JP2012140592A - １，１，１，３，３，３−ヘキサフルオロブテン及び１−クロロ−３，３，３−トリフルオロプロペンを含む混合物 - Google Patents

１，１，１，３，３，３−ヘキサフルオロブテン及び１−クロロ−３，３，３−トリフルオロプロペンを含む混合物 Download PDF

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Publication number
JP2012140592A
JP2012140592A JP2011236240A JP2011236240A JP2012140592A JP 2012140592 A JP2012140592 A JP 2012140592A JP 2011236240 A JP2011236240 A JP 2011236240A JP 2011236240 A JP2011236240 A JP 2011236240A JP 2012140592 A JP2012140592 A JP 2012140592A
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JP
Japan
Prior art keywords
foam
hexafluorobutene
chloro
1336mzzm
trifluoropropene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
JP2011236240A
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English (en)
Japanese (ja)
Inventor
Mary C Bogdan
メアリー・シー・ボグダン
Clifford P Gittere
クリフォード・ピー・ジッテレ
James M Bowman
ジェームズ・エム・ボウマン
Yiu Keung Ling
イウ・キュン・リン
David J Williams
デーヴィッド・ジェイ・ウィリアムズ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honeywell International Inc
Original Assignee
Honeywell International Inc
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Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=44992569&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=JP2012140592(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Honeywell International Inc filed Critical Honeywell International Inc
Publication of JP2012140592A publication Critical patent/JP2012140592A/ja
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/14—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3206—Polyhydroxy compounds aliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/125—Water, e.g. hydrated salts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
    • C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/149—Mixtures of blowing agents covered by more than one of the groups C08J9/141 - C08J9/143
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/16—Unsaturated hydrocarbons
    • C08J2203/162—Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/18—Binary blends of expanding agents
    • C08J2203/182—Binary blends of expanding agents of physical blowing agents, e.g. acetone and butane
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/20—Ternary blends of expanding agents
    • C08J2203/202—Ternary blends of expanding agents of physical blowing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2371/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
    • C08J2371/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08J2371/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C08J2375/08—Polyurethanes from polyethers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
JP2011236240A 2010-10-28 2011-10-27 １，１，１，３，３，３−ヘキサフルオロブテン及び１−クロロ−３，３，３−トリフルオロプロペンを含む混合物 Ceased JP2012140592A (ja)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US40770810P 2010-10-28 2010-10-28
US61/407,708 2010-10-28
US13/276,369 US9145480B2 (en) 2010-10-28 2011-10-19 Mixtures containing 1,1,1,3,3,3-hexafluorobutene and 1-chloro-3,3,3-trifluoropropene
US13/276,369 2011-10-19

Related Child Applications (1)

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JP2017003902A Division JP2017115151A (ja) 2010-10-28 2017-01-13 １，１，１，４，４，４−ヘキサフルオロブテン及び１−クロロ−３，３，３−トリフルオロプロペンを含む混合物

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Publication Number Publication Date
JP2012140592A true JP2012140592A (ja) 2012-07-26

Family

ID=44992569

Family Applications (7)

Application Number Title Priority Date Filing Date
JP2011236240A Ceased JP2012140592A (ja) 2010-10-28 2011-10-27 １，１，１，３，３，３−ヘキサフルオロブテン及び１−クロロ−３，３，３−トリフルオロプロペンを含む混合物
JP2017003902A Withdrawn JP2017115151A (ja) 2010-10-28 2017-01-13 １，１，１，４，４，４−ヘキサフルオロブテン及び１−クロロ−３，３，３−トリフルオロプロペンを含む混合物
JP2018222237A Active JP6503506B1 (ja) 2010-10-28 2018-11-28 １，１，１，４，４，４−ヘキサフルオロブテン及び１−クロロ−３，３，３−トリフルオロプロペンを含む混合物
JP2019076215A Pending JP2019163464A (ja) 2010-10-28 2019-04-12 １，１，１，４，４，４−ヘキサフルオロブテン及び１−クロロ−３，３，３−トリフルオロプロペンを含む混合物
JP2021110525A Active JP7238031B2 (ja) 2010-10-28 2021-07-02 １，１，１，４，４，４－ヘキサフルオロブテン及び１－クロロ－３，３，３－トリフルオロプロペンを含む混合物
JP2023030696A Pending JP2023081917A (ja) 2010-10-28 2023-03-01 １，１，１，４，４，４－ヘキサフルオロブテン及び１－クロロ－３，３，３－トリフルオロプロペンを含む混合物
JP2025022121A Pending JP2025081440A (ja) 2010-10-28 2025-02-14 １，１，１，４，４，４－ヘキサフルオロブテン及び１－クロロ－３，３，３－トリフルオロプロペンを含む混合物

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JP2017003902A Withdrawn JP2017115151A (ja) 2010-10-28 2017-01-13 １，１，１，４，４，４−ヘキサフルオロブテン及び１−クロロ−３，３，３−トリフルオロプロペンを含む混合物
JP2018222237A Active JP6503506B1 (ja) 2010-10-28 2018-11-28 １，１，１，４，４，４−ヘキサフルオロブテン及び１−クロロ−３，３，３−トリフルオロプロペンを含む混合物
JP2019076215A Pending JP2019163464A (ja) 2010-10-28 2019-04-12 １，１，１，４，４，４−ヘキサフルオロブテン及び１−クロロ−３，３，３−トリフルオロプロペンを含む混合物
JP2021110525A Active JP7238031B2 (ja) 2010-10-28 2021-07-02 １，１，１，４，４，４－ヘキサフルオロブテン及び１－クロロ－３，３，３－トリフルオロプロペンを含む混合物
JP2023030696A Pending JP2023081917A (ja) 2010-10-28 2023-03-01 １，１，１，４，４，４－ヘキサフルオロブテン及び１－クロロ－３，３，３－トリフルオロプロペンを含む混合物
JP2025022121A Pending JP2025081440A (ja) 2010-10-28 2025-02-14 １，１，１，４，４，４－ヘキサフルオロブテン及び１－クロロ－３，３，３－トリフルオロプロペンを含む混合物

Country Status (8)

Country Link
US (6) US9145480B2 (enExample)
EP (2) EP2447310A3 (enExample)
JP (7) JP2012140592A (enExample)
KR (3) KR20120044897A (enExample)
CN (2) CN102532582A (enExample)
BR (1) BRPI1105901B1 (enExample)
CA (1) CA2756292C (enExample)
MX (2) MX352158B (enExample)

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JP2014517118A (ja) * 2011-06-08 2014-07-17 ハネウェル・インターナショナル・インコーポレーテッド ハロゲン化オレフィン発泡剤を含むポリウレタンフォームプレミックス及びそれから製造されるフォーム
WO2015050139A1 (ja) * 2013-10-02 2015-04-09 旭硝子株式会社 ポリオールシステム液、および硬質発泡合成樹脂の製造方法
JP2016147941A (ja) * 2015-02-10 2016-08-18 セントラル硝子株式会社 含フッ素オレフィンを構成成分とする共沸様組成物
JP2018517789A (ja) * 2015-03-02 2018-07-05 ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー Ｚ−１−クロロ−３，３，３−トリフルオロプロペンの共沸及び共沸様組成物
JP2018119034A (ja) * 2017-01-24 2018-08-02 東ソー株式会社 硬質ポリウレタンフォーム用組成物及び硬質ポリウレタンフォームの製造方法
WO2019088035A1 (ja) * 2017-11-01 2019-05-09 Ａｇｃ株式会社 硬質発泡合成樹脂の製造方法
JP2020514421A (ja) * 2017-12-14 2020-05-21 浙江衢化▲弗▼化学有限公司Ｚｈｅｊｉａｎｇ Ｑｕｈｕａ Ｆｌｕｏｒ−Ｃｈｅｍｉｓｔｒｙ Ｃｏ Ｌｔｄ 共沸及び共沸様組成物
JP2022030315A (ja) * 2020-08-06 2022-02-18 積水化学工業株式会社 ポリオール組成物、発泡性ポリウレタン組成物、及びポリウレタンフォーム
JP2022527737A (ja) * 2019-04-01 2022-06-06 ハネウェル・インターナショナル・インコーポレーテッド トランス－１－クロロ－３，３，３－トリフルオロプロペン及びトランス－１，３，３，３－テトラフルオロプロペンを含むパーソナルケア組成物及び方法
JP2023135857A (ja) * 2022-03-16 2023-09-29 株式会社東洋クオリティワン 製造用原料及びポリウレタンフォームの製造方法

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US8846754B2 (en) * 2009-12-16 2014-09-30 Honeywell International Inc. Azeotrope-like compositions of cis-1,1,1,4,4,4-hexafluoro-2-butene
US9145480B2 (en) * 2010-10-28 2015-09-29 Honeywell International Inc. Mixtures containing 1,1,1,3,3,3-hexafluorobutene and 1-chloro-3,3,3-trifluoropropene
AU2012346370B2 (en) * 2011-12-02 2016-07-14 The Chemours Company Fc, Llc. Foam expansion agent compositions containing Z-1,1,1,4,4,4-hexafluoro-2-butene and their uses in the preparation of polyurethane and polyisocyanurate polymer foams
US9783721B2 (en) 2012-08-20 2017-10-10 Honeywell International Inc. Low GWP heat transfer compositions
US8940180B2 (en) 2012-11-21 2015-01-27 Honeywell International Inc. Low GWP heat transfer compositions
US9982180B2 (en) 2013-02-13 2018-05-29 Honeywell International Inc. Heat transfer compositions and methods
CA2901417C (en) * 2013-02-26 2021-08-24 Honeywell International Inc. Polyurethane foam premixes containing halogenated olefin blowing agents and foams made from same
CA2902979A1 (en) * 2013-03-06 2014-09-12 Honeywell International Inc. Storage stable foamable compositions containing 1,1,1,4,4,4-hexafluoro-2-butene
CN106414573B (zh) * 2014-01-24 2020-03-17 旭化成建材株式会社 酚醛树脂发泡体及其制造方法
US20150210818A1 (en) * 2014-01-27 2015-07-30 E I Du Pont De Nemours And Company Cryogenic insulation foam
PL3119824T3 (pl) 2014-03-20 2021-11-08 Dow Global Technologies Llc Sformułowane mieszanki reaktywne wobec izocyjanianów zawierające środek porotwórczy na bazie olefin
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