JP2010513355A5 - - Google Patents
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- Publication number
- JP2010513355A5 JP2010513355A5 JP2009541881A JP2009541881A JP2010513355A5 JP 2010513355 A5 JP2010513355 A5 JP 2010513355A5 JP 2009541881 A JP2009541881 A JP 2009541881A JP 2009541881 A JP2009541881 A JP 2009541881A JP 2010513355 A5 JP2010513355 A5 JP 2010513355A5
- Authority
- JP
- Japan
- Prior art keywords
- solvent
- catalyst
- acid
- xylene
- promoter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 claims description 7
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052783 alkali metal Inorganic materials 0.000 claims description 5
- 150000001340 alkali metals Chemical class 0.000 claims description 5
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 5
- 239000002904 solvent Substances 0.000 claims 5
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims 4
- GWQYPLXGJIXMMV-UHFFFAOYSA-M 1-ethyl-3-methylimidazol-3-ium;bromide Chemical group [Br-].CCN1C=C[N+](C)=C1 GWQYPLXGJIXMMV-UHFFFAOYSA-M 0.000 claims 3
- 238000006243 chemical reaction Methods 0.000 claims 3
- 230000001590 oxidative effect Effects 0.000 claims 3
- 239000002253 acid Substances 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims 2
- IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 claims 2
- 239000007800 oxidant agent Substances 0.000 claims 2
- 239000001301 oxygen Substances 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 claims 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- MZZUATUOLXMCEY-UHFFFAOYSA-N cobalt manganese Chemical compound [Mn].[Co] MZZUATUOLXMCEY-UHFFFAOYSA-N 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 239000007791 liquid phase Substances 0.000 claims 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 3
- 229910052792 caesium Inorganic materials 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- LPNBBFKOUUSUDB-UHFFFAOYSA-N p-toluic acid Chemical compound CC1=CC=C(C(O)=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-N 0.000 description 2
- GOUHYARYYWKXHS-UHFFFAOYSA-N 4-formylbenzoic acid Chemical compound OC(=O)C1=CC=C(C=O)C=C1 GOUHYARYYWKXHS-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- ZOAIGCHJWKDIPJ-UHFFFAOYSA-M caesium acetate Chemical compound [Cs+].CC([O-])=O ZOAIGCHJWKDIPJ-UHFFFAOYSA-M 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06026566 | 2006-12-21 | ||
| EP06026566.7 | 2006-12-21 | ||
| PCT/EP2007/011213 WO2008074497A1 (en) | 2006-12-21 | 2007-12-18 | Process for preparing aromatic polycarboxylic acid by liquid phase oxidation |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010513355A JP2010513355A (ja) | 2010-04-30 |
| JP2010513355A5 true JP2010513355A5 (enExample) | 2016-02-04 |
| JP5897243B2 JP5897243B2 (ja) | 2016-03-30 |
Family
ID=38092980
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009541881A Expired - Fee Related JP5897243B2 (ja) | 2006-12-21 | 2007-12-18 | 液相酸化により芳香族ポリカルボン酸を調製する方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7985875B2 (enExample) |
| EP (1) | EP2125686B1 (enExample) |
| JP (1) | JP5897243B2 (enExample) |
| KR (1) | KR20090101265A (enExample) |
| CN (1) | CN101589013B (enExample) |
| ES (1) | ES2625604T3 (enExample) |
| WO (1) | WO2008074497A1 (enExample) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102060686B (zh) * | 2009-11-18 | 2014-08-06 | 中国科学院大连化学物理研究所 | 以含氮杂环化合物作为氧化促进剂生产芳香羧酸的方法 |
| US8884055B2 (en) * | 2010-06-30 | 2014-11-11 | Uop Llc | Process for producing terephthalic acid |
| US9045407B2 (en) * | 2010-06-30 | 2015-06-02 | Uop Llc | Mixtures used in oxidizing alkyl aromatic compounds |
| US8754254B2 (en) * | 2010-06-30 | 2014-06-17 | Uop Llc | Process for purifying terephthalic acid |
| US8884054B2 (en) * | 2010-06-30 | 2014-11-11 | Uop Llc | Process for oxidizing alkyl aromatic compounds |
| US8933266B2 (en) * | 2010-06-30 | 2015-01-13 | Uop Llc | Process for producing terephthalic acid |
| US8835678B2 (en) * | 2010-06-30 | 2014-09-16 | Uop Llc | Solid terephthalic acid composition |
| US8933265B2 (en) * | 2010-06-30 | 2015-01-13 | Uop Llc | Process for oxidizing alkyl aromatic compounds |
| CN102633630A (zh) * | 2011-02-15 | 2012-08-15 | 中国石油化工股份有限公司 | 一种高纯度对苯二甲酸的制备方法 |
| CN103012120A (zh) * | 2011-09-27 | 2013-04-03 | 中国石油化工股份有限公司 | 一种氧化精制法制取对苯二甲酸的方法 |
| US9085522B2 (en) | 2011-12-29 | 2015-07-21 | Uop Llc | Process for producing terephthalic acid |
| US9045408B2 (en) * | 2011-12-29 | 2015-06-02 | Uop Llc | Process for oxidizing alkyl-aromatic compounds |
| US8927764B2 (en) * | 2011-12-29 | 2015-01-06 | Uop Llc | Process for producing terephthalic acid |
| US8946471B2 (en) * | 2011-12-29 | 2015-02-03 | Uop Llc | Process for oxidizing an alkyl-aromatic compound |
| US9024059B2 (en) | 2011-12-29 | 2015-05-05 | Uop Llc | Process for producing terephthalic acid |
| US9150484B2 (en) | 2011-12-29 | 2015-10-06 | Uop Llc | Process for producing terephthalic acid |
| US8697905B2 (en) | 2011-12-29 | 2014-04-15 | Uop Llc | Process for producing terephthalic acid |
| US20130172609A1 (en) * | 2011-12-29 | 2013-07-04 | Uop Llc | Process for oxidizing an alkyl-aromatic compound |
| US8759571B2 (en) | 2011-12-29 | 2014-06-24 | Uop Llc | Process for oxidizing alkyl-aromatic compounds |
| RU2014131232A (ru) * | 2011-12-29 | 2016-02-20 | Юоп Ллк | Способ получения терефталевой кислоты |
| US9156765B2 (en) | 2011-12-29 | 2015-10-13 | Uop Llc | Process for oxidizing alkyl-aromatic compounds |
| US9079846B2 (en) * | 2012-10-12 | 2015-07-14 | Uop Llc | Process for oxidizing impurities in crude terephthalic acid |
| US9233905B2 (en) | 2012-12-14 | 2016-01-12 | Uop Llc | Oxidation and crystallization process for aromatic carboxylic acid production |
| WO2014181345A2 (en) | 2013-04-30 | 2014-11-13 | Reliance Industries Limited | A composition for preparing terephthalic acid |
| EP2997114B1 (en) | 2013-05-14 | 2018-10-17 | Reliance Industries Limited | Ionic liquid composition |
| US9150485B2 (en) | 2013-10-08 | 2015-10-06 | Uop Llc | Process for controlling reaction and crystallization solvent composition in process for production of aromatic carboxylic acid |
| HUE065368T2 (hu) | 2015-04-14 | 2024-05-28 | Du Pont | Eljárás 2,5-furándikabonsav és származékai elõállítására |
| EP3365319A1 (en) | 2015-10-23 | 2018-08-29 | SABIC Global Technologies B.V. | Process for producing terephthalic acid |
| CN107774316B (zh) * | 2016-08-29 | 2020-05-01 | 中国石油化工股份有限公司 | 液相氧化合成芳香多元羧酸催化剂 |
| CN107790179B (zh) * | 2016-08-29 | 2020-04-17 | 中国石油化工股份有限公司 | 液相氧化生产芳香多元羧酸的催化剂 |
| CN111068790B (zh) * | 2018-10-18 | 2023-05-02 | 中国石油化工股份有限公司 | 用于2,6-萘二甲酸合成的催化剂及其应用 |
| CN119954647A (zh) * | 2025-02-24 | 2025-05-09 | 华东理工大学 | 一种采用离子液体制备芳香羧酸的方法 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2833816A (en) * | 1954-05-03 | 1958-05-06 | Mid Century Corp | Preparation of aromatic polycarboxylic acids |
| US3947494A (en) | 1972-12-20 | 1976-03-30 | Standard Oil Company | Quality of phthalic acids improved by haloacetic acid |
| JPS5915895B2 (ja) * | 1976-02-13 | 1984-04-12 | 東洋紡績株式会社 | 芳香族カルボン酸の製造方法 |
| IL84620A (en) * | 1987-11-27 | 1992-03-29 | Gadot Petrochem Ind | Process for the manufacture of aromatic dicarboxylic acids |
| JPH04169551A (ja) * | 1990-10-31 | 1992-06-17 | Mitsui Petrochem Ind Ltd | 芳香族カルボン酸の製造方法 |
| JPH07247239A (ja) * | 1991-01-21 | 1995-09-26 | Mitsubishi Chem Corp | ２，６−ナフタレンジカルボン酸の製造方法 |
| WO2001038279A1 (en) * | 1999-11-26 | 2001-05-31 | Chemintel (India) Private Limited | Process for preparation of benzene dicarboxylic acids |
| US6924253B2 (en) * | 2000-04-07 | 2005-08-02 | Bentley J. Palmer | Scale removal |
| GB0024745D0 (en) * | 2000-10-10 | 2000-11-22 | Univ Belfast | Oxidation of alkyl-aromatic compounds |
| US6649773B2 (en) | 2002-03-22 | 2003-11-18 | General Electric Company | Method for the manufacture of halophthalic acids and anhydrides |
| JP2007531992A (ja) * | 2004-03-30 | 2007-11-08 | ビーエーエスエフ アクチェンゲゼルシャフト | エッチング残渣を除去するための水溶液 |
| US7541489B2 (en) | 2004-06-30 | 2009-06-02 | Sabic Innovative Plastics Ip B.V. | Method of making halophthalic acids and halophthalic anhydrides |
| US20060004223A1 (en) | 2004-06-30 | 2006-01-05 | General Electric Company | Method of making halophthalic acids and halophthalic anhydrides |
| EP2011782A1 (en) * | 2007-07-02 | 2009-01-07 | Huntsman International Llc | Process for the synthesis of carbamates using co2 |
-
2007
- 2007-12-18 JP JP2009541881A patent/JP5897243B2/ja not_active Expired - Fee Related
- 2007-12-18 KR KR1020097015138A patent/KR20090101265A/ko not_active Ceased
- 2007-12-18 ES ES07856936.5T patent/ES2625604T3/es active Active
- 2007-12-18 EP EP07856936.5A patent/EP2125686B1/en not_active Not-in-force
- 2007-12-18 US US12/448,386 patent/US7985875B2/en not_active Expired - Fee Related
- 2007-12-18 WO PCT/EP2007/011213 patent/WO2008074497A1/en not_active Ceased
- 2007-12-18 CN CN2007800502504A patent/CN101589013B/zh not_active Expired - Fee Related
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