JP2009517623A - 手榴弾防護物 - Google Patents
手榴弾防護物 Download PDFInfo
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- JP2009517623A JP2009517623A JP2008542390A JP2008542390A JP2009517623A JP 2009517623 A JP2009517623 A JP 2009517623A JP 2008542390 A JP2008542390 A JP 2008542390A JP 2008542390 A JP2008542390 A JP 2008542390A JP 2009517623 A JP2009517623 A JP 2009517623A
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Classifications
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- B32B5/12—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by the relative arrangement of fibres or filaments of different layers, e.g. the fibres or filaments being parallel or perpendicular to each other
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- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F41—WEAPONS
- F41H—ARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
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- F41H5/04—Plate construction composed of more than one layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
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Abstract
Description
発明の分野
本発明は、優れた耐弾性(ballistic resistant properties)並びに、榴散弾(shrapnel)などの破片の貫通に対して優れた耐性をもつ布帛積層物に関する。特に、本発明は、エラストマー母材中で高強度ポリマー繊維から形成した、軽量、柔軟、不織の耐破片性及び耐弾性材料に関連する。
変形可能な発射体(deformable projectile)に対して優れた耐性をもつ高強度繊維を含む耐弾性物品(ballistic resistant article)は公知である。軍装備品の防弾チョッキ、ヘルメット及び構造部材などの物品は、通常、そのような高強度繊維を含む布帛(fabric)から製造される。通常使用される繊維としては、ポリエチレン繊維、パラ-アラミド繊維、たとえばポリ(フェニレンジアミンテレフタルアミド)、グラファイト繊維、ナイロン繊維、ガラス繊維などが挙げられる。チョッキまたはチョッキの部品などの多くの用途に関しては、その繊維は織り布帛(woven fabric)または編み布帛(knitted fabric)である。他の用途の多くに関しては、繊維を複合材料中に封入または埋め込んで、硬質または軟質布帛を形成する。
本発明は、
a)繊維からなる少なくとも一つの圧密化網状構造であって、前記繊維の圧密化網状構造は、複数の交差して積み重ねられた不織繊維層を含み、それぞれの繊維層は実質的に平行配列に配列された複数の繊維を含み、前記繊維は約7g/デニール以上の靱性と約150g/デニール以上の引っ張り弾性率(tensile modulus)を有し;前記繊維は、その上にエラストマー母材組成物を有し、前記エラストマー母材組成物は、前記繊維の圧密化網状構造の約7重量%〜約15重量%を構成し;複数の交差して積み重ねられた不織繊維層は前記母材組成物で圧密化されて、前記繊維の圧密化網状構造を形成し;前記繊維の圧密化網状構造は、前部表面と後部表面とを有し:ここで前記繊維がアラミド繊維またはポリ(p-フェニレンベンゾビスオキサゾール)繊維を含む場合、前記母材組成物は前記繊維の圧密化網状構造の少なくとも約11重量%を構成するようにしたもの;及び
b)前記の繊維からなる圧密化網状構造の前部表面と後部表面のそれぞれに結合した、少なくとも1層のポリマーフィルムを含む、耐破片性材料を提供する。
a)繊維からなる少なくとも一つの圧密化網状構造であって、前記繊維の圧密化網状構造は、複数の交差して積み重ねられた不織繊維層を含み、それぞれの繊維層は実質的に平行配列に配列された複数の繊維を含み、前記繊維は約7g/デニール以上の靱性と約150g/デニール以上の引っ張り弾性率を有し;前記繊維は、その上にエラストマー母材組成物を有し、前記エラストマー母材組成物は、前記繊維の圧密化網状構造の約7重量%〜約15重量%を構成し;複数の交差して積み重ねられた不織繊維層は前記母材組成物で圧密化されて、前記繊維の圧密化網状構造を形成し;前記繊維の圧密化網状構造は、前部表面と後部表面とを有し:ここで前記繊維がアラミド繊維またはポリ(p-フェニレンベンゾビスオキサゾール)繊維を含む場合、前記母材組成物が前記繊維の圧密化網状構造の少なくとも約11重量%を構成するもの;及び
b)前記の繊維からなる圧密化網状構造の前部表面と後部表面のそれぞれに結合された少なくとも1層のポリマーフィルムを含む。
a)少なくとも二つの繊維層において、各繊維層が、実質的に平行な一方向性配列となるように複数の繊維を配列することによって形成され;前記繊維が約7g/デニール以上の靱性と、約150g/デニール以上の引っ張り弾性率とを有し;前記繊維はその上にエラストマー母材組成物が結合されるように、前記少なくとも二つの繊維層を形成すること;
b)前記繊維層において、各層の繊維の一方向性配列が、それぞれの隣接する繊維層の長手繊維方向(longitudinal fiber direction)に対して90°の角度で交差して積み重なるように、前記繊維層を配列すること;
c)交差して積み重ねられている前記層を、繊維の圧密化網状構造を形成するのに十分な条件下で結合し、前記繊維の圧密化網状構造が前部表面と後部表面とを有し、前記母材組成物が前記繊維の圧密化網状構造の約7重量%〜約15重量%を構成し、前記繊維がアラミド繊維またはポリ(p-フェニレンベンゾビスオキサゾール)繊維を含む場合、前記母材組成物は前記繊維の圧密化網状構造の少なくとも11重量%を構成するようにすること;及び
d)ポリマーフィルムの少なくとも一つの層を前記繊維の圧密化網状構造の前記前部表面と後部表面とに結合させること、
を含む、前記方法を提供する。
a)繊維からなる少なくとも一つの圧密化網状構造であって、前記繊維の圧密化網状構造が、複数の交差して積み重ねられた繊維層を含み、それぞれの繊維層は配列された複数の繊維を含み;前記繊維は約7g/デニール以上の靱性と約150g/デニール以上の引っ張り弾性率を有し;前記繊維は、その上にエラストマー母材組成物を有し、前記エラストマー母材組成物は、前記繊維の圧密化網状構造の約7重量%〜約15重量%を構成し;複数の交差して積み重ねられた繊維層は前記母材組成物で圧密化されて、前記繊維の圧密化網状構造を形成し;前記繊維の圧密化網状構造が、前部表面と後部表面とを有するもの;及び
b)繊維の前記圧密化網状構造の前部表面と後部表面のそれぞれに結合した少なくとも1層のポリマーフィルムを含む、前記耐破片性物品を提供する。
本発明は、優れた弾貫入抵抗性に加えて優れた破片貫入抵抗性(fragment penetration resistance)をもつ不織布帛複合体を提示する。本発明の目的に関して、優れた弾道貫入抵抗性(ballistic penetration resistance)をもつ本発明の耐破片性物質は、変形可能な発射体に対して優れた特性を示すものを表す。
実施例
実施例1(比較例)
弾道シュートパック(ballistic shoot pack)は、18枚の布帛層を重ねて製造し、それぞれの布帛層は、Kraton(登録商標)熱可塑性ポリマーで含浸させた一方向性の高弾性率ポリエチレン(HMPE)繊維の二枚のシート(層:pile)からなる圧密化網状構造によって構成されており、それぞれの層は、互いに直角に(0度/90度)で交差して積み重ねられ、線形低密度ポリエチレン(LLDPE)フィルムの二枚のシートの間にラミネートされている。
の比エネルギー吸収(SEAT)は34.88 J-m2/kgと計算された。
実施例1を繰り返したが、シュートパックは0.44 lb/ft2(2.15kg/m2)の面密度をもつ19枚積み重ねた布帛層であった。試験の結果、このシュートパックのV50は、1217 fpsであった。標的の比エネルギー吸収は、35.01 J-m2/kgと計算された。
弾道シュートパックは、実施例1に記載のようにSPECTRA(登録商標)1000、1100デニールの20枚の布帛層を一緒に積み重ねることによって製造した。それぞれの布帛層は、布帛層の重量を基準として88.7重量%の繊維を含み、布帛層の重量をベースとして母材ポリマー11.3重量%を含んでいた。LLDPEフィルムの厚さは9μmであった。LLDPEフィルムの面密度は8gsmであった。一つの布帛層の全面密度は103.9gsmであった。材料のラミネート化シートの厚さは、0.1524mmであった。
実施例1を繰り返した。但し、シュートパックは32枚の布帛層を含み、9mmのフルメタルジャケット(FMJ)弾丸に対して試験した。シュートパックのサイズは、18”×18”(45.7mm×45.7mm)であった。シュートパックの面密度は0.74 lb/ft2(3.61kg/m2)であった。9mmFMJ弾丸抵抗に対する試験に関しては、シュートパックをPlastilina #1クレーを充填した試験フレームに据え付け、フレーム上に固定した。Plastilina充填フレームを、しっかりと固定したユニバーサルレシーバーから発射した破片のラインに対して90度の方向性で据え付けた。試験に使用した9mm FMJ弾丸から、the National Institute of Justice(NIJ)0101.04試験標準に従って形状、サイズ及び重量を合わせた。
実施例2を繰り返したが、9mmFMJ弾丸に関して試験した。シュートパックのサイズは、18”×18”(45.7mm×45.7mm)であった。シュートパックの面密度は0.43 lb/ft2(2.09kg/m2)であった。弾丸試験は実施例3の通りに実施した。このシュートパックのV50は1272 fpsであった。標的の比エネルギー吸収(SEAT)は284.46J-m2/kgと計算された。この実施例は、実施例3の21%と比較して、11%の母材ポリマーをもつSPECTRA(登録商標)1000、1100デニール布帛を使用して達成された耐破片性の方が優れていることを示している。
弾丸シュートパックは、27枚の布帛層を積み重ねることによって製造し、そのそれぞれの布帛層は、直角に交差して積み重ねられたKraton(登録商標)ポリマーで含浸した一方向性のHMPE繊維2シートをもつ圧密化網状構造から構成され、LLDPEフィルムの二枚のシートの間にラミネートされている。
弾道シュートパックは、実施例5の記載のようにSPECTRA(登録商標)1000、1300デニールの29枚の布帛層を一緒に積み重ねることによって製造した。それぞれの布帛層は、布帛層の重量をベースとして92.9重量%の繊維を含み、布帛層の重量をベースとして母材ポリマー7.1重量%を含んでいた。一つの布帛層の全面密度は129.0gsmであった。シュートパックのサイズは、18”×18”(45.7mm×45.7mm)であった。シートのスタックは互いに結合していなかった。シュートパックの面密度は0.77 lb/ft2(3.75 kg/m2)であった。
SPECTRA(登録商標)1000、1300繊維を実施例5の通りに28枚の布帛層を積み重ねることによって弾道シュートパックを製造した。それぞれの層は布帛層の重量をベースとして繊維89.9重量%を含み、布帛層の重量をベースとして母材ポリマー10.1重量%を含んでいた。一つの布帛層の総面密度は132.8gsmであった。シュートパックのサイズは18”×18”(45.7mm×45.7mm)であった。シートのスタックは互いに結合していなかった。シュートパックの面密度は0.77 lb/ft2(3.75kg/m2)であった。
SPECTRA(登録商標)1000、1300繊維を実施例7の通りに29枚の布帛層を積み重ねることによって弾道シュートパックを製造した。それぞれの布帛層は布帛層の重量を基準として繊維85.0重量%を含み、布帛層の重量を基準として母材ポリマー15.0重量%を含んでいた。シュートパックの面密度は0.83 lb/ft2(4.05kg/m2)であった。
実施例5を、実施例3の通りに9mm FMJ弾丸に対して試験を繰り返した。このシュートパックのV50は1450 fpsであった。標的の比エネルギー吸収(SEAT)は189.22 J-m2/kgと計算された。
実施例7を、実施例3の通りに、但し9mm FMJ弾丸に対して試験を繰り返した。試験は実施例3の通りに実施した。このシュートパックのV50は、1519 fpsであった。標的の比エネルギー吸収(SEAT)は226.54 J-m2/kgと計算された。この実施例は、実施例8の21%と比較して、10%の母材ポリマーをもつSPECTRA(登録商標)1000、1300デニール布帛を使用して達成された耐破片性の方が優れていることを示している。
(**)エマルションポリマー−ポリスチレン−ポリイソプレン−ポリスチレン−ブロックコポリマー。
シュートパック(標的)サイズは18”×18”:面密度はlb/ft2(psf)として弾道シュートパックの重量である。SEATは、Specific Energy Absorption of Targetである。
SPECTRA(登録商標)シールドLCRの三種類のサンプルを剥離強度特性に関して試験した。それぞれのサンプルは異なる母材ポリマー含有量であった。SPECTRA(登録商標)シールドLCRサンプルはそれぞれ、以下の層構造の4層構造であった:LLDPEフィルム/0°繊維層/90°繊維層/LLDPEフィルム。標準剥離強度試験は繊維層間を剥離することによって実施した。結果を以下の表にまとめる。
Claims (33)
- a)繊維からなる少なくとも一つの圧密化網状構造であって、前記繊維の圧密化網状構造は、複数の交差して積み重ねられた不織繊維層を含み、それぞれの繊維層は実質的に平行配列に配列された複数の繊維を含み、前記繊維は約7g/デニール以上の靱性と約150g/デニール以上の引っ張り弾性率を有し;前記繊維は、その上にエラストマー母材組成物を有し、前記エラストマー母材組成物は、前記繊維の圧密化網状構造の約7重量%〜約15重量%を構成し;複数の交差して積み重ねられた前記不織繊維層は前記母材組成物で圧密化されて、前記繊維の圧密化網状構造を形成し;前記繊維の圧密化網状構造は、前部表面と後部表面とを有し:ここで前記繊維がアラミド繊維またはポリ(p-フェニレンベンゾビスオキサゾール)繊維を含む場合、前記母材組成物が前記繊維の圧密化網状構造の少なくとも約11重量%を構成するもの;及び
b)前記の繊維からなる圧密化網状構造の前部表面と後部表面のそれぞれに結合した、少なくとも1層のポリマーフィルム
を含む、耐破片性材料。 - 前記繊維が約15g/デニール以上の靱性と、約400g/デニール以上の引っ張り弾性率をもつ繊維を含む、請求項1に記載の耐破片性材料。
- 前記繊維が、約30g/デニール以上の靱性と、約1000g/デニール以上の引っ張り弾性率とを有する繊維を含む、請求項1に記載の耐破片性材料。
- 前記繊維が、長鎖ポリオレフィン繊維、アラミド繊維、ポリベンザゾール繊維、ポリビニルアルコール繊維、ポリアミド繊維、ポリエチレンテレフタレート繊維、ポリエチレンナフタレート繊維、ポリアクリロニトリル繊維、液晶コポリエステル繊維、ガラス繊維及び炭素繊維からなる群から選択される材料を含む、請求項1に記載の耐破片性材料。
- 前記繊維がポリエチレン繊維を含む、請求項1に記載の耐破片性材料。
- 前記母材組成物が、ポリブタジエン、ポリイソプレン、天然ゴム、エチレン-プロピレンコポリマー、エチレン-プロピレン-ジエンターポリマー、ポリスルフィドポリマー、ポリウレタンエラストマー、クロロスルホン化ポリエチレン、ポリクロロプレン、可塑化ポリ塩化ビニル、ブタジエンアクリロニトリルエラストマー、ポリ(イソブチレン-コ-イソプレン)、ポリアクリレート、ポリエステル、ポリエーテル、フルオロエラストマー、シリコーンエラストマー、エチレンのコポリマー及びその組み合わせからなる群から選択される材料を含む、請求項1に記載の耐破片性材料。
- 前記母材組成物がポリスチレン-ポリイソプレン-ポリスチレン-ブロックコポリマーを含む、請求項1に記載の耐破片性材料。
- 前記母材組成物が前記繊維の圧密化網状構造の約7重量%〜約14重量%を構成する、請求項1に記載の耐破片性材料。
- 前記母材組成物が前記繊維の圧密化網状構造の約7重量%〜約13重量%を構成する、請求項1に記載の耐破片性材料。
- 前記母材組成物が前記繊維の網状構造の約7重量%〜約12重量%を構成する、請求項1に記載の耐破片性材料。
- 前記母材組成物が前記繊維の網状構造の約7重量%〜約11重量%を構成する、請求項1に記載の耐破片性材料。
- 前記母材組成物が前記繊維の網状構造の約11重量%〜約15重量%を構成する、請求項1に記載の耐破片性材料。
- 前記繊維がアラミド繊維またはポリ(p-フェニレンベンゾビスオキサゾール)繊維によって構成され、且つ前記母材組成物が前記繊維の網状構造約11重量%〜約15重量%を構成する、請求項1に記載の耐破片性材料。
- 前記ポリマーフィルム層が、全材料の約2重量%〜約25重量%を構成する、請求項1に記載の耐破片性材料。
- 前記ポリマーフィルム層が、ポリオレフィン、ポリアミド、ポリエステル、ポリウレタン、ビニルポリマー、フルオロポリマー並びにそのコポリマー及びその組み合わせからなる群から選択される材料を含む、請求項1に記載の耐破片性材料。
- 前記ポリマーフィルム層が線状低密度ポリエチレンを含む、請求項1に記載の耐破片性材料。
- 前記繊維層のそれぞれが、それぞれの隣接する繊維層の長手繊維方向に対して90°の角度で交差して積み重ねられている、請求項1に記載の耐破片性材料。
- 耐破片性材料を組み込んだ耐破片性物品であって、前記耐破片性材料が、
a)繊維からなる少なくとも一つの圧密化網状構造であって、前記繊維の圧密化網状構造が、複数の交差して積み重ねられた不織繊維層を含み、それぞれの繊維層は実質的に平行配列に配列された複数の繊維を含み、前記繊維は約7g/デニール以上の靱性と約150g/デニール以上の引っ張り弾性率を有し;前記繊維は、その上にエラストマー母材組成物を有し、前記エラストマー母材組成物は、前記繊維の圧密化網状構造の約7重量%〜約15重量を構成し;複数の交差して積み重ねられた不織繊維層は前記母材組成物で圧密化されて、前記繊維の圧密化網状構造を形成し;前記繊維の圧密化網状構造は、前部表面と後部表面とを有し:ここで前記繊維がアラミド繊維またはポリ(p-フェニレンベンゾビスオキサゾール)繊維を含む場合、前記母材組成物は前記繊維の圧密化網状構造の少なくとも約11重量%を構成するもの;及び
b)前記の繊維からなる圧密化網状構造の前部表面と後部表面のそれぞれに結合された少なくとも1層のポリマーフィルムを含む、前記耐破片性物品。 - 結合された配列で組み立てられた繊維の複数の圧密化網状構造を含む、請求項18に記載の耐破片性材料。
- 結合されていない配列で組み立てられた繊維の複数の圧密化網状構造を含む、請求項18に記載の耐破片性材料。
- 前記の繊維からなる複数の圧密化網状構造が接合されている衣服を含む、請求項18に記載の耐破片性材料。
- 前記衣服が、前記の繊維からなる複数の圧密化網状構造が接合されているチョッキを含む、請求項18に記載の耐破片性材料。
- 前記母材組成物が、前記繊維の網状構造の約7重量%〜約11重量%を構成する、請求項18に記載の耐破片性材料。
- 前記母材組成物が、前記繊維の網状構造の約11重量%〜約15重量%を構成する、請求項18に記載の耐破片性材料。
- 前記繊維がアラミド繊維またはポリ(p-フェニレンベンゾビスオキサゾール)繊維によって構成され、且つ前記母材組成物が前記繊維の網状構造の約11重量%〜約15重量%を構成する、請求項18に記載の耐破片性材料。
- 前記繊維層のそれぞれが、それぞれの隣接する繊維層の長手繊維方向に対して90°の角度で交差して積み重ねられている、請求項18に記載の耐破片性材料。
- 耐破片性材料の製造法であって、
a)少なくとも二つの繊維層において、各繊維層が、実質的に平行な一方向性配列となるように複数の繊維を配列することによって形成され;前記繊維は約7g/デニール以上の靱性と、約150g/デニール以上の引っ張り弾性率とを有し;前記繊維はその上に結合されたエラストマー母材組成物を有するように前記少なくとも二つの繊維層を形成すること;
b)前記繊維層において、各層の繊維の一方向性配列が、それぞれの隣接する繊維層の長手繊維方向に対して平行でない角度で交差して積み重なるように、前記繊維層を配列すること;
c)前記交差して積み重ねられている層を、繊維の圧密化網状構造を形成するのに十分な条件下で結合し、前記繊維の圧密化網状構造が前部表面と後部表面とを有し、ここで前記母材組成物が前記繊維の圧密化網状構造の約7重量%〜約15重量%を構成し、前記繊維がアラミド繊維またはポリ(p-フェニレンベンゾビスオキサゾール)繊維を含む場合、前記母材組成物は前記繊維の圧密化網状構造の少なくとも11重量%を構成するようにすること;及び
d)ポリマーフィルムの少なくとも一つの層を前記繊維の圧密化網状構造の前記前部表面と後部表面とに結合させること、
を含む、前記方法。 - 前記母材組成物が前記繊維の圧密化網状構造の約7重量%〜約11重量%を構成する、請求項27に記載の方法。
- 前記母材組成物が前記繊維の圧密化網状構造の約11重量%〜約15重量%を構成する、請求項27に記載の方法。
- 前記繊維がアラミド繊維またはポリ(p-フェニレンベンゾビスオキサゾール)繊維によって構成され、且つ前記母材組成物が前記繊維の圧密化網状構造の約11重量%〜約15重量%を構成する、請求項27に記載の方法。
- 前記繊維層のそれぞれが、それぞれの隣接する繊維層の長手繊維方向に対して90°の角度で交差して積み重ねられている、請求項27に記載の方法。
- a)繊維からなる少なくとも一つの圧密化網状構造であって、前記繊維の圧密化網状構造が、複数の交差して積み重ねられた繊維層を含み、それぞれの繊維層は配列された複数の繊維を含み;前記繊維は約7g/デニール以上の靱性と約150g/デニール以上の引っ張り弾性率を有し;前記繊維は、その上にエラストマー母材組成物を有し、前記エラストマー母材組成物は、前記繊維の圧密化網状構造の約7重量%〜約15重量%を構成し;複数の交差して積み重ねられた繊維層は前記母材組成物で圧密化されて、前記繊維の圧密化網状構造を形成し;前記繊維の圧密化網状構造が、前部表面と後部表面とを有しているもの;及び
b)繊維の前記圧密化網状構造の前部表面と後部表面のそれぞれに結合した少なくとも1層のポリマーフィルムを含む、前記耐破片性物品。 - 請求項32に記載の耐破片性材料を含む物品。
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BRPI0619072A2 (pt) | 2011-09-20 |
US20070117483A1 (en) | 2007-05-24 |
ES2420956T3 (es) | 2013-08-28 |
CN101370649A (zh) | 2009-02-18 |
RU2008125206A (ru) | 2009-12-27 |
WO2007089317A3 (en) | 2007-09-27 |
WO2007089317A8 (en) | 2008-07-10 |
EP1951510B1 (en) | 2013-04-24 |
KR20080072932A (ko) | 2008-08-07 |
TWI359935B (en) | 2012-03-11 |
KR101360856B1 (ko) | 2014-02-21 |
TW200728679A (en) | 2007-08-01 |
CA2631019A1 (en) | 2007-08-09 |
JP5236482B2 (ja) | 2013-07-17 |
IL191662A0 (en) | 2008-12-29 |
EP1951510A2 (en) | 2008-08-06 |
AR058231A1 (es) | 2008-01-23 |
PE20070885A1 (es) | 2007-10-24 |
CA2631019C (en) | 2014-01-28 |
IL191662A (en) | 2011-08-31 |
US7629277B2 (en) | 2009-12-08 |
WO2007089317A2 (en) | 2007-08-09 |
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