JP2009511686A - カプセル化発光顔料 - Google Patents

Info

Publication number

JP2009511686A

JP2009511686A JP2008534990A JP2008534990A JP2009511686A JP 2009511686 A JP2009511686 A JP 2009511686A JP 2008534990 A JP2008534990 A JP 2008534990A JP 2008534990 A JP2008534990 A JP 2008534990A JP 2009511686 A JP2009511686 A JP 2009511686A

Authority

JP

Japan

Prior art keywords

luminescent pigment

group

microencapsulated

polymer

butyl

Prior art date

2005-10-12

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Pending

Links

• Espacenet
• Global Dossier
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• 239000000049 pigment Substances 0.000 title claims abstract description 114
• 239000000203 mixture Substances 0.000 claims abstract description 61
• 229920000642 polymer Polymers 0.000 claims description 66
• 239000000654 additive Substances 0.000 claims description 32
• 125000004432 carbon atom Chemical group C* 0.000 claims description 32
• 238000000034 method Methods 0.000 claims description 23
• 125000000217 alkyl group Chemical group 0.000 claims description 20
• 239000003094 microcapsule Substances 0.000 claims description 17
• 229920001169 thermoplastic Polymers 0.000 claims description 17
• 239000004952 Polyamide Substances 0.000 claims description 14
• 229920002647 polyamide Polymers 0.000 claims description 14
• 229920006037 cross link polymer Polymers 0.000 claims description 13
• 230000000996 additive effect Effects 0.000 claims description 12
• 229920000877 Melamine resin Polymers 0.000 claims description 11
• 239000002245 particle Substances 0.000 claims description 11
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
• 239000004417 polycarbonate Substances 0.000 claims description 10
• 238000006116 polymerization reaction Methods 0.000 claims description 10
• 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 claims description 9
• CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 claims description 9
• 238000006243 chemical reaction Methods 0.000 claims description 8
• 230000008635 plant growth Effects 0.000 claims description 8
• 239000004814 polyurethane Substances 0.000 claims description 8
• GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 claims description 7
• 238000010521 absorption reaction Methods 0.000 claims description 7
• QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 7
• 239000012964 benzotriazole Substances 0.000 claims description 7
• 239000003795 chemical substances by application Substances 0.000 claims description 7
• 238000011065 in-situ storage Methods 0.000 claims description 7
• QDLAGTHXVHQKRE-UHFFFAOYSA-N lichenxanthone Natural products COC1=CC(O)=C2C(=O)C3=C(C)C=C(OC)C=C3OC2=C1 QDLAGTHXVHQKRE-UHFFFAOYSA-N 0.000 claims description 7
• 229920000728 polyester Polymers 0.000 claims description 7
• 230000005855 radiation Effects 0.000 claims description 7
• 229920002396 Polyurea Polymers 0.000 claims description 6
• 239000003963 antioxidant agent Substances 0.000 claims description 6
• AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims description 6
• 229920002635 polyurethane Polymers 0.000 claims description 6
• 239000000126 substance Substances 0.000 claims description 6
• BCHZICNRHXRCHY-UHFFFAOYSA-N 2h-oxazine Chemical compound N1OC=CC=C1 BCHZICNRHXRCHY-UHFFFAOYSA-N 0.000 claims description 5
• 239000004793 Polystyrene Substances 0.000 claims description 5
• 229920001807 Urea-formaldehyde Polymers 0.000 claims description 5
• 239000006096 absorbing agent Substances 0.000 claims description 5
• PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims description 5
• 150000004056 anthraquinones Chemical group 0.000 claims description 5
• 239000000945 filler Substances 0.000 claims description 5
• IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 claims description 5
• 239000004611 light stabiliser Substances 0.000 claims description 5
• XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 claims description 5
• 229920000098 polyolefin Polymers 0.000 claims description 5
• 229920002223 polystyrene Polymers 0.000 claims description 5
• SWAGSGUXOCHFHN-UHFFFAOYSA-N 12h-benzo[b]xanthene Chemical compound C1=CC=C2C=C3CC4=CC=CC=C4OC3=CC2=C1 SWAGSGUXOCHFHN-UHFFFAOYSA-N 0.000 claims description 4
• MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 4
• 108010010803 Gelatin Proteins 0.000 claims description 4
• 239000006057 Non-nutritive feed additive Substances 0.000 claims description 4
• KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 claims description 4
• 239000002216 antistatic agent Substances 0.000 claims description 4
• 150000007656 barbituric acids Chemical class 0.000 claims description 4
• XJHABGPPCLHLLV-UHFFFAOYSA-N benzo[de]isoquinoline-1,3-dione Chemical compound C1=CC(C(=O)NC2=O)=C3C2=CC=CC3=C1 XJHABGPPCLHLLV-UHFFFAOYSA-N 0.000 claims description 4
• 239000007859 condensation product Substances 0.000 claims description 4
• TXCDCPKCNAJMEE-UHFFFAOYSA-N dibenzofuran Chemical compound C1=CC=C2C3=CC=CC=C3OC2=C1 TXCDCPKCNAJMEE-UHFFFAOYSA-N 0.000 claims description 4
• 239000007850 fluorescent dye Substances 0.000 claims description 4
• SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 claims description 4
• 229920000159 gelatin Polymers 0.000 claims description 4
• 239000008273 gelatin Substances 0.000 claims description 4
• 235000019322 gelatine Nutrition 0.000 claims description 4
• 235000011852 gelatine desserts Nutrition 0.000 claims description 4
• 229920001568 phenolic resin Polymers 0.000 claims description 4
• 229920000058 polyacrylate Polymers 0.000 claims description 4
• 229920002239 polyacrylonitrile Polymers 0.000 claims description 4
• 229920000515 polycarbonate Polymers 0.000 claims description 4
• 229920000647 polyepoxide Polymers 0.000 claims description 4
• ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 claims description 4
• 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
• 239000012779 reinforcing material Substances 0.000 claims description 4
• 239000000377 silicon dioxide Substances 0.000 claims description 4
• JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims description 3
• IEJPPSMHUUQABK-UHFFFAOYSA-N 2,4-diphenyl-4h-1,3-oxazol-5-one Chemical compound O=C1OC(C=2C=CC=CC=2)=NC1C1=CC=CC=C1 IEJPPSMHUUQABK-UHFFFAOYSA-N 0.000 claims description 3
• AGIJRRREJXSQJR-UHFFFAOYSA-N 2h-thiazine Chemical compound N1SC=CC=C1 AGIJRRREJXSQJR-UHFFFAOYSA-N 0.000 claims description 3
• JKOCGAMDKVAHCI-UHFFFAOYSA-N 6,7-Benzocoumarin Chemical compound C1=CC=C2C=C(OC(=O)C=C3)C3=CC2=C1 JKOCGAMDKVAHCI-UHFFFAOYSA-N 0.000 claims description 3
• 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
• 125000005605 benzo group Chemical group 0.000 claims description 3
• 229920002678 cellulose Polymers 0.000 claims description 3
• 239000001913 cellulose Substances 0.000 claims description 3
• 230000002708 enhancing effect Effects 0.000 claims description 3
• 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
• 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 claims description 3
• 229920000193 polymethacrylate Polymers 0.000 claims description 3
• 239000011118 polyvinyl acetate Substances 0.000 claims description 3
• 229920002689 polyvinyl acetate Polymers 0.000 claims description 3
• TZMSYXZUNZXBOL-UHFFFAOYSA-N 10H-phenoxazine Chemical compound C1=CC=C2NC3=CC=CC=C3OC2=C1 TZMSYXZUNZXBOL-UHFFFAOYSA-N 0.000 claims description 2
• YOSZEPWSVKKQOV-UHFFFAOYSA-N 12h-benzo[a]phenoxazine Chemical compound C1=CC=CC2=C3NC4=CC=CC=C4OC3=CC=C21 YOSZEPWSVKKQOV-UHFFFAOYSA-N 0.000 claims description 2
• VVZRKVYGKNFTRR-UHFFFAOYSA-N 12h-benzo[a]xanthene Chemical compound C1=CC=CC2=C3CC4=CC=CC=C4OC3=CC=C21 VVZRKVYGKNFTRR-UHFFFAOYSA-N 0.000 claims description 2
• BDDQPKXDNUKVCC-UHFFFAOYSA-N 12h-benzo[b]phenoxazine Chemical compound C1=CC=C2C=C3NC4=CC=CC=C4OC3=CC2=C1 BDDQPKXDNUKVCC-UHFFFAOYSA-N 0.000 claims description 2
• GPYLCFQEKPUWLD-UHFFFAOYSA-N 1h-benzo[cd]indol-2-one Chemical compound C1=CC(C(=O)N2)=C3C2=CC=CC3=C1 GPYLCFQEKPUWLD-UHFFFAOYSA-N 0.000 claims description 2
• WADCPEMKIBAJHH-UHFFFAOYSA-N 3,4-diphenylpyrrole-2,5-dione Chemical compound O=C1NC(=O)C(C=2C=CC=CC=2)=C1C1=CC=CC=C1 WADCPEMKIBAJHH-UHFFFAOYSA-N 0.000 claims description 2
• GOLORTLGFDVFDW-UHFFFAOYSA-N 3-(1h-benzimidazol-2-yl)-7-(diethylamino)chromen-2-one Chemical compound C1=CC=C2NC(C3=CC4=CC=C(C=C4OC3=O)N(CC)CC)=NC2=C1 GOLORTLGFDVFDW-UHFFFAOYSA-N 0.000 claims description 2
• VDISGEKPIVMONQ-UHFFFAOYSA-N 7h-benzo[c]phenoxazine Chemical compound C1=CC2=CC=CC=C2C2=C1NC1=CC=CC=C1O2 VDISGEKPIVMONQ-UHFFFAOYSA-N 0.000 claims description 2
• RGHINSLFCBMCFS-UHFFFAOYSA-N 7h-benzo[c]xanthene Chemical compound C1=CC2=CC=CC=C2C2=C1CC1=CC=CC=C1O2 RGHINSLFCBMCFS-UHFFFAOYSA-N 0.000 claims description 2
• PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 claims description 2
• CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 claims description 2
• NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 claims description 2
• GCPWJFKTWGFEHH-UHFFFAOYSA-N acetoacetamide Chemical compound CC(=O)CC(N)=O GCPWJFKTWGFEHH-UHFFFAOYSA-N 0.000 claims description 2
• HUVCZKYUWFGVLS-UHFFFAOYSA-N imidazo[4,5-e]thiazine Chemical compound C1=NSC2=NC=NC2=C1 HUVCZKYUWFGVLS-UHFFFAOYSA-N 0.000 claims description 2
• 239000004745 nonwoven fabric Substances 0.000 claims description 2
• XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 claims description 2
• 229920002717 polyvinylpyridine Polymers 0.000 claims description 2
• FYNROBRQIVCIQF-UHFFFAOYSA-N pyrrolo[3,2-b]pyrrole-5,6-dione Chemical compound C1=CN=C2C(=O)C(=O)N=C21 FYNROBRQIVCIQF-UHFFFAOYSA-N 0.000 claims description 2
• 229920002050 silicone resin Polymers 0.000 claims description 2
• 230000000475 sunscreen effect Effects 0.000 claims description 2
• 239000000516 sunscreening agent Substances 0.000 claims description 2
• 150000003852 triazoles Chemical class 0.000 claims description 2
• HUKPVYBUJRAUAG-UHFFFAOYSA-N 7-benzo[a]phenalenone Chemical compound C1=CC(C(=O)C=2C3=CC=CC=2)=C2C3=CC=CC2=C1 HUKPVYBUJRAUAG-UHFFFAOYSA-N 0.000 claims 1
• IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 claims 1
• -1 CF 3 Chemical group 0.000 description 93
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 47
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• 239000011257 shell material Substances 0.000 description 20
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 17
• 229910052757 nitrogen Inorganic materials 0.000 description 17
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• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
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• 125000005843 halogen group Chemical group 0.000 description 12
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 12
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