JP2010516853A - 陰イオン交換膜 - Google Patents
陰イオン交換膜 Download PDFInfo
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- JP2010516853A JP2010516853A JP2009546810A JP2009546810A JP2010516853A JP 2010516853 A JP2010516853 A JP 2010516853A JP 2009546810 A JP2009546810 A JP 2009546810A JP 2009546810 A JP2009546810 A JP 2009546810A JP 2010516853 A JP2010516853 A JP 2010516853A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/12—Chemical modification
- C08J7/16—Chemical modification with polymerisable compounds
- C08J7/18—Chemical modification with polymerisable compounds using wave energy or particle radiation
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
- C08J5/2218—Synthetic macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
- C08J5/2218—Synthetic macromolecular compounds
- C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
- C08J5/2218—Synthetic macromolecular compounds
- C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
- C08J5/2243—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/103—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having nitrogen, e.g. sulfonated polybenzimidazoles [S-PBI], polybenzimidazoles with phosphoric acid, sulfonated polyamides [S-PA] or sulfonated polyphosphazenes [S-PPh]
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
- H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. insitu polymerisation or insitu crosslinking
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2353/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0082—Organic polymers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Abstract
Description
全ポリマーおよび試薬を、受領したまま使用した。低密度ポリエチレン(LDPE)(公称厚さ50μm)をBPI Filmsにより供給し、高密度ポリエチレン(HDPE)(公称厚さ40μm)をMetal Box Co.により供給した。4−ビニルベンジルクロライド(VBC)を、0.05%のtert−ブチルカテコールおよび0.05%のニトロパラフィンを用いて安定化してAldrich(登録商標)により供給した。4−ビニルピリジン(VPy)(95%)を、100ppmヒドロキノンを用いて安定してAldrich(登録商標)により供給した。<50μScm−1の伝導性を備える脱塩水は、混合床Elgastat(登録商標)から供給した。トルエンおよびメタノールは、Fisher Scientific(英国)(SLR等級)により供給した。5M塩酸Analar滴定液を、Merck(登録商標)により供給した。トリメチルアミン(TMA)(50重量%の水溶液)、トリエチルアミン(TEA)(99.5%)、2−クロロアセトアミド(2−CA)およびジメチルホルムアミド(DMF)を、Aldrich(登録商標)により供給した。
Claims (20)
- 陰イオン交換膜を調製するための方法であって、炭化水素ポリマーフィルムを選択する工程、モノマーを用いて炭化水素ポリマーフィルムを放射線グラフトする工程、およびイオン伝導性を付与するために四級化剤を加える工程を含み、モノマーはモノマー/希釈剤混合物の形態で提示され、希釈剤はアルコールおよび炭化水素溶媒を含む方法。
- 任意のホモポリマーを除去するために適切な溶媒中で陰イオン交換膜を洗浄する工程、および一定重量へ乾燥させる工程をさらに含む、請求項1に記載の方法。
- モノマー/希釈剤混合物は、少なくとも10容積%のアルコールを含む、請求項1または2に記載の方法。
- アルコールは、メタノールを含む、請求項1から3のいずれか一項に記載の方法。
- 炭化水素溶媒は、芳香族炭化水素および脂肪族炭化水素からなる群より選択される、請求項1から4のいずれか一項に記載の方法。
- 炭化水素溶媒は、トルエン、キシレンおよびベンゼンからなる群より選択される、請求項5に記載の方法。
- モノマー/希釈剤混合物のモノマー含量は、60容積%未満である、請求項1から6のいずれか一項に記載の方法。
- モノマー/希釈剤混合物のモノマー含量は、30容積%から50容積%である、請求項7に記載の方法。
- モノマーは、ビニルベンゼンクロライド(VBC)およびビニルピリジン(VPy)からなる群より選択される、請求項1から8のいずれか一項に記載の方法。
- 炭化水素ポリマーフィルムは、低密度ポリエチレン(LDPE)および高密度ポリエチレン(HDPE)からなる群より選択される、請求項1から9のいずれか一項に記載の方法。
- 放射線グラフト工程は、相互グラフト法である、請求項1から10のいずれか一項に記載の方法。
- 放射線グラフト工程は、後照射グラフト法である、請求項1から10のいずれか一項に記載の方法。
- 四級化剤は、アミン類からなる群より選択される、請求項1から12のいずれか一項に記載の方法。
- 四級化剤は、アルキルアミン類からなる群より選択される、請求項13に記載の方法。
- 四級化剤は、トリメチルアミン(TMA)およびトリエチルアミン(TEA)からなる群より選択される、請求項14に記載の方法。
- 四級化剤は、塩酸(HCl)、2−クロロアセトアミド(2−CA)、およびジメチルホルムアミド(DMF)からなる群より選択される、請求項1から12のいずれか一項に記載の方法。
- 四級化剤は、架橋剤である、請求項1から16のいずれか一項に記載の方法。
- 添付図面を参照して上記で説明した陰イオン交換膜を実質的に調製するための方法。
- 請求項1から18に記載の方法によって調製された陰イオン交換膜。
- 請求項19に記載の陰イオン交換膜を組み込んでいるアルカリ型燃料電池。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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GBGB0701449.1A GB0701449D0 (en) | 2007-01-26 | 2007-01-26 | Anion Exchange Membranes |
PCT/GB2008/000253 WO2008090351A1 (en) | 2007-01-26 | 2008-01-25 | Anion exchange membranes |
Publications (2)
Publication Number | Publication Date |
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JP2010516853A true JP2010516853A (ja) | 2010-05-20 |
JP2010516853A5 JP2010516853A5 (ja) | 2011-03-10 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2009546810A Pending JP2010516853A (ja) | 2007-01-26 | 2008-01-25 | 陰イオン交換膜 |
Country Status (8)
Country | Link |
---|---|
US (2) | US20100062313A1 (ja) |
EP (2) | EP2468804A1 (ja) |
JP (1) | JP2010516853A (ja) |
CN (1) | CN101622305A (ja) |
AU (1) | AU2008208749A1 (ja) |
CA (1) | CA2676100A1 (ja) |
GB (3) | GB0701449D0 (ja) |
WO (1) | WO2008090351A1 (ja) |
Cited By (7)
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WO2013111583A1 (ja) * | 2012-01-25 | 2013-08-01 | 日東電工株式会社 | アニオン交換膜およびその製造方法ならびにそれを用いた燃料電池 |
KR101394417B1 (ko) * | 2012-09-06 | 2014-05-14 | 한국원자력연구원 | 방사선 그라프트 방법으로 비닐벤질 클로라이드가 그라프트된 탄화수소계 필름을 이용한 연료전지막 제조 방법 |
WO2014103338A1 (ja) | 2012-12-28 | 2014-07-03 | 日東電工株式会社 | アニオン交換膜の製造方法、燃料電池用膜-電極接合体および燃料電池 |
WO2014103335A1 (ja) | 2012-12-28 | 2014-07-03 | 日東電工株式会社 | 燃料電池用膜-電極接合体とその製造方法および燃料電池 |
JP5656201B2 (ja) * | 2010-04-27 | 2015-01-21 | Agcエンジニアリング株式会社 | 陰イオン交換膜およびその製造方法 |
WO2016002227A1 (ja) * | 2014-07-03 | 2016-01-07 | 日東電工株式会社 | 液体燃料電池用隔膜及びそれを備えた膜-電極接合体 |
KR20170020848A (ko) | 2014-06-13 | 2017-02-24 | 닛토덴코 가부시키가이샤 | 음이온 교환형 전해질막, 그것을 구비한 연료 전지용의 막-전극 접합체 및 연료 전지 |
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US8703831B2 (en) | 2009-08-26 | 2014-04-22 | Evoqua Water Technologies Pte. Ltd. | Ion exchange membranes |
GB201015859D0 (en) | 2010-09-21 | 2010-10-27 | Imp Innovations Ltd | Regenerative fuel cells |
WO2012051610A1 (en) | 2010-10-15 | 2012-04-19 | Siemens Industry, Inc. | Process for making a monomer solution for making cation exchange membranes |
ES2768330T3 (es) | 2010-10-15 | 2020-06-22 | Evoqua Water Tech Llc | Membranas de intercambio aniónico y proceso para su producción |
CN102255089A (zh) * | 2011-04-25 | 2011-11-23 | 大连理工大学 | 杂环聚合物碱性阴离子交换膜及其制备方法 |
CN102867929B (zh) * | 2011-07-05 | 2014-10-15 | 中国科学院大连化学物理研究所 | 一种复合阴离子交换膜及其制备和应用 |
WO2014012188A1 (en) | 2012-07-20 | 2014-01-23 | Zhongwei Chen | Highly ion-conductive nano-engineered porous electrolytic composite membrane for alkaline electrochemical energy systems |
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CN104837542B (zh) | 2012-10-11 | 2017-04-05 | 伊沃夸水处理技术有限责任公司 | 涂覆的离子交换膜 |
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- 2007-01-26 GB GBGB0701449.1A patent/GB0701449D0/en not_active Ceased
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2008
- 2008-01-25 US US12/523,533 patent/US20100062313A1/en not_active Abandoned
- 2008-01-25 AU AU2008208749A patent/AU2008208749A1/en not_active Abandoned
- 2008-01-25 CA CA002676100A patent/CA2676100A1/en not_active Abandoned
- 2008-01-25 EP EP12000508A patent/EP2468804A1/en not_active Withdrawn
- 2008-01-25 GB GB0912364.7A patent/GB2458079B/en not_active Expired - Fee Related
- 2008-01-25 JP JP2009546810A patent/JP2010516853A/ja active Pending
- 2008-01-25 CN CN200880002997A patent/CN101622305A/zh active Pending
- 2008-01-25 WO PCT/GB2008/000253 patent/WO2008090351A1/en active Application Filing
- 2008-01-25 GB GB1119902.3A patent/GB2483807B/en not_active Expired - Fee Related
- 2008-01-25 EP EP08701926A patent/EP2125940B1/en not_active Not-in-force
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2012
- 2012-02-28 US US13/406,589 patent/US20120220673A1/en not_active Abandoned
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Cited By (9)
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JP5656201B2 (ja) * | 2010-04-27 | 2015-01-21 | Agcエンジニアリング株式会社 | 陰イオン交換膜およびその製造方法 |
WO2013111583A1 (ja) * | 2012-01-25 | 2013-08-01 | 日東電工株式会社 | アニオン交換膜およびその製造方法ならびにそれを用いた燃料電池 |
KR101394417B1 (ko) * | 2012-09-06 | 2014-05-14 | 한국원자력연구원 | 방사선 그라프트 방법으로 비닐벤질 클로라이드가 그라프트된 탄화수소계 필름을 이용한 연료전지막 제조 방법 |
WO2014103338A1 (ja) | 2012-12-28 | 2014-07-03 | 日東電工株式会社 | アニオン交換膜の製造方法、燃料電池用膜-電極接合体および燃料電池 |
WO2014103335A1 (ja) | 2012-12-28 | 2014-07-03 | 日東電工株式会社 | 燃料電池用膜-電極接合体とその製造方法および燃料電池 |
US9620802B2 (en) | 2012-12-28 | 2017-04-11 | Nitto Denko Corporation | Fuel cell membrane electrode assembly and method for producing the same, and fuel cell |
KR20170020848A (ko) | 2014-06-13 | 2017-02-24 | 닛토덴코 가부시키가이샤 | 음이온 교환형 전해질막, 그것을 구비한 연료 전지용의 막-전극 접합체 및 연료 전지 |
US9692072B2 (en) | 2014-06-13 | 2017-06-27 | Nitto Denko Corporation | Anion exchange electrolyte membrane, membrane-electrode assembly for fuel cell including the same, and fuel cell including the same |
WO2016002227A1 (ja) * | 2014-07-03 | 2016-01-07 | 日東電工株式会社 | 液体燃料電池用隔膜及びそれを備えた膜-電極接合体 |
Also Published As
Publication number | Publication date |
---|---|
GB2483807A (en) | 2012-03-21 |
EP2468804A1 (en) | 2012-06-27 |
GB0701449D0 (en) | 2007-03-07 |
AU2008208749A1 (en) | 2008-07-31 |
CN101622305A (zh) | 2010-01-06 |
US20120220673A1 (en) | 2012-08-30 |
GB201119902D0 (en) | 2011-12-28 |
EP2125940B1 (en) | 2012-08-01 |
GB2458079B (en) | 2012-04-25 |
WO2008090351A1 (en) | 2008-07-31 |
GB2483807B (en) | 2012-06-13 |
WO2008090351A8 (en) | 2009-06-18 |
EP2125940A1 (en) | 2009-12-02 |
GB2458079A (en) | 2009-09-09 |
CA2676100A1 (en) | 2008-07-31 |
GB0912364D0 (en) | 2009-08-26 |
US20100062313A1 (en) | 2010-03-11 |
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