JP2008207550A - 樹脂被覆金属箔及びその製造方法、並びにこの製造方法で得られた樹脂被覆金属箔を用いた金属張積層板及びその製造方法 - Google Patents
樹脂被覆金属箔及びその製造方法、並びにこの製造方法で得られた樹脂被覆金属箔を用いた金属張積層板及びその製造方法 Download PDFInfo
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- JP2008207550A JP2008207550A JP2008018374A JP2008018374A JP2008207550A JP 2008207550 A JP2008207550 A JP 2008207550A JP 2008018374 A JP2008018374 A JP 2008018374A JP 2008018374 A JP2008018374 A JP 2008018374A JP 2008207550 A JP2008207550 A JP 2008207550A
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- Prior art keywords
- resin
- metal foil
- coated metal
- layer
- clad laminate
- Prior art date
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- CVNKFOIOZXAFBO-UHFFFAOYSA-J tin(4+);tetrahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[Sn+4] CVNKFOIOZXAFBO-UHFFFAOYSA-J 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
【解決手段】金属箔の片面に樹脂層が形成され、樹脂層が形成された面と反対側の面に、再剥離性粘着剤が基材に積層されてなる裏打ち材が形成されてなる樹脂被覆金属箔及び絶縁層を、樹脂被覆金属箔の樹脂層が絶縁層と接するように積層して金属張積層板を得る。金属箔は銅箔であり、樹脂層はブロック共重合ポリイミド樹脂を含有し、裏打ち材の厚さは12〜350μmの範囲内となるようにする。
【選択図】図1
Description
樹脂被覆金属箔製造後、金属箔である銅箔の状態を目視により観察し、以下の基準により評価した。
×:銅箔にシワ又はスジが見られる。
JIS C 6481に準拠しマイクロメータにて5点の厚みを測定し、その平均値を求めた。
JIS C 6481に準拠し3回測定し、その平均値を求めた。
樹脂層被覆金属箔を、幅25mm、長さ250mmに切断して試験片とし、この試験片の樹脂層を上にして23℃の温度雰囲気下で1時間放置したときの樹脂層被覆金属箔の状態を目視により観察し、以下の基準により評価した。なお、実施例1の金属張積層板10樹脂層被覆金属箔20及び実施例2の金属張積層板の樹脂層被覆金属箔は、裏打ち材付きで評価した。
×:カールが見られる。
プレス後の銅箔及び絶縁層の状態を目視により観察し、以下の基準で評価した。
×:銅箔に傷や凹みが見られる。
フェノール性水酸其含有芳香族ポリアミド−ポリブタジエン−アクリロニトリル共重合体(固形分20%DMAC溶液品)583質量部、ヒドロキシフェニルメタン型エポキシ樹脂(日本化薬社製、商品名「EPPN502H」100質量部、硬化剤〔10−(2,5−ジヒドロキシフェニル)−10H−9オキサ−10−ホスファフェナントレン−10−オキシド(三光社製、商品名「HCA−HQ」)50質量部及びビフェニル型ナフトールノボラック樹脂(明和化成社製、商品名「MEH−7851−3H」)50質量部〕100質量部、トリフェニルホスフィン3質量部をジメチルアセトアミド800質量部に混合、溶解し樹脂層形成塗工液を調製した。
比較例1の金属張積層板は、樹脂被覆金属箔作成時に裏打ち材を用いなかったこと以外は、全て実施例1と同様の方法で樹脂被覆金属箔及び金属張積層板を作製した。評価結果を表1に示す。
12…基材
14…粘着層
16…金属箔
18…樹脂層
20、20A…樹脂被覆金属箔
22…絶縁層
Claims (12)
- 金属箔の片面に樹脂層が形成された樹脂被覆金属箔の製造方法であって、
再剥離性粘着剤が基材に積層されてなる裏打ち材を、該金属箔の該樹脂層を形成する面とは反対側の面に貼り付ける裏打ち材貼付工程と、
該裏打ち材が貼り付けられた金属箔に前記樹脂層を形成する樹脂層形成工程と、を有することを特徴とする樹脂被覆金属箔の製造方法。 - 請求項1において、
前記樹脂層はポリイミド樹脂を含有することを特徴とする樹脂被覆金属箔の製造方法。 - 請求項2において、
該ポリイミド樹脂が、一般式(1)及び一般式(2)で表される構造単位を有するブロック共重合ポリイミド樹脂であることを特徴とする樹脂被覆金属箔の製造方法。
- 請求項1乃至3のいずれかにおいて、
前記裏打ち材の厚さが12〜350μmの範囲であることを特徴とする樹脂被覆金属箔の製造方法。 - 請求項1乃至4のいずれかに記載の樹脂被覆金属箔の製造方法により樹脂層、金属箔及び裏打ち材がこの順に積層されていることを特徴とする樹脂被覆金属箔。
- 請求項5において、前記金属箔は銅箔であることを特徴とする樹脂被覆金属箔。
- 請求項5又は6に記載の樹脂被覆金属箔及び絶縁層を、該樹脂被覆金属箔の樹脂層が前記絶縁層と接するように一対のプレス板の間にて積層し、
当該積層体を加熱・加圧処理することで樹脂被覆金属箔と絶縁層とからなる金属張積層板を製造することを特徴とする金属張積層板の製造方法。 - 請求項7に記載の製造方法により得られる金属張積層板。
- 樹脂被覆金属箔及び絶縁層を、前記樹脂被覆金属箔の樹脂層が前記絶縁層と接するように積層された金属張積層板であって、
前記樹脂被覆金属箔は、金属箔の片面に樹脂層が形成され、前記金属箔の前記樹脂層が形成された面とは反対側の面に、再剥離性粘着剤が基材に積層されてなる裏打ち材が形成されていることを特徴とする金属張積層板。 - 請求項9において、
前記金属箔は銅箔であることを特徴とする金属張積層板。 - 請求項9又は10において、
前記樹脂層は、一般式(1)及び一般式(2)で表される構造単位を有するブロック共重合ポリイミド樹脂を含有し、前記裏打ち材の厚さが12〜350μmの範囲であることを特徴とする金属張積層板。
- 請求項9乃至11のいずれかにおいて、
前記絶縁層が、Bステージ樹脂組成物からなるBステージ樹脂組成物層であることを特徴とする金属張積層板。
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