JP2013036038A - 液晶媒体 - Google Patents
液晶媒体 Download PDFInfo
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- JP2013036038A JP2013036038A JP2012175915A JP2012175915A JP2013036038A JP 2013036038 A JP2013036038 A JP 2013036038A JP 2012175915 A JP2012175915 A JP 2012175915A JP 2012175915 A JP2012175915 A JP 2012175915A JP 2013036038 A JP2013036038 A JP 2013036038A
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- compounds
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- 125000000217 alkyl group Chemical group 0.000 claims abstract description 76
- 150000001875 compounds Chemical class 0.000 claims description 220
- 239000000203 mixture Substances 0.000 claims description 90
- 125000004432 carbon atom Chemical group C* 0.000 claims description 83
- 239000004973 liquid crystal related substance Substances 0.000 claims description 82
- 229910052731 fluorine Inorganic materials 0.000 claims description 50
- -1 vinyloxy Chemical group 0.000 claims description 46
- 125000003342 alkenyl group Chemical group 0.000 claims description 38
- 229910052801 chlorine Inorganic materials 0.000 claims description 32
- 125000003545 alkoxy group Chemical group 0.000 claims description 25
- 229910052739 hydrogen Inorganic materials 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 16
- 125000000304 alkynyl group Chemical group 0.000 claims description 11
- 229910052740 iodine Inorganic materials 0.000 claims description 10
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 125000006850 spacer group Chemical group 0.000 claims description 7
- 239000000654 additive Substances 0.000 claims description 6
- 125000005194 alkoxycarbonyloxy group Chemical group 0.000 claims description 6
- 125000005196 alkyl carbonyloxy group Chemical group 0.000 claims description 6
- 125000004448 alkyl carbonyl group Chemical group 0.000 claims description 5
- 125000003709 fluoroalkyl group Chemical group 0.000 claims description 5
- 125000004434 sulfur atom Chemical group 0.000 claims description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 5
- 239000012963 UV stabilizer Substances 0.000 claims description 4
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims description 4
- AHHWIHXENZJRFG-UHFFFAOYSA-N oxetane Chemical compound C1COC1 AHHWIHXENZJRFG-UHFFFAOYSA-N 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 4
- 229920002554 vinyl polymer Polymers 0.000 claims description 4
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 3
- 125000003302 alkenyloxy group Chemical group 0.000 claims description 3
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 3
- 125000003700 epoxy group Chemical group 0.000 claims description 3
- ZYMKZMDQUPCXRP-UHFFFAOYSA-N fluoro prop-2-enoate Chemical compound FOC(=O)C=C ZYMKZMDQUPCXRP-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 125000005407 trans-1,4-cyclohexylene group Chemical group [H]C1([H])C([H])([H])[C@]([H])([*:2])C([H])([H])C([H])([H])[C@@]1([H])[*:1] 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims 1
- 210000004027 cell Anatomy 0.000 description 39
- 239000000460 chlorine Substances 0.000 description 29
- 238000006116 polymerization reaction Methods 0.000 description 29
- 239000003999 initiator Substances 0.000 description 21
- 239000003381 stabilizer Substances 0.000 description 20
- 125000003118 aryl group Chemical group 0.000 description 17
- 239000000758 substrate Substances 0.000 description 16
- 230000004044 response Effects 0.000 description 15
- 239000000463 material Substances 0.000 description 14
- 230000003287 optical effect Effects 0.000 description 14
- 125000001072 heteroaryl group Chemical group 0.000 description 13
- 239000011159 matrix material Substances 0.000 description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
- 229910052799 carbon Inorganic materials 0.000 description 10
- 229910052736 halogen Inorganic materials 0.000 description 10
- 150000002367 halogens Chemical class 0.000 description 10
- 239000011737 fluorine Substances 0.000 description 8
- 150000002430 hydrocarbons Chemical group 0.000 description 8
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 7
- 125000001424 substituent group Chemical group 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 0 CCCCC=CC(CC1)CCC1C1CCC(*)CC1 Chemical compound CCCCC=CC(CC1)CCC1C1CCC(*)CC1 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 229910052717 sulfur Inorganic materials 0.000 description 6
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000002019 doping agent Substances 0.000 description 5
- 125000002950 monocyclic group Chemical group 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 230000005855 radiation Effects 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 229910052794 bromium Inorganic materials 0.000 description 4
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 238000013461 design Methods 0.000 description 4
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 125000001153 fluoro group Chemical group F* 0.000 description 4
- 125000005842 heteroatom Chemical group 0.000 description 4
- 125000000623 heterocyclic group Chemical group 0.000 description 4
- 238000011065 in-situ storage Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 4
- 229910052753 mercury Inorganic materials 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- 239000005361 soda-lime glass Substances 0.000 description 4
- 230000007704 transition Effects 0.000 description 4
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 4
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical compound C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 description 3
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 3
- UHFFVFAKEGKNAQ-UHFFFAOYSA-N 2-benzyl-2-(dimethylamino)-1-(4-morpholin-4-ylphenyl)butan-1-one Chemical compound C=1C=C(N2CCOCC2)C=CC=1C(=O)C(CC)(N(C)C)CC1=CC=CC=C1 UHFFVFAKEGKNAQ-UHFFFAOYSA-N 0.000 description 3
- LWRBVKNFOYUCNP-UHFFFAOYSA-N 2-methyl-1-(4-methylsulfanylphenyl)-2-morpholin-4-ylpropan-1-one Chemical compound C1=CC(SC)=CC=C1C(=O)C(C)(C)N1CCOCC1 LWRBVKNFOYUCNP-UHFFFAOYSA-N 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical group C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 3
- 239000004990 Smectic liquid crystal Substances 0.000 description 3
- 125000002723 alicyclic group Chemical group 0.000 description 3
- 125000002619 bicyclic group Chemical group 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 3
- 239000003505 polymerization initiator Substances 0.000 description 3
- 230000000379 polymerizing effect Effects 0.000 description 3
- 238000010526 radical polymerization reaction Methods 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 230000002269 spontaneous effect Effects 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 2
- XMLYCEVDHLAQEL-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-phenylpropan-1-one Chemical compound CC(C)(O)C(=O)C1=CC=CC=C1 XMLYCEVDHLAQEL-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- KDCGOANMDULRCW-UHFFFAOYSA-N 7H-purine Chemical compound N1=CNC2=NC=NC2=C1 KDCGOANMDULRCW-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- QOSSAOTZNIDXMA-UHFFFAOYSA-N Dicylcohexylcarbodiimide Chemical compound C1CCCCC1N=C=NC1CCCCC1 QOSSAOTZNIDXMA-UHFFFAOYSA-N 0.000 description 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 2
- 239000004988 Nematic liquid crystal Substances 0.000 description 2
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Chemical group C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical group C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical group C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical group C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical group C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- DZBUGLKDJFMEHC-UHFFFAOYSA-N acridine Chemical compound C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 125000005248 alkyl aryloxy group Chemical group 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- 125000002102 aryl alkyloxo group Chemical group 0.000 description 2
- 125000004104 aryloxy group Chemical group 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- WDECIBYCCFPHNR-UHFFFAOYSA-N chrysene Chemical compound C1=CC=CC2=CC=C3C4=CC=CC=C4C=CC3=C21 WDECIBYCCFPHNR-UHFFFAOYSA-N 0.000 description 2
- 125000004093 cyano group Chemical group *C#N 0.000 description 2
- 125000006165 cyclic alkyl group Chemical group 0.000 description 2
- 125000000582 cycloheptyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical group C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 2
- 239000007857 degradation product Substances 0.000 description 2
- TXCDCPKCNAJMEE-UHFFFAOYSA-N dibenzofuran Chemical compound C1=CC=C2C3=CC=CC=C3OC2=C1 TXCDCPKCNAJMEE-UHFFFAOYSA-N 0.000 description 2
- IYYZUPMFVPLQIF-UHFFFAOYSA-N dibenzothiophene Chemical compound C1=CC=C2C3=CC=CC=C3SC2=C1 IYYZUPMFVPLQIF-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000005684 electric field Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 229910052732 germanium Inorganic materials 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 2
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- PQNFLJBBNBOBRQ-UHFFFAOYSA-N indane Chemical group C1=CC=C2CCCC2=C1 PQNFLJBBNBOBRQ-UHFFFAOYSA-N 0.000 description 2
- AWJUIBRHMBBTKR-UHFFFAOYSA-N isoquinoline Chemical compound C1=NC=CC2=CC=CC=C21 AWJUIBRHMBBTKR-UHFFFAOYSA-N 0.000 description 2
- CTAPFRYPJLPFDF-UHFFFAOYSA-N isoxazole Chemical compound C=1C=NOC=1 CTAPFRYPJLPFDF-UHFFFAOYSA-N 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000001624 naphthyl group Chemical group 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 2
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 2
- RDOWQLZANAYVLL-UHFFFAOYSA-N phenanthridine Chemical compound C1=CC=C2C3=CC=CC=C3C=NC2=C1 RDOWQLZANAYVLL-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 2
- 125000003367 polycyclic group Chemical group 0.000 description 2
- 229920001690 polydopamine Polymers 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 2
- XSCHRSMBECNVNS-UHFFFAOYSA-N quinoxaline Chemical compound N1=CC=NC2=CC=CC=C21 XSCHRSMBECNVNS-UHFFFAOYSA-N 0.000 description 2
- 229910052711 selenium Inorganic materials 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000003107 substituted aryl group Chemical group 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 229910052714 tellurium Inorganic materials 0.000 description 2
- 125000006737 (C6-C20) arylalkyl group Chemical group 0.000 description 1
- ICPSWZFVWAPUKF-UHFFFAOYSA-N 1,1'-spirobi[fluorene] Chemical compound C1=CC=C2C=C3C4(C=5C(C6=CC=CC=C6C=5)=CC=C4)C=CC=C3C2=C1 ICPSWZFVWAPUKF-UHFFFAOYSA-N 0.000 description 1
- OVFJHQBWUUTRFT-UHFFFAOYSA-N 1,2,3,4-tetrahydrotetrazine Chemical compound C1=CNNNN1 OVFJHQBWUUTRFT-UHFFFAOYSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- HTJMXYRLEDBSLT-UHFFFAOYSA-N 1,2,4,5-tetrazine Chemical group C1=NN=CN=N1 HTJMXYRLEDBSLT-UHFFFAOYSA-N 0.000 description 1
- BBVIDBNAYOIXOE-UHFFFAOYSA-N 1,2,4-oxadiazole Chemical compound C=1N=CON=1 BBVIDBNAYOIXOE-UHFFFAOYSA-N 0.000 description 1
- YGTAZGSLCXNBQL-UHFFFAOYSA-N 1,2,4-thiadiazole Chemical group C=1N=CSN=1 YGTAZGSLCXNBQL-UHFFFAOYSA-N 0.000 description 1
- FYADHXFMURLYQI-UHFFFAOYSA-N 1,2,4-triazine Chemical group C1=CN=NC=N1 FYADHXFMURLYQI-UHFFFAOYSA-N 0.000 description 1
- UDGKZGLPXCRRAM-UHFFFAOYSA-N 1,2,5-thiadiazole Chemical group C=1C=NSN=1 UDGKZGLPXCRRAM-UHFFFAOYSA-N 0.000 description 1
- UUSUFQUCLACDTA-UHFFFAOYSA-N 1,2-dihydropyrene Chemical compound C1=CC=C2C=CC3=CCCC4=CC=C1C2=C43 UUSUFQUCLACDTA-UHFFFAOYSA-N 0.000 description 1
- FKASFBLJDCHBNZ-UHFFFAOYSA-N 1,3,4-oxadiazole Chemical compound C1=NN=CO1 FKASFBLJDCHBNZ-UHFFFAOYSA-N 0.000 description 1
- MBIZXFATKUQOOA-UHFFFAOYSA-N 1,3,4-thiadiazole Chemical group C1=NN=CS1 MBIZXFATKUQOOA-UHFFFAOYSA-N 0.000 description 1
- JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical group C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 description 1
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
- VDFVNEFVBPFDSB-UHFFFAOYSA-N 1,3-dioxane Chemical group C1COCOC1 VDFVNEFVBPFDSB-UHFFFAOYSA-N 0.000 description 1
- HNEGJTWNOOWEMH-UHFFFAOYSA-N 1-fluoropropane Chemical group [CH2]CCF HNEGJTWNOOWEMH-UHFFFAOYSA-N 0.000 description 1
- AUXIEQKHXAYAHG-UHFFFAOYSA-N 1-phenylcyclohexane-1-carbonitrile Chemical compound C=1C=CC=CC=1C1(C#N)CCCCC1 AUXIEQKHXAYAHG-UHFFFAOYSA-N 0.000 description 1
- WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 description 1
- TZMSYXZUNZXBOL-UHFFFAOYSA-N 10H-phenoxazine Chemical compound C1=CC=C2NC3=CC=CC=C3OC2=C1 TZMSYXZUNZXBOL-UHFFFAOYSA-N 0.000 description 1
- QWENRTYMTSOGBR-UHFFFAOYSA-N 1H-1,2,3-Triazole Chemical compound C=1C=NNN=1 QWENRTYMTSOGBR-UHFFFAOYSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- BAXOFTOLAUCFNW-UHFFFAOYSA-N 1H-indazole Chemical compound C1=CC=C2C=NNC2=C1 BAXOFTOLAUCFNW-UHFFFAOYSA-N 0.000 description 1
- IGHOZKDBCCFNNC-UHFFFAOYSA-N 1h-imidazole;quinoxaline Chemical compound C1=CNC=N1.N1=CC=NC2=CC=CC=C21 IGHOZKDBCCFNNC-UHFFFAOYSA-N 0.000 description 1
- GZPPANJXLZUWHT-UHFFFAOYSA-N 1h-naphtho[2,1-e]benzimidazole Chemical compound C1=CC2=CC=CC=C2C2=C1C(N=CN1)=C1C=C2 GZPPANJXLZUWHT-UHFFFAOYSA-N 0.000 description 1
- 125000004206 2,2,2-trifluoroethyl group Chemical group [H]C([H])(*)C(F)(F)F 0.000 description 1
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- 229930192474 thiophene Natural products 0.000 description 1
- 125000006168 tricyclic group Chemical group 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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Abstract
Description
1.基板としてのシリコンウエハー上のMOS(金属酸化物半導体:metal oxide semiconductor)または他のダイオード、
2.基板としてのガラス板上の薄膜トランジスタ(TFT:thin−film transistor)。
−広げられたネマチック相範囲(特に、低い温度まで)、
−極度に低い温度でのスイッチ能力(屋外使用、自動車、航空)、
−UV放射に対する増大された抵抗(より長い寿命)、
−低い閾(駆動)電圧、
−速い応答時間、
−十分に高い複屈折率、
−十分に高い電圧保持率(HR:Voltage Holding Ratio)を提供するための十分に高い抵抗率、
−特に、配向における欠陥を避けるための、セルおよびディスプレイにおける十分に高いプレチルト。
・1種類以上の重合性化合物(1種類または多種類)を含有する重合性成分(A)(好ましくは、メソゲン化合物の群より選択される。)と、
・式Iの1種類以上の化合物および/または式IAの1種類以上の化合物を含有する液晶成分(B)と
を含有することを特徴とする液晶媒体に関する。
R0は1〜15個のC原子を有するアルキルまたはアルコキシ基を表し、ただし加えて、これらの基における1個以上のCH2基は、それぞれ互いに独立に、O原子が互いに直接連結しないようにして、−C≡C−、−CF2O−、−CH=CH−、
X0は、F、Cl、CN、SF5、SCN、NCS、6個までのC原子を有するハロゲン化アルキル基、ハロゲン化アルケニル基、ハロゲン化アルコキシ基またはハロゲン化アルケニルオキシ基を表し、
L1〜6は、それぞれ互いに独立に、HまたはFを表す。
P1およびP2は、それぞれ互いに独立に、重合性基(好ましくは、Pに対して上および下で示される意味の1つを有する。)、特に好ましくは、アクリレート、メタクリレート、フルオロアクリレート、オキセタン、ビニル、ビニルオキシまたはエポキシド基を表し、
Sp1およびSp2は、それぞれ互いに独立に、単結合またはスペーサー基(好ましくは、Spに対して上および下で示される意味の1つを有する。)、特に好ましくは、−(CH2)p1−、−(CH2)p1−O−、−(CH2)p1−CO−O−または−(CH2)p1−O−CO−O−を表し、式中、p1は1〜12の整数であり、ただし、最後に述べた基において隣接する環への連結はO原子を介して起こり、
ただし加えて、存在する基P1−Sp1−およびP2−Sp2−の少なくとも1つがRaaを表さないことを条件として、基P1−Sp1−およびP2−Sp2−の1個以上は基Raaを表してもよく、
Raaは、H、F、Cl、CN、または、1〜25個のC原子を有する直鎖状または分岐状のアルキル(ただし加えて、1個以上の隣接していないCH2基は、Oおよび/またはS原子が互いに直接連結しないようにして、それぞれ互いに独立に、−C(R0)=C(R00)−、−C≡C−、−N(R0)−、−O−、−S−、−CO−、−CO−O−、−O−CO−、−O−CO−O−で置き換えられていてもよく、ただし加えて、1個以上のH原子は、F、Cl、CNまたはP1−Sp1−で置き換えられていてもよい。)、特に好ましくは、直鎖状または分岐状で一フッ素化または多フッ素化されていてもよい1〜12個のC原子を有するアルキル、アルコキシ、アルケニル、アルキニル、アルキルカルボニル、アルコキシカルボニル、アルキルカルボニルオキシまたはアルコキシカルボニルオキシ(ただし、アルケニルおよびアルキニル基は少なくとも2個のC原子を有し、分岐状の基は少なくとも3個のC原子を有する。)を表し、
R0およびR00は、それぞれ互いに独立に、それぞれの出現において同一または異なって、Hまたは1〜12個のC原子を有するアルキルを表し、
RyおよびRzは、それぞれ互いに独立に、H、F、CH3またはCF3を表し、
Z1は、−O−、−CO−、−C(RyRz)−または−CF2CF2−を表し、
Z2およびZ3は、それぞれ互いに独立に、−CO−O−、−O−CO−、−CH2O−、−OCH2−、−CF2O−、−OCF2−または−(CH2)n−を表し、ただし、nは、2、3または4であり、
Lは、それぞれの出現において同一または異なって、F、Cl、CN、または、直鎖状または分岐状で一フッ素化または多フッ素化されていてもよい1〜12個のC原子を有するアルキル、アルコキシ、アルケニル、アルキニル、アルキルカルボニル、アルコキシカルボニル、アルキルカルボニルオキシまたはアルコキシカルボニルオキシ、好ましくは、Fを表し、
L’およびL”は、それぞれ互いに独立に、H、FまたはClを表し、
rは、0、1、2、3または4を表し、
sは、0、1、2または3を表し、
tは、0、1または2を表し、
xは、0または1を表す。
Sp’は、1〜20個、好ましくは、1〜12個のC原子を有するアルキレンを表し、該基は、F、Cl、Br、IまたはCNで一置換または多置換されていてもよく、ただし加えて、1個以上の隣接していないCH2基は、Oおよび/またはS原子が互いに直接連結しないようにして、それぞれ互いに独立に、−O−、−S−、−NH−、−NR0−、−SiR0R00−、−CO−、−COO−、−OCO−、−OCO−O−、−S−CO−、−CO−S−、−NR0−CO−O−、−O−CO−NR0−、−NR0−CO−NR0−、−CH=CH−または−C≡C−で置き換えられていてもよく、
X’は、−O−、−S−、−CO−、−COO−、−OCO−、−O−COO−、−CO−NR0−、−NR0−CO−、−NR0−CO−NR0−、−OCH2−、−CH2O−、−SCH2−、−CH2S−、−CF2O−、−OCF2−、−CF2S−、−SCF2−、−CF2CH2−、−CH2CF2−、−CF2CF2−、−CH=N−、−N=CH−、−N=N−、−CH=CR0−、−CY2=CY3−、−C≡C−、−CH=CH−COO−、−OCO−CH=CH−または単結合を表し、
R0およびR00は、それぞれ互いに独立に、Hまたは1〜12個のC原子を有するアルキルを表し、および
Y2およびY3は、それぞれ互いに独立に、H、F、ClまたはCNを表す。
本発明による重合性化合物は開始剤のない重合に特に適しており、このことは、例えば、材料費がより低く、特に、開始剤またはそれの劣化生成物の残存し得る量によるLC媒体の不純物がより少ないなどの特筆すべき利点を伴う。
式Iの少なくとも1種類の化合物、または、
式Iの少なくとも1種類の化合物および式IAの少なくとも1種類の化合物
を含有する。
Aは、1,4−フェニレンまたはトランス−1,4−シクロヘキシレンを表し、
aは、0または1であり、および
R3は、2〜9個のC原子を有するアルケニルを表し、
および、R4は式IにおいてR0に示される意味を有し、好ましくは、1〜12個のC原子を有するアルキルまたは2〜9個のC原子を有するアルケニルを表す。
R0およびX0は、式Iにおいて示される意味を有し、および
Y1〜6は、それぞれ互いに独立に、HまたはFを表し、
Z0は、−C2H4−、−(CH2)4−、−CH=CH−、−CF=CF−、−C2F4−、−CH2CF2−、−CF2CH2−、−CH2O−、−OCH2−、−COO−、−CF2O−または−OCF2−を表し、式VおよびVIにおいては、また、単結合も表し、および
rは、0または1を表す。
alkylおよびalkyl*は、それぞれ互いに独立に、1〜6個のC原子を有する直鎖状のアルキル基を表し、および
alkenylおよびalkenyl*は、それぞれ互いに独立に、2〜6個のC原子を有する直鎖状のアルケニル基を表す。
しかしながら、本発明によるディスプレイと、ツイストネマチックセルに基づくこれまでの従来ディスプレイとの間の大きな相違点は、液晶層の液晶パラメータの選択にある。 本発明によって使用できる液晶混合物は、例えば、式Iおよび/またはIAの1種類以上の化合物を、式II〜XXVIIの1種類以上の化合物と、または、更なる液晶化合物および/または添加剤と混合し、それ自体従来の様式において調製される。一般に、より少ない量で使用される成分の所望の量を、主要な組成を構成する成分中で、有利には加温して溶解する。また、有機溶媒中、例えば、アセトン、クロロホルムまたはメタノール中の成分溶液を混合し、完全に混合後、例えば、蒸留によって溶媒を再び除去することも可能である。更に、例えば、同族混合物などのプレミックスを例えば使用するか、または、所謂「マルチボトル」系を使用することにより、他の従来の様式において混合物を調製することも可能である。
重合性化合物は個別に液晶媒体に加えることができるが、また、2種類以上の重合性化合物を含む混合物を使用することも可能である。電圧を印加しながらLCディスプレイの基板間のLC媒体中において、その場での重合により、重合性化合物を重合または架橋(1つの化合物が2個以上の重合性基を含有する場合)する。適切で好ましい重合方法は、例えば、熱または光重合で、好ましくは光重合であり、特にはUV光重合である。また、必要に応じて、ここに1種類以上の開始剤を加えることもできる。重合の適切な条件および開始剤の適切なタイプおよび量は当業者に既知であり、文献に記載されている。
例えば、商業的に入手可能な光重合開始剤Irgacure651(登録商標)、Irgacure184(登録商標)、Irgacure907(登録商標)、Irgacure369(登録商標)またはDarocure1173(登録商標)(Ciba社)がフリーラジカル重合に適する。開始剤を用いる場合、混合物全体における開始剤の割合は、好ましくは0.001質量%〜5質量%、特に好ましくは0.001質量%〜1質量%である。しかしながら、また、開始剤を加えることなく、重合を行うこともできる。更に好ましい実施形態において、LC媒体は重合開始剤を含まない。
V10 閾電圧[V]、即ち、相対コントラストが10%における特性電圧、
V90 相対コントラストが90%における特性電圧[V]、
V0 フレデリックス電圧[V]、容量、20℃、
VHR 電圧保持率(voltage holding ratio)[%]、
SR 室温においてx時間UVに曝露後の比抵抗[Ω・cm]、
ne 20℃および589nmにおける異常光屈折率、
n0 20℃および589nmにおける常光屈折率、
Δn 20℃および589nmにおける光学的異方性、
ε⊥ 20℃および1kHzにおける分子長軸に垂直な誘電率、
ε‖ 20℃および1kHzにおけるダイレクターに平行な誘電率、
Δε 20℃および1kHzにおける誘電異方性、
cl.p.、T(N,I) 透明点[℃]、
γ1 20℃における回転粘度[mPa・s]、
K1 20℃における「スプレイ(splay)」変形に対する弾性定数[pN]、
K2 20℃における「ツイスト(twist)」変形に対する弾性定数[pN]、
K3 20℃における「ベンド(bend)」変形に対する弾性定数[pN]。
Claims (22)
- 1種類以上の重合性化合物を含有する重合性成分(A)と、
一般式Iおよび/またはIAの1種類以上の化合物を含有する液晶成分(B)と
を含有することを特徴とする液晶媒体。
R0は1〜15個のC原子を有するアルキルまたはアルコキシ基を表し、ただし加えて、これらの基における1個以上のCH2基は、それぞれ互いに独立に、O原子が互いに直接連結しないようにして、−C≡C−、−CF2O−、−CH=CH−、
X0は、F、Cl、CN、SF5、SCN、NCS、6個までのC原子を有するハロゲン化アルキル基、ハロゲン化アルケニル基、ハロゲン化アルコキシ基またはハロゲン化アルケニルオキシ基を表し、
L1〜6は、それぞれ互いに独立に、HまたはFを表す。) - 重合性成分(A)は、以下の式の化合物群より選択される少なくとも1種類の重合性化合物を含有することを特徴とする請求項1に記載の液晶媒体。
P1およびP2は、それぞれ互いに独立に、重合性基(好ましくは、Pに対して明細書中で示される意味の1つを有する。)、特に好ましくは、アクリレート、メタクリレート、フルオロアクリレート、オキセタン、ビニル、ビニルオキシまたはエポキシド基を表し、
Sp1およびSp2は、それぞれ互いに独立に、単結合またはスペーサー基(好ましくは、Spに対して明細書中で示される意味の1つを有する。)を表し、特に好ましくは、−(CH2)p1−、−(CH2)p1−O−、−(CH2)p1−CO−O−または−(CH2)p1−O−CO−O−を表し、式中、p1は1〜12の整数であり、ただし、最後に述べた基において隣接する環への連結はO原子を介して起こり、
ただし加えて、存在する基P1−Sp1−およびP2−Sp2−の少なくとも一方がRaaを表さないことを条件として、基P1−Sp1−およびP2−Sp2−の1個以上は基Raaを表してもよく、
Raaは、H、F、Cl、CN、または、1〜25個のC原子を有する直鎖状または分岐状のアルキル(ただし加えて、1個以上の隣接していないCH2基は、Oおよび/またはS原子が互いに直接連結しないようにして、それぞれ互いに独立に、−C(R0)=C(R00)−、−C≡C−、−N(R0)−、−O−、−S−、−CO−、−CO−O−、−O−CO−、−O−CO−O−で置き換えられていてもよく、ただし加えて、1個以上のH原子は、F、Cl、CNまたはP1−Sp1−で置き換えられていてもよい。)、特に好ましくは、直鎖状または分岐状で一フッ素化または多フッ素化されていてもよい1〜12個のC原子を有するアルキル、アルコキシ、アルケニル、アルキニル、アルキルカルボニル、アルコキシカルボニル、アルキルカルボニルオキシまたはアルコキシカルボニルオキシ(ただし、アルケニルおよびアルキニル基は少なくとも2個のC原子を有し、分岐状の基は少なくとも3個のC原子を有する。)を表し、
R0およびR00は、それぞれ互いに独立に、それぞれの出現において同一または異なって、Hまたは1〜12個のC原子を有するアルキルを表し、
RyおよびRzは、それぞれ互いに独立に、H、F、CH3またはCF3を表し、
Z1は、−O−、−CO−、−C(RyRz)−または−CF2CF2−を表し、
Z2およびZ3は、それぞれ互いに独立に、−CO−O−、−O−CO−、−CH2O−、−OCH2−、−CF2O−、−OCF2−または−(CH2)n−を表し、ただし、nは、2、3または4であり、
Lは、それぞれの出現において同一または異なって、F、Cl、CN、または、直鎖状または分岐状で一フッ素化または多フッ素化されていてもよい1〜12個のC原子を有するアルキル、アルコキシ、アルケニル、アルキニル、アルキルカルボニル、アルコキシカルボニル、アルキルカルボニルオキシまたはアルコキシカルボニルオキシ、好ましくは、Fを表し、
L’およびL”は、それぞれ互いに独立に、H、FまたはClを表し、
rは、0、1、2、3または4を表し、
sは、0、1、2または3を表し、
tは、0、1または2を表し、
xは、0または1を表す。) - 式Iおよび式IAにおけるR0は1〜6個の炭素原子を有する直鎖状のアルキルまたは2〜6個の炭素原子を有する直鎖状のアルケニルを表すことを特徴とする請求項1〜4のいずれか一項に記載の液晶媒体。
- 成分Bは、式Iの少なくとも1種類の化合物と、式IAの少なくとも1種類の化合物とを含有することを特徴とする請求項1〜5のいずれか一項に記載の液晶媒体。
- 1質量%〜25質量%の式Iの化合物を含有することを特徴とする請求項1〜15のいずれか一項に記載の液晶媒体。
- 液晶混合物を基礎として、0.01質量%〜10質量%の重合性化合物を含有することを特徴とする請求項1〜16のいずれか一項に記載の液晶媒体。
- 1種類以上のUV安定剤および/または酸化防止剤を追加的に含有することを特徴とする請求項1〜17のいずれか一項に記載の液晶媒体。
- 電気光学的目的のための請求項1〜18のいずれか一項に記載の液晶媒体の使用。
- 請求項1〜18のいずれか一項に記載の液晶媒体を含有する電気光学的液晶ディスプレイ。
- PS−TN、PS−TN−TFT、PS−FFS、PS−VA−IPSまたはPS−IPSディスプレイであることを特徴とする請求項20に記載の電気光学的液晶ディスプレイ。
- 式Iおよび/またはIAの少なくとも1種類の化合物および少なくとも1種類の重合性化合物を、少なくとも1種類の更なる液晶化合物および任意成分として1種類以上の適切な添加剤と混合することを特徴とする請求項1〜18のいずれか一項に記載の液晶媒体の調製方法。
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Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009215556A (ja) * | 2008-03-11 | 2009-09-24 | Merck Patent Gmbh | 液晶媒体および液晶ディスプレイ |
WO2009156118A1 (en) * | 2008-06-27 | 2009-12-30 | Merck Patent Gmbh | Liquid-crystalline medium |
WO2010089092A1 (de) * | 2009-02-06 | 2010-08-12 | Merck Patent Gmbh | Flüssigkristallines medium und flüssigkristallanzeige |
JP2011510112A (ja) * | 2008-01-14 | 2011-03-31 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツング | 液晶媒体 |
WO2011050893A1 (de) * | 2009-10-28 | 2011-05-05 | Merck Patent Gmbh | Polymerisierbare verbindungen und ihre verwendung in flüssigkristallanzeigen |
JP2011514410A (ja) * | 2008-02-20 | 2011-05-06 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツング | 液晶媒体 |
JP2011116824A (ja) * | 2009-12-01 | 2011-06-16 | Chisso Corp | 液晶組成物および液晶表示素子 |
WO2011076329A1 (de) * | 2009-12-22 | 2011-06-30 | Merck Patent Gmbh | Flüssigkristallines medium |
US20110180756A1 (en) * | 2010-01-27 | 2011-07-28 | Chisso Corporation | Liquid crystal compound, liquid crystal composition and liquid crystal display device |
WO2012079676A1 (de) * | 2010-12-17 | 2012-06-21 | Merck Patent Gmbh | Flüssigkristallines medium |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3022818C2 (de) | 1980-06-19 | 1986-11-27 | Merck Patent Gmbh, 6100 Darmstadt | Flüssigkristall-Anzeigeelement |
EP0591508B2 (en) | 1992-04-27 | 2003-01-15 | MERCK PATENT GmbH | Electrooptical liquid crystal system |
TWI506123B (zh) * | 2008-02-01 | 2015-11-01 | Merck Patent Gmbh | 液晶介質及液晶顯示器 |
JP5493393B2 (ja) * | 2008-03-18 | 2014-05-14 | Jnc株式会社 | 液晶組成物および液晶表示素子 |
DE102010015824B4 (de) * | 2009-04-30 | 2021-12-30 | Merck Patent Gmbh | Flüssigkristallines Medium und Flüssigkristallanzeige |
DE102010025572A1 (de) * | 2010-06-30 | 2012-01-05 | Merck Patent Gmbh | Flüssigkristallines Medium und dieses enthaltende Hochfrequenzbauteile |
EP2508588B1 (en) * | 2011-04-07 | 2015-02-11 | Merck Patent GmbH | Liquid-crystalline medium and liquid-crystal display |
EP2568032B1 (en) * | 2011-09-06 | 2014-11-26 | Merck Patent GmbH | Liquid crystal medium and liquid crystal display |
DE102012020939B4 (de) * | 2012-10-25 | 2014-12-11 | Merck Patent Gmbh | Flüssigkristallines Medium und und seine Verwendung in einer elektrooptischen Flüssigkristallanzeige |
-
2012
- 2012-07-20 EP EP12005324.4A patent/EP2557140B1/en active Active
- 2012-07-20 EP EP16002042.6A patent/EP3130651B1/en active Active
- 2012-07-26 GB GB1213288.2A patent/GB2493615B/en not_active Expired - Fee Related
- 2012-08-08 TW TW105139296A patent/TWI660032B/zh active
- 2012-08-08 TW TW101128673A patent/TWI651399B/zh active
- 2012-08-08 JP JP2012175915A patent/JP6338814B2/ja not_active Expired - Fee Related
- 2012-08-08 KR KR1020120086863A patent/KR102070043B1/ko active IP Right Grant
- 2012-08-08 US US13/569,397 patent/US20130037745A1/en not_active Abandoned
- 2012-08-09 CN CN201210281661.7A patent/CN102952550B/zh active Active
- 2012-08-09 CN CN201611048013.1A patent/CN106753424B/zh active Active
-
2017
- 2017-10-04 JP JP2017193982A patent/JP2018080323A/ja active Pending
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011510112A (ja) * | 2008-01-14 | 2011-03-31 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツング | 液晶媒体 |
JP2011514410A (ja) * | 2008-02-20 | 2011-05-06 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツング | 液晶媒体 |
JP2009215556A (ja) * | 2008-03-11 | 2009-09-24 | Merck Patent Gmbh | 液晶媒体および液晶ディスプレイ |
WO2009156118A1 (en) * | 2008-06-27 | 2009-12-30 | Merck Patent Gmbh | Liquid-crystalline medium |
WO2010089092A1 (de) * | 2009-02-06 | 2010-08-12 | Merck Patent Gmbh | Flüssigkristallines medium und flüssigkristallanzeige |
WO2011050893A1 (de) * | 2009-10-28 | 2011-05-05 | Merck Patent Gmbh | Polymerisierbare verbindungen und ihre verwendung in flüssigkristallanzeigen |
JP2011116824A (ja) * | 2009-12-01 | 2011-06-16 | Chisso Corp | 液晶組成物および液晶表示素子 |
WO2011076329A1 (de) * | 2009-12-22 | 2011-06-30 | Merck Patent Gmbh | Flüssigkristallines medium |
US20110180756A1 (en) * | 2010-01-27 | 2011-07-28 | Chisso Corporation | Liquid crystal compound, liquid crystal composition and liquid crystal display device |
WO2012079676A1 (de) * | 2010-12-17 | 2012-06-21 | Merck Patent Gmbh | Flüssigkristallines medium |
Cited By (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016502568A (ja) * | 2012-10-25 | 2016-01-28 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツングMerck Patent Gesellschaft mit beschraenkter Haftung | 液晶媒体および電気光学液晶ディスプレイ |
JP5534110B1 (ja) * | 2012-12-27 | 2014-06-25 | Dic株式会社 | フルオロビフェニル含有組成物 |
JP5561438B1 (ja) * | 2012-12-27 | 2014-07-30 | Dic株式会社 | フルオロビフェニル含有組成物 |
US9441160B2 (en) | 2012-12-27 | 2016-09-13 | Dic Corporation | Fluorobiphenyl-containing composition |
WO2014132434A1 (ja) * | 2013-03-01 | 2014-09-04 | Dic株式会社 | 液晶組成物及びこれを用いた液晶表示素子 |
US9580654B2 (en) | 2013-03-01 | 2017-02-28 | Dic Corporation | Liquid crystal composition and liquid crystal display device using the same |
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JP5477502B1 (ja) * | 2013-08-09 | 2014-04-23 | Dic株式会社 | フルオロビフェニル含有組成物 |
WO2015037519A1 (ja) * | 2013-09-12 | 2015-03-19 | Dic株式会社 | 組成物及びそれを使用した液晶表示素子 |
JP2016164256A (ja) * | 2013-09-12 | 2016-09-08 | Dic株式会社 | 組成物及びそれを使用した液晶表示素子 |
JP5892296B2 (ja) * | 2013-09-12 | 2016-03-23 | Dic株式会社 | 組成物及びそれを使用した液晶表示素子 |
WO2015053017A1 (ja) * | 2013-10-08 | 2015-04-16 | Dic株式会社 | 組成物及びそれを使用した液晶表示素子 |
JP5776861B1 (ja) * | 2013-10-08 | 2015-09-09 | Dic株式会社 | 組成物及びそれを使用した液晶表示素子 |
CN104610979A (zh) * | 2013-11-05 | 2015-05-13 | 江苏和成显示科技股份有限公司 | 液晶组合物及其液晶显示器件 |
CN104610979B (zh) * | 2013-11-05 | 2017-02-08 | 江苏和成显示科技股份有限公司 | 液晶组合物及其液晶显示器件 |
JP2017522432A (ja) * | 2014-05-09 | 2017-08-10 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツングMerck Patent Gesellschaft mit beschraenkter Haftung | 液晶媒体およびそれを含む高周波数素子 |
CN104293358B (zh) * | 2014-09-11 | 2016-07-06 | 北京八亿时空液晶科技股份有限公司 | 一种含1,3-二噁烷化合物的液晶组合物及其应用 |
CN104293358A (zh) * | 2014-09-11 | 2015-01-21 | 北京八亿时空液晶科技股份有限公司 | 一种含1,3-二噁烷化合物的液晶组合物及其应用 |
CN104610984A (zh) * | 2014-12-31 | 2015-05-13 | 石家庄诚志永华显示材料有限公司 | 液晶组合物 |
WO2017038617A1 (ja) * | 2015-09-04 | 2017-03-09 | Dic株式会社 | 液晶組成物及びそれを使用した液晶表示素子 |
JPWO2017038552A1 (ja) * | 2015-09-04 | 2017-09-21 | Dic株式会社 | 安定剤化合物、液晶組成物および表示素子 |
JP2018123132A (ja) * | 2015-09-04 | 2018-08-09 | Dic株式会社 | 安定剤化合物、液晶組成物および表示素子 |
US10329252B2 (en) | 2015-09-04 | 2019-06-25 | Dic Corporation | Stabilizer compound, liquid crystal composition, and display element |
US10633590B2 (en) | 2015-09-04 | 2020-04-28 | Dic Corporation | Liquid crystal composition and liquid crystal display device including the same |
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CN102952550A (zh) | 2013-03-06 |
CN102952550B (zh) | 2016-12-21 |
CN106753424B (zh) | 2022-07-26 |
EP3130651B1 (en) | 2019-10-16 |
TW201716554A (zh) | 2017-05-16 |
EP2557140A3 (en) | 2013-07-24 |
TWI651399B (zh) | 2019-02-21 |
JP6338814B2 (ja) | 2018-06-06 |
US20130037745A1 (en) | 2013-02-14 |
KR20130019350A (ko) | 2013-02-26 |
EP3130651A1 (en) | 2017-02-15 |
JP2018080323A (ja) | 2018-05-24 |
GB2493615B (en) | 2014-04-23 |
EP2557140A2 (en) | 2013-02-13 |
GB2493615A (en) | 2013-02-13 |
GB201213288D0 (en) | 2012-09-05 |
EP2557140B1 (en) | 2016-09-21 |
TWI660032B (zh) | 2019-05-21 |
CN106753424A (zh) | 2017-05-31 |
KR102070043B1 (ko) | 2020-01-29 |
TW201311871A (zh) | 2013-03-16 |
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