JP2008101149A - 紫外線硬化発泡体 - Google Patents
紫外線硬化発泡体 Download PDFInfo
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- JP2008101149A JP2008101149A JP2006285840A JP2006285840A JP2008101149A JP 2008101149 A JP2008101149 A JP 2008101149A JP 2006285840 A JP2006285840 A JP 2006285840A JP 2006285840 A JP2006285840 A JP 2006285840A JP 2008101149 A JP2008101149 A JP 2008101149A
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- 239000006260 foam Substances 0.000 title claims abstract description 75
- 238000005187 foaming Methods 0.000 claims abstract description 36
- 229920005989 resin Polymers 0.000 claims abstract description 35
- 239000011347 resin Substances 0.000 claims abstract description 35
- 239000002994 raw material Substances 0.000 claims abstract description 27
- 239000003085 diluting agent Substances 0.000 claims abstract description 20
- 125000005250 alkyl acrylate group Chemical group 0.000 claims abstract description 14
- 239000003505 polymerization initiator Substances 0.000 claims abstract description 8
- 239000003381 stabilizer Substances 0.000 claims abstract description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 15
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000002985 plastic film Substances 0.000 abstract description 29
- 229920006255 plastic film Polymers 0.000 abstract description 29
- 239000011248 coating agent Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 3
- 230000001678 irradiating effect Effects 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 238000004804 winding Methods 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 6
- -1 polyethylene Polymers 0.000 description 6
- 238000007906 compression Methods 0.000 description 5
- 230000006835 compression Effects 0.000 description 5
- 239000011261 inert gas Substances 0.000 description 5
- 229920002635 polyurethane Polymers 0.000 description 5
- 239000004814 polyurethane Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 230000001588 bifunctional effect Effects 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 4
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- RZVINYQDSSQUKO-UHFFFAOYSA-N 2-phenoxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC1=CC=CC=C1 RZVINYQDSSQUKO-UHFFFAOYSA-N 0.000 description 2
- TXFPEBPIARQUIG-UHFFFAOYSA-N 4'-hydroxyacetophenone Chemical compound CC(=O)C1=CC=C(O)C=C1 TXFPEBPIARQUIG-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 241000219492 Quercus Species 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000013011 mating Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 125000006528 (C2-C6) alkyl group Chemical group 0.000 description 1
- 229920003067 (meth)acrylic acid ester copolymer Polymers 0.000 description 1
- STFXXRRQKFUYEU-UHFFFAOYSA-N 16-methylheptadecyl prop-2-enoate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)C=C STFXXRRQKFUYEU-UHFFFAOYSA-N 0.000 description 1
- HEQOJEGTZCTHCF-UHFFFAOYSA-N 2-amino-1-phenylethanone Chemical compound NCC(=O)C1=CC=CC=C1 HEQOJEGTZCTHCF-UHFFFAOYSA-N 0.000 description 1
- RIWRBSMFKVOJMN-UHFFFAOYSA-N 2-methyl-1-phenylpropan-2-ol Chemical compound CC(C)(O)CC1=CC=CC=C1 RIWRBSMFKVOJMN-UHFFFAOYSA-N 0.000 description 1
- JTHZUSWLNCPZLX-UHFFFAOYSA-N 6-fluoro-3-methyl-2h-indazole Chemical compound FC1=CC=C2C(C)=NNC2=C1 JTHZUSWLNCPZLX-UHFFFAOYSA-N 0.000 description 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- ASAPXSLRMDUMFX-QXMHVHEDSA-N [(z)-octadec-9-enyl] prop-2-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)C=C ASAPXSLRMDUMFX-QXMHVHEDSA-N 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000010097 foam moulding Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- KVILQFSLJDTWPU-UHFFFAOYSA-N heptadecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCOC(=O)C=C KVILQFSLJDTWPU-UHFFFAOYSA-N 0.000 description 1
- PZDUWXKXFAIFOR-UHFFFAOYSA-N hexadecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C=C PZDUWXKXFAIFOR-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 229910001872 inorganic gas Inorganic materials 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052754 neon Inorganic materials 0.000 description 1
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- GOZDOXXUTWHSKU-UHFFFAOYSA-N pentadecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCCOC(=O)C=C GOZDOXXUTWHSKU-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 239000011116 polymethylpentene Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- XZHNPVKXBNDGJD-UHFFFAOYSA-N tetradecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCOC(=O)C=C XZHNPVKXBNDGJD-UHFFFAOYSA-N 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- XOALFFJGWSCQEO-UHFFFAOYSA-N tridecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCOC(=O)C=C XOALFFJGWSCQEO-UHFFFAOYSA-N 0.000 description 1
- 125000004417 unsaturated alkyl group Chemical group 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
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- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Molding Of Porous Articles (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
【解決手段】オリゴマー、希釈剤、紫外線重合開始剤、整泡剤を含む紫外線硬化性樹脂原料を機械発泡させて紫外線で硬化させた紫外線硬化発泡体において、オリゴマー70重量部に対して炭素数3〜30の1官能アルキルアクリレートからなる希釈剤を10〜50重量部用いた。紫外線硬化発泡体の製造は、オリゴマー70重量部に対して炭素数3〜30の1官能アルキルアクリレートからなる希釈剤を10〜50重量部含み、機械発泡させた紫外線硬化性樹脂原料Pをプラスチックフィルム11に塗布し、機械発泡させた紫外線硬化性樹脂原料Pに紫外線照射手段41で紫外線を照射することにより紫外線硬化性樹脂原料を硬化させて紫外線硬化発泡体Aとする。
【選択図】図1
Description
21 機械発泡装置
41 紫外線照射手段
A 紫外線硬化発泡体
P 機械発泡後の紫外線硬化性樹脂原料
Claims (3)
- オリゴマー、希釈剤、紫外線重合開始剤、整泡剤を含む紫外線硬化性樹脂原料を機械発泡させて紫外線で硬化させた紫外線硬化発泡体において、
前記希釈剤が炭素数3〜30の1官能アルキルアクリレートからなることを特徴とする紫外線硬化発泡体。 - 前記オリゴマー70重量部に対して前記炭素数3〜30の1官能アルキルアクリレートが10〜50重量部であることを特徴とする請求項1に記載の紫外線硬化発泡体。
- 発泡体の歪みが5%以下であることを特徴とする請求項1または2に記載の紫外線硬化発泡体。
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JP2006285840A JP5063079B2 (ja) | 2006-10-20 | 2006-10-20 | 紫外線硬化発泡体 |
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JP2006285840A JP5063079B2 (ja) | 2006-10-20 | 2006-10-20 | 紫外線硬化発泡体 |
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JP2008101149A true JP2008101149A (ja) | 2008-05-01 |
JP5063079B2 JP5063079B2 (ja) | 2012-10-31 |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008105213A (ja) * | 2006-10-24 | 2008-05-08 | Inoac Corp | 紫外線硬化発泡シートの製造方法 |
JP2008208263A (ja) * | 2007-02-27 | 2008-09-11 | Inoac Corp | 活性エネルギー線硬化樹脂発泡体及びその製造方法 |
JP2008239727A (ja) * | 2007-03-27 | 2008-10-09 | Inoac Corp | 紫外線硬化発泡体 |
JP2014084393A (ja) * | 2012-10-23 | 2014-05-12 | Inoac Gijutsu Kenkyusho:Kk | 光硬化発泡体 |
JP2014084394A (ja) * | 2012-10-23 | 2014-05-12 | Inoac Gijutsu Kenkyusho:Kk | 光硬化発泡体製造方法 |
JP2017002327A (ja) * | 2016-10-12 | 2017-01-05 | 株式会社イノアック技術研究所 | 光硬化発泡体製造方法 |
WO2018003222A1 (ja) * | 2016-06-28 | 2018-01-04 | Dic株式会社 | ポリウレタン発泡シート、その製造方法、及び積層体の製造方法 |
CN113580462A (zh) * | 2021-08-27 | 2021-11-02 | 浙江新恒泰新材料有限公司 | 一种用于可降解发泡材料的生产设备 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62119236A (ja) * | 1985-11-12 | 1987-05-30 | ダブリュー・アール・グレース・アンド・カンパニー―コーン | スキン層を持たない、接着性の独立気泡型硬化高分子発泡体組成物の製造法 |
JPS63130609A (ja) * | 1986-11-21 | 1988-06-02 | Yokohama Rubber Co Ltd:The | 紫外線硬化型樹脂組成物 |
JPH0487669A (ja) * | 1990-08-01 | 1992-03-19 | Oji Paper Co Ltd | 発泡体の製造方法 |
JPH064922A (ja) * | 1992-06-24 | 1994-01-14 | Victor Co Of Japan Ltd | 光磁気記録媒体 |
JPH07278333A (ja) * | 1994-04-12 | 1995-10-24 | Hitachi Cable Ltd | 紫外線照射発泡硬化樹脂組成物、成形品及び電線 |
JPH11235882A (ja) * | 1998-02-23 | 1999-08-31 | Toray Ind Inc | レーザー感応性平版印刷版原版 |
JP2001111290A (ja) * | 1999-10-07 | 2001-04-20 | Sekisui Chem Co Ltd | 透明電磁波シールド衝立 |
-
2006
- 2006-10-20 JP JP2006285840A patent/JP5063079B2/ja active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62119236A (ja) * | 1985-11-12 | 1987-05-30 | ダブリュー・アール・グレース・アンド・カンパニー―コーン | スキン層を持たない、接着性の独立気泡型硬化高分子発泡体組成物の製造法 |
JPH07258978A (ja) * | 1985-11-12 | 1995-10-09 | W R Grace & Co | ラミネート及びその製造法 |
JPS63130609A (ja) * | 1986-11-21 | 1988-06-02 | Yokohama Rubber Co Ltd:The | 紫外線硬化型樹脂組成物 |
JPH0487669A (ja) * | 1990-08-01 | 1992-03-19 | Oji Paper Co Ltd | 発泡体の製造方法 |
JPH064922A (ja) * | 1992-06-24 | 1994-01-14 | Victor Co Of Japan Ltd | 光磁気記録媒体 |
JPH07278333A (ja) * | 1994-04-12 | 1995-10-24 | Hitachi Cable Ltd | 紫外線照射発泡硬化樹脂組成物、成形品及び電線 |
JPH11235882A (ja) * | 1998-02-23 | 1999-08-31 | Toray Ind Inc | レーザー感応性平版印刷版原版 |
JP2001111290A (ja) * | 1999-10-07 | 2001-04-20 | Sekisui Chem Co Ltd | 透明電磁波シールド衝立 |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008105213A (ja) * | 2006-10-24 | 2008-05-08 | Inoac Corp | 紫外線硬化発泡シートの製造方法 |
JP2008208263A (ja) * | 2007-02-27 | 2008-09-11 | Inoac Corp | 活性エネルギー線硬化樹脂発泡体及びその製造方法 |
JP2008239727A (ja) * | 2007-03-27 | 2008-10-09 | Inoac Corp | 紫外線硬化発泡体 |
JP2014084393A (ja) * | 2012-10-23 | 2014-05-12 | Inoac Gijutsu Kenkyusho:Kk | 光硬化発泡体 |
JP2014084394A (ja) * | 2012-10-23 | 2014-05-12 | Inoac Gijutsu Kenkyusho:Kk | 光硬化発泡体製造方法 |
WO2018003222A1 (ja) * | 2016-06-28 | 2018-01-04 | Dic株式会社 | ポリウレタン発泡シート、その製造方法、及び積層体の製造方法 |
JP2017002327A (ja) * | 2016-10-12 | 2017-01-05 | 株式会社イノアック技術研究所 | 光硬化発泡体製造方法 |
CN113580462A (zh) * | 2021-08-27 | 2021-11-02 | 浙江新恒泰新材料有限公司 | 一种用于可降解发泡材料的生产设备 |
CN113580462B (zh) * | 2021-08-27 | 2024-06-11 | 浙江新恒泰新材料有限公司 | 一种用于可降解发泡材料的生产设备 |
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