JP2009514172A - セリウム塩添加物を有する高い耐久性の燃料電池構成要素 - Google Patents

セリウム塩添加物を有する高い耐久性の燃料電池構成要素 Download PDF

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JP2009514172A
JP2009514172A JP2008537882A JP2008537882A JP2009514172A JP 2009514172 A JP2009514172 A JP 2009514172A JP 2008537882 A JP2008537882 A JP 2008537882A JP 2008537882 A JP2008537882 A JP 2008537882A JP 2009514172 A JP2009514172 A JP 2009514172A
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polymer
polymer electrolyte
electrolyte membrane
cation
electrode assembly
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JP2009514172A5 (https=
Inventor
エイチ． フレイ，マシュー
エム． ピアポント，ダニエル
ジェイ． ハムロック，スティーブン
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3M Innovative Properties Co
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1041—Polymer electrolyte composites, mixtures or blends
    • H01M8/1046—Mixtures of at least one polymer and at least one additive
    • H01M8/1051—Non-ion-conducting additives, e.g. stabilisers, SiO2 or ZrO2
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2237—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds containing fluorine
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1027—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1032—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1058—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. in situ polymerisation or in situ crosslinking
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1081—Polymeric electrolyte materials characterised by the manufacturing processes starting from solutions, dispersions or slurries exclusively of polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2327/18—Homopolymers or copolymers of tetrafluoroethylene
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0088—Composites
    • H01M2300/0091—Composites in the form of mixtures
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Composite Materials (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Fuel Cell (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
JP2008537882A 2005-10-28 2006-10-24 セリウム塩添加物を有する高い耐久性の燃料電池構成要素 Pending JP2009514172A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/262,268 US8628871B2 (en) 2005-10-28 2005-10-28 High durability fuel cell components with cerium salt additives
PCT/US2006/041493 WO2007120189A2 (en) 2005-10-28 2006-10-24 High durability fuel cell components with cerium salt additives

Publications (2)

Publication Number Publication Date
JP2009514172A true JP2009514172A (ja) 2009-04-02
JP2009514172A5 JP2009514172A5 (https=) 2009-10-01

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JP2008537882A Pending JP2009514172A (ja) 2005-10-28 2006-10-24 セリウム塩添加物を有する高い耐久性の燃料電池構成要素

Country Status (5)

Country Link
US (2) US8628871B2 (https=)
JP (1) JP2009514172A (https=)
CN (1) CN101297430B (https=)
DE (1) DE112006003025T5 (https=)
WO (1) WO2007120189A2 (https=)

Cited By (2)

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US9849227B2 (en) 2008-06-05 2017-12-26 Fresenius Medical Care Deutschland Gmbh Organizer for releasably accommodating components of blood tube sets, and methods for manufacturing and preparing it
KR20210052820A (ko) * 2019-11-01 2021-05-11 현대자동차주식회사 내구성 및 수소 이온 전도성이 우수한 막-전극 접합체 및 이의 제조방법

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WO2005124911A1 (ja) 2004-06-22 2005-12-29 Asahi Glass Company, Limited 固体高分子型燃料電池用電解質膜、その製造方法及び固体高分子型燃料電池用膜電極接合体
JP3897059B2 (ja) 2004-06-22 2007-03-22 旭硝子株式会社 液状組成物、その製造方法及び固体高分子形燃料電池用膜電極接合体の製造方法
US7572534B2 (en) 2004-09-20 2009-08-11 3M Innovative Properties Company Fuel cell membrane electrode assembly
US8101317B2 (en) * 2004-09-20 2012-01-24 3M Innovative Properties Company Durable fuel cell having polymer electrolyte membrane comprising manganese oxide
US8367267B2 (en) * 2005-10-28 2013-02-05 3M Innovative Properties Company High durability fuel cell components with cerium oxide additives
US8628871B2 (en) * 2005-10-28 2014-01-14 3M Innovative Properties Company High durability fuel cell components with cerium salt additives
US8722569B2 (en) 2006-03-13 2014-05-13 E I Du Pont De Nemours And Company Peroxide decomposition catalyst particles
US8663866B2 (en) 2006-03-13 2014-03-04 E I Du Pont De Nemours And Company Stable proton exchange membranes and membrane electrode assemblies
US20080107945A1 (en) * 2006-11-08 2008-05-08 Gm Global Technology Operations, Inc. Fuel cell substrate with an overcoat
US7593823B2 (en) * 2006-11-21 2009-09-22 The Furukawa Electric Co., Ltd Method and device for determining state of battery, and battery power supply system therewith
JP4765908B2 (ja) * 2006-11-22 2011-09-07 旭硝子株式会社 固体高分子電解質膜及び固体高分子型燃料電池用膜電極接合体
JP5431958B2 (ja) * 2006-12-29 2014-03-05 スリーエム イノベイティブ プロパティズ カンパニー 耐久性のあるポリマー電解質薄膜を製造する方法
CN101919100B (zh) * 2007-11-09 2014-10-01 3M创新有限公司 包含杂多酸的聚合物电解质
US7989115B2 (en) * 2007-12-14 2011-08-02 Gore Enterprise Holdings, Inc. Highly stable fuel cell membranes and methods of making them
CN101953012B (zh) 2007-12-27 2014-05-07 3M创新有限公司 具有组合添加剂的耐久性燃料电池膜电极组件
WO2009086364A1 (en) * 2007-12-27 2009-07-09 3M Innovative Properties Company Electrode inks containing coalescing solvents
WO2009157894A1 (en) * 2008-06-24 2009-12-30 Utc Power Corporation Membrane with increased durability from partial ion exchange
CN102834374B (zh) 2010-04-16 2016-08-03 3M创新有限公司 质子传导材料
CN103004001B (zh) * 2010-05-25 2016-02-17 3M创新有限公司 强化的电解质膜
EP3138875B1 (en) 2011-08-04 2019-11-20 3M Innovative Properties Company Crosslinked fluorinated polymers with manganese or cerium as additives
JP6941604B2 (ja) 2015-09-23 2021-09-29 スリーエム イノベイティブ プロパティズ カンパニー スルホニルペンダント基を有するテトラフルオロエチレンのコポリマーを作製する方法
EP3681948A4 (en) 2017-09-14 2021-07-14 3M Innovative Properties Company FLUORINATED COPOLYMER WITH SULFONYL SIDE GROUPS AS WELL AS COMPOSITIONS AND ARTICLES THEREFORE
KR102791509B1 (ko) * 2018-12-20 2025-04-03 현대자동차주식회사 화학적으로 내구성이 향상된 막-전극 접합체의 전해질막 및 이의 제조방법
WO2020183306A1 (en) 2019-03-12 2020-09-17 3M Innovative Properties Company Dispersible perfluorosulfonic acid ionomer compositions
JP2023504273A (ja) 2019-12-02 2023-02-02 スリーエム イノベイティブ プロパティズ カンパニー ペルフルオロスルホン酸アイオノマーの分散性粒子
CN114901710B (zh) 2019-12-20 2024-01-30 3M创新有限公司 氟化共聚物以及包括其的组合物和制品
EP4081498A1 (en) 2019-12-23 2022-11-02 3M Innovative Properties Company Process of making fluoroolefins by thermal decomposition of fluorinated ionomers
EP4127002A1 (en) 2020-03-30 2023-02-08 3M Innovative Properties Company Fluoropolymer comprising pendent groups with ionic bis(sulfonyl)imide moiety and perfluoroether terminal group
EP4133542A1 (en) 2020-04-09 2023-02-15 3M Innovative Properties Company Composite including fluorinated polymer and salt nanoparticles and articles including the same
US20230279192A1 (en) 2020-06-08 2023-09-07 3M Innovative Properties Company Process for recycling a solid article including a fluorinated polymer
KR102855297B1 (ko) 2020-11-24 2025-09-03 현대자동차주식회사 연료전지의 촉매용 지지체의 제조방법
US12341227B2 (en) 2021-06-04 2025-06-24 3M Innovative Properties Company Perfluorosulfonyl monomers suitable for fluoropolymers and fuel cell membrane articles
WO2022256669A1 (en) 2021-06-04 2022-12-08 3M Innovative Properties Company Fluorinated ionomers, polymer electrolyte membranes, fuel cells, and methods
US20250239638A1 (en) 2021-10-07 2025-07-24 3M Innovative Properties Company Composite including fluorinated polymer and lithium fluoride nanoparticles and articles including the same
WO2023111750A1 (en) 2021-12-13 2023-06-22 3M Innovative Properties Company Process for recycling a solid article including a fluorinated polymer
KR20260030707A (ko) * 2023-04-19 2026-03-06 셀라다인 테크놀로지스, 인코포레이티드 자유-라디칼 보호 막

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