CN101297430B - 具有铈盐添加剂的高耐久性燃料电池元件 - Google Patents

具有铈盐添加剂的高耐久性燃料电池元件 Download PDF

Info

Publication number
CN101297430B
CN101297430B CN2006800402889A CN200680040288A CN101297430B CN 101297430 B CN101297430 B CN 101297430B CN 2006800402889 A CN2006800402889 A CN 2006800402889A CN 200680040288 A CN200680040288 A CN 200680040288A CN 101297430 B CN101297430 B CN 101297430B
Authority
CN
China
Prior art keywords
polymer
typically
polymer electrolyte
cerium
electrolyte membrane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN2006800402889A
Other languages
English (en)
Chinese (zh)
Other versions
CN101297430A (zh
Inventor
马修·H·弗雷
丹尼尔·M·皮尔庞特
史蒂文·J·汉罗克
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of CN101297430A publication Critical patent/CN101297430A/zh
Application granted granted Critical
Publication of CN101297430B publication Critical patent/CN101297430B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1041—Polymer electrolyte composites, mixtures or blends
    • H01M8/1046—Mixtures of at least one polymer and at least one additive
    • H01M8/1051—Non-ion-conducting additives, e.g. stabilisers, SiO2 or ZrO2
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2237—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds containing fluorine
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1027—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1032—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1058—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. in situ polymerisation or in situ crosslinking
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1081—Polymeric electrolyte materials characterised by the manufacturing processes starting from solutions, dispersions or slurries exclusively of polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2327/18—Homopolymers or copolymers of tetrafluoroethylene
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0088—Composites
    • H01M2300/0091—Composites in the form of mixtures
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Composite Materials (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Fuel Cell (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
CN2006800402889A 2005-10-28 2006-10-24 具有铈盐添加剂的高耐久性燃料电池元件 Active CN101297430B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/262,268 US8628871B2 (en) 2005-10-28 2005-10-28 High durability fuel cell components with cerium salt additives
US11/262,268 2005-10-28
PCT/US2006/041493 WO2007120189A2 (en) 2005-10-28 2006-10-24 High durability fuel cell components with cerium salt additives

Publications (2)

Publication Number Publication Date
CN101297430A CN101297430A (zh) 2008-10-29
CN101297430B true CN101297430B (zh) 2010-06-23

Family

ID=37996772

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2006800402889A Active CN101297430B (zh) 2005-10-28 2006-10-24 具有铈盐添加剂的高耐久性燃料电池元件

Country Status (5)

Country Link
US (2) US8628871B2 (https=)
JP (1) JP2009514172A (https=)
CN (1) CN101297430B (https=)
DE (1) DE112006003025T5 (https=)
WO (1) WO2007120189A2 (https=)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005124911A1 (ja) 2004-06-22 2005-12-29 Asahi Glass Company, Limited 固体高分子型燃料電池用電解質膜、その製造方法及び固体高分子型燃料電池用膜電極接合体
JP3897059B2 (ja) 2004-06-22 2007-03-22 旭硝子株式会社 液状組成物、その製造方法及び固体高分子形燃料電池用膜電極接合体の製造方法
US7572534B2 (en) 2004-09-20 2009-08-11 3M Innovative Properties Company Fuel cell membrane electrode assembly
US8101317B2 (en) * 2004-09-20 2012-01-24 3M Innovative Properties Company Durable fuel cell having polymer electrolyte membrane comprising manganese oxide
US8367267B2 (en) * 2005-10-28 2013-02-05 3M Innovative Properties Company High durability fuel cell components with cerium oxide additives
US8628871B2 (en) * 2005-10-28 2014-01-14 3M Innovative Properties Company High durability fuel cell components with cerium salt additives
US8722569B2 (en) 2006-03-13 2014-05-13 E I Du Pont De Nemours And Company Peroxide decomposition catalyst particles
US8663866B2 (en) 2006-03-13 2014-03-04 E I Du Pont De Nemours And Company Stable proton exchange membranes and membrane electrode assemblies
US20080107945A1 (en) * 2006-11-08 2008-05-08 Gm Global Technology Operations, Inc. Fuel cell substrate with an overcoat
US7593823B2 (en) * 2006-11-21 2009-09-22 The Furukawa Electric Co., Ltd Method and device for determining state of battery, and battery power supply system therewith
JP4765908B2 (ja) * 2006-11-22 2011-09-07 旭硝子株式会社 固体高分子電解質膜及び固体高分子型燃料電池用膜電極接合体
JP5431958B2 (ja) * 2006-12-29 2014-03-05 スリーエム イノベイティブ プロパティズ カンパニー 耐久性のあるポリマー電解質薄膜を製造する方法
CN101919100B (zh) * 2007-11-09 2014-10-01 3M创新有限公司 包含杂多酸的聚合物电解质
US7989115B2 (en) * 2007-12-14 2011-08-02 Gore Enterprise Holdings, Inc. Highly stable fuel cell membranes and methods of making them
CN101953012B (zh) 2007-12-27 2014-05-07 3M创新有限公司 具有组合添加剂的耐久性燃料电池膜电极组件
WO2009086364A1 (en) * 2007-12-27 2009-07-09 3M Innovative Properties Company Electrode inks containing coalescing solvents
DE102008026916A1 (de) 2008-06-05 2009-12-17 Fresenius Medical Care Deutschland Gmbh Organizer zum lösbaren Aufnehmen von Komponenten von Blutschlauchsätzen und Verfahren zum Herstellen sowie zum Vorbereiten desselben
WO2009157894A1 (en) * 2008-06-24 2009-12-30 Utc Power Corporation Membrane with increased durability from partial ion exchange
CN102834374B (zh) 2010-04-16 2016-08-03 3M创新有限公司 质子传导材料
CN103004001B (zh) * 2010-05-25 2016-02-17 3M创新有限公司 强化的电解质膜
EP3138875B1 (en) 2011-08-04 2019-11-20 3M Innovative Properties Company Crosslinked fluorinated polymers with manganese or cerium as additives
JP6941604B2 (ja) 2015-09-23 2021-09-29 スリーエム イノベイティブ プロパティズ カンパニー スルホニルペンダント基を有するテトラフルオロエチレンのコポリマーを作製する方法
EP3681948A4 (en) 2017-09-14 2021-07-14 3M Innovative Properties Company FLUORINATED COPOLYMER WITH SULFONYL SIDE GROUPS AS WELL AS COMPOSITIONS AND ARTICLES THEREFORE
KR102791509B1 (ko) * 2018-12-20 2025-04-03 현대자동차주식회사 화학적으로 내구성이 향상된 막-전극 접합체의 전해질막 및 이의 제조방법
WO2020183306A1 (en) 2019-03-12 2020-09-17 3M Innovative Properties Company Dispersible perfluorosulfonic acid ionomer compositions
KR102869213B1 (ko) * 2019-11-01 2025-10-10 현대자동차주식회사 내구성 및 수소 이온 전도성이 우수한 막-전극 접합체 및 이의 제조방법
JP2023504273A (ja) 2019-12-02 2023-02-02 スリーエム イノベイティブ プロパティズ カンパニー ペルフルオロスルホン酸アイオノマーの分散性粒子
CN114901710B (zh) 2019-12-20 2024-01-30 3M创新有限公司 氟化共聚物以及包括其的组合物和制品
EP4081498A1 (en) 2019-12-23 2022-11-02 3M Innovative Properties Company Process of making fluoroolefins by thermal decomposition of fluorinated ionomers
EP4127002A1 (en) 2020-03-30 2023-02-08 3M Innovative Properties Company Fluoropolymer comprising pendent groups with ionic bis(sulfonyl)imide moiety and perfluoroether terminal group
EP4133542A1 (en) 2020-04-09 2023-02-15 3M Innovative Properties Company Composite including fluorinated polymer and salt nanoparticles and articles including the same
US20230279192A1 (en) 2020-06-08 2023-09-07 3M Innovative Properties Company Process for recycling a solid article including a fluorinated polymer
KR102855297B1 (ko) 2020-11-24 2025-09-03 현대자동차주식회사 연료전지의 촉매용 지지체의 제조방법
US12341227B2 (en) 2021-06-04 2025-06-24 3M Innovative Properties Company Perfluorosulfonyl monomers suitable for fluoropolymers and fuel cell membrane articles
WO2022256669A1 (en) 2021-06-04 2022-12-08 3M Innovative Properties Company Fluorinated ionomers, polymer electrolyte membranes, fuel cells, and methods
US20250239638A1 (en) 2021-10-07 2025-07-24 3M Innovative Properties Company Composite including fluorinated polymer and lithium fluoride nanoparticles and articles including the same
WO2023111750A1 (en) 2021-12-13 2023-06-22 3M Innovative Properties Company Process for recycling a solid article including a fluorinated polymer
KR20260030707A (ko) * 2023-04-19 2026-03-06 셀라다인 테크놀로지스, 인코포레이티드 자유-라디칼 보호 막

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6864006B2 (en) * 2001-01-09 2005-03-08 National Institute Of Advanced Industrial Science And Technology Proton-conducting membrane, method for producing the same, and fuel cell using the same

Family Cites Families (100)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB149233A (en) 1920-07-12 1922-01-12 Heylandt Ges Fur App Bau Mit B Improved method and means for storing, transporting, and delivering for use gas under pressure from liquefied gases
US3382105A (en) 1964-12-29 1968-05-07 Nasa Usa Ion-exchange membrane with platinum electrode assembly
US3369938A (en) 1966-01-03 1968-02-20 Varta Ag Catalytic electrodes and fuel cells therewith
US4021369A (en) 1973-06-29 1977-05-03 Sun Ventures, Inc. Ion-exchanged transition metal catalysts for the direct oxidation of olefins to epoxyalcohols
GB1449233A (en) 1973-10-31 1976-09-15 Exxon Research Engineering Co Buffer electrolyte fuel cell with low cost electrodes
SE7603539L (sv) 1975-03-31 1976-10-01 Kureha Chemical Ind Co Ltd Katjonbytarmembran
JPS5482042A (en) 1977-12-14 1979-06-29 Hitachi Ltd Fuel cell
US4340276A (en) * 1978-11-01 1982-07-20 Minnesota Mining And Manufacturing Company Method of producing a microstructured surface and the article produced thereby
US4284835A (en) 1979-07-05 1981-08-18 Shell Oil Company Hydrogenation process
US4358545A (en) * 1980-06-11 1982-11-09 The Dow Chemical Company Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000
US4416801A (en) 1980-12-15 1983-11-22 E. I. Du Pont De Nemours & Co. Toluic acid
US4433082A (en) * 1981-05-01 1984-02-21 E. I. Du Pont De Nemours And Company Process for making liquid composition of perfluorinated ion exchange polymer, and product thereof
US4568598A (en) * 1984-10-30 1986-02-04 Minnesota Mining And Manufacturing Company Article with reduced friction polymer sheet support
US4752369A (en) * 1984-11-05 1988-06-21 The Dow Chemical Company Electrochemical cell with improved energy efficiency
GB8605817D0 (en) 1986-03-10 1986-04-16 Ici Plc Membrane
DE3614000A1 (de) 1986-04-25 1987-10-29 Boehringer Mannheim Gmbh Neue isochinolindione, verfahren zu ihrer herstellung und diese verbindungen enthaltende arzneimittel
US4812352A (en) * 1986-08-25 1989-03-14 Minnesota Mining And Manufacturing Company Article having surface layer of uniformly oriented, crystalline, organic microstructures
US5039561A (en) * 1986-08-25 1991-08-13 Minnesota Mining And Manufacturing Company Method for preparing an article having surface layer of uniformly oriented, crystalline, organic microstructures
US4741744A (en) * 1987-02-20 1988-05-03 The Dow Chemical Company Hydrated metal ionomer membranes for gas separation
US5176786A (en) * 1988-07-13 1993-01-05 Minnesota Mining And Manufacturing Company Organic thin film controlled molecular epitaxy
CA2043583C (en) * 1990-05-31 1999-01-05 Fumio Hanada Bipolar membrane and method for its production
JPH04162365A (ja) 1990-10-25 1992-06-05 Tanaka Kikinzoku Kogyo Kk 燃料電池用電極の作製法
JPH05208135A (ja) 1991-02-23 1993-08-20 Tanaka Kikinzoku Kogyo Kk 負極用電極触媒
US5336558A (en) * 1991-06-24 1994-08-09 Minnesota Mining And Manufacturing Company Composite article comprising oriented microstructures
JPH05258755A (ja) 1991-12-31 1993-10-08 Stonehard Assoc Inc 高分子固体電解質型燃料電池の製造方法
JP3271801B2 (ja) 1992-09-22 2002-04-08 田中貴金属工業株式会社 高分子固体電解質型燃料電池、該燃料電池の加湿方法、及び製造方法
US5523181A (en) 1992-09-25 1996-06-04 Masahiro Watanabe Polymer solid-electrolyte composition and electrochemical cell using the composition
US5338430A (en) * 1992-12-23 1994-08-16 Minnesota Mining And Manufacturing Company Nanostructured electrode membranes
BE1006774A3 (fr) 1993-02-24 1994-12-06 Univ Bruxelles MEMBRANE BIPOLAIRE, PROCEDE POUR SON OBTENTION ET UTILISATION DE CELLE-CI POUR LA PRODUCTION DE BASES ET D'ACIDES OU POUR LA REGULATION DU pH D'UNE SOLUTION AQUEUSE.
US5766787A (en) 1993-06-18 1998-06-16 Tanaka Kikinzoku Kogyo K.K. Solid polymer electrolyte composition
DE69425196T2 (de) 1993-06-18 2000-12-21 Tanaka Kikinzoku Kogyo K.K., Tokio/Tokyo Elektrochemische Zelle die eine polymere Feststoff-Elektrolytzusammensetzung enthält.
JPH08227716A (ja) 1995-02-22 1996-09-03 Tanaka Kikinzoku Kogyo Kk 高分子固体電解質型燃料電池用電極構成原料及びその製造方法
WO1997011081A1 (en) * 1995-09-19 1997-03-27 E.I. Du Pont De Nemours And Company Modified fluorosulfonic acids
JPH1092444A (ja) 1996-09-13 1998-04-10 Japan Gore Tex Inc 電気化学反応装置用固体高分子電解質複合体及びそれを用いた電気化学反応装置
US6059943A (en) 1997-07-30 2000-05-09 Lynntech, Inc. Composite membrane suitable for use in electrochemical devices
US6635384B2 (en) 1998-03-06 2003-10-21 Gore Enterprise Holdings, Inc. Solid electrolyte composite for electrochemical reaction apparatus
US5879827A (en) * 1997-10-10 1999-03-09 Minnesota Mining And Manufacturing Company Catalyst for membrane electrode assembly and method of making
US5879828A (en) * 1997-10-10 1999-03-09 Minnesota Mining And Manufacturing Company Membrane electrode assembly
IT1296949B1 (it) * 1997-12-10 1999-08-03 De Nora Spa Cella a combustibile a membrana polimerica operante a temperatura superiore a 100°c
JP2000106203A (ja) 1998-09-30 2000-04-11 Aisin Seiki Co Ltd 固体高分子電解質膜及び燃料電池用電極及び固体高分子電解質型燃料電池
GB9822576D0 (en) 1998-10-16 1998-12-09 Johnson Matthey Plc Membrane
DE19917812C2 (de) 1999-04-20 2002-11-21 Siemens Ag Membranelektrodeneinheit für eine selbstbefeuchtende Brennstoffzelle, Verfahren zu ihrer Herstellung und Brennstoffzellenbatterie mit einer solchen Membranelektrodeneinheit
DE19919988A1 (de) * 1999-04-30 2000-11-02 Univ Stuttgart Protonenleitende Keramik-Polymer-Kompositmembran für den Temperaturbereich bis 300 DEG C
US6380126B1 (en) 1999-08-20 2002-04-30 Medis El Ltd Class of electrocatalysts and a gas diffusion electrode based thereon for fuel cells
JP4539896B2 (ja) * 1999-09-17 2010-09-08 独立行政法人産業技術総合研究所 プロトン伝導性膜、その製造方法及びそれを用いた燃料電池
JP3925764B2 (ja) 1999-10-19 2007-06-06 株式会社豊田中央研究所 高耐久性固体高分子電解質
US6482763B2 (en) 1999-12-29 2002-11-19 3M Innovative Properties Company Suboxide fuel cell catalyst for enhanced reformate tolerance
IL150645A0 (en) 2000-01-18 2003-02-12 Univ Ramot Fuel cell with proton conducting membrane
KR100343209B1 (ko) 2000-03-27 2002-07-10 윤종용 강화제가 부가된 복합 이온 전도성 고분자막 및 이를채용하고 있는 연료전지
CA2403517A1 (en) 2000-04-18 2001-10-25 3M Innovative Properties Company Membrane electrode assembly having annealed polymer electrolyte membrane
JP2001321664A (ja) 2000-05-12 2001-11-20 Toyota Motor Corp 吸着材およびその製造方法
GB0016379D0 (en) 2000-07-05 2000-08-23 Johnson Matthey Plc Electrochemical cell
KR20000063843A (ko) 2000-08-07 2000-11-06 이홍기 고분자 전해질 연료전지용 백금-금속산화물 촉매의 제조방법
JP3411897B2 (ja) 2000-10-12 2003-06-03 本田技研工業株式会社 固体高分子型燃料電池の活性固体高分子電解質膜
US6630263B1 (en) 2000-11-20 2003-10-07 Plug Power Inc. Fuel cell systems and methods
WO2002061871A2 (en) 2001-01-29 2002-08-08 3M Innovative Properties Company Decal method of making membrane electrode assemblies for fuel cells
KR100916280B1 (ko) * 2001-05-25 2009-09-10 히타치 쓰루 가부시키가이샤 날끝 교환식 회전 공구
DE10130828A1 (de) 2001-06-27 2003-01-16 Basf Ag Brennstoffzelle
JP2003017074A (ja) 2001-07-02 2003-01-17 Honda Motor Co Ltd 燃料電池
EP1415365A4 (en) 2001-07-13 2009-01-14 Univ Brown Res Found POLYMER ELECTROLYTE MEMBRANE FOR ELECTROCHEMICAL AND OTHER APPLICATIONS
JP2003059497A (ja) 2001-08-08 2003-02-28 Mori Fukuo 燃料電池アノード電極保護触媒
JP2003123777A (ja) 2001-10-19 2003-04-25 Matsushita Electric Ind Co Ltd 高分子電解質型燃料電池
JP4472258B2 (ja) 2002-01-17 2010-06-02 日揮触媒化成株式会社 燃料電池用プロトン導電膜および該膜を備えた燃料電池
DE10209774A1 (de) 2002-02-28 2004-07-29 Universität Stuttgart - Institut für Chemische Verfahrenstechnik Composites und Compositemembranen
JP3932409B2 (ja) * 2002-05-23 2007-06-20 ミネベア株式会社 ブラシレス直流１相モータのドライブ回路
JP2004018573A (ja) * 2002-06-13 2004-01-22 Kanegafuchi Chem Ind Co Ltd プロトン伝導性高分子膜
US6630265B1 (en) * 2002-08-13 2003-10-07 Hoku Scientific, Inc. Composite electrolyte for fuel cells
US7112386B2 (en) 2002-09-04 2006-09-26 Utc Fuel Cells, Llc Membrane electrode assemblies with hydrogen peroxide decomposition catalyst
US6946362B2 (en) * 2002-09-06 2005-09-20 Hewlett-Packard Development Company, L.P. Method and apparatus for forming high surface area material films and membranes
JP2004134294A (ja) 2002-10-11 2004-04-30 Toyota Central Res & Dev Lab Inc 固体高分子電解質
US6624328B1 (en) 2002-12-17 2003-09-23 3M Innovative Properties Company Preparation of perfluorinated vinyl ethers having a sulfonyl fluoride end-group
US20040116742A1 (en) 2002-12-17 2004-06-17 3M Innovative Properties Company Selective reaction of hexafluoropropylene oxide with perfluoroacyl fluorides
US7348088B2 (en) 2002-12-19 2008-03-25 3M Innovative Properties Company Polymer electrolyte membrane
JP4161750B2 (ja) 2003-03-12 2008-10-08 トヨタ自動車株式会社 プロトン伝導性材料、プロトン伝導性材料膜、及び燃料電池
JP4883880B2 (ja) * 2003-06-13 2012-02-22 株式会社トクヤマ 直接メタノール型燃料電池用隔膜の製造方法
JP4979179B2 (ja) * 2003-08-22 2012-07-18 株式会社豊田中央研究所 固体高分子型燃料電池およびその製造方法
JP4574149B2 (ja) * 2003-09-17 2010-11-04 株式会社豊田中央研究所 固体高分子型燃料電池用電解質膜電極接合体および固体高分子型燃料電池
US7419741B2 (en) * 2003-09-29 2008-09-02 3M Innovative Properties Company Fuel cell cathode catalyst
US7537857B2 (en) 2003-12-17 2009-05-26 Bdf Ip Holdings Ltd. Reduced degradation of ion-exchange membranes in electrochemical fuel cells
JP4451154B2 (ja) 2004-02-17 2010-04-14 株式会社豊田中央研究所 固体高分子型燃料電池用電解質膜電極接合体および固体高分子型燃料電池
JP4997968B2 (ja) * 2004-04-02 2012-08-15 旭硝子株式会社 固体高分子形燃料電池用電解質材料、電解質膜及び膜電極接合体
JP3897059B2 (ja) * 2004-06-22 2007-03-22 旭硝子株式会社 液状組成物、その製造方法及び固体高分子形燃料電池用膜電極接合体の製造方法
WO2005124911A1 (ja) * 2004-06-22 2005-12-29 Asahi Glass Company, Limited 固体高分子型燃料電池用電解質膜、その製造方法及び固体高分子型燃料電池用膜電極接合体
US7220509B2 (en) * 2004-08-30 2007-05-22 General Motors Corporation Constituents and methods for protecting fuel cell components, including PEMs
US7572534B2 (en) 2004-09-20 2009-08-11 3M Innovative Properties Company Fuel cell membrane electrode assembly
US8101317B2 (en) 2004-09-20 2012-01-24 3M Innovative Properties Company Durable fuel cell having polymer electrolyte membrane comprising manganese oxide
JP2006099999A (ja) 2004-09-28 2006-04-13 Asahi Glass Co Ltd 固体高分子形燃料電池用電解質膜、その製造方法及び固体高分子形燃料電池用膜電極接合体
JP5247974B2 (ja) 2004-10-05 2013-07-24 旭硝子株式会社 固体高分子形水素・酸素燃料電池用電解質膜の製造方法
US20060099475A1 (en) * 2004-11-11 2006-05-11 Mitsubishi Heavy Industries, Ltd. Solid polymer electrolyte membrane electrode assembly and solid polymer electrolyte fuel cell using same
KR101135479B1 (ko) * 2005-01-26 2012-04-13 삼성에스디아이 주식회사 연료전지용 고분자 전해질막, 이의 제조방법, 및 이를포함하는 연료전지 시스템
JP4972867B2 (ja) 2005-03-15 2012-07-11 旭硝子株式会社 固体高分子形燃料電池用電解質膜、その製造方法及び固体高分子形燃料電池用膜電極接合体
JP4765401B2 (ja) 2005-05-18 2011-09-07 旭硝子株式会社 固体高分子形燃料電池用膜の製造方法及び固体高分子形燃料電池用膜電極接合体の製造方法
JP5095089B2 (ja) * 2005-05-31 2012-12-12 株式会社豊田中央研究所 固体高分子電解質、並びに、固体高分子型燃料電池及びその製造方法
EP1912272A4 (en) * 2005-07-12 2009-12-02 Asahi Glass Co Ltd ELECTROLYTE MEMBRANE FOR USE IN A FESTPOLYMER FUEL CELL, PROCESS FOR PRODUCING THE MEMBRANE AND MEMBRANE ELECTRODE ASSEMBLY FOR USE IN A FESTPOLYMER FUEL CELL
US20070082814A1 (en) 2005-10-12 2007-04-12 3M Innovative Properties Company Ternary nanocatalyst and method of making
US8367267B2 (en) * 2005-10-28 2013-02-05 3M Innovative Properties Company High durability fuel cell components with cerium oxide additives
US8628871B2 (en) * 2005-10-28 2014-01-14 3M Innovative Properties Company High durability fuel cell components with cerium salt additives
US7989115B2 (en) * 2007-12-14 2011-08-02 Gore Enterprise Holdings, Inc. Highly stable fuel cell membranes and methods of making them
CN101953012B (zh) * 2007-12-27 2014-05-07 3M创新有限公司 具有组合添加剂的耐久性燃料电池膜电极组件
CN103004001B (zh) * 2010-05-25 2016-02-17 3M创新有限公司 强化的电解质膜

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6864006B2 (en) * 2001-01-09 2005-03-08 National Institute Of Advanced Industrial Science And Technology Proton-conducting membrane, method for producing the same, and fuel cell using the same

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
JP特开2004-273384A 2004.09.30

Also Published As

Publication number Publication date
US20070099053A1 (en) 2007-05-03
US8628871B2 (en) 2014-01-14
US20140093808A1 (en) 2014-04-03
WO2007120189A3 (en) 2007-12-13
WO2007120189A2 (en) 2007-10-25
US9431670B2 (en) 2016-08-30
JP2009514172A (ja) 2009-04-02
CN101297430A (zh) 2008-10-29
DE112006003025T5 (de) 2008-11-06

Similar Documents

Publication Publication Date Title
CN101297430B (zh) 具有铈盐添加剂的高耐久性燃料电池元件
JP6231588B2 (ja) 酸化セリウム添加物を有する高い耐久性の燃料電池構成要素
US7803847B2 (en) Fuel cell membrane electrode assembly
US8092954B2 (en) Method of making a fuel cell polymer electrolyte membrane comprising manganese oxide
WO2008083091A1 (en) Method of making durable polymer electrolyte membranes
Frey et al. High durability fuel cell components with cerium salt additives

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant