JP2009537838A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2009537838A5 JP2009537838A5 JP2009511522A JP2009511522A JP2009537838A5 JP 2009537838 A5 JP2009537838 A5 JP 2009537838A5 JP 2009511522 A JP2009511522 A JP 2009511522A JP 2009511522 A JP2009511522 A JP 2009511522A JP 2009537838 A5 JP2009537838 A5 JP 2009537838A5
- Authority
- JP
- Japan
- Prior art keywords
- plutonium
- uranium
- aqueous phase
- phase
- neptunium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052770 Uranium Inorganic materials 0.000 claims description 147
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 claims description 146
- 239000012071 phase Substances 0.000 claims description 142
- 229910052778 Plutonium Inorganic materials 0.000 claims description 140
- OYEHPCDNVJXUIW-UHFFFAOYSA-N plutonium atom Chemical compound [Pu] OYEHPCDNVJXUIW-UHFFFAOYSA-N 0.000 claims description 139
- 239000008346 aqueous phase Substances 0.000 claims description 122
- 238000000034 method Methods 0.000 claims description 108
- 239000002904 solvent Substances 0.000 claims description 86
- 229910052781 Neptunium Inorganic materials 0.000 claims description 60
- LFNLGNPSGWYGGD-UHFFFAOYSA-N neptunium atom Chemical compound [Np] LFNLGNPSGWYGGD-UHFFFAOYSA-N 0.000 claims description 60
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 50
- 229910017604 nitric acid Inorganic materials 0.000 claims description 50
- 230000008569 process Effects 0.000 claims description 48
- 238000000605 extraction Methods 0.000 claims description 43
- 238000007254 oxidation reaction Methods 0.000 claims description 40
- 230000003647 oxidation Effects 0.000 claims description 39
- 230000004992 fission Effects 0.000 claims description 31
- 238000000658 coextraction Methods 0.000 claims description 29
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 28
- 239000000243 solution Substances 0.000 claims description 25
- AAORDHMTTHGXCV-UHFFFAOYSA-N uranium(6+) Chemical group [U+6] AAORDHMTTHGXCV-UHFFFAOYSA-N 0.000 claims description 25
- 239000003638 chemical reducing agent Substances 0.000 claims description 23
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 23
- IYQHAABWBDVIEE-UHFFFAOYSA-N [Pu+4] Chemical compound [Pu+4] IYQHAABWBDVIEE-UHFFFAOYSA-N 0.000 claims description 20
- OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine group Chemical group NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 20
- 238000005406 washing Methods 0.000 claims description 19
- 239000002915 spent fuel radioactive waste Substances 0.000 claims description 17
- ZLYXMBXMECZBSN-UHFFFAOYSA-N [Pu+3] Chemical compound [Pu+3] ZLYXMBXMECZBSN-UHFFFAOYSA-N 0.000 claims description 15
- WYOWZDGKSKEXCI-UHFFFAOYSA-N [Np+6] Chemical compound [Np+6] WYOWZDGKSKEXCI-UHFFFAOYSA-N 0.000 claims description 14
- 238000012958 reprocessing Methods 0.000 claims description 14
- 238000003860 storage Methods 0.000 claims description 14
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims description 13
- 239000003085 diluting agent Substances 0.000 claims description 13
- 239000002516 radical scavenger Substances 0.000 claims description 13
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 12
- 239000000446 fuel Substances 0.000 claims description 11
- KUKDDTFBSTXDTC-UHFFFAOYSA-N uranium;hexanitrate Chemical group [U].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O KUKDDTFBSTXDTC-UHFFFAOYSA-N 0.000 claims description 11
- 229910002007 uranyl nitrate Inorganic materials 0.000 claims description 11
- HNVACBPOIKOMQP-UHFFFAOYSA-N uranium(4+) Chemical compound [U+4] HNVACBPOIKOMQP-UHFFFAOYSA-N 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 claims description 8
- 230000009467 reduction Effects 0.000 claims description 8
- 229910052695 Americium Inorganic materials 0.000 claims description 7
- 229910052685 Curium Inorganic materials 0.000 claims description 7
- LXQXZNRPTYVCNG-UHFFFAOYSA-N americium atom Chemical compound [Am] LXQXZNRPTYVCNG-UHFFFAOYSA-N 0.000 claims description 7
- NAYOFUASDMNEMW-UHFFFAOYSA-N [Np+5] Chemical compound [Np+5] NAYOFUASDMNEMW-UHFFFAOYSA-N 0.000 claims description 6
- CRJZNQFRBUFHTE-UHFFFAOYSA-N hydroxylammonium nitrate Chemical compound O[NH3+].[O-][N+]([O-])=O CRJZNQFRBUFHTE-UHFFFAOYSA-N 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- WZECUPJJEIXUKY-UHFFFAOYSA-N [O-2].[O-2].[O-2].[U+6] Chemical compound [O-2].[O-2].[O-2].[U+6] WZECUPJJEIXUKY-UHFFFAOYSA-N 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 150000001768 cations Chemical class 0.000 claims description 5
- 230000001590 oxidative effect Effects 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- 229910000439 uranium oxide Inorganic materials 0.000 claims description 5
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 claims description 4
- 125000004429 atom Chemical group 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 238000001354 calcination Methods 0.000 claims description 4
- 238000000975 co-precipitation Methods 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 235000006408 oxalic acid Nutrition 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 claims description 4
- 229910002651 NO3 Inorganic materials 0.000 claims description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 3
- PSPBAKLTRUOTFX-UHFFFAOYSA-N [O-2].[Pu+4].[U+6].[O-2].[O-2].[O-2].[O-2] Chemical compound [O-2].[Pu+4].[U+6].[O-2].[O-2].[O-2].[O-2] PSPBAKLTRUOTFX-UHFFFAOYSA-N 0.000 claims description 3
- NIWWFAAXEMMFMS-UHFFFAOYSA-N curium atom Chemical compound [Cm] NIWWFAAXEMMFMS-UHFFFAOYSA-N 0.000 claims description 3
- -1 uranium plutonium (III) Chemical compound 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 230000006641 stabilisation Effects 0.000 claims 2
- 238000011105 stabilization Methods 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 1
- SNRUBQQJIBEYMU-NJFSPNSNSA-N dodecane Chemical group CCCCCCCCCCC[14CH3] SNRUBQQJIBEYMU-NJFSPNSNSA-N 0.000 claims 1
- 239000003758 nuclear fuel Substances 0.000 description 21
- 238000004519 manufacturing process Methods 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 238000009826 distribution Methods 0.000 description 13
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 10
- 235000019647 acidic taste Nutrition 0.000 description 10
- 238000000746 purification Methods 0.000 description 10
- 238000004140 cleaning Methods 0.000 description 9
- WJWSFWHDKPKKES-UHFFFAOYSA-N plutonium uranium Chemical compound [U].[Pu] WJWSFWHDKPKKES-UHFFFAOYSA-N 0.000 description 9
- NBSLIVIAZBZBFZ-UHFFFAOYSA-N [Np+4] Chemical compound [Np+4] NBSLIVIAZBZBFZ-UHFFFAOYSA-N 0.000 description 8
- 238000010586 diagram Methods 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 238000005202 decontamination Methods 0.000 description 7
- 230000003588 decontaminative effect Effects 0.000 description 7
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 230000002285 radioactive effect Effects 0.000 description 5
- 238000000638 solvent extraction Methods 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 239000008188 pellet Substances 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000000622 liquid--liquid extraction Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000005201 scrubbing Methods 0.000 description 3
- 229910052713 technetium Inorganic materials 0.000 description 3
- GKLVYJBZJHMRIY-UHFFFAOYSA-N technetium atom Chemical compound [Tc] GKLVYJBZJHMRIY-UHFFFAOYSA-N 0.000 description 3
- 241001044053 Mimas Species 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- HRKAMJBPFPHCSD-UHFFFAOYSA-N Tri-isobutylphosphate Chemical compound CC(C)COP(=O)(OCC(C)C)OCC(C)C HRKAMJBPFPHCSD-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 229910052729 chemical element Inorganic materials 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000006166 lysate Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- YTZKOQUCBOVLHL-UHFFFAOYSA-N tert-butylbenzene Chemical compound CC(C)(C)C1=CC=CC=C1 YTZKOQUCBOVLHL-UHFFFAOYSA-N 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- LGXAANYJEHLUEM-UHFFFAOYSA-N 1,2,3-tri(propan-2-yl)benzene Chemical compound CC(C)C1=CC=CC(C(C)C)=C1C(C)C LGXAANYJEHLUEM-UHFFFAOYSA-N 0.000 description 1
- BZJTUOGZUKFLQT-UHFFFAOYSA-N 1,3,5,7-tetramethylcyclooctane Chemical group CC1CC(C)CC(C)CC(C)C1 BZJTUOGZUKFLQT-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 150000001212 Plutonium Chemical class 0.000 description 1
- 150000001224 Uranium Chemical class 0.000 description 1
- 229910052768 actinide Inorganic materials 0.000 description 1
- 150000001255 actinides Chemical class 0.000 description 1
- RAESLDWEUUSRLO-UHFFFAOYSA-O aminoazanium;nitrate Chemical group [NH3+]N.[O-][N+]([O-])=O RAESLDWEUUSRLO-UHFFFAOYSA-O 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- RBLWMQWAHONKNC-UHFFFAOYSA-N hydroxyazanium Chemical compound O[NH3+] RBLWMQWAHONKNC-UHFFFAOYSA-N 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 229940094933 n-dodecane Drugs 0.000 description 1
- LFLZOWIFJOBEPN-UHFFFAOYSA-N nitrate, nitrate Chemical compound O[N+]([O-])=O.O[N+]([O-])=O LFLZOWIFJOBEPN-UHFFFAOYSA-N 0.000 description 1
- FGHSTPNOXKDLKU-UHFFFAOYSA-N nitric acid;hydrate Chemical compound O.O[N+]([O-])=O FGHSTPNOXKDLKU-UHFFFAOYSA-N 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000010349 pulsation Effects 0.000 description 1
- 238000011403 purification operation Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- YQLIHRFKJJQBAF-UHFFFAOYSA-N tris(3-methylbutyl) phosphate Chemical compound CC(C)CCOP(=O)(OCCC(C)C)OCCC(C)C YQLIHRFKJJQBAF-UHFFFAOYSA-N 0.000 description 1
- APPUVMLQTFWVKR-UHFFFAOYSA-N uranium(5+) Chemical compound [U+5] APPUVMLQTFWVKR-UHFFFAOYSA-N 0.000 description 1
- 238000004017 vitrification Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR06/04717 | 2006-05-24 | ||
FR0604717A FR2901627B1 (fr) | 2006-05-24 | 2006-05-24 | Procede de retraitement d'un combustible nucleaire use et de preparation d'un oxyde mixte d'uranium et de plutonium |
US85302406P | 2006-10-20 | 2006-10-20 | |
US60/853,024 | 2006-10-20 | ||
PCT/EP2007/055024 WO2007135178A1 (en) | 2006-05-24 | 2007-05-23 | Process for reprocessing a spent nuclear fuel and of preparing a mixed uranium-plutonium oxide |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2009537838A JP2009537838A (ja) | 2009-10-29 |
JP2009537838A5 true JP2009537838A5 (enrdf_load_stackoverflow) | 2013-05-16 |
JP5325098B2 JP5325098B2 (ja) | 2013-10-23 |
Family
ID=37892451
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2009511522A Active JP5325098B2 (ja) | 2006-05-24 | 2007-05-23 | 使用済み核燃料を再処理しウラン・プルトニウム混合酸化物を調製する方法 |
Country Status (12)
Families Citing this family (52)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2901627B1 (fr) * | 2006-05-24 | 2009-05-01 | Commissariat Energie Atomique | Procede de retraitement d'un combustible nucleaire use et de preparation d'un oxyde mixte d'uranium et de plutonium |
JP5193687B2 (ja) * | 2008-05-30 | 2013-05-08 | 株式会社東芝 | 使用済み燃料再処理方法 |
US20100158772A1 (en) * | 2008-06-13 | 2010-06-24 | Decode Biostructures, Inc. | Nanovolume microcapillary crystallization system |
JP5132476B2 (ja) * | 2008-08-12 | 2013-01-30 | 株式会社東芝 | 使用済核燃料の再処理方法および遠心抽出装置 |
DE102008042518A1 (de) | 2008-10-01 | 2010-04-08 | Robert Bosch Gmbh | Verfahren zur Auswahl von zu ergreifenden Sicherheitsmaßnahmen zur Erhöhung einer Sicherheit von Fahrzeuginsassen |
US8571167B2 (en) * | 2009-06-01 | 2013-10-29 | Advanced Reactor Concepts LLC | Particulate metal fuels used in power generation, recycling systems, and small modular reactors |
FR2947663B1 (fr) * | 2009-07-02 | 2011-07-29 | Areva Nc | Procede ameliore de traitement de combustibles nucleaires uses |
FR2948385B1 (fr) * | 2009-07-27 | 2011-09-23 | Commissariat Energie Atomique | Procede de recuperation selective de l'americium a partir d'une phase aqueuse nitrique |
FR2948384B1 (fr) | 2009-07-27 | 2011-09-23 | Commissariat Energie Atomique | Augmentation du facteur de separation entre l'americium et le curium et/ou entre des lanthanides dans une operation d'extraction liquide-liquide |
FR2954354B1 (fr) * | 2009-12-22 | 2012-01-13 | Commissariat Energie Atomique | Procede de purification de l'uranium d'un concentre d'uranium naturel |
US9008259B2 (en) | 2010-01-13 | 2015-04-14 | Advanced Reactor Concepts LLC | Sheathed, annular metal nuclear fuel |
RU2596160C2 (ru) | 2010-02-22 | 2016-08-27 | Эдвансд Риэктор Консептс Ллк | Небольшая атомная электростанция на быстрых нейтронах с длительным интервалом замены топлива |
US8741237B1 (en) * | 2010-04-12 | 2014-06-03 | U.S. Department Of Energy | Solvent extraction system for plutonium colloids and other oxide nano-particles |
FR2960690B1 (fr) * | 2010-05-27 | 2012-06-29 | Commissariat Energie Atomique | Procede de traitement de combustibles nucleaires uses ne necessitant pas d'operation de desextraction reductrice du plutonium |
RU2456244C2 (ru) * | 2010-08-30 | 2012-07-20 | Федеральное государственное унитарное предприятие "Производственное объединение "Маяк" | Способ переработки отработанных стекловолокнистых аэрозольных фильтров |
FR2968014B1 (fr) | 2010-11-25 | 2012-12-28 | Commissariat Energie Atomique | Procede de separation de l'americium des autres elements metalliques presents dans une phase aqueuse acide ou organique et ses applications |
JP5737931B2 (ja) * | 2010-12-24 | 2015-06-17 | 三菱重工業株式会社 | 抽出装置および使用済核燃料の再処理施設 |
JP5758209B2 (ja) * | 2011-06-14 | 2015-08-05 | 株式会社東芝 | 使用済み燃料再処理方法 |
JP5784476B2 (ja) * | 2011-12-09 | 2015-09-24 | 株式会社東芝 | ウランの回収方法 |
RU2502142C1 (ru) * | 2012-04-19 | 2013-12-20 | Федеральное государственное унитарное предприятие "Научно-исследовательский институт Научно-производственное объединение "ЛУЧ" (ФГУП "НИИ НПО "ЛУЧ") | Способ переработки уран-молибденовой композиции |
RU2537013C2 (ru) * | 2012-12-07 | 2014-12-27 | Открытое акционерное общество "Радиевый институт имени В.Г. Хлопина" | Топливная композиция для водоохлаждаемых реакторов аэс на тепловых нейтронах |
CN103305702B (zh) * | 2013-07-08 | 2014-12-24 | 中国原子能科学研究院 | 一种从Purex流程的2AW+2DW中放废液中回收和纯化镎的工艺 |
FR3015760B1 (fr) * | 2013-12-20 | 2016-01-29 | Commissariat Energie Atomique | Procede de traitement d'un combustible nucleaire use comprenant une etape de decontamination de l'uranium(vi) en au moins un actinide(iv) par complexation de cet actinide(iv) |
KR102374678B1 (ko) * | 2014-04-14 | 2022-03-14 | 어드밴스드 리액터 컨셉트 엘엘씨 | 금속 합금 매트릭스에 분산된 세라믹 핵연료 |
RU2561508C1 (ru) * | 2014-04-29 | 2015-08-27 | Федеральное государственное унитарное предприятие "Научно-исследовательский технологический институт имени А.П. Александрова" | Способ иммобилизации стронций-цезиевой фракции высокоактивных отходов включением в геокерамические матрицы |
CN104407062A (zh) * | 2014-09-11 | 2015-03-11 | 上海大学 | 一种快速分析磷酸三异戊酯的方法 |
JP6479398B2 (ja) * | 2014-10-10 | 2019-03-06 | 三菱重工業株式会社 | 再処理施設 |
FR3039547B1 (fr) | 2015-07-29 | 2017-08-25 | Areva Nc | Nouveaux n,n-dialkylamides dissymetriques, leur synthese et leurs utilisations |
FR3039696B1 (fr) | 2015-07-29 | 2017-07-28 | Commissariat Energie Atomique | Procede de traitement en un cycle, exempt d'operation de desextraction reductrice du plutonium, d'une solution aqueuse nitrique de dissolution d'un combustible nucleaire use |
FR3042903B1 (fr) * | 2015-10-21 | 2017-12-08 | Commissariat Energie Atomique | Utilisation d'acides hydroxyiminoalcanoiques comme agents anti-nitreux dans des operations de desextraction reductrice du plutonium |
CN106119578B (zh) * | 2016-06-27 | 2018-10-09 | 中国原子能科学研究院 | 一种草酸钚沉淀母液中硝酸-草酸浓缩与破坏的一体化方法 |
CN107845432B (zh) * | 2016-09-20 | 2019-09-17 | 中核四〇四有限公司 | 一种mox球磨粉末混料方法 |
CN107845433B (zh) * | 2016-09-20 | 2019-09-17 | 中核四〇四有限公司 | 一种mox粉末成形剂与润滑剂添加方法 |
JP6896561B2 (ja) | 2016-09-26 | 2021-06-30 | 株式会社東芝 | 軽水炉用燃料集合体、軽水炉炉心、軽水炉用燃料集合体製造方法およびmox燃料集合体製造方法 |
CN107610796B (zh) * | 2017-08-29 | 2019-08-13 | 中核四0四有限公司 | Mox制备过程不合格粉末回收方法 |
FR3074794B1 (fr) | 2017-12-11 | 2020-01-10 | Areva Nc | Procede de preparation d'une poudre comprenant des particules de sesquioxyde d'uranium et des particules de dioxyde de plutonium |
WO2019115394A1 (en) | 2017-12-11 | 2019-06-20 | Orano Cycle | Method for preparing a powder comprising particles of triuranium octoxide and particles of plutonium dioxide |
CN108267347A (zh) * | 2017-12-27 | 2018-07-10 | 中核四0四有限公司 | 一种采用tbp萃取剂测定mox芯块中银杂质含量的方法 |
CN108630332B (zh) * | 2018-03-26 | 2021-06-18 | 中国核电工程有限公司 | 一种草酸盐沉淀过滤母液中草酸根的破坏装置及破坏方法 |
CN109234534B (zh) * | 2018-08-08 | 2019-11-08 | 中国原子能科学研究院 | 一种从高放废液中共萃取三价锕系和三价镧系元素的工艺 |
CN109402413B (zh) * | 2018-10-30 | 2020-11-03 | 中国工程物理研究院核物理与化学研究所 | 一种乏燃料元件裂变产物中钯的回收方法 |
CN109735859B (zh) * | 2019-03-18 | 2020-10-09 | 中国原子能科学研究院 | 一种3-戊基肼及其盐的用途 |
CN112309601B (zh) * | 2019-07-26 | 2023-04-11 | 中国科学院大连化学物理研究所 | 一种稀释剂及其制备和应用 |
KR102293451B1 (ko) * | 2019-11-08 | 2021-08-25 | 한국원자력연구원 | 금속연료 폐기물을 이용한 금속연료심 제조방법 및 이 방법에 의해 제조된 금속연료심 |
CN112940781B (zh) * | 2019-12-10 | 2022-10-25 | 中国科学院大连化学物理研究所 | 一种稀释剂和其制备与应用 |
CN112941346A (zh) * | 2019-12-10 | 2021-06-11 | 中国科学院大连化学物理研究所 | 一种稀释剂及其制备和应用 |
RU2727140C1 (ru) * | 2020-01-28 | 2020-07-21 | Федеральное государственное унитарное предприятие "Горно-химический комбинат" (ФГУП "ГХК") | Способ экстракционной переработки облученного ядерного топлива |
CN111863303B (zh) * | 2020-06-10 | 2022-08-05 | 中国原子能科学研究院 | 一种purex流程含钚团聚物的溶解与回收方法 |
CN113512653A (zh) * | 2021-06-16 | 2021-10-19 | 中国原子能科学研究院 | 一种从辐照镎靶中提取钚-238的方法 |
CN113241208B (zh) * | 2021-06-22 | 2024-05-14 | 中国原子能科学研究院 | 用于钚尾端处理的容纳装置、蒸发煅烧系统及方法 |
FR3139408B1 (fr) | 2022-09-02 | 2024-09-13 | Commissariat Energie Atomique | Procédé de désextraction d’uranium(vi) et d’un actinide(iv) d’une solution organique par précipitation oxalique |
WO2024238826A1 (en) * | 2023-05-16 | 2024-11-21 | Shine Technologies, Llc | Methods and systems of partitioning, transmuting, and recycling used nuclear fuel |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL301862A (enrdf_load_stackoverflow) * | 1962-12-26 | 1900-01-01 | ||
GB2004407B (en) * | 1977-09-16 | 1982-03-03 | British Nuclear Fuels Ltd | Purification of plutonium |
DE2838541A1 (de) * | 1977-09-16 | 1979-04-05 | British Nuclear Fuels Ltd | Verfahren zur reinigung einer plutonium enthaltenden phase |
US4278559A (en) * | 1978-02-16 | 1981-07-14 | Electric Power Research Institute | Method for processing spent nuclear reactor fuel |
FR2607823B1 (fr) * | 1986-12-03 | 1989-02-17 | Commissariat Energie Atomique | Procede pour separer le technetium present dans un solvant organique avec du zirconium et au moins un autre metal tel que l'uranium ou le plutonium, utilisable notamment pour le retraitement des combustibles nucleaires irradies |
RU2132578C1 (ru) * | 1997-06-16 | 1999-06-27 | Научно-производственное объединение "Радиевый институт им.В.Г.Хлопина" | Способ переработки облученного ядерного топлива (оят) аэс |
GB9722930D0 (en) * | 1997-10-31 | 1998-01-07 | British Nuclear Fuels Plc | Nuclear fuel reprocessing |
GB9802852D0 (en) * | 1998-02-11 | 1998-04-08 | British Nuclear Fuels Plc | Nuclear fuel reprocessing |
FR2815035B1 (fr) * | 2000-10-05 | 2003-03-07 | Commissariat Energie Atomique | Procede de coprecipitation d'actinides et procede de preparation d'oxydes mixtes d'actinides |
CN1182543C (zh) * | 2003-04-04 | 2004-12-29 | 清华大学 | 一种乏燃料后端处理一体化的方法 |
FR2862804B1 (fr) * | 2003-11-20 | 2006-01-13 | Commissariat Energie Atomique | Procede de separation de l'uranium (vi) d'actinides (iv) et/ou (vi)et ses utilisations |
FR2870841B1 (fr) * | 2004-05-28 | 2007-02-09 | Commissariat Energie Atomique | Procede de coprecipitation d'actinides a des etats d'oxydation distincts et procede de preparation de composes mixtes d'actinides |
FR2901627B1 (fr) * | 2006-05-24 | 2009-05-01 | Commissariat Energie Atomique | Procede de retraitement d'un combustible nucleaire use et de preparation d'un oxyde mixte d'uranium et de plutonium |
-
2006
- 2006-05-24 FR FR0604717A patent/FR2901627B1/fr not_active Expired - Fee Related
-
2007
- 2007-05-23 RU RU2008151145A patent/RU2431896C2/ru active
- 2007-05-23 WO PCT/EP2007/055024 patent/WO2007135178A1/en active Application Filing
- 2007-05-23 US US12/300,705 patent/US20090184298A1/en not_active Abandoned
- 2007-05-23 DE DE200760003013 patent/DE602007003013D1/de active Active
- 2007-05-23 EP EP20070729457 patent/EP2022061B1/en active Active
- 2007-05-23 KR KR1020087028715A patent/KR101386696B1/ko not_active Expired - Fee Related
- 2007-05-23 JP JP2009511522A patent/JP5325098B2/ja active Active
- 2007-05-23 CN CN2007800188112A patent/CN101449338B/zh active Active
- 2007-05-23 ES ES07729457T patent/ES2334852T3/es active Active
- 2007-05-23 AT AT07729457T patent/ATE447231T1/de not_active IP Right Cessation
- 2007-05-24 US US11/753,182 patent/US7887767B2/en active Active
-
2008
- 2008-11-04 ZA ZA200809415A patent/ZA200809415B/xx unknown
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5325098B2 (ja) | 使用済み核燃料を再処理しウラン・プルトニウム混合酸化物を調製する方法 | |
JP2009537838A5 (enrdf_load_stackoverflow) | ||
Herbst et al. | Standard and advanced separation: PUREX processes for nuclear fuel reprocessing | |
JP5802660B2 (ja) | 使用済み核燃料の改善された処理方法 | |
Sood et al. | Chemistry of nuclear fuel reprocessing: current status | |
RU2558332C2 (ru) | Способ переработки отработанного ядерного топлива, не требующий восстановительной реэкстракции плутония | |
US3374068A (en) | Irradiated fuel reprocessing | |
CN107851470B (zh) | 处理由溶解废核燃料产生的硝酸水溶液的方法 | |
US20080224106A1 (en) | Process for treating compositions containing uranium and plutonium | |
Campbell et al. | The chemistry of fuel reprocessing: present practices, future trends | |
Law | Aqueous reprocessing of used nuclear fuel | |
Gray et al. | Separation of plutonium from irradiated fuels and targets | |
JP4338898B2 (ja) | 使用済み燃料の再処理方法およびピューレックス式再処理方法 | |
US20100301287A1 (en) | Process for Treating Spent Nuclear Fuel | |
EP1105884A1 (en) | Nuclear fuel processing including reduction of np(vi) to np(v) with a hydrophilic substitituted hydroxylamine | |
Thompson et al. | Recent Savannah River exterience and development with actinide separations | |
JP4338899B2 (ja) | 使用済み燃料再処理方法、ピューレックス式再処理方法、Np(VI)をNp(V)に還元する方法、及びPu(IV)をPu(III)に還元する方法 | |
US2995588A (en) | Extraction of tetravalent plutonium values with methyl ethyl ketone, methyl isobutylketone, acetophenone or menthone | |
WO1999023668A1 (en) | Nuclear fuel reprocessing | |
Bykhovskii et al. | Combined processing scheme of WWER-1000 spent nuclear fuel: 2. Experimental trial of extraction processing of fluoride cinder | |
Chung et al. | The Application of Acetohydroxamic Acid to the TBP Extraction of Uranium and Neptunium from a Simulated Solution |