JP2009185296A5

JP2009185296A5 -

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Publication number: JP2009185296A5
Authority: JP; Japan
Prior art keywords: group; mass; parts; organopolysiloxane; sio
Prior art date: 2009-04-02
Legal status : Granted

Application number

JP2009090561A

Other languages

English (en)

Japanese (ja)

Other versions

JP2009185296A (ja

JP5015994B2 (ja

Filing date

2009-04-02

Publication date

2009-10-08

2009-04-02 Application filed filed Critical

2009-04-02 Priority to JP2009090561A priority Critical patent/JP5015994B2/ja

2009-04-02 Priority claimed from JP2009090561A external-priority patent/JP5015994B2/ja

2009-08-20 Publication of JP2009185296A publication Critical patent/JP2009185296A/ja

2009-10-08 Publication of JP2009185296A5 publication Critical patent/JP2009185296A5/ja

2012-09-05 Application granted granted Critical

2012-09-05 Publication of JP5015994B2 publication Critical patent/JP5015994B2/ja

Status Active legal-status Critical Current

2027-06-18 Anticipated expiration legal-status Critical

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-1 polysiloxane Polymers 0.000 claims description 157
229920001296 polysiloxane Polymers 0.000 claims description 157
239000000203 mixture Substances 0.000 claims description 123
229920000642 polymer Polymers 0.000 claims description 105
239000003921 oil Substances 0.000 claims description 85
235000019198 oils Nutrition 0.000 claims description 85
239000000843 powder Substances 0.000 claims description 63
239000002537 cosmetic Substances 0.000 claims description 59
LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 57
239000006071 cream Substances 0.000 claims description 51
CXQXSVUQTKDNFP-UHFFFAOYSA-N Simethicone Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 claims description 42
239000007788 liquid Substances 0.000 claims description 42
239000004205 dimethyl polysiloxane Substances 0.000 claims description 39
235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 39
229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 39
229920002545 silicone oil Polymers 0.000 claims description 30
125000004432 carbon atoms Chemical group C* 0.000 claims description 28
235000014113 dietary fatty acids Nutrition 0.000 claims description 28
239000000194 fatty acid Substances 0.000 claims description 28
239000003795 chemical substances by application Substances 0.000 claims description 26
239000000839 emulsion Substances 0.000 claims description 22
125000000217 alkyl group Chemical group 0.000 claims description 21
150000002430 hydrocarbons Chemical class 0.000 claims description 20
125000001931 aliphatic group Chemical group 0.000 claims description 18
229920005989 resin Polymers 0.000 claims description 16
239000011347 resin Substances 0.000 claims description 16
229920002050 silicone resin Polymers 0.000 claims description 16
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
210000003491 Skin Anatomy 0.000 claims description 12
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 11
239000007787 solid Substances 0.000 claims description 11
230000001166 anti-perspirant Effects 0.000 claims description 10
239000003213 antiperspirant Substances 0.000 claims description 10
125000004435 hydrogen atoms Chemical group [H]* 0.000 claims description 10
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 10
239000004094 surface-active agent Substances 0.000 claims description 10
239000010696 ester oil Substances 0.000 claims description 9
150000004665 fatty acids Chemical class 0.000 claims description 9
239000004215 Carbon black (E152) Substances 0.000 claims description 8
210000004209 Hair Anatomy 0.000 claims description 7
238000007259 addition reaction Methods 0.000 claims description 7
125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims description 6
239000002245 particle Substances 0.000 claims description 6
125000000962 organic group Chemical group 0.000 claims description 5
235000011837 pasties Nutrition 0.000 claims description 5
229910004298 SiO 2 Inorganic materials 0.000 claims description 4
239000010775 animal oil Substances 0.000 claims description 4
HNJBEVLQSNELDL-UHFFFAOYSA-N 2-Pyrrolidone Chemical group O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 claims description 3
229920001971 elastomer Polymers 0.000 claims description 3
125000001153 fluoro group Chemical group F* 0.000 claims description 3
125000003709 fluoroalkyl group Chemical group 0.000 claims description 3
235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
239000008158 vegetable oil Substances 0.000 claims description 3
239000006072 paste Substances 0.000 claims description 2
238000002360 preparation method Methods 0.000 claims description 2
239000007921 spray Substances 0.000 claims description 2
125000000547 substituted alkyl group Chemical group 0.000 claims description 2
125000001183 hydrocarbyl group Chemical group 0.000 claims 9
229910052731 fluorine Inorganic materials 0.000 claims 2
239000011737 fluorine Substances 0.000 claims 2
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
YCKRFDGAMUMZLT-UHFFFAOYSA-N fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims 1
230000001681 protective Effects 0.000 claims 1
238000006467 substitution reaction Methods 0.000 claims 1
238000004519 manufacturing process Methods 0.000 description 39
OGIDPMRJRNCKJF-UHFFFAOYSA-N TiO Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 26
GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 26
229910001929 titanium oxide Inorganic materials 0.000 description 26
239000000243 solution Substances 0.000 description 24
239000002253 acid Substances 0.000 description 23
239000011780 sodium chloride Substances 0.000 description 23
239000000049 pigment Substances 0.000 description 21
229920003171 Poly (ethylene oxide) Polymers 0.000 description 20
230000000052 comparative effect Effects 0.000 description 20
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 18
LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 18
RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 17
125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 17
150000003839 salts Chemical class 0.000 description 16
PRAKJMSDJKAYCZ-UHFFFAOYSA-N Squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 15
239000000047 product Substances 0.000 description 15
229940032094 squalane Drugs 0.000 description 15
238000003756 stirring Methods 0.000 description 15
XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 14
239000006185 dispersion Substances 0.000 description 14
230000000694 effects Effects 0.000 description 14
239000001257 hydrogen Substances 0.000 description 14
229910052739 hydrogen Inorganic materials 0.000 description 14
229940057995 liquid paraffin Drugs 0.000 description 14
239000004166 Lanolin Substances 0.000 description 12
229940039717 Lanolin Drugs 0.000 description 12
150000001875 compounds Chemical class 0.000 description 12
235000019388 lanolin Nutrition 0.000 description 12
238000002156 mixing Methods 0.000 description 11
UIIMBOGNXHQVGW-UHFFFAOYSA-M NaHCO3 Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 10
229920001577 copolymer Polymers 0.000 description 10
239000006096 absorbing agent Substances 0.000 description 9
239000007795 chemical reaction product Substances 0.000 description 9
238000006116 polymerization reaction Methods 0.000 description 9
239000002562 thickening agent Substances 0.000 description 9
GTJOHISYCKPIMT-UHFFFAOYSA-N 2-Methylundecane Chemical compound CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 description 8
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 8
XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 8
150000001298 alcohols Chemical class 0.000 description 7
235000001014 amino acid Nutrition 0.000 description 7
HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol group Chemical group [C@@H]1(CC[C@H]2[C@@H]3CC=C4C[C@@H](O)CC[C@]4(C)[C@H]3CC[C@]12C)[C@H](C)CCCC(C)C HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 7
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 7
239000010445 mica Substances 0.000 description 7
229910052618 mica group Inorganic materials 0.000 description 7
239000001993 wax Substances 0.000 description 7
WPYMKLBDIGXBTP-UHFFFAOYSA-N Benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 6
VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
QIQXTHQIDYTFRH-UHFFFAOYSA-N Stearic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 6
239000002585 base Substances 0.000 description 6
235000015165 citric acid Nutrition 0.000 description 6
229960004106 citric acid Drugs 0.000 description 6
125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 6
229910052751 metal Inorganic materials 0.000 description 6
239000002184 metal Substances 0.000 description 6
238000003892 spreading Methods 0.000 description 6
ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 5
241000195940 Bryophyta Species 0.000 description 5
210000004709 Eyebrows Anatomy 0.000 description 5
FSIJKGMIQTVTNP-UHFFFAOYSA-N bis(ethenyl)-methyl-trimethylsilyloxysilane Chemical compound C[Si](C)(C)O[Si](C)(C=C)C=C FSIJKGMIQTVTNP-UHFFFAOYSA-N 0.000 description 5
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
239000004359 castor oil Substances 0.000 description 5
235000019438 castor oil Nutrition 0.000 description 5
229920002678 cellulose Polymers 0.000 description 5
239000001913 cellulose Substances 0.000 description 5
125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
238000011156 evaluation Methods 0.000 description 5
239000010419 fine particle Substances 0.000 description 5
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
KFZMGEQAYNKOFK-UHFFFAOYSA-N iso-propanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 5
235000011929 mousse Nutrition 0.000 description 5
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
229910000030 sodium bicarbonate Inorganic materials 0.000 description 5
235000017557 sodium bicarbonate Nutrition 0.000 description 5
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
229940024606 Amino Acids Drugs 0.000 description 4
229940019746 Antifibrinolytic amino acids Drugs 0.000 description 4
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 4
239000004375 Dextrin Substances 0.000 description 4
229920001353 Dextrin Polymers 0.000 description 4
PVNIIMVLHYAWGP-UHFFFAOYSA-N Nicotinic acid Natural products OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 4
YGSDEFSMJLZEOE-UHFFFAOYSA-N Salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 4
YYGNTYWPHWGJRM-RUSDCZJESA-N Squalene Natural products C(=C\CC/C(=C\CC/C=C(\CC/C=C(\CC/C=C(\C)/C)/C)/C)/C)(\CC/C=C(\C)/C)/C YYGNTYWPHWGJRM-RUSDCZJESA-N 0.000 description 4
KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 4
238000007792 addition Methods 0.000 description 4
150000001413 amino acids Chemical class 0.000 description 4
OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
229910052799 carbon Inorganic materials 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
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235000019425 dextrin Nutrition 0.000 description 4
KARVSHNNUWMXFO-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane;hydrate Chemical compound O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O KARVSHNNUWMXFO-UHFFFAOYSA-N 0.000 description 4
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
238000004898 kneading Methods 0.000 description 4
HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 4
229910052901 montmorillonite Inorganic materials 0.000 description 4
125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
235000021317 phosphate Nutrition 0.000 description 4
NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
239000002904 solvent Substances 0.000 description 4
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239000000126 substance Substances 0.000 description 4
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VLPFTAMPNXLGLX-UHFFFAOYSA-N Axona Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 3
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239000004677 Nylon Substances 0.000 description 3
239000004698 Polyethylene (PE) Substances 0.000 description 3
239000002202 Polyethylene glycol Substances 0.000 description 3
RMAQACBXLXPBSY-UHFFFAOYSA-N Silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 3
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LSNNMFCWUKXFEE-UHFFFAOYSA-L Sulphite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 3
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QTBSBXVTEAMEQO-UHFFFAOYSA-M acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N acetic acid ethyl ester Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
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150000005215 alkyl ethers Chemical group 0.000 description 3
FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 3
125000000129 anionic group Chemical group 0.000 description 3
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125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
235000010233 benzoic acid Nutrition 0.000 description 3
125000002091 cationic group Chemical group 0.000 description 3
235000012000 cholesterol Nutrition 0.000 description 3
238000004132 cross linking Methods 0.000 description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Substances OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
235000019197 fats Nutrition 0.000 description 3
229940107187 fructooligosaccharide Drugs 0.000 description 3
239000003349 gelling agent Substances 0.000 description 3
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PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
229920000591 gum Polymers 0.000 description 3
125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 3
125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
229910000460 iron oxide Inorganic materials 0.000 description 3
238000000034 method Methods 0.000 description 3
235000001968 nicotinic acid Nutrition 0.000 description 3
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125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
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235000012239 silicon dioxide Nutrition 0.000 description 3
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PPBRXRYQALVLMV-UHFFFAOYSA-N styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 3
239000000454 talc Substances 0.000 description 3
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125000000725 trifluoropropyl group Chemical group [H]C([H])(*)C([H])([H])C(F)(F)F 0.000 description 3
229920003169 water-soluble polymer Polymers 0.000 description 3
NRWMBHYHFFGEEC-KTKRTIGZSA-N (9Z)-1-O-octadec-9-enyl glycerol Chemical compound CCCCCCCC\C=C/CCCCCCCCOCC(O)CO NRWMBHYHFFGEEC-KTKRTIGZSA-N 0.000 description 2
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WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
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MPDGHEJMBKOTSU-YKLVYJNSSA-N 18β-glycyrrhetic acid Chemical compound C([C@H]1C2=CC(=O)[C@H]34)[C@@](C)(C(O)=O)CC[C@]1(C)CC[C@@]2(C)[C@]4(C)CC[C@@H]1[C@]3(C)CC[C@H](O)C1(C)C MPDGHEJMBKOTSU-YKLVYJNSSA-N 0.000 description 2
IUMSDRXLFWAGNT-UHFFFAOYSA-N 2,2,4,4,6,6,8,8,10,10,12,12-dodecamethyl-1,3,5,7,9,11-hexaoxa-2,4,6,8,10,12-hexasilacyclododecane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 IUMSDRXLFWAGNT-UHFFFAOYSA-N 0.000 description 2
BVDRUCCQKHGCRX-UHFFFAOYSA-N 2,3-dihydroxypropyl formate Chemical compound OCC(O)COC=O BVDRUCCQKHGCRX-UHFFFAOYSA-N 0.000 description 2
GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 description 2
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LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 description 2
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JP2009090561A 2009-04-02 2009-04-02 オルガノポリシロキサン及びその製法ならびに該オルガノポリシロキサンを含む化粧料組成物 Active JP5015994B2 (ja)