IT1296949B1 - Cella a combustibile a membrana polimerica operante a temperatura superiore a 100°c - Google Patents

Cella a combustibile a membrana polimerica operante a temperatura superiore a 100°c

Info

Publication number
IT1296949B1
IT1296949B1 IT97MI002733A ITMI972733A IT1296949B1 IT 1296949 B1 IT1296949 B1 IT 1296949B1 IT 97MI002733 A IT97MI002733 A IT 97MI002733A IT MI972733 A ITMI972733 A IT MI972733A IT 1296949 B1 IT1296949 B1 IT 1296949B1
Authority
IT
Italy
Prior art keywords
fuel cell
temperature above
polymer membrane
membrane fuel
cell operating
Prior art date
Application number
IT97MI002733A
Other languages
English (en)
Inventor
Vincenzo Antonucci
Antonino Arico'
Original Assignee
De Nora Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by De Nora Spa filed Critical De Nora Spa
Priority to IT97MI002733A priority Critical patent/IT1296949B1/it
Priority to US09/206,849 priority patent/US6156184A/en
Priority to CA002255515A priority patent/CA2255515A1/en
Priority to DK98123433T priority patent/DK0926754T3/da
Priority to DE69813752T priority patent/DE69813752T2/de
Priority to EP98123433A priority patent/EP0926754B1/en
Priority to ES98123433T priority patent/ES2198030T3/es
Priority to JP10349825A priority patent/JPH11250922A/ja
Publication of ITMI972733A1 publication Critical patent/ITMI972733A1/it
Application granted granted Critical
Publication of IT1296949B1 publication Critical patent/IT1296949B1/it
Priority to US09/702,322 priority patent/US6780537B1/en

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1067—Polymeric electrolyte materials characterised by their physical properties, e.g. porosity, ionic conductivity or thickness
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2243—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2243—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231
    • C08J5/225—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231 containing fluorine
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0289—Means for holding the electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1041—Polymer electrolyte composites, mixtures or blends
    • H01M8/1046—Mixtures of at least one polymer and at least one additive
    • H01M8/1048—Ion-conducting additives, e.g. ion-conducting particles, heteropolyacids, metal phosphate or polybenzimidazole with phosphoric acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Electrochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Composite Materials (AREA)
  • Fuel Cell (AREA)
IT97MI002733A 1997-12-10 1997-12-10 Cella a combustibile a membrana polimerica operante a temperatura superiore a 100°c IT1296949B1 (it)

Priority Applications (9)

Application Number Priority Date Filing Date Title
IT97MI002733A IT1296949B1 (it) 1997-12-10 1997-12-10 Cella a combustibile a membrana polimerica operante a temperatura superiore a 100°c
US09/206,849 US6156184A (en) 1997-12-10 1998-12-07 Polymeric membrane electrochemical cell operating at temperatures above 100° C.
CA002255515A CA2255515A1 (en) 1997-12-10 1998-12-08 Polymeric membrane electrochemical cell operating at temperatures above 100 c
DE69813752T DE69813752T2 (de) 1997-12-10 1998-12-09 Elektrochemische Polymermembranzelle mit Betriebstemperatur über 100 C
DK98123433T DK0926754T3 (da) 1997-12-10 1998-12-09 Elektrokemisk celle med polymermembran, der arbejder ved temperaturer over 100øC
EP98123433A EP0926754B1 (en) 1997-12-10 1998-12-09 Polymeric membrane electrochemical cell operating at temperatures above 100 C
ES98123433T ES2198030T3 (es) 1997-12-10 1998-12-09 Celula electroquimica con membrana polimera que opera de temperatura mayor que 100 grados c.
JP10349825A JPH11250922A (ja) 1997-12-10 1998-12-09 １００℃を超える温度で動作するポリマー膜電気化学的電池
US09/702,322 US6780537B1 (en) 1997-12-10 2000-10-31 Polymeric membrane electrochemical cell operating at temperatures above 100 c

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT97MI002733A IT1296949B1 (it) 1997-12-10 1997-12-10 Cella a combustibile a membrana polimerica operante a temperatura superiore a 100°c

Publications (2)

Publication Number Publication Date
ITMI972733A1 ITMI972733A1 (it) 1999-06-10
IT1296949B1 true IT1296949B1 (it) 1999-08-03

Family

ID=11378343

Family Applications (1)

Application Number Title Priority Date Filing Date
IT97MI002733A IT1296949B1 (it) 1997-12-10 1997-12-10 Cella a combustibile a membrana polimerica operante a temperatura superiore a 100°c

Country Status (8)

Country Link
US (1) US6156184A (it)
EP (1) EP0926754B1 (it)
JP (1) JPH11250922A (it)
CA (1) CA2255515A1 (it)
DE (1) DE69813752T2 (it)
DK (1) DK0926754T3 (it)
ES (1) ES2198030T3 (it)
IT (1) IT1296949B1 (it)

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BR0011217A (pt) * 1999-04-30 2002-03-19 Du Pont Método para a formação de um conjunto de eletrodos de membrana, método para a formação de uma membrana revestida com catalisador e conjunto de eletrodos de membrana
WO2001003212A2 (de) * 1999-07-05 2001-01-11 Siemens Aktiengesellschaft Hochtemperatur-polymer-elektrolyt-membran (htm)-brennstoffzelle, htm-brennstoffzellenanlage, verfahren zum betreiben einer htm-brennstoffzelle und/oder einer htm-brennstroffzellenanlage
DE19943244A1 (de) 1999-09-10 2001-03-15 Daimler Chrysler Ag Membran für eine Brennstoffzelle und Verfahren zur Herstellung
AU2001271398B2 (en) 2000-07-31 2007-06-28 Nuvant Systems, Inc. Hydrogen permeable membrane for use in fuel cells, and partial reformate fuel cell system having reforming catalysts in the anode fuel cell compartment
WO2002021619A1 (fr) * 2000-09-01 2002-03-14 Hitachi, Ltd. Pile a combustible electrolytique a polymere solide
IT1319649B1 (it) * 2000-11-14 2003-10-23 Nuvera Fuel Cells Europ Srl Assieme membrana-elettrodo per cella a combustibile a membranapolimerica.
ITMI20010459A1 (it) 2001-03-06 2002-09-06 Nuvera Fuel Cells Europ Srl Metodi per il funzionamento di celle a combustibile alimentate con gas contenenti idrogeno monossido di carbonio e raltivi dispositivi
WO2002072678A1 (en) * 2001-03-14 2002-09-19 Princeton University High temperature, carbon monoxide-tolerant perfluorosulfonic acid composite membranes and methods of making same
GB0107075D0 (en) * 2001-03-21 2001-05-09 Victrex Mfg Ltd Fuel cell
US6689501B2 (en) * 2001-05-25 2004-02-10 Ballard Power Systems Inc. Composite ion exchange membrane for use in a fuel cell
EP1284518A1 (en) * 2001-08-16 2003-02-19 Samsung Electronics Co., Ltd. Reinforced composite ionic conductive polymer membrane and fuel cell adopting the same
US6756142B2 (en) * 2001-10-31 2004-06-29 Motorola, Inc. Fuel cell using non-linear positive temperature coefficient material
US6743543B2 (en) 2001-10-31 2004-06-01 Motorola, Inc. Fuel cell using variable porosity gas diffusion material
US20030170521A1 (en) * 2001-11-16 2003-09-11 Zhengming Zhang Proton exchange membrane (PEM) for a fuel cell
ITPG20020013A1 (it) * 2002-03-13 2003-09-15 Fuma Tech Membrane a conduzione protonica contenenti fosfato di zirconio o fosfati solfoarilenfosfonati di zirconio dispersi in una matrice polimerica
US20050053818A1 (en) * 2002-03-28 2005-03-10 Marc St-Arnaud Ion exchange composite material based on proton conductive functionalized inorganic support compounds in a polymer matrix
CA2489299A1 (en) 2002-06-13 2003-12-24 Darryl Pollica Preferential oxidation reactor temperature regulation
US7601759B2 (en) * 2003-10-10 2009-10-13 Bdf Ip Holdings Ltd. Water insoluble additive for improving conductivity of an ion exchange membrane
US20050227135A1 (en) * 2004-04-12 2005-10-13 Elena Chalkova Composite membrane for fuel cell and fuel cells incorporating said membranes
CN100345326C (zh) * 2004-05-14 2007-10-24 武汉理工大学 一种单元组合式高温质子交换膜燃料电池膜电极及制备
US8101317B2 (en) * 2004-09-20 2012-01-24 3M Innovative Properties Company Durable fuel cell having polymer electrolyte membrane comprising manganese oxide
US7572534B2 (en) * 2004-09-20 2009-08-11 3M Innovative Properties Company Fuel cell membrane electrode assembly
US8628871B2 (en) * 2005-10-28 2014-01-14 3M Innovative Properties Company High durability fuel cell components with cerium salt additives
US8367267B2 (en) * 2005-10-28 2013-02-05 3M Innovative Properties Company High durability fuel cell components with cerium oxide additives
US8357085B2 (en) 2009-03-31 2013-01-22 Ethicon Endo-Surgery, Inc. Devices and methods for providing access into a body cavity
KR100846478B1 (ko) 2006-05-16 2008-07-17 삼성에스디아이 주식회사 담지 촉매, 그 제조방법 및 이를 이용한 연료전지
CN100570936C (zh) * 2008-07-21 2009-12-16 中国科学院长春应用化学研究所 Nafion/介孔二氧化硅复合质子交换膜的制备方法
US9737334B2 (en) 2009-03-06 2017-08-22 Ethicon Llc Methods and devices for accessing a body cavity
US8226553B2 (en) 2009-03-31 2012-07-24 Ethicon Endo-Surgery, Inc. Access device with insert
US8353824B2 (en) 2009-03-31 2013-01-15 Ethicon Endo-Surgery, Inc. Access method with insert
US9474540B2 (en) 2009-10-08 2016-10-25 Ethicon-Endo-Surgery, Inc. Laparoscopic device with compound angulation
US8562592B2 (en) 2010-05-07 2013-10-22 Ethicon Endo-Surgery, Inc. Compound angle laparoscopic methods and devices
US9226760B2 (en) 2010-05-07 2016-01-05 Ethicon Endo-Surgery, Inc. Laparoscopic devices with flexible actuation mechanisms
US8460337B2 (en) 2010-06-09 2013-06-11 Ethicon Endo-Surgery, Inc. Selectable handle biasing
CN101938002B (zh) * 2010-07-23 2012-09-05 北京化工大学 全氟磺酸树脂/磺化SiO2分子筛复合质子交换膜及其制备方法
KR102586433B1 (ko) * 2018-04-26 2023-10-06 현대자동차주식회사 연료전지용 전해질막의 제조방법 및 이로 제조된 전해질막
CN111048811B (zh) * 2019-01-29 2020-09-18 南京攀峰赛奥能源科技有限公司 一种复合质子交换膜、制备方法以及质子交换膜燃料电池

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US5366818A (en) * 1991-01-15 1994-11-22 Ballard Power Systems Inc. Solid polymer fuel cell systems incorporating water removal at the anode
JPH06251781A (ja) * 1993-02-26 1994-09-09 Asahi Chem Ind Co Ltd 表面に電極触媒層を有する燃料電池用隔膜製造方法
US5766787A (en) * 1993-06-18 1998-06-16 Tanaka Kikinzoku Kogyo K.K. Solid polymer electrolyte composition
JP3489148B2 (ja) * 1993-09-03 2004-01-19 トヨタ自動車株式会社 高分子イオン交換膜の不純物除去方法

Also Published As

Publication number Publication date
EP0926754A1 (en) 1999-06-30
US6156184A (en) 2000-12-05
DE69813752D1 (de) 2003-05-28
DK0926754T3 (da) 2003-08-18
ES2198030T3 (es) 2004-01-16
DE69813752T2 (de) 2004-02-26
EP0926754B1 (en) 2003-04-23
CA2255515A1 (en) 1999-06-10
ITMI972733A1 (it) 1999-06-10
JPH11250922A (ja) 1999-09-17

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