JP2009102558A - 積層フィルム - Google Patents
積層フィルム Download PDFInfo
- Publication number
- JP2009102558A JP2009102558A JP2007277226A JP2007277226A JP2009102558A JP 2009102558 A JP2009102558 A JP 2009102558A JP 2007277226 A JP2007277226 A JP 2007277226A JP 2007277226 A JP2007277226 A JP 2007277226A JP 2009102558 A JP2009102558 A JP 2009102558A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- resin
- coating
- chlorine
- resins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000576 coating method Methods 0.000 claims abstract description 78
- 239000011248 coating agent Substances 0.000 claims abstract description 71
- 229920005989 resin Polymers 0.000 claims abstract description 63
- 239000011347 resin Substances 0.000 claims abstract description 63
- 229920005672 polyolefin resin Polymers 0.000 claims abstract description 46
- 229920003023 plastic Polymers 0.000 claims abstract description 44
- 239000004033 plastic Substances 0.000 claims abstract description 44
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 39
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 39
- 239000000460 chlorine Substances 0.000 claims abstract description 39
- 125000004122 cyclic group Chemical group 0.000 claims abstract description 37
- 239000000178 monomer Substances 0.000 claims abstract description 31
- 229920000642 polymer Polymers 0.000 claims abstract description 21
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 claims abstract description 10
- 239000000758 substrate Substances 0.000 claims description 37
- 239000007788 liquid Substances 0.000 claims description 24
- 229920001225 polyester resin Polymers 0.000 claims description 9
- 239000004645 polyester resin Substances 0.000 claims description 9
- 229920006122 polyamide resin Polymers 0.000 claims description 8
- 239000012461 cellulose resin Substances 0.000 claims description 7
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 6
- 230000000379 polymerizing effect Effects 0.000 claims description 5
- 239000000463 material Substances 0.000 abstract description 15
- 230000001070 adhesive effect Effects 0.000 abstract description 12
- 238000000034 method Methods 0.000 abstract description 9
- 238000006116 polymerization reaction Methods 0.000 abstract description 4
- 239000010410 layer Substances 0.000 description 139
- -1 etc.) Polymers 0.000 description 65
- 239000010408 film Substances 0.000 description 52
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- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 24
- 239000012948 isocyanate Substances 0.000 description 21
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 18
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 16
- 150000001336 alkenes Chemical class 0.000 description 13
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 13
- 239000000853 adhesive Substances 0.000 description 11
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 10
- 150000002513 isocyanates Chemical class 0.000 description 9
- 229920000098 polyolefin Polymers 0.000 description 9
- 229920002554 vinyl polymer Polymers 0.000 description 9
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 8
- 238000001035 drying Methods 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 8
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical class CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 8
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 7
- 229920000728 polyester Polymers 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- 229920002678 cellulose Polymers 0.000 description 6
- 150000001993 dienes Chemical class 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical class C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- NNOZGCICXAYKLW-UHFFFAOYSA-N 1,2-bis(2-isocyanatopropan-2-yl)benzene Chemical compound O=C=NC(C)(C)C1=CC=CC=C1C(C)(C)N=C=O NNOZGCICXAYKLW-UHFFFAOYSA-N 0.000 description 4
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- 229920002284 Cellulose triacetate Polymers 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 4
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 4
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 4
- 238000007611 bar coating method Methods 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 150000002170 ethers Chemical class 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- 229920001169 thermoplastic Polymers 0.000 description 4
- 239000004416 thermosoftening plastic Substances 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 4
- 239000004711 α-olefin Substances 0.000 description 4
- PCBPVYHMZBWMAZ-UHFFFAOYSA-N 5-methylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C)CC1C=C2 PCBPVYHMZBWMAZ-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- 229920002292 Nylon 6 Polymers 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 229920002873 Polyethylenimine Polymers 0.000 description 3
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 3
- 239000004823 Reactive adhesive Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 238000012644 addition polymerization Methods 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 125000001118 alkylidene group Chemical group 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- 229920002301 cellulose acetate Polymers 0.000 description 3
- 238000003851 corona treatment Methods 0.000 description 3
- 150000004292 cyclic ethers Chemical class 0.000 description 3
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentenylidene Natural products C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 3
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical group 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- 150000002848 norbornenes Chemical class 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 239000005033 polyvinylidene chloride Substances 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 238000007152 ring opening metathesis polymerisation reaction Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- 229920001567 vinyl ester resin Polymers 0.000 description 3
- 229920003067 (meth)acrylic acid ester copolymer Polymers 0.000 description 2
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 2
- XWJBRBSPAODJER-UHFFFAOYSA-N 1,7-octadiene Chemical compound C=CCCCCC=C XWJBRBSPAODJER-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 2
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 description 2
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- WWUVJRULCWHUSA-UHFFFAOYSA-N 2-methyl-1-pentene Chemical compound CCCC(C)=C WWUVJRULCWHUSA-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- UIERETOOQGIECD-UHFFFAOYSA-N Angelic acid Natural products CC=C(C)C(O)=O UIERETOOQGIECD-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 2
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 description 2
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
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- 229920000571 Nylon 11 Polymers 0.000 description 2
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- 239000004952 Polyamide Substances 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
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- 125000002252 acyl group Chemical group 0.000 description 2
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- UIERETOOQGIECD-ARJAWSKDSA-N angelic acid Chemical compound C\C=C(\C)C(O)=O UIERETOOQGIECD-ARJAWSKDSA-N 0.000 description 2
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- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 2
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- 235000009508 confectionery Nutrition 0.000 description 2
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 2
- 150000001925 cycloalkenes Chemical class 0.000 description 2
- 125000000392 cycloalkenyl group Chemical group 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 208000028659 discharge Diseases 0.000 description 2
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- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 2
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- 150000008282 halocarbons Chemical class 0.000 description 2
- OTTZHAVKAVGASB-UHFFFAOYSA-N hept-2-ene Chemical compound CCCCC=CC OTTZHAVKAVGASB-UHFFFAOYSA-N 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 2
- 125000001841 imino group Chemical group [H]N=* 0.000 description 2
- LDHQCZJRKDOVOX-IHWYPQMZSA-N isocrotonic acid Chemical compound C\C=C/C(O)=O LDHQCZJRKDOVOX-IHWYPQMZSA-N 0.000 description 2
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- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical class O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
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- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
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- 125000000027 (C1-C10) alkoxy group Chemical group 0.000 description 1
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
- 125000006713 (C5-C10) cycloalkyl group Chemical group 0.000 description 1
- RMCLVYNUTRHDDI-UHFFFAOYSA-N 1,1-dichloroethene;ethenyl acetate Chemical compound ClC(Cl)=C.CC(=O)OC=C RMCLVYNUTRHDDI-UHFFFAOYSA-N 0.000 description 1
- FMZITCJWMYHQFG-UHFFFAOYSA-N 1,2,3,4,4a,5,8,8a-octahydro-2-methyl-1,4:5,8-dimethanonaphthalene Chemical compound C1C(C23)C=CC1C3C1CC2CC1C FMZITCJWMYHQFG-UHFFFAOYSA-N 0.000 description 1
- PCHXZXKMYCGVFA-UHFFFAOYSA-N 1,3-diazetidine-2,4-dione Chemical group O=C1NC(=O)N1 PCHXZXKMYCGVFA-UHFFFAOYSA-N 0.000 description 1
- IKYNWXNXXHWHLL-UHFFFAOYSA-N 1,3-diisocyanatopropane Chemical compound O=C=NCCCN=C=O IKYNWXNXXHWHLL-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- OVBFMUAFNIIQAL-UHFFFAOYSA-N 1,4-diisocyanatobutane Chemical compound O=C=NCCCCN=C=O OVBFMUAFNIIQAL-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
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Abstract
【解決手段】プラスチック基材に積層され、塩素含有樹脂で構成された第一層と、この第一層に積層され、環状ポリオレフィン系樹脂で構成された第二層とで積層フィルムを構成する。前記第一層及び前記第二層は、それぞれコーティングにより形成されている。前記第一層は、少なくとも塩素含有モノマーを重合した重合体で構成されていてもよい。また、第一層は、少なくとも塩化ビニリデン系重合体で構成されていてもよい。前記第二層の厚みは、0.1〜20μm程度であってもよい。前記第一層と前記第二層との厚みの比率は、第一層/第二層=1/0.5〜1/10程度であってもよい。
【選択図】なし
Description
プラスチック基材を構成する樹脂としては、特に制限されず、熱硬化性樹脂(フェノール樹脂、ユリア樹脂、メラミン樹脂、エポキシ樹脂、ケイ素樹脂、ポリウレタン、ポリイミドなど)、熱可塑性樹脂(ポリオレフィン系樹脂、アクリル系樹脂、ビニル系樹脂、ポリエステル系樹脂、ポリアミド系樹脂、ポリカーボネート系樹脂、セルロース系樹脂など)などの合成樹脂などが挙げられる。これらの樹脂のうち、ポリオレフィン系樹脂、ビニル系樹脂、ポリエステル系樹脂、ポリアミド系樹脂、セルロース系樹脂などの熱可塑性樹脂などを用いる場合が多い。
前記プラスチック基材に積層される第一層は、塩素含有樹脂で構成されている。
前記第一層に積層される第二層は、環状ポリオレフィン系樹脂で構成されている。前記環状ポリオレフィン系樹脂は、環内にエチレン性二重結合を有する重合性の環状オレフィンを少なくとも重合成分とする樹脂であればよい。環状オレフィンは、単環式オレフィンであってもよく、多環式オレフィンであってもよい。
本発明の積層フィルムは、前記塩素含有樹脂を含む塗布液(以下、「第一の塗布液」と記載する場合がある)をプラスチック基材にコーティングして第一層を形成した後、前記環状ポリオレフィン系樹脂を含む塗布液(以下、「第二の塗布液」と記載する場合がある)を前記第一層にコーティングして第二層を形成して得ることができる。
プラスチック基材上に形成した第一層を10cm×25cmに切り出しサンプルとし、重量を測定した後、第一層をテトラヒドロフランにて、プラスチック基材から溶出させた後、十分に拭き取った。再度サンプルの重量を測定し、重量の減少から第一層の塗布量を算出した。また、プラスチック基材に積層された第一層上に形成した第二層を10cm×25cmに切り出しサンプルとし、重量を測定した後、第一層及び第二層をテトラヒドロフランにて、プラスチック基材から十分に剥がした。再度サンプルの重量を測定し、重量の減少から第一層及び第二層の合計の塗布量を算出し、第二層の塗布量も算出した。
温度23±5℃、相対湿度50±10%の条件下で、第一層(又は第二層)の表面に、50mmを超える長さのテープ(ニチバン(株)製、セロテープ(登録商標)CT405AP−24)を表面に重ね、第一層(又は第二層)に接触させるために、指先でしっかりとテープをこすって押しつけた。テープ全体が均一に第一層(又は第二層)に付着しているか確認後、5分以内に、第一層(又は第二層)の表面に対して、できるだけ60度に近い角度でテープの端をつかみ、0.5〜1秒間で引き離した。第一層(又は第二層)のテープを付着した部分を観察し、密着性を以下の基準で評価した。
○…全く剥がれない
△…部分的に剥がれる
×…全面が剥がれる
(第一の塗布液の調製)
トルエン、メチルエチルケトン、及びテトラヒドロフラン(トルエン:メチルエチルケトン:テトラヒドロフラン(重量比)=1.5:1.5:7)を混合し、撹拌して均一な溶媒(溶剤)を調製した。この溶媒に、塩化ビニリデン系重合体(旭化成ケミカルズ(株)製、PVDCレジン R204)100重量部、及びトリレンジイソシアネート(TDI)3重量部を溶解し、固形分濃度12重量%の塗布液Pを得た。
環状オレフィン系樹脂(ポリプラスチックス(株)製、TOPAS 6013S)をトルエンに撹拌溶解し、固形分濃度15重量%の塗布液Cを得た。
プラスチック基材として、二軸延伸ポリエチレンテレフタレートフィルム(ユニチカ(株)製、ポリエステルフィルムエンブレット S50、厚み50μm)を用い、このフィルムの片面にコロナ放電処理を施した。コロナ放電処理を施した面に、塗布液Pをメイヤーバーコーティング法によりコーティングし、130℃の温度で1分間乾燥して第一層を形成した。さらに第一層に塗布液Cをメイヤーバーコーティング法によりコーティングし、100℃の温度で1分間乾燥して第二層を形成し積層フィルムを得た。第一層の厚みは1μm、第二層の厚みは3μmであった。また、第一層及び第二層それぞれについて、塗布量を測定し、密着性を評価した。
二軸延伸ポリエステルフィルムの代わりに、トリアセチルセルロースフィルム(富士フィルム(株)製、厚み80μm)を用いる以外は、実施例1と同様にして積層フィルムを得た。第一層の厚みは2μm、第二層の厚みは5μmであった。また、第一層及び第二層それぞれについて、塗布量を測定し、密着性を評価した。
塗布液Pの代わりに、共重合ポリエステル(日本合成化学工業(株)製、ニチゴーポリエスターTP220)をトルエン及びメチルエチルケトンの混合溶媒(トルエン:メチルエチルケトン(重量比)=1:2)に溶解した固形分濃度12重量%の塗布液Aを用いる以外は、実施例1と同様にして積層フィルムを得た。第一層の厚みは1μm、第二層の厚みは2μmであった。また、第一層及び第二層それぞれについて、塗布量を測定し、密着性を評価した。
塗布液Pの代わりに、ポリエチレンイミン(日本触媒(株)製、エポミンP−1000)を水に溶解した固形分濃度1重量%の塗布液Bを用い、二軸延伸ポリエステルフィルムの代わりに、二軸延伸ポリオレフィンフィルム(ダイセルバリューコーティング(株)製、二軸延伸ポリオレフィンフィルムD1、厚み20μm)を用いる以外は、実施例1と同様にして積層フィルムを得た。第一層の厚みは0.5μm以下、第二層の厚みは1μmであった。また、第一層及び第二層それぞれについて、塗布量を測定し、密着性を評価した。
塗布液Pの代わりに、アクリル系樹脂(BASFジャパン(株)製、JONCRYL840)を水に溶解した固形分濃度10重量%の塗布液Dを用いる以外は、実施例1と同様にして積層フィルムを得た。第一層の厚みは0.5μm以下、第二層の厚みは1μmであった。また、第一層及び第二層それぞれについて、塗布量を測定し、密着性を評価した。
Claims (7)
- プラスチック基材に積層され、塩素含有樹脂で構成された第一層と、この第一層に積層され、環状ポリオレフィン系樹脂で構成された第二層とで構成された積層フィルムであって、前記第一層及び前記第二層がそれぞれコーティングにより形成された積層フィルム。
- 第一層が、少なくとも塩素含有モノマーを重合した重合体で構成されている請求項1記載の積層フィルム。
- 第一層が、少なくとも塩化ビニリデン系重合体で構成されている請求項1又は2記載の積層フィルム。
- 第二層の厚みが0.1〜20μmである請求項1〜3のいずれかに記載の積層フィルム。
- 第一層と第二層との厚みの比率が、第一層/第二層=1/0.5〜1/10である請求項1〜4のいずれかに記載の積層フィルム。
- プラスチック基材が、ポリオレフィン系樹脂、ポリビニルアルコール系樹脂、ポリエステル系樹脂、ポリアミド系樹脂、及びセルロース系樹脂から選択された少なくとも一種である請求項1〜5のいずれかに記載の積層フィルム。
- 塩素含有樹脂を含む塗布液をプラスチック基材にコーティングして第一層を形成した後、環状ポリオレフィン系樹脂を含む塗布液を前記第一層にコーティングして第二層を形成する請求項1〜6のいずれかに記載の積層フィルムの製造方法。
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Free format text: JAPANESE INTERMEDIATE CODE: R250 |