JP2009539603A5 - - Google Patents
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- Publication number
- JP2009539603A5 JP2009539603A5 JP2009515477A JP2009515477A JP2009539603A5 JP 2009539603 A5 JP2009539603 A5 JP 2009539603A5 JP 2009515477 A JP2009515477 A JP 2009515477A JP 2009515477 A JP2009515477 A JP 2009515477A JP 2009539603 A5 JP2009539603 A5 JP 2009539603A5
- Authority
- JP
- Japan
- Prior art keywords
- weight
- coating composition
- silica nanoparticles
- reactive
- substrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 53
- 239000002105 nanoparticle Substances 0.000 claims description 25
- 239000000377 silicon dioxide Substances 0.000 claims description 25
- 229920000642 polymer Polymers 0.000 claims description 24
- 239000000758 substrate Substances 0.000 claims description 22
- 239000008199 coating composition Substances 0.000 claims description 16
- 239000003431 cross linking reagent Substances 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 8
- 229910000077 silane Inorganic materials 0.000 claims description 8
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 6
- 239000007822 coupling agent Substances 0.000 claims description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 6
- 238000005299 abrasion Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims description 4
- 239000004593 Epoxy Substances 0.000 claims description 4
- -1 alkoxy silane Chemical compound 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 239000002270 dispersing agent Substances 0.000 claims description 4
- 239000012948 isocyanate Substances 0.000 claims description 4
- 150000002513 isocyanates Chemical class 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 claims description 4
- 229920000058 polyacrylate Polymers 0.000 description 5
- 229920001228 polyisocyanate Polymers 0.000 description 4
- 239000005056 polyisocyanate Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical group NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical class O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- IZXIZTKNFFYFOF-UHFFFAOYSA-N 2-Oxazolidone Chemical compound O=C1NCCO1 IZXIZTKNFFYFOF-UHFFFAOYSA-N 0.000 description 1
- KMDXTDGLBCKTQX-UHFFFAOYSA-N 2-[1,2-bis(2-trimethoxysilylethyl)cyclohexyl]ethyl-trimethoxysilane Chemical compound CO[Si](OC)(OC)CCC1CCCCC1(CC[Si](OC)(OC)OC)CC[Si](OC)(OC)OC KMDXTDGLBCKTQX-UHFFFAOYSA-N 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910020175 SiOH Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 229910009257 Y—Si Inorganic materials 0.000 description 1
- 125000004423 acyloxy group Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000004104 aryloxy group Chemical group 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- OTARVPUIYXHRRB-UHFFFAOYSA-N diethoxy-methyl-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CCO[Si](C)(OCC)CCCOCC1CO1 OTARVPUIYXHRRB-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 125000005647 linker group Chemical group 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical group CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US81345806P | 2006-06-14 | 2006-06-14 | |
| US85873806P | 2006-11-14 | 2006-11-14 | |
| PCT/US2007/013912 WO2007146353A2 (en) | 2006-06-14 | 2007-06-14 | Coated substrate having enhanced scratch and mar resistance |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2009539603A JP2009539603A (ja) | 2009-11-19 |
| JP2009539603A5 true JP2009539603A5 (https=) | 2010-07-29 |
Family
ID=38657041
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009515477A Pending JP2009539603A (ja) | 2006-06-14 | 2007-06-14 | 向上した耐引掻き性及び耐摩耗性を有する塗装基材 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US8974898B2 (https=) |
| EP (1) | EP2027224A2 (https=) |
| JP (1) | JP2009539603A (https=) |
| CA (1) | CA2649178A1 (https=) |
| MX (1) | MX325549B (https=) |
| WO (1) | WO2007146353A2 (https=) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100594223C (zh) * | 2004-05-27 | 2010-03-17 | 株式会社Pi技术研究所 | 印刷用嵌段共聚聚酰亚胺油墨组合物 |
| WO2008145585A1 (de) * | 2007-05-25 | 2008-12-04 | Basf Se | Verfahren zur verteilung von silikaten in beschichtungsmassen |
| DE102007061871A1 (de) * | 2007-12-19 | 2009-06-25 | Bayer Materialscience Ag | Silan-modifizierte Bindemitteldispersion |
| US20090191407A1 (en) * | 2008-01-18 | 2009-07-30 | Lewarchik Ronald J | Coatings providing low surface emissivity |
| WO2009108574A2 (en) * | 2008-02-25 | 2009-09-03 | Honeywell International Inc. | Processable inorganic and organic polymer formulations, methods of production and uses thereof |
| WO2009131907A1 (en) * | 2008-04-22 | 2009-10-29 | E. I. Du Pont De Nemours And Company | Coating composition containing polytrimethylene ether diol |
| US7910644B2 (en) * | 2008-07-02 | 2011-03-22 | E.I. Du Pont De Nemours & Company | High film build coating composition containing polytrimethylene ether diol |
| JP5351279B2 (ja) * | 2008-12-05 | 2013-11-27 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 自己組織化シリカ縮合物 |
| EP2379656B1 (de) | 2008-12-17 | 2013-02-27 | Basf Se | Schnelltrocknende beschichtungsmassen |
| JP5382611B2 (ja) * | 2009-02-16 | 2014-01-08 | 日産自動車株式会社 | 微粒子含有軟質塗膜及び積層塗膜 |
| US8512464B2 (en) * | 2009-12-02 | 2013-08-20 | 3M Innovative Properties Company | Functionalized zirconia nanoparticles and high index films made therefrom |
| US9540479B2 (en) * | 2009-12-29 | 2017-01-10 | 3M Innovative Properties Company | Polyurethane nanocomposites |
| US20130309516A1 (en) * | 2010-10-12 | 2013-11-21 | U S Coatings Ip Co Llc | Coating composition containing polytrimethylene ether diol |
| US10655003B2 (en) | 2010-10-14 | 2020-05-19 | Lg Chem, Ltd. | Resin blend for melting process |
| US9000112B2 (en) * | 2010-10-14 | 2015-04-07 | Lg Chem, Ltd. | Resin blend for melting process |
| US9328257B2 (en) * | 2010-11-19 | 2016-05-03 | Basf Coatings Gmbh | Coating composition having a high solids content and good levelling and also multilayer surface coatings produced therefrom and their use |
| US8153711B1 (en) | 2011-03-03 | 2012-04-10 | Ayumu Yokoyama | Polyurea sag control agent in polytrimethylene ether diol |
| US20120309246A1 (en) | 2011-06-03 | 2012-12-06 | Alexander Tseitlin | Curable biopolymer nanoparticle latex binder for mineral, natural organic, or synthetic fiber products and non-woven mats |
| JP6111264B2 (ja) * | 2011-12-22 | 2017-04-05 | ナノコ テクノロジーズ リミテッド | 表面修飾ナノ粒子 |
| WO2013165650A1 (en) * | 2012-04-30 | 2013-11-07 | 3M Innovative Properties Company | High solar-reflectivity roofing granules utilizing low absorption components |
| CN103481584B (zh) * | 2012-06-11 | 2016-08-10 | 株式会社神户制钢所 | 薄膜黑色涂装金属板 |
| CN102827500B (zh) * | 2012-07-16 | 2015-09-16 | 长兴(中国)投资有限公司 | 一种抗刮且耐磨的组合物及其制备方法和应用 |
| JP2014091750A (ja) * | 2012-11-01 | 2014-05-19 | Kikusui Chemical Industries Co Ltd | コーティング剤組成物 |
| JP5696735B2 (ja) | 2013-03-25 | 2015-04-08 | 日油株式会社 | ウレタン硬化性組成物 |
| JP2016539235A (ja) | 2013-12-05 | 2016-12-15 | エコシンセティックス リミテッド | ホルムアルデヒド非含有バインダーおよび多成分ナノ粒子 |
| EP2907840B1 (en) * | 2014-02-12 | 2018-10-31 | Essilor International | Optical article comprising a hard coat, and production method |
| US10703927B2 (en) | 2014-04-10 | 2020-07-07 | 3M Innovative Properties Company | Adhesion promoting and/or dust suppression coating |
| US9120916B1 (en) * | 2014-06-12 | 2015-09-01 | Ppg Industries Ohio, Inc. | Acrylic polymers, curable film-forming compositions prepared therefrom, and method of mitigating dirt build-up on a substrate |
| US10479926B2 (en) | 2015-02-17 | 2019-11-19 | Halliburton Energy Services, Inc. | Polyamino-functionalized nanoparticles as hardeners for particulate consolidation |
| US9784079B2 (en) | 2015-06-29 | 2017-10-10 | Halliburton Energy Services, Inc. | Functionalized nanoparticles as crosslinking agents for sealant application |
| JP6615549B2 (ja) * | 2015-09-17 | 2019-12-04 | 株式会社松風 | 歯科用硬化性組成物 |
| JP6863962B2 (ja) * | 2016-03-14 | 2021-04-21 | 旭化成株式会社 | 高耐久防曇塗膜およびコーティング組成物 |
| WO2018184000A2 (en) * | 2017-03-31 | 2018-10-04 | RADCO Infusion Technologies, LLC | Organic substrates having improved weatherability and mar resistance |
| WO2019020688A1 (en) | 2017-07-26 | 2019-01-31 | Ineos Styrolution Group Gmbh | STYRENE COPOLYMER COMPOSITION HAVING ENHANCED RESIDUAL GLOSS |
| CN111511831B (zh) | 2017-07-26 | 2023-04-07 | 英力士苯领集团股份公司 | 含有无机金属化合物纳米颗粒的抗刮擦苯乙烯共聚物组合物 |
| WO2019163918A1 (ja) * | 2018-02-23 | 2019-08-29 | 旭化成株式会社 | 高耐久防曇塗膜およびコーティング組成物 |
| CN112513196B (zh) * | 2018-07-30 | 2023-01-10 | 3M创新有限公司 | 透明的弹性体纳米复合材料共混物 |
| US20200325289A1 (en) * | 2019-04-15 | 2020-10-15 | Ppg Industries Ohio, Inc. | Curable film-forming compositions containing rheology modifiers comprising non-aqueous dispersions |
| KR20220081336A (ko) * | 2019-10-09 | 2022-06-15 | 바스프 코팅스 게엠베하 | 카르복실-관능성 수지를 위한 실란-관능성 경화제, 그의 결합제 및 2k 코팅 조성물 |
| KR102212543B1 (ko) * | 2020-07-20 | 2021-02-08 | 문갑중 | 수용성 도료를 이용한 자동차의 친환경 보수도장 방법 |
| CN111944354B (zh) * | 2020-07-28 | 2022-05-24 | 荆门东方雨虹建筑材料有限公司 | 一种抗老化剂及应用和弹性体改性沥青防水卷材涂盖料及其制备方法和改性沥青防水卷材 |
| JP2023144229A (ja) * | 2022-03-28 | 2023-10-11 | 三菱ケミカル株式会社 | 樹脂組成物、塗料組成物及び硬化物 |
| CN115491073A (zh) * | 2022-09-20 | 2022-12-20 | 中国船舶重工集团公司第七二五研究所 | 一种超支化聚酯改性二氧化硅纳米线及制备方法 |
| CN116463044B (zh) * | 2023-05-15 | 2024-06-18 | 珠海光驭科技有限公司 | 光子晶体涂层组合物及薄膜和制备方法 |
| CN117304785A (zh) * | 2023-10-16 | 2023-12-29 | 广州境好新材料有限公司 | 一种水性纳米高抗刮清漆及其制备方法 |
Family Cites Families (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3585160A (en) | 1969-04-21 | 1971-06-15 | Du Pont | Polymer having pendent amino acrylate goups and pendent oxazoline ester groups useful for forming coating compositions |
| USRE31309E (en) | 1979-07-18 | 1983-07-12 | E. I. Du Pont De Nemours And Company | High solids ambient temperature curing coatings of acrylic-fatty acid drying oil resins |
| US4242243A (en) | 1979-07-18 | 1980-12-30 | E. I. Du Pont De Nemours And Company | High solids ambient temperature curing coatings of acrylic-fatty acid drying oil resins |
| US4508880A (en) | 1981-06-30 | 1985-04-02 | E. I. Du Pont De Nemours And Company | "Living" polymers and process for their preparation |
| US4692481A (en) | 1984-09-27 | 1987-09-08 | E. I. Du Pont De Nemours And Company | Process for matching color of paint to a colored surface |
| US4659780A (en) | 1985-03-18 | 1987-04-21 | E. I. Du Pont De Nemours And Company | Acrylourethane reaction product |
| US5244696A (en) | 1990-12-17 | 1993-09-14 | E. I. Du Pont De Nemours And Company | Automotive coating composition comprising an organosilane polymer |
| US5378790A (en) | 1992-09-16 | 1995-01-03 | E. I. Du Pont De Nemours & Co. | Single component inorganic/organic network materials and precursors thereof |
| DE69413713T2 (de) | 1993-12-29 | 1999-02-25 | E.I. Du Pont De Nemours And Co., Wilmington, Del. | Überzugsmittel mit hohem feststoffanteil |
| CN1088082C (zh) | 1995-06-05 | 2002-07-24 | 纳幕尔杜邦公司 | 含有硅烷官能团的涂料组合物 |
| US5853809A (en) | 1996-09-30 | 1998-12-29 | Basf Corporation | Scratch resistant clearcoats containing suface reactive microparticles and method therefore |
| ES2199319T3 (es) * | 1996-09-30 | 2004-02-16 | Basf Corporation | Capas transparentes, resistentes al rayado, que contienen microparticulas reactivas en superficie y metodo para su preparacion. |
| DE69829588T2 (de) | 1997-01-10 | 2006-01-19 | E.I. Du Pont De Nemours And Co., Wilmington | Farblose wässrige Ammoniumsulfidlösung |
| US5866259A (en) | 1997-06-30 | 1999-02-02 | Basf Corporation | Primer coating compositions containing carbamate-functional acrylic polymers |
| CA2319547A1 (en) * | 1998-02-06 | 1999-08-12 | E.I. Du Pont De Nemours And Company | Silicon reactive oligomers and coating compositions made therefrom |
| US6140445A (en) * | 1998-04-17 | 2000-10-31 | Crompton Corporation | Silane functional oligomer |
| DE19917232A1 (de) | 1999-04-16 | 2000-10-19 | Herberts Gmbh & Co Kg | Zur Mehrschichtlackierung verwendbare Überzugsmittel |
| US6221484B1 (en) | 1999-04-30 | 2001-04-24 | Flexipak Distribution | Venting tape |
| US6294492B1 (en) | 1999-06-30 | 2001-09-25 | Philips Petroleum Company | Catalytic reforming catalyst activation |
| BR0012882A (pt) | 1999-07-30 | 2002-04-09 | Ppg Ind Ohio Inc | Revestimentos curados tendo resistência ao risco melhorada, substratos revestidos e métodos a eles relacionados |
| PT1204709E (pt) * | 1999-07-30 | 2007-05-31 | Ppg Ind Ohio Inc | Composições de revestimento que têm resistência ao arranhão melhorada, substratos revestidos e métodos relacionados com eles |
| CN1209427C (zh) * | 1999-07-30 | 2005-07-06 | 匹兹堡玻璃板工业俄亥俄股份有限公司 | 具有改进抗刮性的涂料组合物、涂覆基材及其有关方法 |
| US6462125B1 (en) | 1999-12-16 | 2002-10-08 | Ppg Industries Ohio, Inc. | Pigment dispersions containing dispersants prepared by controlled radical polymerization having hydrophilic and hydrophobic segments |
| US6472463B1 (en) | 1999-12-17 | 2002-10-29 | E. I. Du Pont De Nemours And Company | Graft copolymer pigment dispersant |
| US6329489B1 (en) * | 1999-12-20 | 2001-12-11 | E. I. Du Pont De Nemours And Company | Process for producing reactive silane oligomers |
| US6451950B1 (en) | 2000-07-05 | 2002-09-17 | E. I. Du Pont De Nemours And Company | Polymeric pigment dispersants having multiple pigment anchoring groups |
| US6462144B1 (en) | 2000-12-22 | 2002-10-08 | Basf Corporation | Carbamate-functional resins and their use in high solids coating compositions |
| US6596837B2 (en) * | 2001-03-27 | 2003-07-22 | Acushnet Company | Abrasion resistant coated golf equipment |
| US6605669B2 (en) | 2001-04-03 | 2003-08-12 | E. I. Du Pont De Nemours And Company | Radiation-curable coating compounds |
| US20030050388A1 (en) | 2001-09-06 | 2003-03-13 | Strickland Debra S. | Aqueous coating composition |
| DE10150274A1 (de) | 2001-10-12 | 2003-04-30 | Wacker Chemie Gmbh | Kieselsäure mit homogener Silyliermittelschicht |
| ATE328973T1 (de) | 2002-02-20 | 2006-06-15 | Du Pont | Lacke mit hochverzweigtem copolyesterpolyol |
| US6916368B2 (en) * | 2002-02-20 | 2005-07-12 | Ppg Industries Ohio, Inc. | Curable film-forming composition exhibiting improved scratch resistance |
| US6790904B2 (en) * | 2002-06-03 | 2004-09-14 | Ppg Industries Ohio, Inc. | Liquid coating of film-forming resin and particles chemically modified to lower surface tension |
| US7585924B2 (en) | 2002-07-11 | 2009-09-08 | E. I. Du Pont De Nemours And Company | Pressurized high temperature polymerization process and polymerization system used therein |
| US6905765B2 (en) | 2002-08-09 | 2005-06-14 | E.I. Du Pont De Nemours And Company | Polyether ester elastomers comprising poly(trimethylene-ethylene ether) ester soft segment and alkylene ester hard segment |
| DE10241510A1 (de) | 2002-09-07 | 2004-03-18 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Nanokomposite, Verfahren zu ihrer Herstellung und ihre Verwendung |
| US7189768B2 (en) * | 2003-11-25 | 2007-03-13 | 3M Innovative Properties Company | Solution containing surface-modified nanoparticles |
| US20060100350A1 (en) | 2004-11-08 | 2006-05-11 | Barsotti Robert J | Rapid drying lacquers containing graft copolymers with segmented arms |
| US20060100351A1 (en) | 2004-11-08 | 2006-05-11 | Butera Robert J | Rapid drying lacquers containing impoved rheology control additive |
| EP1717278A1 (en) * | 2005-04-26 | 2006-11-02 | Nuplex Resins B.V. | Coated particles and coating compositions comprising coated particles |
-
2007
- 2007-06-14 EP EP20070809531 patent/EP2027224A2/en not_active Withdrawn
- 2007-06-14 JP JP2009515477A patent/JP2009539603A/ja active Pending
- 2007-06-14 US US11/818,460 patent/US8974898B2/en active Active
- 2007-06-14 CA CA 2649178 patent/CA2649178A1/en not_active Abandoned
- 2007-06-14 WO PCT/US2007/013912 patent/WO2007146353A2/en not_active Ceased
- 2007-06-14 MX MX2008015712A patent/MX325549B/es active IP Right Grant
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