JP2007505169A - フッ素化ポリエーテルイソシアナートから誘導されたシラン組成物 - Google Patents

フッ素化ポリエーテルイソシアナートから誘導されたシラン組成物 Download PDF

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Publication number
JP2007505169A
JP2007505169A JP2006525351A JP2006525351A JP2007505169A JP 2007505169 A JP2007505169 A JP 2007505169A JP 2006525351 A JP2006525351 A JP 2006525351A JP 2006525351 A JP2006525351 A JP 2006525351A JP 2007505169 A JP2007505169 A JP 2007505169A
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JP
Japan
Prior art keywords
group
composition
isocyanate
nco
independently
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2006525351A
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English (en)
Japanese (ja)
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JP2007505169A5 (enExample
Inventor
ジェイ． ダムス，ルドルフ
ジェイ． マーティン，スティーブン
エム． フライン，リチャード
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3M Innovative Properties Co
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3M Innovative Properties Co
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Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of JP2007505169A publication Critical patent/JP2007505169A/ja
Publication of JP2007505169A5 publication Critical patent/JP2007505169A5/ja
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225—Polyamines
    • C08G18/3228—Polyamines acyclic
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/11—Anti-reflection coatings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3271—Hydroxyamines
    • C08G18/3275—Hydroxyamines containing two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/46—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen
    • C08G18/4607—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen having halogens
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5003—Polyethers having heteroatoms other than oxygen having halogens
    • C08G18/5015—Polyethers having heteroatoms other than oxygen having halogens having fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/71—Monoisocyanates or monoisothiocyanates
    • C08G18/718—Monoisocyanates or monoisothiocyanates containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/002—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds
    • C08G65/005—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds containing halogens
    • C08G65/007—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds containing halogens containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/336—Polymers modified by chemical after-treatment with organic compounds containing silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/18—Coatings for keeping optical surfaces clean, e.g. hydrophobic or photo-catalytic films
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B27/00—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
    • G02B27/0006—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00 with means to keep optical surfaces clean, e.g. by preventing or removing dirt, stains, contamination, condensation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31598—Next to silicon-containing [silicone, cement, etc.] layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31598—Next to silicon-containing [silicone, cement, etc.] layer
    • Y10T428/31601—Quartz or glass

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • General Physics & Mathematics (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paints Or Removers (AREA)
  • Polyethers (AREA)
  • Silicon Polymers (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Surface Treatment Of Glass (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyurethanes Or Polyureas (AREA)
JP2006525351A 2003-09-08 2004-08-20 フッ素化ポリエーテルイソシアナートから誘導されたシラン組成物 Pending JP2007505169A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/657,644 US7652115B2 (en) 2003-09-08 2003-09-08 Fluorinated polyether isocyanate derived silane compositions
PCT/US2004/026949 WO2005026236A1 (en) 2003-09-08 2004-08-20 Fluorinated polyether isocyanate derived silane compositions

Publications (2)

Publication Number Publication Date
JP2007505169A true JP2007505169A (ja) 2007-03-08
JP2007505169A5 JP2007505169A5 (enExample) 2007-10-18

Family

ID=34226610

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2006525351A Pending JP2007505169A (ja) 2003-09-08 2004-08-20 フッ素化ポリエーテルイソシアナートから誘導されたシラン組成物

Country Status (9)

Country Link
US (1) US7652115B2 (enExample)
EP (1) EP1664155B1 (enExample)
JP (1) JP2007505169A (enExample)
CN (1) CN100519622C (enExample)
AT (1) ATE420913T1 (enExample)
DE (1) DE602004019111D1 (enExample)
ES (1) ES2320134T3 (enExample)
MX (1) MXPA06002588A (enExample)
WO (1) WO2005026236A1 (enExample)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007513239A (ja) * 2003-12-05 2007-05-24 スリーエム イノベイティブ プロパティズ カンパニー パーフルオロポリエーテルイソシアネート誘導シランおよびアルコキシシランを有するコーティング組成物
JP2012503712A (ja) * 2008-09-25 2012-02-09 スリーエム イノベイティブ プロパティズ カンパニー ホイールリムの処理方法及び方法に使用するための組成物
KR101463641B1 (ko) * 2007-05-18 2014-11-19 닛산 가가쿠 고교 가부시키 가이샤 저굴절률 피막 형성용 도포액, 그 제조 방법 및 반사 방지재
KR20170123262A (ko) * 2016-04-28 2017-11-07 스미또모 가가꾸 가부시끼가이샤 분무 도포용 조성물

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US7247386B2 (en) * 2003-12-23 2007-07-24 3M Innovative Properties Company Composition of an oligomeric fluorosilane and surface treatment of retroreflective sheet
US20050137266A1 (en) * 2003-12-23 2005-06-23 Naiyong Jing Aqueous composition of an oligomeric fluorosilane and use thereof for surface treatment of optical elements
US7147634B2 (en) 2005-05-12 2006-12-12 Orion Industries, Ltd. Electrosurgical electrode and method of manufacturing same
US8814861B2 (en) 2005-05-12 2014-08-26 Innovatech, Llc Electrosurgical electrode and method of manufacturing same
US7294731B1 (en) 2006-08-28 2007-11-13 3M Innovative Properties Company Perfluoropolyether silanes and use thereof
US7553514B2 (en) * 2006-08-28 2009-06-30 3M Innovative Properties Company Antireflective article
US8158264B2 (en) * 2006-10-20 2012-04-17 3M Innovative Properties Company Method for easy-to-clean substrates and articles therefrom
WO2008070704A1 (en) * 2006-12-07 2008-06-12 3M Innovative Properties Company Particles comprising a fluorinated siloxane and methods of making and using the same
CN101563383B (zh) * 2006-12-20 2012-08-15 3M创新有限公司 具有侧链甲硅烷基的含氟氨基甲酸酯化合物
US7745653B2 (en) * 2007-03-08 2010-06-29 3M Innovative Properties Company Fluorochemical compounds having pendent silyl groups
US7335786B1 (en) 2007-03-29 2008-02-26 3M Innovative Properties Company Michael-adduct fluorochemical silanes
US8015970B2 (en) * 2007-07-26 2011-09-13 3M Innovative Properties Company Respirator, welding helmet, or face shield that has low surface energy hard-coat lens
US7897678B2 (en) * 2007-07-26 2011-03-01 3M Innovative Properties Company Fluorochemical urethane compounds having pendent silyl groups
US8058463B2 (en) * 2007-12-04 2011-11-15 E. I. Du Pont De Nemours And Compnay Fluorosilanes
CN101959982B (zh) 2007-12-27 2014-08-06 3M创新有限公司 保护涂层组合物
US20110020657A1 (en) * 2007-12-27 2011-01-27 Cheng-Chung Chang Protective coating compositions
US8663874B2 (en) * 2008-03-11 2014-03-04 3M Innovative Properties Company Hardcoat composition
JP2012509937A (ja) * 2008-11-25 2012-04-26 スリーエム イノベイティブ プロパティズ カンパニー フッ素化エーテルウレタン及びその使用方法
US8329830B2 (en) 2009-06-30 2012-12-11 3M Innovative Properties Company Surface treatment process and treated article
BR112012000479A2 (pt) 2009-07-09 2016-02-16 3M Innovative Properties Co métodos para tratar formações contendo hidrocarboneto-carbonato com compostos anfotéricos fluorinados e formação contendo hidrocarboneto
CN102597116B (zh) 2009-07-21 2013-12-11 3M创新有限公司 可固化组合物、涂覆底片的方法、以及被涂覆的底片
US8420281B2 (en) 2009-09-16 2013-04-16 3M Innovative Properties Company Epoxy-functionalized perfluoropolyether polyurethanes
WO2011034845A1 (en) 2009-09-16 2011-03-24 3M Innovative Properties Company Fluorinated coating and phototools made therewith
WO2011034847A1 (en) 2009-09-16 2011-03-24 3M Innovative Properties Company Fluorinated coating and phototools made therewith
GB0917450D0 (en) 2009-10-06 2009-11-18 3M Innovative Properties Co Triazine containing fluoropolyether elastomers having very low glass transition temperatures, compositions containing them and methods of making them
US8268067B2 (en) * 2009-10-06 2012-09-18 3M Innovative Properties Company Perfluoropolyether coating composition for hard surfaces
WO2011079020A1 (en) 2009-12-22 2011-06-30 3M Innovative Properties Company Process for preparing shelf-stable curable polysilazanes, and polysilazanes prepared thereby
US8664323B2 (en) * 2010-06-25 2014-03-04 3M Innovative Properties Company Fluorinated composition, method of coating the composition, and article thereby
KR20140111005A (ko) 2012-01-10 2014-09-17 쓰리엠 이노베이티브 프로퍼티즈 컴파니 플루오르화 실란 수성 분산물
EP2920216B1 (en) 2012-11-13 2016-09-21 3M Innovative Properties Company Curable antifouling composition, method of use, and articles
CN105531337B (zh) 2013-09-16 2020-01-10 霍尼韦尔国际公司 含氟聚硅氧烷涂料
CN106102935A (zh) 2014-03-18 2016-11-09 3M创新有限公司 经处理的制品及其制备方法
CN106457305B (zh) 2014-05-22 2020-06-02 3M创新有限公司 涂覆工艺
BR112017008787A2 (pt) 2014-10-28 2017-12-26 3M Innovative Properties Co componentes de um sistema de aplicação de aspersões que compreende uma superfície repelente & métodos
WO2016091633A1 (de) * 2014-12-08 2016-06-16 Basf Coatings Gmbh Beschichtungsmittelzusammensetzungen und daraus hergestellte beschichtungen und sowie deren verwendung
JP6445162B2 (ja) * 2014-12-08 2018-12-26 ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングＢＡＳＦ Ｃｏａｔｉｎｇｓ ＧｍｂＨ 非水性コーティング材料組成物、それらから生成され、付着性および引っ掻き抵抗性が改善されたコーティング、ならびにその使用方法
US10858540B2 (en) 2015-09-23 2020-12-08 3M Innovative Properties Company Composition including silanes and methods of making a treated article
CN113145341A (zh) 2015-10-28 2021-07-23 3M创新有限公司 包括拒液表面的喷雾施用系统部件和方法
WO2017074708A1 (en) 2015-10-28 2017-05-04 3M Innovative Properties Company Articles subject to ice formation comprising a repellent surface
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US10730993B2 (en) * 2016-12-15 2020-08-04 The Government Of The United States Of America, As Represented By The Secretary Of The Navy Silyl-containing alcohols and amines for thermosets that disassemble on-demand
US10367228B2 (en) 2017-04-07 2019-07-30 Seeo, Inc. Diester-based polymer electrolytes for high voltage lithium ion batteries
CN107603474B (zh) * 2017-08-01 2020-11-03 衢州氟硅技术研究院 一种用于透明光学器件防污涂层的组合物
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US11779716B2 (en) 2017-08-03 2023-10-10 Kindeva Drug Delivery L.P. Method for making medicinal delivery device having multi-layer coating
US10544260B2 (en) 2017-08-30 2020-01-28 Ppg Industries Ohio, Inc. Fluoropolymers, methods of preparing fluoropolymers, and coating compositions containing fluoropolymers
CN110698406B (zh) * 2018-07-09 2021-10-01 乳源东阳光氟有限公司 一种全氟聚醚咪唑啉化合物及其制备方法和用途
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CN110003422A (zh) * 2019-04-03 2019-07-12 广州五行材料科技有限公司 一种高溶解性防污树脂及其制备方法和应用
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US12023156B2 (en) 2021-10-13 2024-07-02 Satio, Inc. Dermal patch for collecting a physiological sample
US11964121B2 (en) 2021-10-13 2024-04-23 Satio, Inc. Mono dose dermal patch for pharmaceutical delivery
US12053284B2 (en) 2021-11-08 2024-08-06 Satio, Inc. Dermal patch for collecting a physiological sample
US12214346B2 (en) 2021-10-13 2025-02-04 Satio, Inc. Dermal patch with a diagnostic test strip
US11877848B2 (en) 2021-11-08 2024-01-23 Satio, Inc. Dermal patch for collecting a physiological sample
US12178979B2 (en) 2021-10-13 2024-12-31 Satio, Inc. Dermal patch for delivering a pharmaceutical
US12048543B2 (en) 2021-11-08 2024-07-30 Satio, Inc. Dermal patch for collecting a physiological sample with removable vial
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JPH09151235A (ja) * 1995-10-23 1997-06-10 Oce Nederland Bv 鎖長を延長した二官能基を有するパーフルオロポリエーテル油及びこれより調製したゴム
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