JP2007327063A5 - - Google Patents
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- Publication number
- JP2007327063A5 JP2007327063A5 JP2007174536A JP2007174536A JP2007327063A5 JP 2007327063 A5 JP2007327063 A5 JP 2007327063A5 JP 2007174536 A JP2007174536 A JP 2007174536A JP 2007174536 A JP2007174536 A JP 2007174536A JP 2007327063 A5 JP2007327063 A5 JP 2007327063A5
- Authority
- JP
- Japan
- Prior art keywords
- tetramethyl
- methyl
- composition according
- isopropylphenyl
- pentene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 claims 11
- 239000003999 initiator Substances 0.000 claims 5
- 150000003254 radicals Chemical class 0.000 claims 5
- -1 2,2,6,6-tetramethyl-1-piperidyloxy, 4-hydroxy-2,2,6,6-tetramethyl-1-piperidyloxy, 4-methoxy-2,2,6,6-tetramethyl-1 -Piperidyloxy, 4-oxo-2,2,6,6-tetramethyl-1-piperidyloxy Chemical group 0.000 claims 4
- 229920001577 copolymer Polymers 0.000 claims 4
- AVXURJPOCDRRFD-UHFFFAOYSA-N hydroxylamine Chemical class ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims 3
- 229920001169 thermoplastic Polymers 0.000 claims 3
- 239000005977 Ethylene Substances 0.000 claims 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 2
- UPJVEXRKOWFEIG-UHFFFAOYSA-N 1-[2-methyl-4-(3-propan-2-ylphenyl)pent-4-en-2-yl]-3-propan-2-ylbenzene Chemical compound CC(C)C1=CC=CC(C(=C)CC(C)(C)C=2C=C(C=CC=2)C(C)C)=C1 UPJVEXRKOWFEIG-UHFFFAOYSA-N 0.000 claims 1
- ICRPDMMPXGVIQA-UHFFFAOYSA-N 1-[2-methyl-4-(3-propan-2-ylphenyl)pent-4-en-2-yl]-4-propan-2-ylbenzene Chemical compound C1=CC(C(C)C)=CC=C1C(C)(C)CC(=C)C1=CC=CC(C(C)C)=C1 ICRPDMMPXGVIQA-UHFFFAOYSA-N 0.000 claims 1
- PWLJXFFLHZAFNN-UHFFFAOYSA-N 1-[2-methyl-4-(4-propan-2-ylphenyl)pent-4-en-2-yl]-3-propan-2-ylbenzene Chemical compound C1=CC(C(C)C)=CC=C1C(=C)CC(C)(C)C1=CC=CC(C(C)C)=C1 PWLJXFFLHZAFNN-UHFFFAOYSA-N 0.000 claims 1
- XLFOYVHYOLEKPZ-UHFFFAOYSA-N 1-[2-methyl-4-(4-propan-2-ylphenyl)pent-4-en-2-yl]-4-propan-2-ylbenzene Chemical compound C1=CC(C(C)C)=CC=C1C(=C)CC(C)(C)C1=CC=C(C(C)C)C=C1 XLFOYVHYOLEKPZ-UHFFFAOYSA-N 0.000 claims 1
- JAHVAVMRZBZGSU-UHFFFAOYSA-N 1-methyl-4-[2-methyl-4-(4-methylphenyl)pent-4-en-2-yl]benzene Chemical compound C1=CC(C)=CC=C1C(=C)CC(C)(C)C1=CC=C(C)C=C1 JAHVAVMRZBZGSU-UHFFFAOYSA-N 0.000 claims 1
- KOFZWWMCDUHEEM-UHFFFAOYSA-N 1-methylpyrrolidine Chemical group [CH2]N1CCCC1 KOFZWWMCDUHEEM-UHFFFAOYSA-N 0.000 claims 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical group C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims 1
- JTXMVXSTHSMVQF-UHFFFAOYSA-N 2-acetyloxyethyl acetate Chemical compound CC(=O)OCCOC(C)=O JTXMVXSTHSMVQF-UHFFFAOYSA-N 0.000 claims 1
- JCXAUCALQHVSQD-UHFFFAOYSA-N 2-propan-2-yl-1,4-bis(prop-1-en-2-yl)benzene Chemical group CC(C)C1=CC(C(C)=C)=CC=C1C(C)=C JCXAUCALQHVSQD-UHFFFAOYSA-N 0.000 claims 1
- BIISIZOQPWZPPS-UHFFFAOYSA-N 2-tert-butylperoxypropan-2-ylbenzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=CC=C1 BIISIZOQPWZPPS-UHFFFAOYSA-N 0.000 claims 1
- PWIOPFROWLLYOF-UHFFFAOYSA-M CC1(C)CC(O)CC(C)(C)N1OOP([O-])=O Chemical compound CC1(C)CC(O)CC(C)(C)N1OOP([O-])=O PWIOPFROWLLYOF-UHFFFAOYSA-M 0.000 claims 1
- QYGQRVXBOCZSTJ-UHFFFAOYSA-N CC=1C=C(C=CC=1)C=CCC(C)C Chemical compound CC=1C=C(C=CC=1)C=CCC(C)C QYGQRVXBOCZSTJ-UHFFFAOYSA-N 0.000 claims 1
- 239000004709 Chlorinated polyethylene Substances 0.000 claims 1
- STVZJERGLQHEKB-UHFFFAOYSA-N Ethylene glycol dimethacrylate Chemical compound CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims 1
- 229920002681 Hypalon Polymers 0.000 claims 1
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 claims 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 1
- 125000004432 carbon atoms Chemical group C* 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 238000004132 cross linking Methods 0.000 claims 1
- 229920001973 fluoroelastomer Polymers 0.000 claims 1
- 229920001903 high density polyethylene Polymers 0.000 claims 1
- 239000004700 high-density polyethylene Substances 0.000 claims 1
- 229920000092 linear low density polyethylene Polymers 0.000 claims 1
- 239000004707 linear low-density polyethylene Substances 0.000 claims 1
- 229920001684 low density polyethylene Polymers 0.000 claims 1
- 239000004702 low-density polyethylene Substances 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 150000001451 organic peroxides Chemical class 0.000 claims 1
- 150000002978 peroxides Chemical class 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 230000002028 premature Effects 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 229940116351 sebacate Drugs 0.000 claims 1
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 claims 1
- 229920002379 silicone rubber Polymers 0.000 claims 1
- 239000004945 silicone rubber Substances 0.000 claims 1
- 229920001897 terpolymer Polymers 0.000 claims 1
Claims (10)
- ２，２，６，６−テトラメチル−１−ピペリジロキシ、４−ヒドロキシ−２，２，６，６−テトラメチル−１−ピペリジロキシ、４−メトキシ−２，２，６，６−テトラメチル−１−ピペリジロキシ、４−オキソ−２，２，６，６−テトラメチル−１−ピペリジロキシ、２，２，５，５−テトラメチル−１−ピロリジニリジロキシ、ビス（１−オキシ−２，２，６，６−テトラメチル−４−ピペリジル）セバケート、２，２，６，６−テトラメチル−４−ヒドロキシ−１−ピペリジロキシモノホスホネートおよび３−カルボキシ−２，２，５，５−テトラメチルピロリジニリジロキシの中から選択されるニトロキシドと、下記一般式（II）で示される化合物の中から選択される少なくとも１種の促進剤とを含むことを特徴とする早期架橋を遅らせる組成物：
（ここで、Ｒ y およびＲ z は１〜９個の炭素原子を有するアルキル基を表し、互いに同一でも異なっていてもよい）
- 存在する促進剤の量に対するニトロキシドの重量比が１：０．２〜１：５である請求項１の組成物。
- 有機過酸化物、アゾ化合物およびこれらの混合物から成る群の中から選択される遊離ラジカル開始剤をさらに含む請求項１または２に記載の組成物。
- 存在するニトロキシド量に対する遊離ラジカル開始剤の重量比が１：０．０２〜１：１である請求項３に記載の組成物。
- 使用した促進剤に対する遊離ラジカル開始剤の重量比が１：０．０２〜１：１である請求項３または４に記載の組成物。
- 過酸化物またはアゾ化合物によって架橋可能な熱可塑性ポリマーおよび／または弾性ポリマーをさらに含む請求項３〜５のいずれか一項に記載の組成物。
- １００重量部の熱可塑性ポリマーに対して遊離ラジカル開始剤が０．２〜５重量部の比率で存在する請求項６に記載の組成物。
- 促進剤が２−イソプロピル−ｐ−ジイソプロペニルベンゼン、２，４−ビス（３−イソプロピルフェニル）−４−メチル−１−ペンテン、２，４−ビス（４−イソプロピルフェニル）−４−メチル−１−ペンテン、２−（３−イソプロピルフェニル）−４−（４−イソプロピルフェニル）−４−メチル−１−ペンテン、２−（４−イソプロピルフェニル）−４−（３−イソプロピルフェニル）−４−メチル−１−ペンテン、２，４−ビス（３−メチルフェニル）−４−メチル−１−ペンテンまたは２，４−ビス（４−メチルフェニル）−４−メチル−１−ペンテンである請求項１〜７のいずれか一項に記載の組成物。
- 遊離ラジカル開始剤がジクミルペルオキシドまたはα，α−ジ[（ｔ−ブチルペルオキシ）イソプロピル]ベンゼンである請求項３〜８のいずれか一項に記載の組成物。
- 上記熱可塑性ポリマーが直鎖低密度ポリエチレン、低密度ポリエチレン、高密度ポリエチレン、塩素化ポリエチレン、エチレン／プロピレン／ブタジエンターポリマー、エチレン／酢酸ビニルコポリマー、エチレン／プロピレンコポリマー、シリコンゴム、クロロスルホン化ポリエチレン、フルオロエラストマー、エチレン／メチル（メタ）アクリレートコポリマーおよびエチレン／グリシジルメタクリレートコポリマーからなる群の中から選択される請求項６〜９のいずれか一項に記載の組成物。
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0012580A FR2819517B1 (fr) | 2000-10-03 | 2000-10-03 | Composition comprenant un nitroxyde, un promoteur et eventuellement un initiateur de radicaux libres |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002532523A Division JP4086144B2 (ja) | 2000-10-03 | 2001-09-28 | ニトロキシドと促進剤を含み、必要に応じて遊離ラジカル開始剤をさらに含む組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2007327063A JP2007327063A (ja) | 2007-12-20 |
| JP2007327063A5 true JP2007327063A5 (ja) | 2008-11-27 |
Family
ID=8854922
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002532523A Expired - Lifetime JP4086144B2 (ja) | 2000-10-03 | 2001-09-28 | ニトロキシドと促進剤を含み、必要に応じて遊離ラジカル開始剤をさらに含む組成物 |
| JP2007174536A Pending JP2007327063A (ja) | 2000-10-03 | 2007-07-02 | ニトロキシドと促進剤を含み、必要に応じて遊離ラジカル開始剤をさらに含む組成物 |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002532523A Expired - Lifetime JP4086144B2 (ja) | 2000-10-03 | 2001-09-28 | ニトロキシドと促進剤を含み、必要に応じて遊離ラジカル開始剤をさらに含む組成物 |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP1322696B1 (ja) |
| JP (2) | JP4086144B2 (ja) |
| KR (1) | KR100735589B1 (ja) |
| CN (1) | CN100564430C (ja) |
| AT (1) | ATE274545T1 (ja) |
| AU (1) | AU2001293932A1 (ja) |
| CA (1) | CA2424912C (ja) |
| DE (1) | DE60105183T2 (ja) |
| ES (1) | ES2227278T3 (ja) |
| FR (1) | FR2819517B1 (ja) |
| PT (1) | PT1322696E (ja) |
| WO (1) | WO2002028946A1 (ja) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2814749B1 (fr) * | 2000-10-03 | 2003-06-13 | Atofina | Composition retardant le grillage |
| EP1699881A2 (en) * | 2003-12-24 | 2006-09-13 | The Dow Global Technologies Inc. | Free-radical crosslinkable polymers: improved process for crosslinking and compositions |
| FR2875502B1 (fr) * | 2004-09-22 | 2007-01-05 | Arkema Sa | Composition retardant le grillage |
| US7465769B2 (en) | 2006-10-09 | 2008-12-16 | Dow Global Technologies Inc. | Nitroxide compounds for minimizing scorch in crosslinkable compositions |
| US8283420B2 (en) * | 2007-02-05 | 2012-10-09 | Dow Global Technologies Llc | Crosslinkable polyethylene composition, method of making the same, and articles made therefrom |
| JP5133983B2 (ja) * | 2007-04-25 | 2013-01-30 | 日本ケミコン株式会社 | 電解コンデンサの封口体とその封口体を用いた電解コンデンサ |
| EP2014707B1 (en) * | 2007-07-12 | 2014-04-23 | Borealis Technology Oy | Modified polymer compositions, modification process and free radical generating agents for i.a. wire and cable applications |
| US9234093B2 (en) | 2008-03-31 | 2016-01-12 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates |
| US8644470B2 (en) | 2008-04-15 | 2014-02-04 | Cequint, Inc. | Methods and systems for improved caller name identification on a telephone network |
| US8983540B2 (en) | 2008-09-22 | 2015-03-17 | Cequint, Inc. | Delivery of caller identification data to a mobile device using application directed short messaging service |
| US8877867B2 (en) | 2008-11-06 | 2014-11-04 | Exxonmobil Chemical Patents Inc. | Process for forming thermoplastic vulcanizates and extruded articles therefrom |
| US8160556B2 (en) | 2009-04-13 | 2012-04-17 | Cequint, Inc. | System and method for local handset check of the NXX local exchange to determine carrier |
| US8620281B2 (en) | 2009-04-13 | 2013-12-31 | Cequint, Inc. | System and method for determination and display of “in-network caller” notification on a mobile device |
| US8160555B2 (en) | 2009-04-13 | 2012-04-17 | Cequint, Inc. | System and method for determination of network and conditional execution of applications and promotions |
| US8160554B2 (en) | 2009-04-13 | 2012-04-17 | Cequint, Inc. | System and method for enhanced display of in-network caller information on a mobile device |
| CN101820001B (zh) * | 2010-04-30 | 2011-08-31 | 南京红宝丽新材料有限公司 | 太阳能电池封装胶膜 |
| JP5533208B2 (ja) * | 2010-05-06 | 2014-06-25 | 横浜ゴム株式会社 | ゴム組成物およびホース |
| ES2643047T3 (es) | 2012-04-20 | 2017-11-21 | Hilti Aktiengesellschaft | Radical indolin-nitróxido como estabilizante e inhibidor para resinas de reacción, resinas de reacción que lo contienen y su uso |
| WO2013157643A1 (ja) * | 2012-04-20 | 2013-10-24 | 旭化成イーマテリアルズ株式会社 | ラジカル架橋性基を有するポリシロキサン組成物 |
| FR2995313B1 (fr) * | 2012-09-12 | 2015-08-21 | Arkema France | Melange primaire d'initiateur et de promoteur de reticulation |
| CN103206541B (zh) * | 2013-04-23 | 2015-07-15 | 广州机械科学研究院有限公司 | 一种夹布油封及其制备方法与应用 |
| BR112016020830B1 (pt) * | 2014-03-14 | 2021-08-17 | Milliken & Company | Composição de poliolefina heterofásica modificada e método de preparação |
| JP6355375B2 (ja) * | 2014-03-18 | 2018-07-11 | 日本バルカー工業株式会社 | パーフルオロエラストマー組成物及びシール材 |
| EP2995631A1 (en) | 2014-09-12 | 2016-03-16 | Borealis AG | Process for producing graft copolymers on polyolefin backbone |
| KR102519231B1 (ko) * | 2014-12-09 | 2023-04-07 | 알케마 인코포레이티드 | 대기 산소의 존재 하에서 중합체를 가교시키기 위한 조성물 및 방법 |
| EP3230362A4 (en) * | 2014-12-09 | 2018-07-25 | Arkema, Inc. | Liquid and meltable solid grades of scorch protected peroxides |
| CA3019189C (en) * | 2016-03-30 | 2024-01-16 | Dow Global Technologies Llc | Crosslinkable polymeric compositions with methyl-radical scavengers and articles made therefrom |
| CN110520471B (zh) | 2017-02-28 | 2022-05-24 | 埃克森美孚化学专利公司 | 用油增量的双峰茂金属合成的epdm制备的热塑性硫化橡胶 |
| WO2019003885A1 (ja) | 2017-06-28 | 2019-01-03 | Nok株式会社 | ゴム組成物および燃料電池セパレータ用シール材 |
| BR112020008188A2 (pt) | 2017-11-08 | 2020-10-13 | Dow Global Technologies Llc | composição de interpolímeros de etileno/alfa-olefina/dieno curável ao ar |
| EP3827033A4 (en) | 2018-07-23 | 2022-06-01 | ExxonMobil Chemical Patents Inc. | PREPARATION OF BIMODAL RUBBER, THERMOPLASTIC VULCANIZES AND ARTICLES MADE THEREOF |
| CA3177546A1 (en) | 2020-05-27 | 2021-12-02 | Axial Therapeutics, Inc. | Tlr2 modulator compounds, pharmaceutical compositions and uses thereof |
| US11674024B2 (en) | 2020-05-29 | 2023-06-13 | Exxonmobil Chemical Patents Inc. | Sequential, double elastomer vulcanization system, method and composition |
| WO2022005634A1 (en) | 2020-07-02 | 2022-01-06 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizate compositions containing metallocene multimodal copolymer rubber and processes for making same |
| FR3139825A1 (fr) | 2022-09-21 | 2024-03-22 | Arkema France | Composition comprenant au moins un peroxyde de dialkyle ou de peroxycétal et au moins un peroxyde organique insaturé |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0499581B1 (de) * | 1991-02-13 | 1997-07-09 | Ciba SC Holding AG | Stabilisierte Polymermischung |
| EP0870798B1 (en) * | 1996-10-25 | 2004-02-11 | The Yokohama Rubber Co., Ltd. | Rubber composition |
| JPH1149865A (ja) * | 1997-07-31 | 1999-02-23 | Nof Corp | エチレン系ポリマーの架橋用組成物、架橋方法及びポリマー組成物 |
| FR2768739B1 (fr) * | 1997-09-19 | 2004-08-06 | Atochem Elf Sa | Polymere vinylaromatique choc obtenu a partir d'un caoutchouc porteur d'un groupement generateur d'un radical libre stable |
| SE9802386D0 (sv) * | 1998-07-03 | 1998-07-03 | Borealis As | Composition for elektric cables |
| FR2791060A1 (fr) * | 1999-03-18 | 2000-09-22 | Atochem Elf Sa | Procede de preparation d'un caoutchouc porteur de radical libre stable et utilisation dudit caoutchouc porteur pour la preparation d'un polymere vinylaromatique choc |
-
2000
- 2000-10-03 FR FR0012580A patent/FR2819517B1/fr not_active Expired - Fee Related
-
2001
- 2001-09-28 CA CA002424912A patent/CA2424912C/fr not_active Expired - Lifetime
- 2001-09-28 CN CNB018200095A patent/CN100564430C/zh not_active Expired - Lifetime
- 2001-09-28 PT PT01974408T patent/PT1322696E/pt unknown
- 2001-09-28 AU AU2001293932A patent/AU2001293932A1/en not_active Abandoned
- 2001-09-28 DE DE60105183T patent/DE60105183T2/de not_active Expired - Lifetime
- 2001-09-28 WO PCT/FR2001/003011 patent/WO2002028946A1/fr active IP Right Grant
- 2001-09-28 ES ES01974408T patent/ES2227278T3/es not_active Expired - Lifetime
- 2001-09-28 JP JP2002532523A patent/JP4086144B2/ja not_active Expired - Lifetime
- 2001-09-28 EP EP01974408A patent/EP1322696B1/fr not_active Expired - Lifetime
- 2001-09-28 AT AT01974408T patent/ATE274545T1/de active
- 2001-09-28 KR KR1020037004684A patent/KR100735589B1/ko active IP Right Grant
-
2007
- 2007-07-02 JP JP2007174536A patent/JP2007327063A/ja active Pending
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