JP2008530338A5

JP2008530338A5 -

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Publication number: JP2008530338A5
Authority: JP; Japan
Prior art keywords: amine; compound; composition; organic; groups
Prior art date: 2006-01-11
Legal status : Granted

Application number

JP2007556139A

Other languages

English (en)

Japanese (ja)

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JP2008530338A (ja

JP5039567B2 (ja

Filing date

2006-01-11

Publication date

2012-06-07

2006-01-11 Application filed filed Critical

2006-01-11 Priority claimed from PCT/US2006/000767 external-priority patent/WO2006088571A1/en

2008-08-07 Publication of JP2008530338A publication Critical patent/JP2008530338A/ja

2012-06-07 Publication of JP2008530338A5 publication Critical patent/JP2008530338A5/ja

2012-10-03 Application granted granted Critical

2012-10-03 Publication of JP5039567B2 publication Critical patent/JP5039567B2/ja

Status Expired - Fee Related legal-status Critical Current

2026-01-11 Anticipated expiration legal-status Critical

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-1 amine compound Chemical class 0.000 claims description 158
239000002245 particle Substances 0.000 claims description 144
229920000642 polymer Polymers 0.000 claims description 138
239000000203 mixture Substances 0.000 claims description 119
150000001412 amines Chemical class 0.000 claims description 72
150000001875 compounds Chemical class 0.000 claims description 70
238000006116 polymerization reaction Methods 0.000 claims description 69
239000000178 monomer Substances 0.000 claims description 64
238000000034 method Methods 0.000 claims description 54
239000002904 solvent Substances 0.000 claims description 42
229920001296 polysiloxane Polymers 0.000 claims description 32
150000003254 radicals Chemical class 0.000 claims description 32
239000004480 active ingredient Substances 0.000 claims description 31
239000007787 solid Substances 0.000 claims description 29
239000003054 catalyst Substances 0.000 claims description 27
229920005989 resin Polymers 0.000 claims description 27
239000011347 resin Substances 0.000 claims description 27
238000006243 chemical reaction Methods 0.000 claims description 26
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
125000005375 organosiloxane group Chemical group 0.000 claims description 18
238000003756 stirring Methods 0.000 claims description 18
239000006185 dispersion Substances 0.000 claims description 17
239000012530 fluid Substances 0.000 claims description 17
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 16
235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 16
229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 16
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 15
229910052710 silicon Inorganic materials 0.000 claims description 15
UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 claims description 14
150000002894 organic compounds Chemical class 0.000 claims description 14
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 12
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 12
230000008569 process Effects 0.000 claims description 12
239000002253 acid Substances 0.000 claims description 11
239000004205 dimethyl polysiloxane Substances 0.000 claims description 11
239000010703 silicon Substances 0.000 claims description 11
YFCGDEUVHLPRCZ-UHFFFAOYSA-N [dimethyl(trimethylsilyloxy)silyl]oxy-dimethyl-trimethylsilyloxysilane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C YFCGDEUVHLPRCZ-UHFFFAOYSA-N 0.000 claims description 10
229910000085 borane Inorganic materials 0.000 claims description 10
125000004432 carbon atom Chemical group C* 0.000 claims description 10
150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 10
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 9
239000003205 fragrance Substances 0.000 claims description 9
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 8
150000001282 organosilanes Chemical class 0.000 claims description 8
239000000975 dye Substances 0.000 claims description 7
238000010526 radical polymerization reaction Methods 0.000 claims description 7
125000001931 aliphatic group Chemical group 0.000 claims description 6
JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 6
230000000977 initiatory effect Effects 0.000 claims description 6
230000007246 mechanism Effects 0.000 claims description 6
229910052751 metal Inorganic materials 0.000 claims description 6
239000002184 metal Substances 0.000 claims description 6
150000003839 salts Chemical class 0.000 claims description 6
229910000077 silane Inorganic materials 0.000 claims description 6
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 5
239000002318 adhesion promoter Substances 0.000 claims description 5
239000003814 drug Substances 0.000 claims description 5
239000000976 ink Substances 0.000 claims description 5
239000012948 isocyanate Substances 0.000 claims description 5
150000002513 isocyanates Chemical class 0.000 claims description 5
229930003231 vitamin Natural products 0.000 claims description 5
239000011782 vitamin Substances 0.000 claims description 5
235000013343 vitamin Nutrition 0.000 claims description 5
229940088594 vitamin Drugs 0.000 claims description 5
125000003118 aryl group Chemical group 0.000 claims description 4
239000002537 cosmetic Substances 0.000 claims description 4
150000002118 epoxides Chemical class 0.000 claims description 4
239000003337 fertilizer Substances 0.000 claims description 4
239000000796 flavoring agent Substances 0.000 claims description 4
235000019634 flavors Nutrition 0.000 claims description 4
239000004009 herbicide Substances 0.000 claims description 4
UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 claims description 4
150000002430 hydrocarbons Chemical group 0.000 claims description 4
239000002608 ionic liquid Substances 0.000 claims description 4
YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical compound ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 claims description 4
SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 claims description 3
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 3
XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 claims description 3
239000002841 Lewis acid Substances 0.000 claims description 3
239000003153 chemical reaction reagent Substances 0.000 claims description 3
239000003431 cross linking reagent Substances 0.000 claims description 3
229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
239000002917 insecticide Substances 0.000 claims description 3
150000007517 lewis acids Chemical class 0.000 claims description 3
239000006249 magnetic particle Substances 0.000 claims description 3
239000011707 mineral Substances 0.000 claims description 3
HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 claims description 3
CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 claims description 3
239000000049 pigment Substances 0.000 claims description 3
125000002029 aromatic hydrocarbon group Chemical group 0.000 claims description 2
NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 claims 2
229940079593 drug Drugs 0.000 claims 2
125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims 2
230000002363 herbicidal effect Effects 0.000 claims 2
150000003722 vitamin derivatives Chemical class 0.000 claims 2
230000014759 maintenance of location Effects 0.000 claims 1
LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 claims 1
239000011521 glass Substances 0.000 description 33
XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 28
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 25
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 21
125000000962 organic group Chemical group 0.000 description 21
YOBOXHGSEJBUPB-MTOQALJVSA-N (z)-4-hydroxypent-3-en-2-one;zirconium Chemical compound [Zr].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O YOBOXHGSEJBUPB-MTOQALJVSA-N 0.000 description 20
239000011859 microparticle Substances 0.000 description 20
239000004743 Polypropylene Substances 0.000 description 18
229920001155 polypropylene Polymers 0.000 description 18
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 17
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 16
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 15
125000000524 functional group Chemical group 0.000 description 14
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 13
239000003795 chemical substances by application Substances 0.000 description 13
239000000945 filler Substances 0.000 description 13
LALRXNPLTWZJIJ-UHFFFAOYSA-N triethylborane Chemical compound CCB(CC)CC LALRXNPLTWZJIJ-UHFFFAOYSA-N 0.000 description 12
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 11
229910052796 boron Inorganic materials 0.000 description 10
229920001577 copolymer Polymers 0.000 description 10
238000005538 encapsulation Methods 0.000 description 10
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 9
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
230000015572 biosynthetic process Effects 0.000 description 9
230000000052 comparative effect Effects 0.000 description 9
239000000463 material Substances 0.000 description 9
CERQOIWHTDAKMF-UHFFFAOYSA-M methacrylate group Chemical group C(C(=C)C)(=O)[O-] CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 9
125000005702 oxyalkylene group Chemical group 0.000 description 9
239000001301 oxygen Substances 0.000 description 9
229910052760 oxygen Inorganic materials 0.000 description 9
229920003023 plastic Polymers 0.000 description 9
239000004033 plastic Substances 0.000 description 9
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 9
IUVCFHHAEHNCFT-INIZCTEOSA-N 2-[(1s)-1-[4-amino-3-(3-fluoro-4-propan-2-yloxyphenyl)pyrazolo[3,4-d]pyrimidin-1-yl]ethyl]-6-fluoro-3-(3-fluorophenyl)chromen-4-one Chemical compound C1=C(F)C(OC(C)C)=CC=C1C(C1=C(N)N=CN=C11)=NN1[C@@H](C)C1=C(C=2C=C(F)C=CC=2)C(=O)C2=CC(F)=CC=C2O1 IUVCFHHAEHNCFT-INIZCTEOSA-N 0.000 description 8
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 8
125000003342 alkenyl group Chemical group 0.000 description 8
239000013078 crystal Substances 0.000 description 8
238000001000 micrograph Methods 0.000 description 8
239000000377 silicon dioxide Substances 0.000 description 8
UHUUYVZLXJHWDV-UHFFFAOYSA-N trimethyl(methylsilyloxy)silane Chemical compound C[SiH2]O[Si](C)(C)C UHUUYVZLXJHWDV-UHFFFAOYSA-N 0.000 description 8
239000001993 wax Substances 0.000 description 8
229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 7
229910052753 mercury Inorganic materials 0.000 description 7
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 6
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
KPSZQYZCNSCYGG-UHFFFAOYSA-N [B].[B] Chemical class [B].[B] KPSZQYZCNSCYGG-UHFFFAOYSA-N 0.000 description 6
239000000853 adhesive Substances 0.000 description 6
230000001070 adhesive effect Effects 0.000 description 6
125000000217 alkyl group Chemical group 0.000 description 6
125000000304 alkynyl group Chemical group 0.000 description 6
125000003277 amino group Chemical group 0.000 description 6
238000004132 cross linking Methods 0.000 description 6
KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 6
238000002156 mixing Methods 0.000 description 6
HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 6
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 6
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 6
229920002554 vinyl polymer Polymers 0.000 description 6
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 5
125000002843 carboxylic acid group Chemical group 0.000 description 5
238000009826 distribution Methods 0.000 description 5
125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 5
239000004615 ingredient Substances 0.000 description 5
239000003999 initiator Substances 0.000 description 5
239000000314 lubricant Substances 0.000 description 5
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
125000002568 propynyl group Chemical group [*]C#CC([H])([H])[H] 0.000 description 5
238000001878 scanning electron micrograph Methods 0.000 description 5
230000007704 transition Effects 0.000 description 5
125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 4
125000000143 2-carboxyethyl group Chemical group [H]OC(=O)C([H])([H])C([H])([H])* 0.000 description 4
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
239000005058 Isophorone diisocyanate Substances 0.000 description 4
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
150000001299 aldehydes Chemical group 0.000 description 4
HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 4
150000008064 anhydrides Chemical group 0.000 description 4
239000012296 anti-solvent Substances 0.000 description 4
TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
125000004369 butenyl group Chemical group C(=CCC)* 0.000 description 4
238000000576 coating method Methods 0.000 description 4
238000012674 dispersion polymerization Methods 0.000 description 4
238000001704 evaporation Methods 0.000 description 4
230000004927 fusion Effects 0.000 description 4
229910052736 halogen Inorganic materials 0.000 description 4
125000005843 halogen group Chemical group 0.000 description 4
125000004356 hydroxy functional group Chemical group O* 0.000 description 4
NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 4
229910052697 platinum Inorganic materials 0.000 description 4
239000011164 primary particle Substances 0.000 description 4
239000000523 sample Substances 0.000 description 4
239000004094 surface-active agent Substances 0.000 description 4
229910052725 zinc Inorganic materials 0.000 description 4
239000011701 zinc Substances 0.000 description 4
125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 description 3
NRGGMCIBEHEAIL-UHFFFAOYSA-N 2-ethylpyridine Chemical compound CCC1=CC=CC=N1 NRGGMCIBEHEAIL-UHFFFAOYSA-N 0.000 description 3
FAOPZUAEZGKQNC-UHFFFAOYSA-N 3-propyl-1h-pyrrole Chemical group CCCC=1C=CNC=1 FAOPZUAEZGKQNC-UHFFFAOYSA-N 0.000 description 3
JIUWLLYCZJHZCZ-UHFFFAOYSA-N 3-propyloxolane-2,5-dione Chemical compound CCCC1CC(=O)OC1=O JIUWLLYCZJHZCZ-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
239000004793 Polystyrene Substances 0.000 description 3
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 3
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
239000000654 additive Substances 0.000 description 3
238000013459 approach Methods 0.000 description 3
239000012298 atmosphere Substances 0.000 description 3
230000008901 benefit Effects 0.000 description 3
238000012662 bulk polymerization Methods 0.000 description 3
229910000019 calcium carbonate Inorganic materials 0.000 description 3
239000006229 carbon black Substances 0.000 description 3
239000011248 coating agent Substances 0.000 description 3
238000009833 condensation Methods 0.000 description 3
230000005494 condensation Effects 0.000 description 3
125000004966 cyanoalkyl group Chemical group 0.000 description 3
125000000753 cycloalkyl group Chemical group 0.000 description 3
UKJLNMAFNRKWGR-UHFFFAOYSA-N cyclohexatrienamine Chemical group NC1=CC=C=C[CH]1 UKJLNMAFNRKWGR-UHFFFAOYSA-N 0.000 description 3
125000004188 dichlorophenyl group Chemical group 0.000 description 3
239000000839 emulsion Substances 0.000 description 3
238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 3
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
239000010419 fine particle Substances 0.000 description 3
239000007789 gas Substances 0.000 description 3
230000009477 glass transition Effects 0.000 description 3
239000001257 hydrogen Substances 0.000 description 3
229910052739 hydrogen Inorganic materials 0.000 description 3
125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
239000003607 modifier Substances 0.000 description 3
239000003960 organic solvent Substances 0.000 description 3
229910052763 palladium Inorganic materials 0.000 description 3
239000000575 pesticide Substances 0.000 description 3
229920001223 polyethylene glycol Polymers 0.000 description 3
239000003505 polymerization initiator Substances 0.000 description 3
229920002223 polystyrene Polymers 0.000 description 3
239000000843 powder Substances 0.000 description 3
230000002028 premature Effects 0.000 description 3
238000012545 processing Methods 0.000 description 3
WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical group CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 3
229910052709 silver Inorganic materials 0.000 description 3
239000004332 silver Substances 0.000 description 3
239000011734 sodium Substances 0.000 description 3
229910052708 sodium Inorganic materials 0.000 description 3
239000003381 stabilizer Substances 0.000 description 3
238000004381 surface treatment Methods 0.000 description 3
239000000725 suspension Substances 0.000 description 3
239000011135 tin Substances 0.000 description 3
229910052718 tin Inorganic materials 0.000 description 3
125000003944 tolyl group Chemical group 0.000 description 3
125000005023 xylyl group Chemical group 0.000 description 3
229910052726 zirconium Inorganic materials 0.000 description 3
KJPRLNWUNMBNBZ-QPJJXVBHSA-N (E)-cinnamaldehyde Chemical compound O=C\C=C\C1=CC=CC=C1 KJPRLNWUNMBNBZ-QPJJXVBHSA-N 0.000 description 2
DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 2
GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
OFHHDSQXFXLTKC-UHFFFAOYSA-N 10-undecenal Chemical compound C=CCCCCCCCCC=O OFHHDSQXFXLTKC-UHFFFAOYSA-N 0.000 description 2
COXCGWKSEPPDAA-UHFFFAOYSA-N 2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)C#N COXCGWKSEPPDAA-UHFFFAOYSA-N 0.000 description 2
LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 2
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JP2007556139A 2005-02-16 2006-01-11 ポリマー粒子、および、有機ボランアミン錯体を用いた封入（ｅｎｃａｐｓｕｌａｔｅｄ）組成物 Expired - Fee Related JP5039567B2 (ja)