JP2009145877A - 磁性トナー - Google Patents
磁性トナー Download PDFInfo
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- JP2009145877A JP2009145877A JP2008290468A JP2008290468A JP2009145877A JP 2009145877 A JP2009145877 A JP 2009145877A JP 2008290468 A JP2008290468 A JP 2008290468A JP 2008290468 A JP2008290468 A JP 2008290468A JP 2009145877 A JP2009145877 A JP 2009145877A
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- Prior art keywords
- magnetic toner
- toner
- magnetic
- acid
- particles
- Prior art date
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- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- JIYXDFNAPHIAFH-UHFFFAOYSA-N tert-butyl 3-tert-butylperoxycarbonylbenzoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC(C(=O)OC(C)(C)C)=C1 JIYXDFNAPHIAFH-UHFFFAOYSA-N 0.000 description 1
- NMOALOSNPWTWRH-UHFFFAOYSA-N tert-butyl 7,7-dimethyloctaneperoxoate Chemical compound CC(C)(C)CCCCCC(=O)OOC(C)(C)C NMOALOSNPWTWRH-UHFFFAOYSA-N 0.000 description 1
- SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 229910003470 tongbaite Inorganic materials 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- CAPIMQICDAJXSB-UHFFFAOYSA-N trichloro(1-chloroethyl)silane Chemical compound CC(Cl)[Si](Cl)(Cl)Cl CAPIMQICDAJXSB-UHFFFAOYSA-N 0.000 description 1
- FLPXNJHYVOVLSD-UHFFFAOYSA-N trichloro(2-chloroethyl)silane Chemical compound ClCC[Si](Cl)(Cl)Cl FLPXNJHYVOVLSD-UHFFFAOYSA-N 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- XYJRNCYWTVGEEG-UHFFFAOYSA-N trimethoxy(2-methylpropyl)silane Chemical compound CO[Si](OC)(OC)CC(C)C XYJRNCYWTVGEEG-UHFFFAOYSA-N 0.000 description 1
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 description 1
- PZJJKWKADRNWSW-UHFFFAOYSA-N trimethoxysilicon Chemical group CO[Si](OC)OC PZJJKWKADRNWSW-UHFFFAOYSA-N 0.000 description 1
- KHOQXNHADJBILQ-UHFFFAOYSA-N trimethyl(sulfanyl)silane Chemical compound C[Si](C)(C)S KHOQXNHADJBILQ-UHFFFAOYSA-N 0.000 description 1
- 239000005051 trimethylchlorosilane Substances 0.000 description 1
- 229940096522 trimethylolpropane triacrylate Drugs 0.000 description 1
- PQDJYEQOELDLCP-UHFFFAOYSA-N trimethylsilane Chemical compound C[SiH](C)C PQDJYEQOELDLCP-UHFFFAOYSA-N 0.000 description 1
- GRPURDFRFHUDSP-UHFFFAOYSA-N tris(prop-2-enyl) benzene-1,2,4-tricarboxylate Chemical compound C=CCOC(=O)C1=CC=C(C(=O)OCC=C)C(C(=O)OCC=C)=C1 GRPURDFRFHUDSP-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
- FUSUHKVFWTUUBE-UHFFFAOYSA-N vinyl methyl ketone Natural products CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 235000019386 wax ester Nutrition 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
- KRJOFJHOZZPBKI-KSWODRSDSA-N α-defensin-1 Chemical compound C([C@H]1C(=O)N[C@H]2CSSC[C@H]3C(=O)N[C@H](C(N[C@@H](C)C(=O)NCC(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H](CCCNC(N)=N)C(=O)N[C@@H](CCCNC(N)=N)C(=O)N[C@@H](CC=4C=CC(O)=CC=4)C(=O)NCC(=O)N[C@H](C(=O)N[C@@H](CSSC[C@H](NC(=O)[C@H](CC=4C=CC(O)=CC=4)NC(=O)[C@H](CSSC[C@H](NC2=O)C(O)=O)NC(=O)[C@H](C)N)C(=O)N[C@@H](CCCNC(N)=N)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N2[C@@H](CCC2)C(=O)N[C@@H](C)C(=O)N3)C(=O)N[C@H](C(=O)N[C@@H](CC=2C=CC(O)=CC=2)C(=O)N[C@@H](CCC(N)=O)C(=O)NCC(=O)N[C@@H](CCCNC(N)=N)C(=O)N[C@@H](CC(C)C)C(=O)N[C@@H](CC=2C3=CC=CC=C3NC=2)C(=O)N[C@@H](C)C(=O)N1)[C@@H](C)CC)[C@@H](C)O)=O)[C@@H](C)CC)C1=CC=CC=C1 KRJOFJHOZZPBKI-KSWODRSDSA-N 0.000 description 1
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Abstract
【解決手段】結着樹脂、磁性体を含む磁性トナー母体と、無機微粉体を有する磁性トナーであって、
(i)該磁性トナーの平均円形度が0.950以上1.000以下であり、(ii)該磁性トナーの圧縮率が30以下であり、(iii)該磁性トナーが、無機微粉体としてメジアン径(D50)0.5μm以上8.0μm以下の窒化ほう素粒子を磁性トナー母体100質量部あたり0.05質量部以上1.00質量部以下含有していることを特徴とする。
【選択図】なし
Description
(1)結着樹脂、磁性体を少なくとも含む磁性トナー母体と、無機微粉体を有する磁性トナーであって、
(i)該磁性トナーの平均円形度が0.950以上1.000以下であり、
(ii)該磁性トナーの下記式(1)
圧縮率={1−(見掛け密度/タップ密度)}×100 式(1)
から得られる圧縮率が30以下であり、
(iii)該磁性トナーが、無機微粉体としてメジアン径(D50)0.5μm以上8.0μm以下の窒化ほう素粒子を磁性トナー母体100質量部あたり0.05質量部以上1.00質量部以下含有していることを特徴とする磁性トナー。
(2)該磁性トナーの重量平均粒径(D4)が4.0μm以上9.0μm以下であり、重量平均粒径(D4)と個数平均粒径(D1)の比が1.25以下であることを特徴とする(1)記載の磁性トナー。
(3)該窒化ほう素粒子のメジアン径(D50)が1.0μm以上6.0μm以下であり、変動係数が70以下であることを特徴とする(1)または(2)に記載の磁性トナー。
(4)該磁性トナーが、磁性トナー母体と窒化ほう素粒子及び粒径の異なる2種類の無機酸化物を少なくとも含有することを特徴とする(1)乃至(3)のいずれかに記載の磁性トナー。
(5)該磁性トナーが、磁性トナー母体と窒化ほう素粒子、及び、比表面積が100乃至300m2/gの疎水性シリカを磁性トナー母体100質量部あたり0.1乃至3質量部と、個数平均粒径が80nm乃至1μmの金属酸化物を磁性トナー母体100質量部あたり0.1乃至3質量部とを少なくとも含有することを特徴とする(1)乃至(4)のいずれかに記載の磁性トナー。
(6)該磁性トナーの磁場79.6kA/mで着磁されたときの残留磁化が4.0Am2/kg以下であることを特徴とする(1)乃至(5)のいずれかに記載の磁性トナー。
圧縮率={1−(見掛け密度/タップ密度)}×100 式(1)
(A)磁性トナーの形状(平均円形度)及び表面平滑性を高め、トナー粒子間の接触面積を減少させる方法
(B)磁性トナーの粒度分布を適正化し、微粉及び粗粉量を適正化してパッキング性を制御する方法
(C)磁性トナー表面に表面エネルギー/疎水性/粒径などを適正化した有機及びまたは無機微粒子層を複数種付着させる方法
(D)磁性トナーの磁気特性を適正化し、磁気凝集性を低減させる方法
RmSiYn (A)
[式中、Rはアルコキシ基を示し、mは1乃至3の整数を示し、Yはアルキル基、ビニル基、メタクリル基、フェニル基、アミノ基、エポキシ基、メルカプト基又はこれらの誘導体を示し、nは1乃至3の整数を示す。]
で示されるものである。例えばビニルトリメトキシシラン、ビニルトリエトキシシラン、γ−メタクリルオキシプロピルトリメトキシシラン、ビニルトリアセトキシシラン、メチルトリメトキシシラン、メチルトリエトキシシラン、イソブチルトリメトキシシラン、ジメチルジメトキシシラン、ジメチルジエトキシシラン、トリメチルメトキシシラン、ヒドロキシプロピルトリメトキシシラン、フェニルトリメトキシシラン、n−ヘキサデシルトリメトキシシラン、n−オクタデシルトリメトキシシランを挙げることができる。
CpH2p+1−Si−(OCqH2q+1)3 (B)
[式中、pは2乃至20の整数を示し、qは1乃至3の整数を示す]
で示されるアルキルトリアルコキシシランカップリング剤を使用して磁性酸化鉄表面を疎水化処理するのが良い。
本発明の見掛け密度、タップ密度は、パウダーテスター(ホソカワミクロン社製)を用いて以下の方法で測定する。
本発明で用いられる窒化ほう素の体積基準のメジアン径(D50)の測定は、JIS Z8825−1(2001年)に準じて測定されるが、具体的には以下の通りである。
(1)バッチ式セルホルダーをLA−920に取り付ける。
(2)所定量のイオン交換水をバッチ式セルに入れ、バッチ式セルをバッチ式セルホルダーにセットする。
(3)専用のスターラーチップを用いて、バッチ式セル内を撹拌する。
(4)「表示条件設定」画面の「屈折率」ボタンを押し、ファイル「110A000I」(相対屈折率1.10)を選択する。
(5)「表示条件設定」画面において、粒子径基準を体積基準とする。
(6)1時間以上の暖気運転を行なった後、光軸の調整、光軸の微調整、ブランク測定を行なう。
(7)ガラス製の100ml平底ビーカーに約60mlのイオン交換水を入れる。この中に分散剤として、「コンタミノンN」(非イオン界面活性剤、陰イオン界面活性剤、有機ビルダーからなるpH7の精密測定器洗浄用中性洗剤の10質量%水溶液、和光純薬工業社製)をイオン交換水で約3質量倍に希釈した希釈液を約0.3ml加える。
(8)発振周波数50kHzの発振器2個を、位相を180度ずらした状態で内蔵し、電気的出力120Wの超音波分散器「Ultrasonic Dispension System Tetora150」(日科機バイオス社製)を準備する。超音波分散器の水槽内に約3.3lのイオン交換水を入れ、この水槽中にコンタミノンNを約2ml添加する。
(9)前記(7)のビーカーを前記超音波分散器のビーカー固定穴にセットし、超音波分散器を作動させる。そして、ビーカー内の水溶液の液面の共振状態が最大となるようにビーカーの高さ位置を調整する。
(10)前記(9)のビーカー内の水溶液に超音波を照射した状態で、約1mgの窒化ほう素を少量ずつ前記ビーカー内の水溶液に添加し、分散させる。そして、さらに60秒間超音波分散処理を継続する。尚、この際に窒化ほう素が固まりとなって液面に浮く場合があるが、その場合はビーカーを揺り動かすことで固まりを水中に沈めてから60秒間の超音波分散を行なう。また、超音波分散にあたっては、水槽の水温が10℃以上40℃以下となる様に適宜調節する。
(11)前記(10)で調製した窒化ほう素が分散した水溶液を、気泡が入らないように注意しながら直ちにバッチ式セルに少量ずつ添加して、タングステンランプの透過率が90%〜95%となるように調整する。そして、粒度分布の測定を行う。得られた体積基準の粒度分布のデータを元に、体積基準のメジアン径(D50)及び変動係数を算出する。
トナーの重量平均粒径(D4)および個数平均粒径(D1)は、以下のようにして算出する。測定装置としては、100μmのアパーチャーチューブを備えた細孔電気抵抗法による精密粒度分布測定装置「コールター・カウンター Multisizer 3」(登録商標、ベックマン・コールター社製)を用いる。測定条件の設定及び測定データの解析は、付属の専用ソフト「ベックマン・コールター Multisizer 3 Version3.51」(ベックマン・コールター社製)を用いる。尚、測定は実効測定チャンネル数2万5千チャンネルで行なう。
(1)Multisizer 3専用のガラス製250ml丸底ビーカーに前記電解水溶液約200mlを入れ、サンプルスタンドにセットし、スターラーロッドの撹拌を反時計回りで24回転/秒にて行なう。そして、専用ソフトの「アパーチャーのフラッシュ」機能により、アパーチャーチューブ内の汚れと気泡を除去しておく。
(2)ガラス製の100ml平底ビーカーに前記電解水溶液約30mlを入れる。この中に分散剤として「コンタミノンN」(非イオン界面活性剤、陰イオン界面活性剤、有機ビルダーからなるpH7の精密測定器洗浄用中性洗剤の10質量%水溶液、和光純薬工業社製)をイオン交換水で約3質量倍に希釈した希釈液を約0.3ml加える。
(3)発振周波数50kHzの発振器2個を位相を180度ずらした状態で内蔵し、電気的出力120Wの超音波分散器「Ultrasonic Dispension System Tetora150」(日科機バイオス社製)を準備する。超音波分散器の水槽内に所定量のイオン交換水を入れ、この水槽中に前記コンタミノンNを約2ml添加する。
(4)前記(2)のビーカーを前記超音波分散器のビーカー固定穴にセットし、超音波分散器を作動させる。そして、ビーカー内の電解水溶液の液面の共振状態が最大となるようにビーカーの高さ位置を調整する。
(5)前記(4)のビーカー内の電解水溶液に超音波を照射した状態で、トナー約10mgを少量ずつ前記電解水溶液に添加し、分散させる。そして、さらに60秒間超音波分散処理を継続する。尚、超音波分散にあたっては、水槽の水温が10℃以上40℃以下となる様に適宜調節する。
(6)サンプルスタンド内に設置した前記(1)の丸底ビーカーに、ピペットを用いてトナーを分散した前記(5)の電解質水溶液を滴下し、測定濃度が約5%となるように調整する。そして、測定粒子数が50000個になるまで測定を行なう。
(7)測定データを装置付属の前記専用ソフトにて解析を行ない、重量平均粒径(D4)および個数平均粒径(D1)を算出する。尚、専用ソフトでグラフ/体積%と設定したときの、「分析/体積統計値(算術平均)」画面の「平均径」が重量平均粒径(D4)であり、専用ソフトでグラフ/個数%と設定したときの、「分析/個数統計値(算術平均)」画面の「平均径」が個数平均粒径(D1)である。
トナーの平均円形度は、フロー式粒子像測定装置「FPIA−2100」(シスメックス社製)を用いて測定する。詳細は以下の通りである。
硫酸第一鉄水溶液中に、鉄イオンに対して1.0乃至1.1当量の苛性ソーダ溶液(Feに対しP換算で1質量%のヘキサメタリン酸ナトリウムを含有)を混合し、水酸化第一鉄を含む水溶液を調製した。水溶液をpH9に維持しながら、空気を吹き込み、80乃至90℃で酸化反応を行ない、種晶を生成させるスラリー液を調製した。
表6に示すように、磁性酸化鉄の磁気特性及びシランカップリング剤での表面処理no有無を変更した以外は同様にして、磁性酸化鉄2及び3を得た。
イオン交換水709部に0.1mol/リットル−Na3PO4水溶液451部を投入し60℃に加温した後、1.0mol/l−CaCl2水溶液67.7部を徐々に添加してCa3(PO4)2を含む水系媒体を得た。
・スチレン 80部
・n−ブチルアクリレート 20部
・飽和ポリエステル樹脂 6部(モノマー構成;ビスフェノールAプロピレンオキサイド付加物/テレフタル酸、酸価; 12mgKOH/g、Tg=72℃、Mn=3900、Mw=10000)
・負荷電性制御剤 3部
(T−77;モノアゾ染料系のFe化合物(保土ヶ谷化学工業社製))
・磁性酸化鉄1 95部
磁性トナーAの製造例において、重合性単量体を反応後、系内に水蒸気を導入する時間を1時間及び5時間に変更した以外は同様にして磁性トナー母体b及びcを得た。その後表9に示す外添剤を使用し磁性トナーB及びCを得た。この磁性トナーB及びCの物性を表10に示す。
表9に示す通りに磁性体、外添剤、Ca3(PO4)2の添加量を調整しトナーの粒径を変更した以外は同様にして、磁性トナーD乃至Mを得た。磁性トナーD乃至Mの物性を表10に示す。
(結着樹脂の製造例)
テレフタル酸 27mol%
アジピン酸 15mol%
トリメリット酸 6mol%
前記式(ア)で示されるビスフェノール誘導体 35mol%
(プロピレンオキサイド2.5mol付加物)
前記式(ア)で示されるビスフェノール誘導体 17mol%
(エチレンオキサイド2.5mol付加物)
上記に示すポリエステルモノマー及びエステル化触媒を4口フラスコに仕込み、減圧装置、水分離装置、窒素ガス導入装置、温度測定装置及び攪拌装置を装着し、窒素雰囲気下にて230℃に昇温して反応を行った。反応終了後、生成物を容器から取り出し、冷却、粉砕し、軟化点143℃の樹脂Aを得た。
テレフタル酸 24mol%
アジピン酸 16mol%
トリメリット酸 10mol%
前記式(ア)で示されるビスフェノール誘導体 30mol%
(プロピレンオキサイド2.5mol付加物)
前記式(ア)で示されるビスフェノール誘導体 20mol%
(エチレンオキサイド2.5mol付加物)
上記に示すポリエステルモノマー及びエステル化触媒を4口フラスコに仕込み、減圧装置、水分離装置、窒素ガス導入装置、温度測定装置及び攪拌装置を装着し、窒素雰囲気下にて230℃に昇温して反応を行った。反応終了後、生成物を容器から取り出し、冷却、粉砕し、軟化点98℃の樹脂Bを得た。
・磁性酸化鉄3 90部
・モノアゾ鉄錯体(T−77:保土ヶ谷化学社製) 1部
・フィッシャートロプシュワックス(融点100℃) 5部
(日本精鑞社製、FT100)
上記混合物をヘンシェルミキサーで前混合した後、110℃に加熱された2軸エクストルーダで溶融混練し、冷却した混練物をハンマーミルで粗粉砕してトナー粗粉砕物を得た。得られた粗粉砕物を、機械式粉砕機ターボミル(ターボ工業社製;回転子および固定子の表面に炭化クロムを含有したクロム合金めっきでコーティング(めっき厚150μm、表面硬さHV1050))を用いて機械式粉砕させて微粉砕し、得られた微粉砕物をコアンダ効果を利用した多分割分級装置(日鉄鉱業社製エルボジェット分級機)で微粉及び粗粉を同時に分級除去した。そこで得られたトナー粒子のコールターカウンター法で測定される重量平均粒径(D4)は7.2μmであった。
磁性トナーAの製造例において、表9に示す通りに磁性酸化鉄及び外添剤を変更し、更にトナー粒径を変更した以外は上記磁性トナーAの製造と同様にして、比較用磁性トナーa乃至dを得た。比較用磁性トナーa乃至dの物性を表10に示す。
磁性トナーNの製造例において、表9に示す通りに磁性酸化鉄及び外添剤を変更し、更にトナー粒径を変更した以外は上記磁性トナーNの製造と同様にして、比較用磁性トナーeを得た。比較用磁性トナーeの物性を表10に示す。
市販のキヤノン製複写機IR3570に磁性トナーAを充填したもので下記評価を実施した。
1.画像濃度
画像濃度は、常温低湿環境(温度23℃、湿度5%)において初期及び5万枚の通紙耐久後、及び、高温高湿環境(温度30%、湿度80%)において初期及び5万枚の通紙耐久後に、印字紙全面にベタ画像部を形成し、このベタ画像をマクベス濃度計(マクベス社製)でSPIフィルターを使用して、反射濃度計にて測定を行った。
カブリは、常温低湿環境(温度23℃、湿度5%)において初期及び5万枚の通紙耐久後に、カブリ測定用反射測定機REFLECTMETER(東京電色(株))にて、上記の画像の白部及び未使用紙の反射率を測定し、両者の差をカブリとした。
(未使用紙反射率−画像白部の反射率=カブリ%)
A:カブリ0.3%未満
B:カブリ0.3〜1.0%未満
C:カブリ1.0〜2.0%未満
D:カブリ2.0〜2.5%未満
E:カブリ2.5%以上
ライン及び文字を含む原稿を使用し、常温低湿環境において5万枚の通紙耐久後、及び、高温高湿環境において5万枚の通紙耐久後の画像を目視及び拡大顕微鏡を使用して、以下の基準で評価した。
A:文字画像及びライン画像ともに、細部まで忠実に再現している
B:細部に多少の乱れまたは飛び散りが生じているが、目視では問題ないレベルである
C:目視でも乱れや飛び散りがわかるレベルである
D:乱れ、飛び散りが多数発生し、原稿を再現していない
高温高湿環境(温度30%、湿度80%)において5万枚通紙耐久後の現像スリーブを目視し、汚染レベルを下記基準で評価した。
A:スリーブ上、画像上ともに問題なし
B:スリーブ上の一部に若干の汚染があるが、画像上問題なし
C:スリーブ上の一部に汚染があり、画像の一部で濃度薄などが発生する
D:スリーブ全体に汚染があり、画像全体に濃度薄などが発生する
A:感光体融着及びクリーニング不良の発生が全く見られない
B:感光体上に融着が見られるが、画像にはほとんど影響ない
C:クリーニングブレードの設定圧が+30%もしくは−30%のどちらかで融着もしく はクリーニング不良の画像が見られる
D:クリーニングブレードの設定圧が+30%、−30%の両方で融着もしくはクリーニ ング不良の画像が見られる
実施例1において、磁性トナーB乃至Nを用いて同様の評価を行った結果、表11に示すように良好な結果が得られた。
実施例1において、比較用磁性トナーa乃至eを用いて同様の評価を行った結果、表11に示すような結果が得られた。
Claims (6)
- 結着樹脂、磁性体を少なくとも含む磁性トナー母体と、無機微粉体を有する磁性トナーであって、
(i)該磁性トナーの平均円形度が0.950以上1.000以下であり、
(ii)該磁性トナーの下記式(1)
圧縮率={1−(見掛け密度/タップ密度)}×100 式(1)
から得られる圧縮率が30以下であり、
(iii)該磁性トナーが、無機微粉体としてメジアン径(D50)が0.5μm以上8.0μm以下の窒化ほう素粒子を磁性トナー母体100質量部あたり0.05質量部以上1.00質量部以下含有していることを特徴とする磁性トナー。 - 該磁性トナーの重量平均粒径(D4)が4.0μm以上9.0μm以下であり、重量平均粒径(D4)と個数平均粒径(D1)の比が1.25以下であることを特徴とする請求項1記載の磁性トナー。
- 該窒化ほう素粒子のメジアン径(D50)が1.0μm以上6.0μm以下であり、変動係数が70以下であることを特徴とする請求項1又は2に記載の磁性トナー。
- 該磁性トナーが、磁性トナー母体と窒化ほう素粒子及び粒径の異なる2種類の無機酸化物を少なくとも含有することを特徴とする請求項1乃至3のいずれかに記載の磁性トナー。
- 該磁性トナーが、磁性トナー母体と窒化ほう素粒子、及び、比表面積が100乃至300m2/gの疎水性シリカを磁性トナー母体100質量部あたり0.1乃至3質量部と、個数平均粒径が80nm乃至1μmの金属酸化物を磁性トナー母体100質量部あたり0.1乃至3質量部とを少なくとも含有することを特徴とする請求項1乃至4のいずれかに記載の磁性トナー。
- 該磁性トナーの磁場79.6kA/mで着磁されたときの残留磁化が4.0Am2/kg以下であることを特徴とする請求項1乃至5のいずれかに記載の磁性トナー。
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JP2016170234A (ja) * | 2015-03-11 | 2016-09-23 | サカタインクス株式会社 | 静電荷像現像用二成分トナー |
JP2017146538A (ja) * | 2016-02-19 | 2017-08-24 | 富士ゼロックス株式会社 | 静電荷像現像用トナー、静電荷像現像剤、トナーカートリッジ、プロセスカートリッジ、画像形成装置、及び画像形成方法 |
JP2021047320A (ja) * | 2019-09-19 | 2021-03-25 | 富士ゼロックス株式会社 | 静電荷像現像用トナー、静電荷像現像剤、トナーカートリッジ、プロセスカートリッジ、画像形成装置及び画像形成方法 |
JP7331575B2 (ja) | 2019-09-19 | 2023-08-23 | 富士フイルムビジネスイノベーション株式会社 | 静電荷像現像用トナー、静電荷像現像剤、トナーカートリッジ、プロセスカートリッジ、画像形成装置及び画像形成方法 |
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US20090130580A1 (en) | 2009-05-21 |
JP5284049B2 (ja) | 2013-09-11 |
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