for reducing carbon dioxide to provide a product |
| US4545872A (en) | 1984-03-27 | 1985-10-08 | Texaco Inc. | Method for reducing carbon dioxide to provide a product |
| DE3417790A1 (de) | 1984-05-14 | 1985-11-14 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von ameisensaeure |
| US4595465A (en) | 1984-12-24 | 1986-06-17 | Texaco Inc. | Means and method for reducing carbn dioxide to provide an oxalate product |
| US4620906A (en) | 1985-01-31 | 1986-11-04 | Texaco Inc. | Means and method for reducing carbon dioxide to provide formic acid |
| US4608132A (en) | 1985-06-06 | 1986-08-26 | Texaco Inc. | Means and method for the electrochemical reduction of carbon dioxide to provide a product |
| US4673473A (en) | 1985-06-06 | 1987-06-16 | Peter G. Pa Ang | Means and method for reducing carbon dioxide to a product |
| US4608133A (en) * | 1985-06-10 | 1986-08-26 | Texaco Inc. | Means and method for the electrochemical reduction of carbon dioxide to provide a product |
| US4609440A (en) | 1985-12-18 | 1986-09-02 | Gas Research Institute | Electrochemical synthesis of methane |
| US4609441A (en) | 1985-12-18 | 1986-09-02 | Gas Research Institute | Electrochemical reduction of aqueous carbon dioxide to methanol |
| CA1272180A (fr) * | 1986-03-20 | 1990-07-31 | Andre Mortreux | Systeme catalytique, son procede de preparation et son application a la fabrication d'aldehydes |
| US4711708A (en) | 1986-10-09 | 1987-12-08 | Gas Research Institute | Chemically modified electrodes for the catalytic reduction of CO2 |
| US4756807A (en) | 1986-10-09 | 1988-07-12 | Gas Research Institute | Chemically modified electrodes for the catalytic reduction of CO2 |
| US4668349A (en) | 1986-10-24 | 1987-05-26 | The Standard Oil Company | Acid promoted electrocatalytic reduction of carbon dioxide by square planar transition metal complexes |
| JPS63111193A (ja) | 1986-10-30 | 1988-05-16 | Asahi Chem Ind Co Ltd | アジポニトリルの製法 |
| IT1216929B (it) * | 1987-04-16 | 1990-03-14 | Enichem Sintesi | Procedimento per la sintesi di acidi 2-aril-propionici. |
| GB8712582D0 (en) * | 1987-05-28 | 1987-07-01 | Neotronics Ltd | Acidic gas sensors |
| US4818353A (en) | 1987-07-07 | 1989-04-04 | Langer Stanley H | Method for modifying electrocatalyst material, electrochemical cells and electrodes containing this modified material, and synthesis methods utilizing the cells |
| FR2624884B1 (fr) * | 1987-12-18 | 1990-04-20 | Poudres & Explosifs Ste Nale | Procede de synthese electrochimique de cetones alpha saturees |
| US4771708A (en) | 1988-01-11 | 1988-09-20 | Douglass Jr Edward T | Incinerator and heat recovery system for drying wood poles |
| US4968393A (en) * | 1988-04-18 | 1990-11-06 | A. L. Sandpiper Corporation | Membrane divided aqueous-nonaqueous system for electrochemical cells |
| FR2646441B1 (fr) * | 1989-04-28 | 1991-07-12 | Poudres & Explosifs Ste Nale | Procede d'electrosynthese d'un ester beta gamma insature |
| US5064733A (en) | 1989-09-27 | 1991-11-12 | Gas Research Institute | Electrochemical conversion of CO2 and CH4 to C2 hydrocarbons in a single cell |
| JP3009703B2 (ja) | 1990-05-02 | 2000-02-14 | 正道 藤平 | 二酸化炭素ガス還元用電極触媒 |
| DE4016063A1 (de) | 1990-05-18 | 1991-11-21 | Hoechst Ag | Verfahren zur teilweisen elektrolytischen enthalogenierung von di- und trichloressigsaeure sowie elektrolyseloesung |
| DE4211141A1 (de) | 1992-04-03 | 1993-10-07 | Basf Ag | Verfahren zur Herstellung von Ameisensäure durch thermische Spaltung von quartären Ammoniumformiaten |
| DE4227394A1 (de) | 1992-08-19 | 1994-02-24 | Basf Ag | Verfahren zur Herstellung von Ameisensäure aus Kohlenmonoxid und Wasser |
| JP3360850B2 (ja) | 1992-09-21 | 2003-01-07 | 株式会社日立製作所 | 銅系酸化触媒とその用途 |
| EP0652202B1 (en) | 1993-11-04 | 1997-06-04 | Research Development Corporation Of Japan | A method for producing formic acid or its derivatives |
| KR0169188B1 (ko) * | 1995-07-31 | 1999-03-20 | 강박광 | 탄화수소의 제조방법 |
| DE19544671A1 (de) | 1995-11-30 | 1997-06-05 | Bayer Ag | Urethan(meth)acrylate mit cyclischen Carbonatgruppen |
| FR2745297B1 (fr) | 1996-02-26 | 1998-05-22 | Lesaffre Dev | Utilisation d'une souche bacterienne pour la fabrication de l'acide formique ou du formiate et procede de fermentation utilisant cette souche |
| FR2747694B1 (fr) | 1996-04-18 | 1998-06-05 | France Etat | Cathode pour la reduction de dioxyde de carbone et procede de fabrication d'une telle cathode |
| JP3019776B2 (ja) * | 1996-07-04 | 2000-03-13 | 三菱化学株式会社 | Ｎ−アルキル−ｎ′−メチルイミダゾリニウム有機酸塩の製造方法 |
| US5709789A (en) | 1996-10-23 | 1998-01-20 | Sachem, Inc. | Electrochemical conversion of nitrogen containing gas to hydroxylamine and hydroxylammonium salts |
| US6660680B1 (en) | 1997-02-24 | 2003-12-09 | Superior Micropowders, Llc | Electrocatalyst powders, methods for producing powders and devices fabricated from same |
| US5928806A (en) | 1997-05-07 | 1999-07-27 | Olah; George A. | Recycling of carbon dioxide into methyl alcohol and related oxygenates for hydrocarbons |
| US6024855A (en) | 1997-08-15 | 2000-02-15 | Sachem, Inc. | Electrosynthesis of hydroxylammonium salts and hydroxylamine using a mediator |
| US6099990A (en) | 1998-03-26 | 2000-08-08 | Motorola, Inc. | Carbon electrode material for electrochemical cells and method of making same |
| FI107528B (fi) | 1998-12-23 | 2001-08-31 | Kemira Chemicals Oy | Menetelmä muurahaishapon valmistamiseksi |
| CA2620783C (en) | 1999-04-09 | 2011-04-05 | Evalve, Inc. | Methods and apparatus for cardiac valve repair |
| DE19953832A1 (de) | 1999-11-09 | 2001-05-10 | Basf Ag | Verfahren zur Herstellung von Ameisensäure |
| KR100351625B1 (ko) | 1999-11-11 | 2002-09-11 | 한국화학연구원 | 탄화수소 제조용 촉매 |
| DE10002795A1 (de) | 2000-01-24 | 2001-08-02 | Basf Ag | Werkstoff für eine Anlage zur Herstellung von wasserfreier Ameisensäure |
| DE10002791A1 (de) | 2000-01-24 | 2001-07-26 | Basf Ag | Verfahren zur Gewinnung von wasserfreier Ameisensäure |
| DE10002794A1 (de) | 2000-01-24 | 2001-07-26 | Basf Ag | Abwasserreinigung beim Verfahren zur Herstellung von wasserfreier Ameisensäure |
| FR2804622B1 (fr) * | 2000-02-04 | 2002-04-05 | Inst Francais Du Petrole | Composition catalytique pour la dimerisation, la codimerisation et l'oligomerisation des olefines |
| CN1275915C (zh) | 2000-02-25 | 2006-09-20 | 新日本制铁株式会社 | 甲酸酯或甲醇的生产方法及其合成催化剂 |
| FI117633B (fi) | 2000-12-29 | 2006-12-29 | Chempolis Oy | Kemikaalien talteenotto ja valmistus massan valmistuksen yhteydessä |
| GB0116505D0 (en) | 2001-07-06 | 2001-08-29 | Univ Belfast | Electrosynthesis of organic compounds |
| US6963909B1 (en) | 2001-07-24 | 2005-11-08 | Cisco Technology, Inc. | Controlling the response domain of a bootP/DHCP server by using network physical topology information |
| DE10138778A1 (de) | 2001-08-07 | 2003-02-20 | Basf Ag | Flexibles Verfahren zur gemeinsamen Herstellung von Ameisensäure sowie einer Carbonsäure mit mindestens zwei Kohlenstoffatomen und/oder deren Derivaten |
| CA2421242C (en) | 2001-11-08 | 2010-06-29 | Mks Marmara Entegre Kimya San. A.S. | Production of potassium formate |
| CA2464762A1 (en) | 2001-11-09 | 2003-05-15 | Basf Aktiengesellschaft | Method for production of formic acid formates |
| GB0215384D0 (en) | 2002-07-04 | 2002-08-14 | Johnson Matthey Plc | Improvements in metal salts |
| DE10237380A1 (de) | 2002-08-12 | 2004-02-19 | Basf Ag | Verfahren und Vorrichtung zur Herstellung von ameisensauren Formlaten und deren Verwendung |
| DE10237379A1 (de) | 2002-08-12 | 2004-02-19 | Basf Ag | Verfahren und Vorrichtung zur Herstellung von ameisensauren Formiaten und deren Verwendung |
| US6939453B2 (en) * | 2002-08-14 | 2005-09-06 | Large Scale Proteomics Corporation | Electrophoresis process using ionic liquids |
| DE10249928A1 (de) | 2002-10-26 | 2004-05-06 | Basf Ag | Flexibles Verfahren zur gemeinsamen Herstellung von (i) Ameisensäure, (ii) einer Carbonsäure mit mindestens zwei Kohlenstoffatomen und/oder deren Derivate und (iii) eines -Carbonsäureanhydrids |
| EP1669341A4 (en) | 2003-09-17 | 2007-01-03 | Japan Science & Tech Agency | PROCESS FOR REDUCING CARBON DIOXIDE WITH A METAL ORGANIC COMPLEX |
| FR2863911B1 (fr) | 2003-12-23 | 2006-04-07 | Inst Francais Du Petrole | Procede de sequestration de carbone sous la forme d'un mineral dans lequel le carbone est au degre d'oxydation +3 |
| US6987134B1 (en) | 2004-07-01 | 2006-01-17 | Robert Gagnon | How to convert carbon dioxide into synthetic hydrocarbon through a process of catalytic hydrogenation called CO2hydrocarbonation |
| DE102004040789A1 (de) | 2004-08-23 | 2006-03-02 | Basf Ag | Verfahren zur Herstellung von Ameisensäure |
| ES2263346B1 (es) * | 2004-08-25 | 2007-12-16 | Consejo Superior De Investigaciones Cientificas | Uso de una composicion catalitica en la insercion de dioxido de carbo no en acetales, ortoesteres y epoxidos. |
| US7618725B2 (en) * | 2004-09-21 | 2009-11-17 | The Board Of Trustees Of The University Of Illinois | Low contaminant formic acid fuel for direct liquid fuel cell |
| US7811433B2 (en) | 2004-10-15 | 2010-10-12 | Giner, Inc. | Electrochemical carbon dioxide sensor |
| EP1652814A1 (de) * | 2004-10-27 | 2006-05-03 | Solvay Fluor GmbH | Verfahren zur Gastrennung |
| WO2006101987A2 (en) * | 2005-03-17 | 2006-09-28 | Southwest Research Institute | Use of recirculated exhaust gas in a burner-based exhaust generation system for reduced fuel consumption and for cooling |
| JP5145213B2 (ja) | 2005-04-15 | 2013-02-13 | ユニヴァーシティー オブ サザン カリフォルニア | 二酸化炭素のメタノール、ジメチルエーテルおよび派生生成物への効率的且つ選択的変換法 |
| US7608743B2 (en) | 2005-04-15 | 2009-10-27 | University Of Southern California | Efficient and selective chemical recycling of carbon dioxide to methanol, dimethyl ether and derived products |
| DE102005020890A1 (de) | 2005-05-04 | 2006-11-09 | Basf Ag | Herstellung von Natriumformiat |
| WO2007018558A2 (en) | 2005-07-20 | 2007-02-15 | The Trustees Of Columbia University In The City Of New York | Electrochemical recovery of carbon dioxide from alkaline solvents |
| EP1938406A4 (en) | 2005-08-25 | 2010-04-21 | Ceramatec Inc | ELECTROCHEMICAL CELL FOR PRODUCING SYNTHESIS GAS USING ATMOSPHERIC AIR AND WATER |
| EP1947663B1 (en) | 2005-09-29 | 2012-02-01 | Sanyo Chemical Industries, Ltd. | Electrolyte solution for electrochemical device and electrochemical device using same |
| EP1951933A4 (en) | 2005-10-13 | 2011-08-24 | Mantra Energy Alternatives Ltd | CONTINUOUS ELECTROCHEMICAL DC REDUCTION OF CARBON DIOXIDE |
| US7378561B2 (en) | 2006-08-10 | 2008-05-27 | University Of Southern California | Method for producing methanol, dimethyl ether, derived synthetic hydrocarbons and their products from carbon dioxide and water (moisture) of the air as sole source material |
| GB0704972D0 (en) * | 2007-03-15 | 2007-04-25 | Varney Mark S | Neoteric room temperature ionic liquid gas sensor |
| US20090016948A1 (en) | 2007-07-12 | 2009-01-15 | Young Edgar D | Carbon and fuel production from atmospheric CO2 and H2O by artificial photosynthesis and method of operation thereof |
| WO2009012154A2 (en) * | 2007-07-13 | 2009-01-22 | University Of Southern California | Electrolysis of carbon dioxide in aqueous media to carbon monoxide and hydrogen for production of methanol |
| US8138380B2 (en) * | 2007-07-13 | 2012-03-20 | University Of Southern California | Electrolysis of carbon dioxide in aqueous media to carbon monoxide and hydrogen for production of methanol |
| CN101687648B (zh) | 2007-12-28 | 2015-01-28 | 卡勒拉公司 | 封存co2的方法 |
| CN101250711B (zh) | 2008-03-27 | 2010-11-10 | 昆明理工大学 | 二氧化碳在离子液体中的电化学还原方法和装置 |
| WO2009145624A1 (en) * | 2008-05-30 | 2009-12-03 | Inoviakem B.V. | Use of activated carbon dioxide in the oxidation of compounds having a hydroxy group |
| US7938892B2 (en) * | 2008-06-10 | 2011-05-10 | Palo Alto Research Center Incorporated | Producing articles that include ionic liquids |
| US20100137457A1 (en) | 2008-07-01 | 2010-06-03 | Kaplan Thomas Proger | Method for conversion of atmospheric carbon dioxide into useful materials |
| US20110162975A1 (en) | 2008-07-18 | 2011-07-07 | Ffgf Limited | The production of hydrogen, oxygen and hydrocarbons |
| DE102008044240B4 (de) | 2008-12-01 | 2013-12-05 | Msa Auer Gmbh | Elektrochemischer Gassensor mit einer ionischen Flüssigkeit als Elektrolyt, welche mindestens ein Mono-, Di- oder Trialkylammonium-Kation enthält |
| US8313634B2 (en) * | 2009-01-29 | 2012-11-20 | Princeton University | Conversion of carbon dioxide to organic products |
| US8366894B2 (en) * | 2009-02-20 | 2013-02-05 | Giner, Inc. | Multi-gas microsensor assembly |
| US20110114502A1 (en) * | 2009-12-21 | 2011-05-19 | Emily Barton Cole | Reducing carbon dioxide to products |
| US8721866B2 (en) * | 2010-03-19 | 2014-05-13 | Liquid Light, Inc. | Electrochemical production of synthesis gas from carbon dioxide |
| US8845877B2 (en) * | 2010-03-19 | 2014-09-30 | Liquid Light, Inc. | Heterocycle catalyzed electrochemical process |
| US8500987B2 (en) * | 2010-03-19 | 2013-08-06 | Liquid Light, Inc. | Purification of carbon dioxide from a mixture of gases |
| US20110237830A1 (en) | 2010-03-26 | 2011-09-29 | Dioxide Materials Inc | Novel catalyst mixtures |
| US8956990B2 (en) | 2010-03-26 | 2015-02-17 | Dioxide Materials, Inc. | Catalyst mixtures |
| US9566574B2 (en) | 2010-07-04 | 2017-02-14 | Dioxide Materials, Inc. | Catalyst mixtures |
| JP5591606B2 (ja) | 2010-07-08 | 2014-09-17 | 三井造船株式会社 | 二酸化炭素の還元，固定方法 |
| US8524066B2 (en) * | 2010-07-29 | 2013-09-03 | Liquid Light, Inc. | Electrochemical production of urea from NOx and carbon dioxide |
| RU2013133653A (ru) | 2010-12-21 | 2015-01-27 | Басф Се | Способ получения муравьиной кислоты в результате взаимодействия диоксида углерода с водородом |
| EP2729601B1 (en) * | 2011-07-06 | 2018-05-09 | Avantium Knowledge Centre B.V. | Reduction of carbon dioxide to oxalic acid, and hydrogenation thereof |
| GB201112389D0 (en) | 2011-07-19 | 2011-08-31 | Fujifilm Mfg Europe Bv | Curable compositions and membranes |
| US8858777B2 (en) | 2012-07-26 | 2014-10-14 | Liquid Light, Inc. | Process and high surface area electrodes for the electrochemical reduction of carbon dioxide |
-
2010
- 2010-07-04 US US12/830,338 patent/US20110237830A1/en not_active Abandoned
-
2011
- 2011-03-25 AU AU2011230545A patent/AU2011230545C1/en active Active
- 2011-03-25 KR KR1020127027866A patent/KR101721287B1/ko active Active
- 2011-03-25 CN CN201180023851.2A patent/CN102892929B/zh active Active
- 2011-03-25 CA CA2794105A patent/CA2794105C/en active Active
- 2011-03-25 WO PCT/US2011/030098 patent/WO2011120021A1/en not_active Ceased
- 2011-03-25 EP EP11713569.9A patent/EP2553147B1/en active Active
- 2011-03-25 JP JP2013501536A patent/JP2013525088A/ja not_active Withdrawn
-
2015
- 2015-01-08 US US14/592,246 patent/US10023967B2/en active Active
- 2015-11-30 JP JP2015232576A patent/JP6254565B2/ja active Active
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2013525088A5 (https=) | ||
| JP6254565B2 (ja) | 二酸化炭素を電気化学的に転換するための新規触媒混合物及び電気化学的装置 | |
| US8956990B2 (en) | Catalyst mixtures | |
| JP6449839B2 (ja) | 電気化学セル | |
| JP2013538285A5 (https=) | ||
| US20160327508A1 (en) | Sensors For Carbon Dioxide And Other End Uses | |
| US20250011947A1 (en) | Electrochemical cell, method for producing carbonyl compound, and synthesis system | |
| US9957624B2 (en) | Electrochemical devices comprising novel catalyst mixtures | |
| EP2588647A1 (en) | Novel catalyst mixtures |