JP2011522786A - ハロアルキニル化合物、アゾール、及び不飽和酸を含む、抗変色菌(antisapstain)組成物 - Google Patents
ハロアルキニル化合物、アゾール、及び不飽和酸を含む、抗変色菌(antisapstain)組成物 Download PDFInfo
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- JP2011522786A JP2011522786A JP2011506771A JP2011506771A JP2011522786A JP 2011522786 A JP2011522786 A JP 2011522786A JP 2011506771 A JP2011506771 A JP 2011506771A JP 2011506771 A JP2011506771 A JP 2011506771A JP 2011522786 A JP2011522786 A JP 2011522786A
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- 239000000203 mixture Substances 0.000 title claims abstract description 218
- -1 haloalkynyl compound Chemical class 0.000 title claims abstract description 70
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 239000002253 acid Substances 0.000 title claims description 48
- 239000002023 wood Substances 0.000 claims abstract description 51
- 239000000758 substrate Substances 0.000 claims abstract description 34
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 15
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims abstract description 14
- 229940099451 3-iodo-2-propynylbutylcarbamate Drugs 0.000 claims description 66
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 claims description 66
- 239000005822 Propiconazole Substances 0.000 claims description 42
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 claims description 42
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 32
- 150000003839 salts Chemical class 0.000 claims description 32
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 30
- 239000004299 sodium benzoate Substances 0.000 claims description 30
- 235000010234 sodium benzoate Nutrition 0.000 claims description 30
- 239000002243 precursor Substances 0.000 claims description 27
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 21
- 150000001875 compounds Chemical class 0.000 claims description 21
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 claims description 17
- BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 claims description 17
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 claims description 16
- 239000005839 Tebuconazole Substances 0.000 claims description 16
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims description 16
- 125000004432 carbon atom Chemical group C* 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 14
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims description 11
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- 239000004334 sorbic acid Substances 0.000 claims description 11
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- 125000000217 alkyl group Chemical group 0.000 claims description 10
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 9
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 claims description 9
- 239000000839 emulsion Substances 0.000 claims description 9
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 9
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 8
- 125000003118 aryl group Chemical group 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 8
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 7
- 239000004302 potassium sorbate Substances 0.000 claims description 7
- 235000010241 potassium sorbate Nutrition 0.000 claims description 7
- 229940069338 potassium sorbate Drugs 0.000 claims description 7
- 229910052708 sodium Inorganic materials 0.000 claims description 7
- YWWVWXASSLXJHU-AATRIKPKSA-N (9E)-tetradecenoic acid Chemical compound CCCC\C=C\CCCCCCCC(O)=O YWWVWXASSLXJHU-AATRIKPKSA-N 0.000 claims description 6
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 6
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 6
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 6
- 239000005711 Benzoic acid Substances 0.000 claims description 6
- 239000005642 Oleic acid Substances 0.000 claims description 6
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 claims description 6
- 235000010233 benzoic acid Nutrition 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 claims description 6
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 6
- MHVJRKBZMUDEEV-UHFFFAOYSA-N (-)-ent-pimara-8(14),15-dien-19-oic acid Natural products C1CCC(C(O)=O)(C)C2C1(C)C1CCC(C=C)(C)C=C1CC2 MHVJRKBZMUDEEV-UHFFFAOYSA-N 0.000 claims description 5
- STMIIPIFODONDC-UHFFFAOYSA-N 2-(2,4-dichlorophenyl)-1-(1H-1,2,4-triazol-1-yl)hexan-2-ol Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(O)(CCCC)CN1C=NC=N1 STMIIPIFODONDC-UHFFFAOYSA-N 0.000 claims description 5
- UFNOUKDBUJZYDE-UHFFFAOYSA-N 2-(4-chlorophenyl)-3-cyclopropyl-1-(1H-1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1CC(O)(C=1C=CC(Cl)=CC=1)C(C)C1CC1 UFNOUKDBUJZYDE-UHFFFAOYSA-N 0.000 claims description 5
- NSPMIYGKQJPBQR-UHFFFAOYSA-N 4H-1,2,4-triazole Chemical compound C=1N=CNN=1 NSPMIYGKQJPBQR-UHFFFAOYSA-N 0.000 claims description 5
- 239000005757 Cyproconazole Substances 0.000 claims description 5
- 229910052736 halogen Inorganic materials 0.000 claims description 5
- 150000002367 halogens Chemical class 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- MHVJRKBZMUDEEV-APQLOABGSA-N (+)-Pimaric acid Chemical compound [C@H]1([C@](CCC2)(C)C(O)=O)[C@@]2(C)[C@H]2CC[C@](C=C)(C)C=C2CC1 MHVJRKBZMUDEEV-APQLOABGSA-N 0.000 claims description 4
- 239000004283 Sodium sorbate Substances 0.000 claims description 4
- YZXBAPSDXZZRGB-DOFZRALJSA-N arachidonic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O YZXBAPSDXZZRGB-DOFZRALJSA-N 0.000 claims description 4
- AKNQMEBLVAMSNZ-UHFFFAOYSA-N azaconazole Chemical compound ClC1=CC(Cl)=CC=C1C1(CN2N=CN=C2)OCCO1 AKNQMEBLVAMSNZ-UHFFFAOYSA-N 0.000 claims description 4
- 229950000294 azaconazole Drugs 0.000 claims description 4
- 239000001530 fumaric acid Substances 0.000 claims description 4
- 125000001624 naphthyl group Chemical group 0.000 claims description 4
- 229910052700 potassium Inorganic materials 0.000 claims description 4
- 235000019250 sodium sorbate Nutrition 0.000 claims description 4
- YNWVFADWVLCOPU-MDWZMJQESA-N (1E)-1-(4-chlorophenyl)-4,4-dimethyl-2-(1H-1,2,4-triazol-1-yl)pent-1-en-3-ol Chemical compound C1=NC=NN1/C(C(O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1 YNWVFADWVLCOPU-MDWZMJQESA-N 0.000 claims description 3
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 claims description 3
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 3
- LQDARGUHUSPFNL-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)-3-(1,1,2,2-tetrafluoroethoxy)propyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(COC(F)(F)C(F)F)CN1C=NC=N1 LQDARGUHUSPFNL-UHFFFAOYSA-N 0.000 claims description 3
- WKBPZYKAUNRMKP-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)pentyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(CCC)CN1C=NC=N1 WKBPZYKAUNRMKP-UHFFFAOYSA-N 0.000 claims description 3
- ZOMKCDYJHAQMCU-UHFFFAOYSA-N 4-butyl-1,2,4-triazole Chemical group CCCCN1C=NN=C1 ZOMKCDYJHAQMCU-UHFFFAOYSA-N 0.000 claims description 3
- YWWVWXASSLXJHU-UHFFFAOYSA-N 9E-tetradecenoic acid Natural products CCCCC=CCCCCCCCC(O)=O YWWVWXASSLXJHU-UHFFFAOYSA-N 0.000 claims description 3
- 239000005760 Difenoconazole Substances 0.000 claims description 3
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- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 3
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- 125000003710 aryl alkyl group Chemical group 0.000 claims description 3
- 125000003785 benzimidazolyl group Chemical group N1=C(NC2=C1C=CC=C2)* 0.000 claims description 3
- SECPZKHBENQXJG-UHFFFAOYSA-N cis-palmitoleic acid Natural products CCCCCCC=CCCCCCCCC(O)=O SECPZKHBENQXJG-UHFFFAOYSA-N 0.000 claims description 3
- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical compound O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 claims description 3
- IJJVMEJXYNJXOJ-UHFFFAOYSA-N fluquinconazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1N1C(=O)C2=CC(F)=CC=C2N=C1N1C=NC=N1 IJJVMEJXYNJXOJ-UHFFFAOYSA-N 0.000 claims description 3
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- LROWVYNUWKVTCU-STWYSWDKSA-M sodium sorbate Chemical compound [Na+].C\C=C\C=C\C([O-])=O LROWVYNUWKVTCU-STWYSWDKSA-M 0.000 claims description 3
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- QEZOJSVHYQKBOV-UHFFFAOYSA-N (3-iodo-2-prop-1-ynylhexyl)carbamic acid Chemical compound CCCC(I)C(C#CC)CNC(O)=O QEZOJSVHYQKBOV-UHFFFAOYSA-N 0.000 claims description 2
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- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 2
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Images
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/343—Heterocyclic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/50—Mixtures of different organic impregnating agents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31971—Of carbohydrate
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31971—Of carbohydrate
- Y10T428/31975—Of cellulosic next to another carbohydrate
- Y10T428/31978—Cellulosic next to another cellulosic
- Y10T428/31986—Regenerated or modified
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31971—Of carbohydrate
- Y10T428/31989—Of wood
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Dentistry (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Forests & Forestry (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Dispersion Chemistry (AREA)
- Toxicology (AREA)
Abstract
Description
mは、1〜3の整数であり;
Xは、(1)有機官能基の一部である酸素;(2)有機官能基の一部である窒素;(3)有機官能基の一部である硫黄;又は(4)有機官能基の一部である炭素であり得る。)
各Rは、独立して、C1〜C4アルキル、OH、OMe、OEt、NH2、NMe2、CO2M、又はハロゲンを表し、
2個のR基は任意にナフチルを形成してよく;
Mは、H、K、又はNaを表し;
mは、0〜5を表す。)
Xは、CR4又はNを表し;
R1は、水素、又は直鎖、分岐、環式、芳香族、又はその任意の組合せの、飽和又は不飽和、置換又は未置換のC1〜C40基を表し、
ここで、式(IV)中で示される窒素原子に結合している炭素原子以外の炭素原子はいずれも、置換されていてもよいヘテロ原子で置き換えられていてもよい;
R2は、水素、C1〜C8アルキル、C2〜C8アルケニル、C6〜C10芳香族、C5〜C10複素環芳香族、又はC1〜C4アルキルカルバマートを表し;
R3及びR4は、水素を表すか、あるいは
R3及びR4は、一緒になってベンズイミダゾール基を形成してもよい。)
野外試験を開始し、複数の配合物(formulation)について、処理した材木を変色及びカビの無い状態に維持することができる期間を延ばす能力を調べた。
Dowanol DPM(登録商標) 5.01
テブオコナゾール(97%) 0.50
IPBC(98%) 0.50
プロピコナゾール(50%) 0.50
Dehscofix CO130F(登録商標)(4OM エトキシレートひまし油界面活性剤) 4.99
水 88.50
3.33%に希釈
Dowanol DPM(登録商標)(グリコールエーテル溶媒) 8.99
テブオコナゾール(97%) 1
プロピコナゾール(50%) 1.03
Dehscofix CO130F(登録商標)(4OM エトキシレートひまし油界面活性剤) 11.34
EDTA四ナトリウム(45%) 1.5
安息香酸ナトリウム 22.5
水 53.64
1.17%に希釈
テブオコナゾール(97%) 0.33
プロピコナゾール(50%) 0.33
Uradil AZ543(登録商標)(水溶性アルキド樹脂) 15
Carboquat(登録商標)(ジデシルジメチル炭酸アンモニウム) 10
安息香酸ナトリウム 22.5
水 51.84
1.33%に希釈
Dowanol DPM(登録商標)(グリコールエーテル溶媒) 8.99
テブオコナゾール(97%) 1
IPBC(98%) 1.2
プロピコナゾール(50%) 1.04
Dehscofix CO130F(登録商標)(4OM エトキシレートひまし油界面活性剤) 11.24
EDTA四ナトリウム(45%) 1.5
安息香酸ナトリウム 22.5
水 52.53
1.02%に希釈
Dowanol DPM(登録商標)(グリコールエーテル溶媒) 8.99
テブオコナゾール(97%) 0.75
IPBC(98%) 1.2
トリアダメドン(97%) 0.75
Dehscofix CO130F(登録商標)(4OM エトキシレートひまし油界面活性剤) 11.24
EDTA四ナトリウム(45%) 1.5
安息香酸ナトリウム 22.5
水 53.07
1.17%に希釈
Dowanol DPM(登録商標)(グリコールエーテル溶媒) 4.99
テブオコナゾール(97%) 0.51
プロピコナゾール(50%) 0.51
Dehscofix CO130F(登録商標)(4OM エトキシレートひまし油界面活性剤) 5.00
ロジン酸エマルション(50%ロジン酸) 2.52
水 86.48
3.33%に希釈
Dowanol DPM(登録商標)(グリコールエーテル溶媒) 5.00
テブオコナゾール(97%) 0.51
IPBC(98%) 0.51
プロピコナゾール(50%) 0.51
Dehscofix CO130F(登録商標)(4OM エトキシレートひまし油界面活性剤) 4.99
ロジン酸エマルション(50%ロジン酸) 2.52
水 85.96
3.33%に希釈
Dowanol DPM(登録商標)(グリコールエーテル溶媒) 8.99
テブコナゾール(97%) 1
IPBC(98%) 1.2
プロピコナゾール(50%) 1.04
Dehscofix CO130F(登録商標)(4OM エトキシレートひまし油界面活性剤) 11.24
EDTA四ナトリウム(45%) 1.5
亜硝酸ナトリウム 18.5
水 56.53
1.17%に希釈
Dowanol DPM(登録商標)(グリコールエーテル溶媒) 5.00
テブオコナゾール(97%) 0.35
IPBC(98%) 0.39
プロピコナゾール(50%) 0.66
Dehscofix CO130F(登録商標)(4OM エトキシレートひまし油界面活性剤) 5.05
スチレン−アクリル樹脂 9.99
水 78.56
3.33%に希釈
Dowanol DPM(登録商標)(グリコールエーテル溶媒) 4.98
テブオコナゾール(97%) 0.35
IPBC(98%) 0.39
プロピコナゾール(50%) 0.66
Dehscofix CO130F(登録商標)(4OM エトキシレートひまし油界面活性剤) 4.98
酸化鉄顔料 0.50
水 88.15
3.33%に希釈
Dowanol DPM(登録商標)(グリコールエーテル溶媒) 4.98
テブオコナゾール(97%) 0.35
IPBC(98%) 0.39
プロピコナゾール(50%) 0.66
Uradil AZ543(登録商標)(水溶性アルキド樹脂) 4.98
アニラジン 0.35
水 88.15
3.33%に希釈
Dowanol DPM(登録商標)(グリコールエーテル溶媒) 4.97
テブオコナゾール(97%) 0.50
IPBC(98%) 0.51
プロピコナゾール(50%) 0.51
Dehscofix CO130F(登録商標)(4OM エトキシレートひまし油界面活性剤) 4.96
HAL*(4−ヒドロキシ−2,2,6,6−テトラメチルピペリジノキシル)
0.29
水 88.27
3.33%に希釈
*HAL=ヒンダードアミン系光捕捉剤(Hindered amine light scavenger)
Dowanol DPM(登録商標)(グリコールエーテル溶媒) 4.98
テブオコナゾール(97%) 0.35
IPBC(98%) 0.39
プロピコナゾール(50%) 0.66
Uradil AZ543(登録商標)(水溶性アルキド樹脂) 4.98
二酸化チタン顔料 0.50
水 88.15
3.33%に希釈
Dowanol DPM(登録商標)(グリコールエーテル溶媒) 4.61
テブオコナゾール(97%) 0.47
IPBC(98%) 0.47
プロピコナゾール(50%) 0.48
Dehscofix CO130F(登録商標)(4OM エトキシレートひまし油界面活性剤) 4.61
Vantocil IB(登録商標)(20% PHMB) 11.08
水 78.27
3.33%に希釈
Dowanol DPM(登録商標)(グリコールエーテル溶媒) 4.95
テブオコナゾール(97%) 0.50
IPBC(98%) 0.50
Barlene 12C(アミン) 2.39
プロピオン酸 1.48
プロピコナゾール(50%) 0.50
Dehscofix CO130F(登録商標)(4OM エトキシレートひまし油界面活性剤) 4.95
水 84.72
3.33%に希釈
Dowanol DPM(登録商標)(グリコールエーテル溶媒) 5.00
テブオコナゾール(97%) 0.35
プロピコナゾール(50%) 0.66
Uradil AZ543(登録商標)(水溶性アルキド樹脂) 5.00
Ethoduomeen T13(登録商標) 1.34
水 87.65
3.33%に希釈
(実施例2)
IPBC(98%) 1.11
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
水 78.84
IPBC(98%) 1.11
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
安息香酸ナトリウム 22.5
水 56.34
IPBC(98%) 1.11
界面活性剤 30.05
Dowanol DPM(登録商標) 16.6
アビエチン酸 3.76
水 48.48
テブコナゾール(95%) 1.5
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
水 78.45
プロピコナゾール(50%) 3
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
水 76.95
トリアジメホン(95%) 1.5
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
水 78.45
イマザリル(97.5%) 1.5
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
水 78.45
テブコナゾール(95%) 1
プロピコナゾール(50%) 1
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
水 77.95
テブコナゾール(95%) 0.75
トリアジメホン(95%) 0.75
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
水 78.45
テブコナゾール(95%) 1.5
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
安息香酸ナトリウム 22.5
水 55.95
プロピコナゾール(50%) 3
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
安息香酸ナトリウム 22.5
水 54.45
トリアジメホン(95%) 1.5
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
安息香酸ナトリウム 22.5
水 55.95
イマザリル(97.5%) 1.5
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
安息香酸ナトリウム 22.5
水 55.95
テブコナゾール(95%) 1
プロピコナゾール(50%) 1
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
安息香酸ナトリウム 22.5
水 55.45
テブコナゾール(95%) 0.75
トリアジメホン(95%) 0.75
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
安息香酸ナトリウム 22.5
水 55.95
IPBC(98%) 1.11
プロピコナゾール(50%) 3
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
水 75.84
IPBC(98%) 1.11
プロピコナゾール(50%) 3
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
水 75.84
IPBC(98%) 1.11
イマザリル(97.5%) 1.5
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
水 77.34
IPBC(98%) 1.11
テブコナゾール(95%) 1
プロピコナゾール(50%) 1
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
水 76.84
IPBC(98%) 1.11
テブコナゾール(95%) 0.75
トリアジメホン(95%) 0.75
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
水 77.34
IPBC(98%) 1.11
プロピコナゾール(50%) 3
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
安息香酸ナトリウム 22.5
水 53.34
IPBC(98%) 1.11
プロピコナゾール(50%) 3
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
安息香酸ナトリウム 22.5
水 53.34
IPBC(98%) 1.11
プロピコナゾール(50%) 3
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
安息香酸ナトリウム 22.5
水 53.34
IPBC(98%) 1.11
プロピコナゾール(50%) 3
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
安息香酸ナトリウム 22.5
水 53.34
IPBC(98%) 1.11
テブコンゾール(95%) 0.75
トリアジメホン(95%) 0.75
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
安息香酸ナトリウム 22.5
水 54.84
IPBC(98%) 1.11
テブコンゾール(95%) 1.5
界面活性剤 30.05
Dowanol DPM(登録商標) 16.6
アビエチン酸 3.76
水 46.98
IPBC(98%) 1.11
プロピコナゾール(50%) 3
界面活性剤 30.05
Dowanol DPM(登録商標) 16.6
アビエチン酸 3.76
水 45.48
IPBC(98%) 1.11
トリアジメホン(95%) 1.5
界面活性剤 30.05
Dowanol DPM(登録商標) 16.6
アビエチン酸 3.76
水 46.98
テブコンゾール(95%) 1.5
界面活性剤 30.05
Dowanol DPM(登録商標) 16.6
アビエチン酸 3.76
水 48.09
プロピコナゾール(50%) 3
界面活性剤 30.05
Dowanol DPM(登録商標) 16.6
アビエチン酸 3.76
水 46.59
トリアジメホン(95%) 1.5
界面活性剤 30.05
Dowanol DPM(登録商標) 16.6
アビエチン酸 3.76
水 48.09
IPBC(98%) 1.11
テブコンゾール(95%) 1
プロピコナゾール(50%) 1
界面活性剤 30.05
Dowanol DPM(登録商標) 16.6
サリチル酸ナトリウム 3.76
水 46.48
IPBC(98%) 1.11
テブコンゾール(95%) 1
プロピコナゾール(50%) 1
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
ソルビン酸カリウム 22.5
水 54.34
IPBC(98%) 1.11
テブコンゾール(95%) 1
プロピコナゾール(50%) 1
界面活性剤 11.25
Dowanol DPM(登録商標) 8.8
ロジン酸エマルション(50%) 7.57
水 69.27
IPBC(98%) 1.11
テブコンゾール(95%) 1
プロピコナゾール(50%) 1
界面活性剤 28.02
Dowanol DPM(登録商標) 46.1
ソルビン酸 3.76
水 19.01
IPBC(98%) 1.11
テブコンゾール(95%) 1
プロピコナゾール(50%) 1
界面活性剤 28.02
Dowanol DPM(登録商標) 46.1
オレイン酸 3.76
水 19.01
(実施例3)
IPBC(98%) 1.11
テブコナゾール(95%) 1.5
界面活性剤 11.25
溶媒 8.8
安息香酸ナトリウム 22.5
水 54.84
IPBC(98%) 1.11
テブコンゾール(95%) 1
プロピコナゾール(50%) 1
界面活性剤 30.05
溶媒 16.6
リノール酸 3.76
水 46.48
IPBC(98%) 1.11
テブコンゾール(95%) 1
プロピコナゾール(50%) 1
界面活性剤 28.02
溶媒 46.1
フマル酸 3.76
水 19.01
C12ジメチルアミン(100% a.i.) 10.0%w/w
C12ジプロピオン酸アミン(35% a.i) 20
IPBC(98% a.i.) 2.1
プロピコナゾール(50% a.i.) 0.8
Dowanol DPM(登録商標) 12
プロピオン酸 3.4
40モルのエトキシ化ひまし油 10
安息香酸ナトリウム 5
消泡剤 0.2
水 100になるまで
C12ジプロピオン酸アミン(35% a.i.) 20%w/w
C12ジメチルアミン(100% a.i.) 10
IPBC(98% a.i.) 2.1
プロピコナゾール(50% a.i.) 0.8
Dowanol DPM 12
プロピオン酸 3.4
40モルのエトキシ化ひまし油 10
C12酸化アミン(30% a.i) 3.0
安息香酸ナトリウム 5
消泡剤 0.2
水 100になるまで
Claims (26)
- ハロアルキニル化合物、アゾール、及び不飽和のカルボン酸若しくはスルホン酸又はその塩若しくは前駆物質、を含む抗変色菌(antisapstain)組成物。
- 前記ハロプロピニル化合物が、3−ヨード−2−プロピニルプロピルカルバマート、3−ヨード−2−プロピニルブチルカルバマート、3−ヨード−2−プロピニルヘキシルカルバマート、3−ヨード−2−プロピニルシクロヘキシルカルバマート、3−ヨード−2−プロピニルフェニルカルバマート、及びこれらの混合物から選択される、請求項3に記載の組成物。
- 前記ハロプロピニル化合物が3−ヨード−2−プロピニルブチルカルバマート(IPBC)である、請求項4に記載の組成物。
- 前記不飽和のカルボン酸若しくはスルホン酸又はその塩若しくは前駆物質が、不飽和環式カルボン酸又はその塩若しくは前駆物質である、先行する請求項のいずれかに記載の組成物。
- 前記不飽和のカルボン酸若しくはスルホン酸又はその塩若しくは前駆物質が、芳香族酸又はその塩若しくは前駆物質である、請求項1〜5のいずれか一項に記載の組成物。
- 前記芳香族酸又はその塩が安息香酸及び安息香酸ナトリウムから選択される、請求項8に記載の組成物。
- 前記環式カルボン酸が樹脂酸又はその塩である、請求項6に記載の組成物。
- 前記樹脂酸又はその塩が、アビエチン酸、アビエチン酸ナトリウム、ピマル酸、及びピマル酸ナトリウムから選択される、請求項10に記載の組成物。
- 前記不飽和のカルボン酸若しくはスルホン酸又はその塩若しくは又は前駆物質が、直鎖不飽和酸又はその塩若しくは前駆物質である、請求項1〜5のいずれか一項に記載の組成物。
- 前記不飽和酸又はその塩若しくは前駆物質が少なくとも4個の炭素原子を有する、請求項12に記載の組成物。
- 前記不飽和酸又はその塩若しくは前駆物質が、ソルビン酸、ソルビン酸ナトリウム、ソルビン酸カリウム、ミリストレイン酸、パルミトレイン酸、オレイン酸、エライジン酸、リノール酸、α−リノレン酸、アラキドン酸、エイコサペンタエン酸、エウリン酸、ドコサヘキサン酸、フマル酸、マレイン酸、無水マレイン酸、及びこれらの混合物から選択される、請求項12に記載の組成物。
- 前記不飽和酸又はその塩若しくは又は前駆物質が、ソルビン酸、ソルビン酸ナトリウム、及びソルビン酸カリウムから選択される、請求項14に記載の組成物。
- 前記アゾール化合物が、イミダゾール、1,2,4−トリアゾール、又は両者の混合物である、先行する請求項のいずれかに記載の組成物。
- 前記イミダゾールがベンズイミダゾールである、請求項16に記載の組成物。
- 前記イミダゾールが、チアベンダゾール、イマザリル、カルベンダジム、及びプロクロラズから選択される、請求項17に記載の組成物。
- 前記1,2,4−トリアゾールが、
式(VI)の化合物:
式(VII)の化合物:
あるいは、トリアジメホン、トリアジメノール、トリアズブチル、シプロコナゾール、ジフェノコナゾール、フルキンコナゾール、フルシラゾール、ウニコナゾール、ジニコナゾール、ビテルタノール、ヘキサコナゾール、フルトリアホール、エポキシコナゾール、テトラコナゾール、ペンコナゾール、及びこれらの混合物を含む群から選択される、請求項16〜18のいずれか一項に記載の組成物。 - 前記1,2,4−トリアゾールが、トリアジメホン、トリアジメノール、トリアズブチル、プロピコナゾール、シプロコナゾール、ジフェノコナゾール、フルキンコナゾール、テブコナゾール、フルシラゾール、ウニコナゾール、ジニコナゾール、ビテルタノール、ヘキサコナゾール、アザコナゾール、フルトリアホール、エポキシコナゾール、テトラコナゾール、ペンコナゾール、及びこれらの混合物から選択される、請求項19に記載の組成物。
- 前記1,2,4−トリアゾールが、プロピコナゾール、アザコナゾール、ヘキサコナゾール、テブコナゾール、シプロコナゾール、トリアジメホン、及びこれらの混合物から選択される、請求項19又は20に記載の組成物。
- 前記組成物が液体の形態である、先行する請求項のいずれかに記載の組成物。
- 前記組成物がエマルションである、請求項22に記載の組成物。
- 木材その他のセルロース材料の基材を保護する方法であって、先行する請求項のいずれか一項に記載の組成物を基材に塗布すること、あるいは基材が先行する請求項のいずれかに記載の組成物を効果的に受け取るように個々の成分を基材に塗布することを含む、方法。
- 請求項1〜23のいずれか一項に記載の組成物で処理された木材その他のセルロース材料で構成される基材。
- ハロアルキニル化合物、アゾール、及び不飽和のカルボン酸若しくはスルホン酸又はその塩若しくは又は前駆物質を含む、木材その他のセルロース材料の基材。
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JP2020090545A (ja) * | 2015-07-30 | 2020-06-11 | 住化エンバイロメンタルサイエンス株式会社 | 木材用抗菌組成物 |
JP2020090546A (ja) * | 2020-03-03 | 2020-06-11 | 住化エンバイロメンタルサイエンス株式会社 | 木材用抗菌組成物 |
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JP2013507347A (ja) * | 2009-10-08 | 2013-03-04 | タイガ ポリマーズ オーワイ | 抗微生物組成物 |
JP2016500680A (ja) * | 2012-10-12 | 2016-01-14 | アーチ・ケミカルズ・インコーポレーテッド | 鉄キレーターを含む殺生物性組成物 |
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JP2022502395A (ja) * | 2018-09-27 | 2022-01-11 | 0903608 ビー シー リミテッド | 相乗的駆除組成物及び活性成分の送達方法 |
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JP2016094400A (ja) | 2016-05-26 |
NZ588690A (en) | 2012-11-30 |
CN102202510B (zh) | 2015-05-20 |
GB0807905D0 (en) | 2008-06-04 |
KR20110013407A (ko) | 2011-02-09 |
GB2459691B (en) | 2013-05-22 |
WO2009133374A3 (en) | 2011-06-23 |
AU2009241641A1 (en) | 2009-11-05 |
CN102202510A (zh) | 2011-09-28 |
AU2009241641B2 (en) | 2014-03-13 |
EP2282637B1 (en) | 2015-06-17 |
RU2489252C2 (ru) | 2013-08-10 |
GB2459691A (en) | 2009-11-04 |
EP2282637A2 (en) | 2011-02-16 |
WO2009133374A2 (en) | 2009-11-05 |
US8435643B2 (en) | 2013-05-07 |
MX2010011577A (es) | 2011-05-30 |
CA2722770C (en) | 2015-02-17 |
CA2722770A1 (en) | 2009-11-05 |
KR20160054029A (ko) | 2016-05-13 |
NZ602993A (en) | 2014-05-30 |
RU2010147324A (ru) | 2012-06-10 |
US20110111245A1 (en) | 2011-05-12 |
JP5906084B2 (ja) | 2016-04-20 |
BRPI0911776A2 (pt) | 2015-08-04 |
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